ES2095572T3 - Proceso para la produccion de acido acetico. - Google Patents
Proceso para la produccion de acido acetico.Info
- Publication number
- ES2095572T3 ES2095572T3 ES93303977T ES93303977T ES2095572T3 ES 2095572 T3 ES2095572 T3 ES 2095572T3 ES 93303977 T ES93303977 T ES 93303977T ES 93303977 T ES93303977 T ES 93303977T ES 2095572 T3 ES2095572 T3 ES 2095572T3
- Authority
- ES
- Spain
- Prior art keywords
- acetic acid
- production
- weight
- product
- liquid reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 12
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 abstract 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Luminescent Compositions (AREA)
- Developing Agents For Electrophotography (AREA)
- Compression Or Coding Systems Of Tv Signals (AREA)
- Iron Core Of Rotating Electric Machines (AREA)
- Glass Compositions (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
EN UN PROCEDIMIENTO PARA LA PRODUCCION DE ACIDO ACETICO MEDIANTE CARBONILACION DE METANOL EN PRESENCIA DE UN CATALIZADOR DE CARBONILACION DE RODIO, YODURO DE METILO Y UN ESTABILIADOR DE SAL DE YODURO, EL PERFECCIONAMIENTO RADICA EN EL MANTENIMIENTO DE UNA CONCENTRACION LIMITADA DE AGUA DE HASTA UN 10% POR PESO Y UNA CONCENTRACION DE ACETATO DE METILO DE, AL MENOS, 2% POR PESO, EN LA COMPOSICION DE REACCION LIQUIDA Y RECUPERACION DEL PRODUCTO DE ACIDO ACETICO MEDIANTE EL PASE DE LA COMPOSICION DE REACCION LIQUIDA A TRAVES DE UNA ZONA MUY RAPIDA, PARA PRODUCIR UNA FRACCION DE VAPOR, QUE SE PASA A UNA COLUMNA DE DESTILACION UNICA, DESDE LA CUAL SE EXTRAE UN PRODUCTO DE ACIDO ACETICO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB929211671A GB9211671D0 (en) | 1992-06-02 | 1992-06-02 | Process |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2095572T3 true ES2095572T3 (es) | 1997-02-16 |
Family
ID=10716405
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES93303977T Expired - Lifetime ES2095572T3 (es) | 1992-06-02 | 1993-05-21 | Proceso para la produccion de acido acetico. |
Country Status (21)
Country | Link |
---|---|
US (1) | US5416237A (es) |
EP (1) | EP0573189B1 (es) |
JP (1) | JP3616400B2 (es) |
KR (1) | KR100280254B1 (es) |
CN (1) | CN1041820C (es) |
AT (1) | ATE146770T1 (es) |
AU (1) | AU646367B2 (es) |
CA (1) | CA2097478C (es) |
DE (1) | DE69306861T2 (es) |
ES (1) | ES2095572T3 (es) |
FI (1) | FI932515A (es) |
GB (1) | GB9211671D0 (es) |
IN (1) | IN186334B (es) |
MX (1) | MX9303294A (es) |
MY (1) | MY109016A (es) |
NO (1) | NO179040C (es) |
NZ (1) | NZ247742A (es) |
RU (1) | RU2102379C1 (es) |
SG (1) | SG50365A1 (es) |
TW (1) | TW345573B (es) |
UA (1) | UA26854C2 (es) |
Families Citing this family (114)
Publication number | Priority date | Publication date | Assignee | Title |
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GB9120902D0 (en) * | 1991-10-02 | 1991-11-13 | Bp Chem Int Ltd | Purification process |
GB9306409D0 (en) * | 1993-03-26 | 1993-05-19 | Bp Chem Int Ltd | Process |
JP3332594B2 (ja) | 1994-08-12 | 2002-10-07 | ダイセル化学工業株式会社 | 酢酸の精製方法 |
GB9503385D0 (en) * | 1995-02-21 | 1995-04-12 | Bp Chem Int Ltd | Process |
KR100403367B1 (ko) * | 1995-04-27 | 2004-03-26 | 다이셀 가가꾸 고교 가부시끼가이샤 | 아세트산제조법 |
US5760279A (en) * | 1995-06-19 | 1998-06-02 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols |
GB9512427D0 (en) * | 1995-06-19 | 1995-08-23 | Bp Chem Int Ltd | Process |
US6031129A (en) * | 1995-10-03 | 2000-02-29 | Quantum Chemical Corporation | Use of pentavalent group VA oxides in acetic acid processing |
US5817869A (en) * | 1995-10-03 | 1998-10-06 | Quantum Chemical Corporation | Use of pentavalent Group VA oxides in acetic acid processing |
US5831120A (en) * | 1996-11-19 | 1998-11-03 | Watson; Derrick John | Process for the production of acetic acid |
GB9626324D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
US6066762A (en) * | 1996-12-30 | 2000-05-23 | Chiyoda Corporation | Process for the production of carbonyl compound |
GB9711492D0 (en) * | 1997-06-03 | 1997-07-30 | Bp Chem Int Ltd | Compounds |
US6043392A (en) * | 1997-06-30 | 2000-03-28 | Texas A&M University System | Method for conversion of biomass to chemicals and fuels |
GB9715489D0 (en) * | 1997-07-23 | 1997-10-01 | Bp Chem Int Ltd | Composition |
GB9816385D0 (en) * | 1998-07-29 | 1998-09-23 | Bp Chem Int Ltd | Process |
GB9819606D0 (en) | 1998-09-08 | 1998-11-04 | Bp Chem Int Ltd | Carbonylation process |
US6552221B1 (en) | 1998-12-18 | 2003-04-22 | Millenium Petrochemicals, Inc. | Process control for acetic acid manufacture |
US6225498B1 (en) * | 2000-03-24 | 2001-05-01 | Celanese International Corporation | Method of removing organic iodides from organic media |
JP4891482B2 (ja) * | 2001-02-06 | 2012-03-07 | 千代田化工建設株式会社 | カルボン酸の製造方法 |
US6657078B2 (en) | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
CN100430363C (zh) * | 2003-10-30 | 2008-11-05 | 上海吴泾化工有限公司 | 一种羰基化生产醋酸的改进方法及其装置 |
US7208624B2 (en) * | 2004-03-02 | 2007-04-24 | Celanese International Corporation | Process for producing acetic acid |
US7271293B2 (en) * | 2004-03-02 | 2007-09-18 | Celanese International Corporation | Control method for process of removing permanganate reducing compounds from methanol carbonylation process |
US7223886B2 (en) * | 2004-03-02 | 2007-05-29 | Celanese International Corporation | Removal of permanganate reducing compounds from methanol carbonylation process stream |
US7223883B2 (en) * | 2004-03-02 | 2007-05-29 | Celanese International Corporation | Removal of permanganate reducing compounds from methanol carbonylation process stream |
JP4489487B2 (ja) * | 2004-04-02 | 2010-06-23 | ダイセル化学工業株式会社 | ヨウ化水素の分離方法 |
JP4732743B2 (ja) * | 2004-12-06 | 2011-07-27 | ダイセル化学工業株式会社 | 蒸留方法 |
JP4526381B2 (ja) | 2004-12-27 | 2010-08-18 | ダイセル化学工業株式会社 | 酢酸の製造方法 |
US7855306B2 (en) * | 2005-04-28 | 2010-12-21 | Celanese International Corporation | Process for the production of acetic acid |
US20100189705A1 (en) * | 2005-06-03 | 2010-07-29 | Squires Stephen B | Biological decontamination system |
KR101300960B1 (ko) | 2005-07-14 | 2013-08-27 | 가부시끼가이샤 다이셀 | 카르복실산의 제조 방법 |
US7737298B2 (en) * | 2006-06-09 | 2010-06-15 | Eastman Chemical Company | Production of acetic acid and mixtures of acetic acid and acetic anhydride |
US7582792B2 (en) * | 2006-06-15 | 2009-09-01 | Eastman Chemical Company | Carbonylation process |
CN100427449C (zh) * | 2006-06-19 | 2008-10-22 | 上海吴泾化工有限公司 | 一种低压甲醇羰基合成醋酸的提纯方法 |
US7253304B1 (en) | 2006-06-20 | 2007-08-07 | Eastman Chemical Company | Carbonylation process |
US7629491B2 (en) * | 2006-06-26 | 2009-12-08 | Eastman Chemical Company | Hydrocarboxylation process |
US7485749B2 (en) * | 2006-08-22 | 2009-02-03 | Lyondell Chemical Technology, L.P. | Preparation of acetic acid |
US7902398B2 (en) | 2007-04-25 | 2011-03-08 | Celanese International Corporation | Method and apparatus for carbonylation with reduced catalyst loss |
US20090247783A1 (en) * | 2008-04-01 | 2009-10-01 | Eastman Chemical Company | Carbonylation process |
MX2010011850A (es) * | 2008-04-29 | 2010-11-30 | Celanese Int Corp | Sistema de carbonilacion de metanol que tiene un absorbedor con multiples opciones de disolvente. |
US7820855B2 (en) | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
KR20110056280A (ko) * | 2008-08-13 | 2011-05-26 | 에이엠티 인터내셔널 인코포레이티드 | 대응하는 에스테르를 함유하는 공급 흐름으로부터 아세트산의 회수를 위한 공정 및 장치 |
US8076508B2 (en) * | 2008-12-08 | 2011-12-13 | Lyondell Chemical Technology | Preparation of acetic acid |
US7588690B1 (en) | 2009-02-10 | 2009-09-15 | The Purolite Company | Method of iodide removal |
US8168822B2 (en) * | 2009-07-07 | 2012-05-01 | Celanese International Corporation | Acetic acid production by way of carbonylation with enhanced reaction and flashing |
US8455685B2 (en) * | 2009-07-07 | 2013-06-04 | Celanese International Corporation | Acetic anhydride production by way of carbonylation with enhanced reaction and flashing |
US8076512B2 (en) * | 2009-08-27 | 2011-12-13 | Equistar Chemicals, L.P. | Preparation of acetic acid |
US20110086929A1 (en) * | 2009-10-13 | 2011-04-14 | Brotech Corporation, doing business as The Purolite Company | Method of iodide removal |
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US8835681B2 (en) | 2010-06-14 | 2014-09-16 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst and a lanthanide metal co-catalyst |
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US9024061B2 (en) | 2010-06-14 | 2015-05-05 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst and a metallic co-catalyst selected from transition metals, zinc, beryllium, indium, tin, strontium and barium |
US9272970B2 (en) | 2010-07-09 | 2016-03-01 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
US8710279B2 (en) | 2010-07-09 | 2014-04-29 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
US8846988B2 (en) | 2010-07-09 | 2014-09-30 | Celanese International Corporation | Liquid esterification for the production of alcohols |
US8664454B2 (en) | 2010-07-09 | 2014-03-04 | Celanese International Corporation | Process for production of ethanol using a mixed feed using copper containing catalyst |
US8704008B2 (en) | 2010-07-09 | 2014-04-22 | Celanese International Corporation | Process for producing ethanol using a stacked bed reactor |
CN103038207B (zh) * | 2010-07-26 | 2015-03-04 | 株式会社大赛璐 | 生产乙酸的方法 |
MY160523A (en) * | 2010-10-06 | 2017-03-15 | Daicel Corp | Process for producing acetic acid |
US9012683B2 (en) | 2010-11-12 | 2015-04-21 | Eastman Chemical Company | Coproduction of acetic acid and acetic anhydride |
JP6166043B2 (ja) * | 2010-12-15 | 2017-07-19 | 株式会社ダイセル | 酢酸の製造方法 |
WO2012081416A1 (ja) * | 2010-12-15 | 2012-06-21 | 株式会社ダイセル | 酢酸の製造方法 |
US8637699B2 (en) | 2011-04-15 | 2014-01-28 | Lyondell Chemical Technology, L.P. | Process for the manufacture of acetic acid |
WO2012149137A1 (en) | 2011-04-26 | 2012-11-01 | Celanese International Corporation | Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed |
US8592635B2 (en) | 2011-04-26 | 2013-11-26 | Celanese International Corporation | Integrated ethanol production by extracting halides from acetic acid |
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US8742168B2 (en) | 2011-05-31 | 2014-06-03 | Lyondell Chemical Technology, L.P. | Process for the production of acetic acid |
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US9260369B1 (en) | 2014-11-14 | 2016-02-16 | Celanese International Corporation | Processes for producing acetic acid product having low butyl acetate content |
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US5001259A (en) * | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
US5026908A (en) * | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
CA1228867A (en) * | 1984-05-03 | 1987-11-03 | G. Paull Torrence | Methanol carbonylation process |
US5144068A (en) * | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
US4615806B1 (en) * | 1985-03-07 | 1994-05-03 | Hoechst Co American | Removal of iodide compounds from non-aqueous organic media |
US4628041A (en) * | 1986-02-10 | 1986-12-09 | Celanese Corporation | Rhodium and iodine recovery method |
CA1299195C (en) * | 1986-06-16 | 1992-04-21 | G. Paull Torrence | Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol |
US4894477A (en) * | 1986-10-14 | 1990-01-16 | Hoechst Celanese Corporation | Process for regenerating a carbonylation catalyst solution to remove corrosion metals and carbonylation of methanol to acetic acid |
JPH0714488B2 (ja) * | 1987-06-24 | 1995-02-22 | ユニオン・カーバイド・コーポレーション | カルボン酸からのハライドの除去 |
GB8822661D0 (en) * | 1988-09-27 | 1988-11-02 | Bp Chem Int Ltd | Removal of iodine/iodide impurities |
GB8904125D0 (en) * | 1989-02-23 | 1989-04-05 | British Petroleum Co Plc | Process for preparing carboxylic acids |
CA2028821A1 (en) * | 1989-04-06 | 1990-10-07 | Robert G. Beevor | Process for preparing carboxylic acids |
US5237097A (en) * | 1990-02-09 | 1993-08-17 | Quantum Chemical Corporation | Catalytic carbonylation process |
GB9022787D0 (en) * | 1990-10-19 | 1990-12-05 | British Petroleum Co Plc | Process |
GB9023634D0 (en) * | 1990-10-31 | 1990-12-12 | British Petroleum Co Plc | Process for purifying acetic acid and/or acetic anhydride |
GB9106298D0 (en) * | 1991-03-25 | 1991-05-08 | Bp Chem Int Ltd | Process |
GB9122168D0 (en) * | 1991-10-18 | 1991-11-27 | Bp Chem Int Ltd | Process |
-
1992
- 1992-06-02 GB GB929211671A patent/GB9211671D0/en active Pending
-
1993
- 1993-05-21 DE DE69306861T patent/DE69306861T2/de not_active Revoked
- 1993-05-21 AT AT93303977T patent/ATE146770T1/de not_active IP Right Cessation
- 1993-05-21 EP EP93303977A patent/EP0573189B1/en not_active Revoked
- 1993-05-21 SG SG1995001773A patent/SG50365A1/en unknown
- 1993-05-21 ES ES93303977T patent/ES2095572T3/es not_active Expired - Lifetime
- 1993-05-26 IN IN545DE1993 patent/IN186334B/en unknown
- 1993-05-27 AU AU39855/93A patent/AU646367B2/en not_active Ceased
- 1993-05-27 TW TW081107532A01A patent/TW345573B/zh active
- 1993-05-31 RU RU93048334A patent/RU2102379C1/ru not_active IP Right Cessation
- 1993-05-31 NZ NZ247742A patent/NZ247742A/en unknown
- 1993-06-01 NO NO931984A patent/NO179040C/no unknown
- 1993-06-01 CA CA002097478A patent/CA2097478C/en not_active Expired - Fee Related
- 1993-06-02 MX MX9303294A patent/MX9303294A/es not_active IP Right Cessation
- 1993-06-02 CN CN93108283A patent/CN1041820C/zh not_active Expired - Lifetime
- 1993-06-02 KR KR1019930009898A patent/KR100280254B1/ko not_active IP Right Cessation
- 1993-06-02 MY MYPI93001066A patent/MY109016A/en unknown
- 1993-06-02 FI FI932515A patent/FI932515A/fi unknown
- 1993-06-02 JP JP13194093A patent/JP3616400B2/ja not_active Expired - Fee Related
- 1993-06-03 UA UA93004524A patent/UA26854C2/uk unknown
-
1994
- 1994-07-18 US US08/276,873 patent/US5416237A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
GB9211671D0 (en) | 1992-07-15 |
AU646367B2 (en) | 1994-02-17 |
JPH0640999A (ja) | 1994-02-15 |
CN1085540A (zh) | 1994-04-20 |
US5416237A (en) | 1995-05-16 |
DE69306861T2 (de) | 1997-05-07 |
NZ247742A (en) | 1994-10-26 |
RU2102379C1 (ru) | 1998-01-20 |
DE69306861D1 (de) | 1997-02-06 |
CA2097478C (en) | 2004-05-04 |
TW345573B (en) | 1998-11-21 |
MX9303294A (es) | 1994-07-29 |
NO931984D0 (no) | 1993-06-01 |
MY109016A (en) | 1996-11-30 |
KR100280254B1 (ko) | 2001-02-01 |
NO931984L (no) | 1993-12-03 |
AU3985593A (en) | 1993-12-16 |
NO179040B (no) | 1996-04-15 |
FI932515A (fi) | 1993-12-03 |
CA2097478A1 (en) | 1993-12-03 |
ATE146770T1 (de) | 1997-01-15 |
CN1041820C (zh) | 1999-01-27 |
SG50365A1 (en) | 1998-07-20 |
KR940000414A (ko) | 1994-01-03 |
FI932515A0 (fi) | 1993-06-02 |
JP3616400B2 (ja) | 2005-02-02 |
IN186334B (es) | 2001-08-11 |
UA26854C2 (uk) | 1999-12-29 |
NO179040C (no) | 1996-07-24 |
EP0573189B1 (en) | 1996-12-27 |
EP0573189A1 (en) | 1993-12-08 |
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