ES2083728T3 - Procedimiento para la preparacion de hidroximetil-5 furfural mediante catalisis heterogenea. - Google Patents

Procedimiento para la preparacion de hidroximetil-5 furfural mediante catalisis heterogenea.

Info

Publication number
ES2083728T3
ES2083728T3 ES92901021T ES92901021T ES2083728T3 ES 2083728 T3 ES2083728 T3 ES 2083728T3 ES 92901021 T ES92901021 T ES 92901021T ES 92901021 T ES92901021 T ES 92901021T ES 2083728 T3 ES2083728 T3 ES 2083728T3
Authority
ES
Spain
Prior art keywords
furfural
preparation
hydroximetil
procedure
heterogenous catalysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92901021T
Other languages
English (en)
Inventor
Gerard Avignon
Robert Durand
Pierre Faugeras
Patrick Geneste
Claude Moreau
Patrick Rivalier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FURCHIM
Agrichimie
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
FURCHIM
Commissariat a lEnergie Atomique CEA
Agrichimie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FURCHIM, Commissariat a lEnergie Atomique CEA, Agrichimie filed Critical FURCHIM
Application granted granted Critical
Publication of ES2083728T3 publication Critical patent/ES2083728T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40Radicals substituted by oxygen atoms
    • C07D307/46Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48Furfural
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40Radicals substituted by oxygen atoms
    • C07D307/46Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCESO DE PREPARACION DE HIDROXIMETIL-5 FURFURAL POR CATALISIS HETEROGENEA. ESTE PROCESO CONSISTE EN PONER EN CONTACTO UN MEDIO LIQUIDO QUE CONTIENE AL MENOS UN HESOSA, POR EJEMPLO FRUCTOSA CON UN CATALIZADOR SOLIDO CONSTITUIDO POR UN TECTOSILICATO O UNA ARCILLA NO FUNCIONALIZADA POR GRUPOS ACIDOS, POR EJEMPLO UNA ZEOLITA EN FORMA PROTONICA TAL COMO UNA MORDENITA H. SE PUEDE ASI EXTRAER EL HMF FORMADO MEDIANTE UN SOLVENTE ORGANICO TAL COMO LA METILISOBUTILCETONA EN UNA INSTALACION DE EXTRACCION A CONTRACORRIENTE.
ES92901021T 1990-12-07 1991-12-05 Procedimiento para la preparacion de hidroximetil-5 furfural mediante catalisis heterogenea. Expired - Lifetime ES2083728T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9015350A FR2670209B1 (fr) 1990-12-07 1990-12-07 Procede de preparation d'hydroxymethyl-5 furfural par catalyse heterogene.

Publications (1)

Publication Number Publication Date
ES2083728T3 true ES2083728T3 (es) 1996-04-16

Family

ID=9403006

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92901021T Expired - Lifetime ES2083728T3 (es) 1990-12-07 1991-12-05 Procedimiento para la preparacion de hidroximetil-5 furfural mediante catalisis heterogenea.

Country Status (9)

Country Link
EP (1) EP0561928B1 (es)
JP (1) JPH06504272A (es)
CA (1) CA2097812A1 (es)
DE (1) DE69117528T2 (es)
DK (1) DK0561928T3 (es)
ES (1) ES2083728T3 (es)
FR (1) FR2670209B1 (es)
WO (1) WO1992010486A1 (es)
ZA (1) ZA919648B (es)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2727968A1 (fr) * 1994-12-07 1996-06-14 Agrichimie Sa Procede de preparation en continu d'une solution de cetose par isomerisation d'aldose, et installation de mise en oeuvre
FR2727967A1 (fr) * 1994-12-07 1996-06-14 Agrichimie Sa Procede de fabrication d'hydroxymethylfurfural a partir d'aldohexose
FR2727876A1 (fr) * 1994-12-07 1996-06-14 Agrichimie Sa Procede pour effectuer une reaction en continu avec au moins une phase liquide et au moins un catalyseur solide dans une colonne pulsee
FR2741345B1 (fr) * 1995-11-20 1998-08-07 Agrichimie Sa Procede et installation de condensation selective d'un derive aromatique avec un derive carbonyle dans un reacteur continu multicontact vertical
FR2741344B1 (fr) * 1995-11-20 1998-01-23 Agrichimie Sa Procede et installation de fabrication selective d'hydroxymethylfurfural par hydroxymethylation du furfural
FR2858618B1 (fr) * 2003-08-07 2006-02-24 Sucreries Et Raffineries D Ers Procede et reacteur de fabrication d'hydroxymethylfurfural
US7393963B2 (en) * 2004-12-10 2008-07-01 Archer-Daniels-Midland Company Conversion of 2,5-(hydroxymethyl)furaldehyde to industrial derivatives, purification of the derivatives, and industrial uses therefor
US7317116B2 (en) 2004-12-10 2008-01-08 Archer-Daniels-Midland-Company Processes for the preparation and purification of hydroxymethylfuraldehyde and derivatives
EP2050742B1 (en) 2006-03-10 2010-07-07 Furanix Technologies B.V Use of an organic acid esters of 5-hydroxymethylfurfural
EP1834950A1 (en) 2006-03-10 2007-09-19 Avantium International B.V. Method for the synthesis of 5-alkoxymethylfurfural ethers and their use
EP2032550B1 (en) 2006-06-06 2013-11-20 Wisconsin Alumni Research Foundation Catalytic process for producing furan derivatives from carbohydrates in a biphasic reactor
US7880049B2 (en) 2006-06-06 2011-02-01 Wisconsin Alumni Research Foundation Production of liquid alkanes in the jet fuel range (C8-C15) from biomass-derived carbohydrates
DE102008009933A1 (de) 2008-02-18 2009-08-20 Friedrich-Schiller-Universität Jena Verfahren zur Herstellung von 5-Hydroxymethylfurfural mit Hilfe von ionischen Flüssigkeiten
WO2009155297A1 (en) 2008-06-17 2009-12-23 Wisconsin Alumni Research Foundation Chemical transformation of lignocellulosic biomass into fuels and chemicals
JP2012121811A (ja) * 2009-03-06 2012-06-28 Japan Advanced Institute Of Science & Technology Hokuriku 5−ヒドロキシメチルフルフラールの製造方法
WO2010144873A1 (en) 2009-06-13 2010-12-16 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
CN102803194B (zh) 2009-06-13 2016-01-20 莱诺维亚公司 由含碳水化合物的物质生产戊二酸和衍生物
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
EP3095789A1 (en) 2009-07-01 2016-11-23 Wisconsin Alumni Research Foundation Biomass hydrolysis
US8669393B2 (en) 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
FR2975396B1 (fr) 2011-05-16 2013-12-27 Centre Nat Rech Scient Procede de preparation de 5-hydroxymethylfurfural
FR2979345B1 (fr) * 2011-08-26 2014-02-21 Centre Nat Rech Scient Procede d'isomerisation du glucose en fructose
KR101374209B1 (ko) * 2011-09-29 2014-03-13 한국생산기술연구원 유기용매 하에서 이온교환수지를 이용한 5-히드록시메틸-2-푸르푸랄 또는 그의 알킬 에테르 유도체의 제조방법
JP6253203B2 (ja) 2012-01-18 2017-12-27 レノヴィア インコーポレイテッド 5−ヒドロキシメチルフルフラールからのヘキサメチレンジアミンの生成方法
WO2013146085A1 (ja) * 2012-03-27 2013-10-03 花王株式会社 5-ヒドロキシメチルフルフラールの製造方法
EP2813494A1 (de) 2013-06-12 2014-12-17 Basf Se Verfahren zur Herstellung von 5-Hydroxymethylfurfural (HMF)
DE102013223496A1 (de) 2013-11-18 2015-05-21 Tesa Se Neuartiges Polyester geeignet zur Herstellung von Trägermaterialien für Klebebändern
EP3099670A2 (en) 2014-01-27 2016-12-07 Rennovia Inc. Conversion of fructose-containing feedstocks to hmf-containing product
AU2015358536A1 (en) 2014-12-02 2017-05-18 Archer-Daniels-Midland Company Process for production of 2,5-bis-hydroxymethylfuran, 2,5-bis-hydroxymethyltetrahydrofuran, 1,6-hexanediol and 1,2,6-hexanetriol from 5-hydroxymethylfurfural
CN105503789B (zh) * 2015-10-29 2018-03-06 常州大学 蒙脱土负载金属离子固体酸催化木糖转化为糠醛的方法
WO2017123763A1 (en) 2016-01-13 2017-07-20 Rennovia Inc. Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
JP6293333B2 (ja) 2016-06-27 2018-03-14 日本食品化工株式会社 5−ヒドロキシメチル−2−フルフラールの製造方法
US11274089B2 (en) 2016-06-27 2022-03-15 Nihon Shokuhin Kako Co., Ltd. 5-hydroxymethyl-2-furfural production method
US11192872B2 (en) 2017-07-12 2021-12-07 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
JP7093623B2 (ja) 2017-12-08 2022-06-30 日本食品化工株式会社 副産物の生成が抑制された5-ヒドロキシメチル-2-フルフラールの製造方法
CN110818659B (zh) * 2019-10-09 2021-12-21 浙江工业大学 一种催化纤维素水解制备还原糖和5-hmf的方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2464260A1 (fr) * 1979-09-05 1981-03-06 Roquette Freres Procede de fabrication du 5-hydroxymethylfurfural
FR2551754B1 (fr) * 1983-09-14 1988-04-08 Roquette Freres Procede de fabrication du 5-hydroxymethylfurfural

Also Published As

Publication number Publication date
ZA919648B (en) 1992-09-30
EP0561928A1 (en) 1993-09-29
FR2670209B1 (fr) 1995-04-28
DE69117528T2 (de) 1996-09-12
DK0561928T3 (da) 1996-07-01
FR2670209A1 (fr) 1992-06-12
DE69117528D1 (de) 1996-04-04
CA2097812A1 (fr) 1992-06-08
WO1992010486A1 (fr) 1992-06-25
JPH06504272A (ja) 1994-05-19
EP0561928B1 (fr) 1996-02-28

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