ES2081399T3 - Procedimiento para la obtencion de espumas duras de poliuretano. - Google Patents

Procedimiento para la obtencion de espumas duras de poliuretano.

Info

Publication number
ES2081399T3
ES2081399T3 ES91113487T ES91113487T ES2081399T3 ES 2081399 T3 ES2081399 T3 ES 2081399T3 ES 91113487 T ES91113487 T ES 91113487T ES 91113487 T ES91113487 T ES 91113487T ES 2081399 T3 ES2081399 T3 ES 2081399T3
Authority
ES
Spain
Prior art keywords
weight
parts
agent
polyester
crosslinking agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91113487T
Other languages
English (en)
Inventor
Rolf Dr Wiedermann
Gerhard Dr Heilig
Wolfgang Schmitz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Application granted granted Critical
Publication of ES2081399T3 publication Critical patent/ES2081399T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4202Two or more polyesters of different physical or chemical nature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • C08G18/6637Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • C08G18/6637Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6644Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/521Esters of phosphoric acids, e.g. of H3PO4
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0025Foam properties rigid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0033Foam properties having integral skins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0041Foam properties having specified density
    • C08G2110/005< 50kg/m3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/906Polyurethane cellular product containing unreacted flame-retardant material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Fireproofing Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

LOS MATERIALES ESPONJOSOS DE POLIURETANO DURO SE OBTIENEN A TRAVES DE TRANSFORMACION DE 1) POLISOCIANATOS CON 2) AL MENOS DOS ATOMOS DE AGUA CONTRA ISOCIANATOS ACTIVOS QUE MUESTRAN POLIESTERES DE PESO MOLECULAR 400 HASTA 10.000 EN PRESENCIA DE 3) AGUA Y FERMENTOS ORGANICOS Y DE 4) MEDIOS IGNIFUGOS ASI COMO 5) COMPUESTOS CON AL MENOS DOS ATOMOS DE AGUA CAPACES DE REACCIONAR CONTRA ISOCIANATOS Y UN PESO MOLECULAR DE 32 HASTA 399 COMO RETICULANTE Y EN CASOS DADOS EN PRESENCIA DE 6) PRODUCTOS QUIMICOS AUXILIARES CONOCIDOS Y ACCESORIOS, EN LOS QUE SE UTILIZAN LOS COMPONENTES POLIESTER 2), EL MEDIO IGNIFUGO 4) Y EL COMPONENTE DE RETICULACION 5) COMO FORMULACION EN LA QUE PARTICIPAN LOS COMPONENTES 2) DE 15 HASTA 35 PARTES EN PESO LOS COMPONENTES 4) EN UNA MEZCLA DE 50 HASTA EN 80 PARTES EN PESO Y LOS COMPONENTES 5) EN UNA CANTIDAD DE 5 HASTA 15 PARTES EN PESO DONDE SE COMPLEMENTAN LAS PARTES EN PESO HASTA ALCANZAR EL 100 EN SUS COMPONENTES.
ES91113487T 1990-08-24 1991-08-12 Procedimiento para la obtencion de espumas duras de poliuretano. Expired - Lifetime ES2081399T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4026702A DE4026702A1 (de) 1990-08-24 1990-08-24 Verfahren zur herstellung von harten polyurethanschaumstoffen

Publications (1)

Publication Number Publication Date
ES2081399T3 true ES2081399T3 (es) 1996-03-01

Family

ID=6412774

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91113487T Expired - Lifetime ES2081399T3 (es) 1990-08-24 1991-08-12 Procedimiento para la obtencion de espumas duras de poliuretano.

Country Status (7)

Country Link
US (1) US5223549A (es)
EP (1) EP0472080B1 (es)
JP (1) JP3023521B2 (es)
AT (1) ATE130016T1 (es)
CA (1) CA2049516C (es)
DE (2) DE4026702A1 (es)
ES (1) ES2081399T3 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3933705C1 (es) * 1989-04-24 1990-12-13 Hans Wilhelm 4060 Viersen De Huetzen
JP3030106B2 (ja) * 1991-02-22 2000-04-10 三洋電機株式会社 低沸点発泡剤のミキシング装置
DE4129285A1 (de) * 1991-09-03 1993-03-04 Bayer Ag Verfahren zur herstellung von flammgeschuetzten, urethangruppen aufweisenden hartschaumstoffen
DE4302460A1 (de) * 1993-01-29 1994-08-04 Bayer Ag Verfahren zur Herstellung von Urethan- und Isocyanuratgruppen aufweisenden Hartschaumstoffen und ihre Verwendung als Dämmaterial
DE4339702A1 (de) * 1993-11-22 1995-05-24 Bayer Ag Verfahren zur Herstellung von harten Polyurethanschaumstoffen
US5387618A (en) * 1993-12-27 1995-02-07 The Dow Chemical Company Process for preparing a polyurethane foam in the presence of a hydrocarbon blowing agent
JP2000512332A (ja) * 1996-06-18 2000-09-19 インペリアル・ケミカル・インダストリーズ・ピーエルシー 硬質イソシアヌラート改質ポリウレタンフォーム
DE29820653U1 (de) * 1998-11-18 1999-01-28 TRW Automotive Safety Systems GmbH, 63743 Aschaffenburg Kunststoff-Formkörper
US20050148250A1 (en) * 2003-11-19 2005-07-07 O'connor Terence J. Reinforcement composite for a bituminous roofing membrane and method of making the composite
DE102009053224A1 (de) * 2009-11-06 2011-07-14 Bayer MaterialScience AG, 51373 Verfahren zur Herstellung eines Polyurethanschaums und hieraus erhältlicher Polyurethanschaum
US20140213679A1 (en) * 2011-08-26 2014-07-31 Bayer Intellectual Property Gmbh Emulsions and their use in the production of foams based on isocyanates
EP2818489A1 (de) * 2013-06-28 2014-12-31 Basf Se Hydrolysebeständige Polyurethanformkörper
BR112016016766B1 (pt) 2014-01-22 2021-05-25 Huntsman International Llc processo e sistema de reação para preparar espuma de poli-isocianurato rígida, espuma de poli-isocianurato rígida, e, composição reativa a isocianato polifuncional

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2421986A1 (de) * 1974-05-07 1975-11-27 Bayer Ag Verfahren zur herstellung von flammwidrigen, harten, urethangruppen aufweisenden schaumstoffen
DE2512170C3 (de) * 1975-03-20 1981-06-11 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von gegebenenfalls schaumförmigem, harten anorganisch-organischem Verbundmaterial
JPS5352562A (en) * 1976-10-26 1978-05-13 Marubishi Oil Chemical Fireeretardant polyurethan formulations and their production method
DE2832253A1 (de) * 1978-07-22 1980-01-31 Bayer Ag Verfahren zur herstellung von formschaumstoffen
DE2846809A1 (de) * 1978-10-27 1980-05-08 Bayer Ag Verfahren zur herstellung von polyurethankunststoffen
DE3402310A1 (de) * 1984-01-24 1985-07-25 Bayer Ag, 5090 Leverkusen Harte, geschlossenzellige, flammfeste polyurethanschaumstoffe
US4849459A (en) * 1985-06-27 1989-07-18 Basf Corporation Flame retardant polyurethane foams
GB2177405B (en) * 1985-06-28 1989-08-23 Basf Corp Flame retardant polyurethane foams
CA1274946A (en) * 1986-03-31 1990-10-02 James Raymond Dell Flame retardant high density rigid polyurethane foams
CA1315465C (en) * 1987-07-31 1993-03-30 Hans-Helmut Goertz Polymers of oxyalkylated unsaturated quaternary ammonium salts, their preparation and their use
ATE72253T1 (de) * 1987-09-15 1992-02-15 Bayer Ag Verfahren zur herstellung von polyurethanhartschaumstoffen.
GB8801525D0 (en) * 1988-01-23 1988-02-24 Ciba Geigy Ag Smoke & toxic gas suppressant composition
DE3812348A1 (de) * 1988-04-14 1989-10-26 Bayer Ag Verfahren zur herstellung von polyurethanschaumstoffen
US4908161A (en) * 1988-06-23 1990-03-13 Harry Fischer Fire retardant for isocyanate-based foams comprising ammonium sulfate and a cyanuric acid derivative
JP2710368B2 (ja) * 1988-12-06 1998-02-10 日本化成株式会社 難燃性ポリウレタンフォーム
JP2667889B2 (ja) * 1988-12-21 1997-10-27 マナック株式会社 難燃性ポリウレタンフォーム
JPH02185562A (ja) * 1989-01-12 1990-07-19 Hitachi Chem Co Ltd 発泡用樹脂組成物,発泡体および構造体
JP2775798B2 (ja) * 1989-01-24 1998-07-16 日本化成株式会社 難燃性ポリウレタンフォーム
JPH02206649A (ja) * 1989-02-03 1990-08-16 Nippon Kasei Kk 難燃性ポリウレタンフォーム
JP2679214B2 (ja) * 1989-02-16 1997-11-19 日本化成株式会社 難燃性ポリウレタンフォーム
JPH02273112A (ja) * 1989-04-14 1990-11-07 Iseki & Co Ltd 施肥装置の施肥量調節装置
JPH0762090B2 (ja) * 1989-04-24 1995-07-05 ビルヘルム フュッツェン,ハンス ハロゲン化炭化水素を含まないウレタンフォーム材料およびその製造方法
US4940632A (en) * 1989-10-06 1990-07-10 Mobay Corporation Foam laminates which include ASTM E-84 class 1 rated foams
GB8922930D0 (en) * 1989-10-11 1989-11-29 Ici Plc Fire retardant compositions
JPH04279619A (ja) * 1990-05-25 1992-10-05 Mitsui Toatsu Chem Inc 硬質ポリウレタンフォーム複合体の製造方法

Also Published As

Publication number Publication date
DE4026702A1 (de) 1992-02-27
EP0472080A3 (en) 1992-09-30
US5223549A (en) 1993-06-29
EP0472080A2 (de) 1992-02-26
DE59106848D1 (de) 1995-12-14
CA2049516C (en) 2002-12-10
JP3023521B2 (ja) 2000-03-21
ATE130016T1 (de) 1995-11-15
CA2049516A1 (en) 1992-02-25
JPH04270718A (ja) 1992-09-28
EP0472080B1 (de) 1995-11-08

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