ES2053479T3 - Hidrorepelente para albañileria. - Google Patents
Hidrorepelente para albañileria.Info
- Publication number
- ES2053479T3 ES2053479T3 ES87110996T ES87110996T ES2053479T3 ES 2053479 T3 ES2053479 T3 ES 2053479T3 ES 87110996 T ES87110996 T ES 87110996T ES 87110996 T ES87110996 T ES 87110996T ES 2053479 T3 ES2053479 T3 ES 2053479T3
- Authority
- ES
- Spain
- Prior art keywords
- units
- radical
- sio2
- resin
- masonry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011347 resin Substances 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- 230000002940 repellent Effects 0.000 abstract 1
- 239000005871 repellent Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/495—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
- C04B41/4961—Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/64—Insulation or other protection; Elements or use of specified material therefor for making damp-proof; Protection against corrosion
- E04B1/644—Damp-proof courses
- E04B1/648—Damp-proof courses obtained by injection or infiltration of water-proofing agents into an existing wall
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/66—Sealings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Paints Or Removers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Abstract
SEPROPORCIONA UN METODO PARA PRODUCIR UN REPELENTE AL AGUA PARA UNA OBRE DE ALBAÑILERIA QUE COMPRENDE: (A) PONER EN CONTACTO LA OBRA CON UNA SOLUCION QUE COMPRENDE UNA RESINA ORGANOPOLIXILOXANA ELEGIDA DEL GRUPO QUE CONSISTE DE LAS RESINAS QUE CONTIENEN UNIDADES R3 SI O 0,5 Y UNIDADES SIO2 Y RESINAS QUE CONTIENEN UNIDADES R3 SIO 0,5, UNIDADES R2 SIO2 Y UNIDADES SIO2, LA PROPORCION DE UNIDADES SIR3O0,5, UNIDADES R2SIO, Y LA PROPORCION DE UNIDADES SIO2 A UNIDADES SIO2 SON MAYORES A UNAS 0,1:1 DONDE CADA R ES UN RADICAL ALQUIL ELEGIDO, SUBBSTITUIDO O NO SUBSTITUIDO, RADICAL ALQUIL, RADICAL ALKARIL, RADICAL ALKARIL, RADICAL CICLOALQUIL O RADICAL ALQUENIL Y (B) EVAPORAR EL DISOLVENTE. PREFERIBLEMENTE, LA SOLUCION RESINOSA ADEMAS COMPRENDE UNA RESINA ALQUILALCOXIPOLISILOXANA.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/940,126 US4753977A (en) | 1986-12-10 | 1986-12-10 | Water repellent for masonry |
EP87110996A EP0304497B1 (en) | 1986-12-10 | 1987-07-29 | Water repellent for masonry |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2053479T3 true ES2053479T3 (es) | 1994-08-01 |
Family
ID=39671983
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES87110996T Expired - Lifetime ES2053479T3 (es) | 1986-12-10 | 1987-07-29 | Hidrorepelente para albañileria. |
Country Status (7)
Country | Link |
---|---|
US (1) | US4753977A (es) |
EP (2) | EP0304497B1 (es) |
JP (1) | JPS63170484A (es) |
CA (1) | CA1309539C (es) |
DE (2) | DE3784501T2 (es) |
ES (1) | ES2053479T3 (es) |
ZA (1) | ZA877769B (es) |
Families Citing this family (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2656785B2 (ja) * | 1988-02-24 | 1997-09-24 | 日東電工株式会社 | 光デイスク |
US4846886A (en) * | 1988-05-05 | 1989-07-11 | Dow Corning Corporation | Water beading-water shedding repellent composition |
US4874431A (en) * | 1988-07-14 | 1989-10-17 | Dow Corning Corporation | Low volatility water repellents |
DE3834462A1 (de) * | 1988-10-10 | 1990-04-12 | Rudolf Dr Herrmann | Verfahren und mittel zur baustoffkonsolidierung und si-haltige polykondensate hierfuer |
JP2685852B2 (ja) * | 1988-12-02 | 1997-12-03 | 東芝シリコーン株式会社 | 浸透性防水剤組成物 |
JP2541646B2 (ja) * | 1988-12-02 | 1996-10-09 | 東芝シリコーン株式会社 | 浸透性防水剤組成物 |
GB8902183D0 (en) * | 1989-02-01 | 1989-03-22 | Perennator Gmbh | Elastomer-forming compositions |
US5051129A (en) * | 1990-06-25 | 1991-09-24 | Dow Corning Corporation | Masonry water repellent composition |
US5112393A (en) * | 1990-10-09 | 1992-05-12 | Prosoco, Inc. | Method of rendering masonry materials water repellent with low voc organoalkoxysilanes |
JP3187445B2 (ja) * | 1991-03-28 | 2001-07-11 | 東レ・ダウコーニング・シリコーン株式会社 | 固体材料の撥水処理剤組成物 |
US5210156A (en) * | 1991-08-22 | 1993-05-11 | Dow Corning Corporation | Stable, moisture-curable silicone pressure sensitive adhesives |
FR2684682B1 (fr) * | 1991-12-05 | 1994-09-16 | Coppa Cie | Composition pour la protection et la preservation de surfaces vis-a-vis des graffitis, et ses applications. |
JP3378590B2 (ja) * | 1992-02-28 | 2003-02-17 | 東レ・ダウコーニング・シリコーン株式会社 | 化粧料用撥水性粉体およびその製造方法 |
CA2090302A1 (en) * | 1992-03-20 | 1993-09-21 | Larry D. Rich | Aqueous dispersable oil and water repellent silane masonry penetrants |
US5432007A (en) * | 1992-10-06 | 1995-07-11 | Shizu Naito | Solvent-free organosiloxane composition and its use |
US5905123A (en) * | 1993-06-11 | 1999-05-18 | Dow Corning Corporation | Moisture-curable hot melt silicone pressure-sensitive adhesives |
US5389170A (en) * | 1993-06-11 | 1995-02-14 | Dow Corning Corporation | Method for bonding substrates using molten moisture reactive organosiloxane compositions |
AUPM295293A0 (en) * | 1993-12-14 | 1994-01-13 | Victoria University Of Technology | Method of producing stable silane/siloxane emulsions for rendering masonry surfaces water repellent |
AUPM399794A0 (en) * | 1994-02-21 | 1994-03-17 | Victoria University Of Technology | Aqueous compositions for the water repellent treatment of masonry |
AU689224B2 (en) * | 1994-02-21 | 1998-03-26 | Victoria University Of Technology | Aqueous compositions for the water repellent treatment of masonry |
US5502145A (en) * | 1994-03-02 | 1996-03-26 | Dsm Desotech. Inc. | Coating system for glass strength retention |
US5561203A (en) * | 1994-06-20 | 1996-10-01 | Dow Corning Corporation | Silicone pressure sensitive adhesive composition |
BE1008724A3 (nl) * | 1994-09-27 | 1996-07-02 | Couttenier Andre | Samenstelling voor het beschermen en waterafstotend maken van een siliciumhoudend substraat. |
FR2746052B1 (fr) * | 1996-03-15 | 1998-07-03 | Procede de moulage et d'hydrofugation d'elements moules en beton, mortier, ciment, par une resine silicone | |
US5817262A (en) * | 1996-12-20 | 1998-10-06 | United States Gypsum Company | Process of producing gypsum wood fiber product having improved water resistance |
US6403163B1 (en) * | 2000-06-27 | 2002-06-11 | Chemrex, Inc. | Method of treating surfaces with organosilicon water repellent compositions |
ES2221566B1 (es) * | 2003-05-13 | 2005-10-01 | Texsa Morteros, S.A. | Mortero para construccion y procedimiento para su aplicacion. |
JP2005002180A (ja) * | 2003-06-11 | 2005-01-06 | Yamane Norimasa | 外構物用被膜形成材 |
US7527703B2 (en) * | 2004-09-09 | 2009-05-05 | Jeffrey Swain | Submerged masonry surface treating method |
US8450931B2 (en) * | 2005-05-10 | 2013-05-28 | Dow Corning Corporation | Process for minimizing electromigration in an electronic device |
USRE44070E1 (en) | 2005-06-09 | 2013-03-12 | United States Gypsum Company | Composite light weight gypsum wallboard |
WO2007011540A1 (en) * | 2005-07-19 | 2007-01-25 | Dow Corning Corporation | Structural attachment media |
KR101285144B1 (ko) | 2005-07-19 | 2013-07-15 | 다우 코닝 코포레이션 | 감압 접착제 및 이의 제조방법 |
FR2889185B1 (fr) | 2005-07-29 | 2007-10-12 | Rhodia Chimie Sa | Procede pour hydrofuger et ameliorer l'effet perlant de materiaux de construction |
US7459186B2 (en) * | 2005-08-05 | 2008-12-02 | Wacker Chemical Corporation | Masonry sealing compositions comprising semi-crystalline ethylene-vinyl acetate polymer emulsions |
WO2008004243A2 (en) * | 2006-07-07 | 2008-01-10 | Ranka, Seema, Ajay | Ionic organosilicon compounds and compositions thereof |
US7553983B2 (en) | 2006-07-07 | 2009-06-30 | Zydex Industries | Organosilicon compounds |
EA017089B1 (ru) * | 2006-07-07 | 2012-09-28 | Ранка, Сима Аджай | Способы обработки поверхностей ионными кремнийорганическими композициями |
EP2263990B1 (en) | 2006-11-03 | 2012-12-26 | E. I. du Pont de Nemours and Company | Liquid-repellent and stain-resistant cementitious product |
KR20090093999A (ko) * | 2006-12-21 | 2009-09-02 | 다우 코닝 코포레이션 | 이중 경화 중합체, 이의 제조방법 및 용도 |
US8168737B2 (en) * | 2006-12-21 | 2012-05-01 | Dow Corning Corporation | Dual curing polymers and methods for their preparation and use |
US8286561B2 (en) | 2008-06-27 | 2012-10-16 | Ssw Holding Company, Inc. | Spill containing refrigerator shelf assembly |
US11786036B2 (en) | 2008-06-27 | 2023-10-17 | Ssw Advanced Technologies, Llc | Spill containing refrigerator shelf assembly |
WO2010042668A1 (en) | 2008-10-07 | 2010-04-15 | Ross Technology Corporation | Spill resistant surfaces having hydrophobic and oleophobic borders |
US9593209B2 (en) | 2009-10-22 | 2017-03-14 | Dow Corning Corporation | Process for preparing clustered functional polyorganosiloxanes, and methods for their use |
US9074778B2 (en) | 2009-11-04 | 2015-07-07 | Ssw Holding Company, Inc. | Cooking appliance surfaces having spill containment pattern |
TWI502004B (zh) | 2009-11-09 | 2015-10-01 | Dow Corning | 群集官能性聚有機矽氧烷之製法及其使用方法 |
EP2547832A4 (en) | 2010-03-15 | 2016-03-16 | Ross Technology Corp | PISTON AND METHODS FOR PRODUCING HYDROPHOBIC SURFACES |
EP2678400A4 (en) | 2011-02-21 | 2015-11-18 | Ross Technology Corp | SUPERHYDROPHOBIC AND OIL-REPELLENT COATINGS WITH BINDING SYSTEMS WITH A LOW CONTENT OF VOLATILE ORGANIC COMPOUNDS |
DE102011085428A1 (de) | 2011-10-28 | 2013-05-02 | Schott Ag | Einlegeboden |
WO2013090939A1 (en) | 2011-12-15 | 2013-06-20 | Ross Technology Corporation | Composition and coating for superhydrophobic performance |
WO2013101535A1 (en) | 2011-12-29 | 2013-07-04 | 3M Innovative Properties Company | Curable polysiloxane compositions and pressure sensitive adhesives made therefrom |
WO2014003852A2 (en) | 2012-06-25 | 2014-01-03 | Ross Technology Corporation | Elastomeric coatings having hydrophobic and/or oleophobic properties |
KR102186328B1 (ko) | 2013-02-11 | 2020-12-03 | 다우 실리콘즈 코포레이션 | 알콕시-작용성 유기폴리실록산 수지 및 중합체와 이의 관련된 형성 방법 |
US10370574B2 (en) | 2013-02-11 | 2019-08-06 | Dow Silicones Corporation | Method for forming thermally conductive thermal radical cure silicone compositions |
KR102170923B1 (ko) | 2013-02-11 | 2020-10-29 | 다우 실리콘즈 코포레이션 | 클러스터형 작용성 폴리오르가노실록산 및 실리콘 반응성 희석제를 포함하는 경화성 실리콘 조성물 |
WO2014124362A1 (en) | 2013-02-11 | 2014-08-14 | Dow Corning Corporation | Clustered functional polyorganosiloxanes, processes for forming same and methods for their use |
CN104968749B (zh) | 2013-02-11 | 2017-03-29 | 道康宁公司 | 稳定性热自由基可固化有机硅粘合剂组合物 |
US10370572B2 (en) | 2013-02-11 | 2019-08-06 | Dow Silicones Corporation | Moisture-curable hot melt silicone adhesive compositions including an alkoxy-functional siloxane reactive resin |
KR102192489B1 (ko) | 2013-02-11 | 2020-12-17 | 다우 실리콘즈 코포레이션 | 열 전도성 열 라디칼 경화 실리콘 조성물을 형성하는 원 위치 방법 |
JP6433808B2 (ja) * | 2015-02-18 | 2018-12-05 | 鹿島建設株式会社 | 構造物の構築方法、及び、岩盤の保護方法 |
EP3196229B1 (en) | 2015-11-05 | 2018-09-26 | Dow Silicones Corporation | Branched polyorganosiloxanes and related curable compositions, methods, uses and devices |
EP3901360A4 (en) * | 2018-12-21 | 2022-09-07 | Dow Toray Co., Ltd. | WATER REPELLENT COMPOSITION AND METHOD FOR PRODUCTION OF WATER REPELLENT FIBROUS PRODUCT |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2736721A (en) * | 1952-10-08 | 1956-02-28 | Optionally | |
US2810704A (en) * | 1954-04-19 | 1957-10-22 | Gen Electric | Process for making moisture-unstable methyl methoxypolysiloxane |
GB860522A (en) * | 1957-11-04 | 1961-02-08 | Midland Silicones Ltd | Improvements in or relating to silicone compositions |
FR1241740A (fr) * | 1958-08-18 | 1960-09-23 | Dow Corning | Matières d'impression organosiliciques pour enduits à base de ciment |
FR1590745A (es) * | 1967-11-03 | 1970-04-20 | ||
US3629358A (en) * | 1969-07-02 | 1971-12-21 | Gen Electric | Tough unsupported films formed from organopolysiloxanes |
US4255316A (en) * | 1979-04-26 | 1981-03-10 | Dow Corning Corporation | Ceramifiable silicone adhesives |
JPS56157465A (en) * | 1980-05-09 | 1981-12-04 | Toshiba Silicone Co Ltd | Polysiloxane coat formation |
JPS56157464A (en) * | 1980-05-09 | 1981-12-04 | Toshiba Silicone Co Ltd | Coat formation |
US4273813A (en) * | 1980-05-19 | 1981-06-16 | Dow Corning Corporation | Method of providing waterproof coating for masonry walls |
US4490500A (en) * | 1981-02-26 | 1984-12-25 | General Electric Company | Completely solventless two component RTV silicone composition |
US4515932A (en) * | 1982-09-29 | 1985-05-07 | General Electric Company | End-capping catalysts for forming alkoxy-functional one component RTV compositions |
US4423095A (en) * | 1983-01-28 | 1983-12-27 | Dow Corning Corporation | Silicone-organic coating compositions |
DE3312911C2 (de) * | 1983-04-11 | 1986-01-02 | Th. Goldschmidt Ag, 4300 Essen | Mittel zum Wasserabweisendmachen anorganischer Bauelemente |
DE3418623A1 (de) * | 1983-06-02 | 1984-12-13 | General Electric Co., Schenectady, N.Y. | Konturgetreue siliconueberzuege |
JPS6018544A (ja) * | 1983-07-11 | 1985-01-30 | Toshiba Silicone Co Ltd | 室温硬化性ポリオルガノシロキサン組成物 |
DE3332997A1 (de) * | 1983-09-13 | 1985-03-28 | Wacker-Chemie GmbH, 8000 München | Verfahren zur impraegnierung von textilien aus organischen fasern |
US4495340A (en) * | 1983-12-23 | 1985-01-22 | Dow Corning Corporation | Curable masses producing carboxyfunctional silicone coatings |
US4595610A (en) * | 1984-07-02 | 1986-06-17 | Dow Corning Corporation | Curable silicone compositions for the protection of polyurethane foam |
-
1986
- 1986-12-10 US US06/940,126 patent/US4753977A/en not_active Expired - Lifetime
-
1987
- 1987-07-29 ES ES87110996T patent/ES2053479T3/es not_active Expired - Lifetime
- 1987-07-29 EP EP87110996A patent/EP0304497B1/en not_active Expired - Lifetime
- 1987-07-29 DE DE87110996T patent/DE3784501T2/de not_active Expired - Lifetime
- 1987-10-15 ZA ZA877769A patent/ZA877769B/xx unknown
- 1987-10-28 DE DE8787115846T patent/DE3778863D1/de not_active Expired - Fee Related
- 1987-10-28 EP EP87115846A patent/EP0275378B1/en not_active Expired - Lifetime
- 1987-11-25 JP JP62295441A patent/JPS63170484A/ja active Granted
- 1987-12-10 CA CA000554014A patent/CA1309539C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH0563511B2 (es) | 1993-09-10 |
US4753977A (en) | 1988-06-28 |
EP0275378B1 (en) | 1992-05-06 |
ZA877769B (en) | 1988-06-20 |
JPS63170484A (ja) | 1988-07-14 |
DE3784501T2 (de) | 1993-10-07 |
EP0304497B1 (en) | 1993-03-03 |
DE3784501D1 (de) | 1993-04-08 |
DE3778863D1 (de) | 1992-06-11 |
CA1309539C (en) | 1992-10-27 |
EP0304497A1 (en) | 1989-03-01 |
EP0275378A1 (en) | 1988-07-27 |
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