EP4038214A1 - Toles de precision en alliage d'aluminium - Google Patents
Toles de precision en alliage d'aluminiumInfo
- Publication number
- EP4038214A1 EP4038214A1 EP20793025.6A EP20793025A EP4038214A1 EP 4038214 A1 EP4038214 A1 EP 4038214A1 EP 20793025 A EP20793025 A EP 20793025A EP 4038214 A1 EP4038214 A1 EP 4038214A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sheet
- thickness
- weight
- deflection
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/002—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working by rapid cooling or quenching; cooling agents used therefor
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/05—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys of the Al-Si-Mg type, i.e. containing silicon and magnesium in approximately equal proportions
Definitions
- the invention relates to aluminum alloy sheets of the 6xxx series, particularly for use as precision plates.
- Excellent dimensional stability is very important for precision sheet metal applications, typically between 8 and 150mm thick.
- This type of product is typically used for the production of machine elements, in particular as reference plates for assembly or inspection tools. For these applications, it is particularly important to reduce as much as possible any deformation of the sheet during its machining, which makes it possible to avoid additional pre-machining or final touch-up operations.
- the patent application EP2263811 relates to rolled products whose surface is machined having a flatness of 0.2 mm or less.
- the alloy contains 0.3 to 1.5% by mass of Mg, 0.2 to 1.6% by mass of Si, and in addition one or more elements chosen from the group consisting of 0.8 wt% or less of Fe, 1.0 wt% or less of Cu, 0.6 wt% or less of Mn, 0.5 wt% or less of Cr,
- Patent application WO2014 / 060660 relates to a vacuum chamber element obtained by machining and surface treatment of a sheet of thickness at least equal to 10 mm made of aluminum alloy of composition, in% by weight, Si: 0 , 4 - 0.7; Mg: 0.4-0.7; Ti 0.01 - ⁇ 0.15, Fe ⁇ 0.25; Cu ⁇ 0.04; Mn ⁇ 0.4; Cr 0.01 - ⁇ 0.1; Zn ⁇ 0.04; other elements ⁇ 0.05 each and ⁇ 0.15 in total, remainder aluminum.
- Patent application WO2018 / 162823 relates to a vacuum chamber element obtained by machining and surface treatment of a sheet of thickness at least equal to 10 mm made of aluminum alloy of composition, in% by weight, Si: 0 , 4 -0.7; Mg: 0.4 -1.0; the ratio in% by weight Mg / Si being less than 1.8; Ti: 0.01-0.15, Fe 0.08-0.25; Cu ⁇ 0.35; Mn ⁇ 0.4; Cr: ⁇ 0.25; Zn ⁇ 0.04; other elements ⁇ 0.05 each and ⁇ 0.15 in total, remainder aluminum, characterized in that the grain size of said sheet is such that the average linear intercept length measured in the L / TC plane according to the AS standard TM E112, is at least equal to 350 / ⁇ m between surface and 1/2 thickness.
- Patent application US2010018617 discloses an aluminum alloy for the anodic oxidation treatment which comprises as alloying elements 0.1 to 2.0% of Mg, 0.1 to 2.0% of Si and 0.1. 2.0% Mn, each Fe, Cr and Cu content being limited to 0.03 mass. % or less, and in which the remainder is Al and unavoidable impurities.
- This application teaches in particular a homogenization treatment at a temperature greater than 550 ° C and less than or equal to 600 ° C.
- Patent application CN108239712 relates to a 6082 aluminum alloy plate for aviation and a method of manufacturing the same.
- the chemical components of 6082 aluminum alloy plate include, in weight percent, 1.0% to 1.3% Si, 0.1% to 0.3% Fe, 0.05% to 0, 10% Cu, 0.5% to 0.8% Mn, 0.6% to 0.9%.
- Patent application CN108239713 relates to an aluminum alloy plate for an electronic product and a method of manufacturing the aluminum alloy plate.
- the chemical components of the aluminum alloy plate for the appearance of the electronic product include, in weight percentage, 0.3% to 0.4% Si, not more than 0.10% Fe, not more than 0.05% Cu, not more than 0.05% Mn, 0.45% to 0.55% Mg, not more than 0.05% Zn, not more than 0.05% Cr, not more than 0.05% Ti and the rest Al and inevitable elements. Alloys of the 6XXX family are also known for forging.
- Patent application WO2017 / 207603 discloses a hot rolled semi-finished aluminum alloy forge blank of the 6xxx series having a thickness in the range of 2mm to 30mm, and having a composition comprising, by weight. %, Si 0.65-1.4%, Mg 0.60-0.95%, Mn 0.40-0.80%, Cu 0.04-0.28%, Fe up to 0.5% , Cr up to 0.18%, Zr up to 0.20%, Ti up to 0.15%, Zn up to 0.25%, impurities each ⁇ 0.05%, total ⁇ 0.2 %, aluminum equilibrium, and in which it has a substantially non-recrystallized microstructure.
- the application also relates to a method of manufacturing such a hot-rolled aluminum alloy forging material of the 6xxx series.
- the forge blank manufacturing process does not include stress relief and dimensional stability during machining is not a criterion for this type of product intended to be strongly deformed when hot by forging.
- Patent application US2005 / 095167 discloses a component or a semi-finished part made from an aluminum alloy hot formed, typically by forging, of the following composition by weight.
- the forge blank manufacturing process does not include stress relief and dimensional stability during machining is not a criterion for this type of product intended to be strongly deformed when hot by fbrgeage.
- a first object of the invention is a method of manufacturing an aluminum alloy sheet with a final thickness of between 8 and 50 mm in which a) a rolling plate made of an aluminum alloy of composition, in % by weight, Si:
- said rolling plate is homogenized, c) said rolling plate is rolled at a temperature of at least 340 ° C to obtain a sheet of thickness at least equal to 12 mm, d) optionally a heat treatment and / or cold rolling of the sheet thus obtained is carried out, e) a solution treatment of the optionally heat-treated sheet is carried out and / or cold rolled and quenched, f) the said sheet thus dissolved and quenched is relaxed by controlled traction with a permanent elongation of 1 to 5%, g) the sheet thus pulled is tempered, h) optionally, said sheet thus returned is machined to obtain
- a second subject of the invention is a sheet with a thickness of between 8 and 50 mm made of an aluminum alloy of composition, in 96 by weight, Si: 0.7 - 1.3; Mg: 0.6 - 1.2; Mn: 0.65 - 1.0; Fe: 0.05 - 0.35; at least one element chosen from Cr: 0.1-0.3 and Zr: 0.06-0.15; Ti ⁇
- Another object of the invention is the use of a sheet according to the invention as a precision sheet, in particular for the production of machine elements, for example assembly or inspection tools.
- Figure 1 shows the granular structure in section @ L / TC after hot rolling to a thickness of 25 mm of the product in alloy A ( Figure la) and the product in alloy B ( Figure 1b)
- Figure 2 shows the Taylor factor in the longitudinal direction measured at 1/12 th of the thickness and at 1 ⁇ 2 thickness for sheets of alloy A and B with a final thickness of 20 mm and 25 mm.
- Figure 3 shows the steps performed for the measurement of deflection deviations.
- Figure 3A initial measurement of bar deflection;
- Figure 3B machining to remove 1 ⁇ 4 of the thickness,
- Figure 3C second measurement.
- alloys are made in accordance with the regulations of The Aluminum Association (AA), known to those skilled in the art.
- AA The Aluminum Association
- the definitions of metallurgical states are given in European standard EN 515. Unless otherwise stated, the definitions of standard EN12258-1 apply. Unless otherwise indicated, the compositions are expressed in% by weight.
- the static mechanical characteristics in other words the tensile strength Rm, the conventional yield strength at 0.2% elongation Rp 0.2 and the elongation at break A%, are determined by a tensile test according to standard ISO 6892-1, the sampling and direction of the test being defined by standard EN 485-1.
- improved aluminum alloy sheets of the 6XXX series in particular precision sheets, exhibiting improved dimensional stability, in particular during the machining steps, while having sufficient static mechanical properties, and excellent suitability.
- composition in% by weight Si: 0.7 - 1.3; Mg: 0.6 - 1.2; Mn: 0.65 - 1.0; Fe: 0.05 - 0.35; at least one element chosen from Cr: 0.1-0.3 and Zr: 0.06-0.15; Ti ⁇ 0.15; Cu ⁇ 0.4; Zn ⁇ 0.1; other elements ⁇ 0.05 each and ⁇ 0.15 in total, remainder of aluminum and to the process according to the invention.
- composition according to the invention makes it possible in particular to obtain a low deformation during the machining of the products.
- the present inventors believe that the composition according to the invention makes it possible to obtain an essentially non-recrystallized structure throughout the thickness after hot rolling which, surprisingly, allows after dissolution and quenching, stress relieving and tempering to obtain a product having very low internal stresses and therefore deforming little during machining.
- the present inventors have observed in particular that compared to a standard composition of the AA6082 alloy, the presence of a high amount of Mn and of at least one element chosen from Cr and Zr makes it possible to improve the properties.
- the Mn content is between 0.65 and 1.0% by weight.
- the minimum content of Mn is 0.70%, advantageously 0.75% and preferably 0.80% or even 0.85%.
- the maximum Mn content is 0.95%.
- the Mn content is between 0.8 and 1.0% by weight.
- the presence of at least one anti-recrystallizing element chosen from Cr: 0.1-0.3% and Zr: 0.06-0.15% is necessary.
- Cr is the preferred anti-recrystallizing element in the context of the invention.
- the minimum Cr content is 0.12%, advantageously 0.15% and preferably 0.18%.
- the maximum Cr content is 0.28%, advantageously 0.25% and preferably 0.23%.
- the Cr content is between 0.15 and 0.25% by weight and the Zr content is less than 0.05% by weight. If Zr is added alone or in combination with Cr, the preferred content is 0.08-0.13%.
- the Fe content is between 0.05 and 0.35% by weight.
- the minimum Fe content is 0.06%, advantageously 0.07% and preferably 0.08%.
- the maximum Fe content is 0.30%, advantageously 0.25% and preferably 0.15%, which can contribute in particular to obtaining the advantageous essentially non-recrystallized granular structure after hot rolling.
- the Fe content is between 0.08 and 0.15% by weight.
- Mg and Si are added to achieve the desired mechanical characteristics through the formation of Mg 2 Si.
- the Mg content is between 0.6 and 1.2% by weight.
- the minimum Mg content is 0.61%, advantageously 0.62% and preferably 0.63%.
- the maximum Mg content is 1.1%, advantageously 1.0% and preferably 0.9% or even 0.8%. In one embodiment of the invention, the Mg content is between 0.6 and 0.8% by weight.
- the SI content is between 0.7 and 1.3% by weight.
- the minimum Si content is 0.72%, advantageously 0.75% and preferably 0.80%.
- the maximum Si content is 1.2%, advantageously 1.1% and preferably 1.0% or even 0.95%.
- the Si content is between 0.8 and 1.0% by weight.
- the Si content is greater than the Mg content and preferably Si / Mg is greater than 1.1 and even more preferably greater than 1.2 or even 1.3 so as to further strengthen the mechanical characteristics by the presence of silicon phases.
- the Ti content is less than 0.15% by weight. It may be advantageous to add Ti, in particular for controlling the grain size during casting. In one embodiment of the invention, the Ti content is between 0.01 and 0.05% by weight.
- the Cu content is less than 0.4% by weight. In an embodiment of the invention aimed at obtaining higher mechanical characteristics, an addition of Cu is carried out and the content is between 0.1 and 0.3% by weight. However, in the preferred embodiment Cu is not added and is present only as an inevitable impurity, its content being less than 0.05% by weight and preferably less than 0.04% by weight so in particular to not to degrade the aptitude for anodization.
- the Zn content is less than 0.1% by weight. In one embodiment of the invention, an addition of Zn is carried out and the content is between 0.05 and 0.1% by weight. However, in the preferred embodiment Zn is not added and is present only as an unavoidable impurity, its content being less than 0.05% by weight. The other elements may be present as unavoidable impurities with a content of less than 0.05% by weight each and less than 0.15% by weight in total, the remainder being aluminum.
- the manufacturing process according to the invention comprises steps of casting, homogenization, hot rolling, optionally heat treatment and / or cold rolling, dissolving, quenching, stress relieving, tempering and optionally machining.
- a rolling plate made of an aluminum alloy of the composition according to the invention is cast, preferably by vertical semi-continuous casting with direct cooling.
- the plate thus obtained can be scalped, that is to say machined, before the subsequent steps.
- the rolling plate is then homogenized.
- the homogenization temperature is below 550 ° C.
- the homogenization temperature is between 515 ° C and 545 ° C.
- Hot rolling is then carried out to obtain a sheet of thickness at least equal to 12 mm, either directly after homogenization or after cooling and reheating to a temperature of at least 340 ° C, preferably at least 370. ° C and preferably at least 380 ° C.
- the hot rolling temperature is preferably maintained at at least 340 ° C, preferably at least 350 ° C and more preferably at least 360 ° C or even at least 370 ° C.
- the hot rolling temperature is preferably at most 450 ° C and preferably at most 420 ° C.
- the hot rolling outlet temperature is preferably at most 410 ° C and preferably at most 400 ° C.
- the maximum reduction rate of the passes during hot rolling is less than 50%, preferably less than 45% and preferably less than 40%, or even more preferably less than 35%.
- the maximum rate of reduction of hot rolling passes depends on the exit thickness of the hot rolling and is less than one hundredth of 1.56 times the thickness - 5.9, per example for an exit thickness of 25 mm, the reduction rate of each pass during hot rolling is preferably less than one hundredth of 1.56 times 25-5.9, ie 33.1%.
- the combination of composition, homogenization and hot-rolled conditions results in a substantially non-recrystallized structure, throughout the thickness of the hot-rolled product.
- essentially non-recrystallized throughout the thickness is meant that the rate of recrystallization regardless of the position in the thickness is less than 10% and preferably less than 5%.
- a heat treatment, making it possible in particular to restore the sheet thus hot-rolled can optionally be carried out then, advantageously at a temperature between 300 ° C and 400 ° C.
- Cold rolling typically 10 to 50%, can optionally be performed following heat treatment or independently.
- the sheet thus hot-rolled and optionally heat-treated and / or cold-rolled then undergoes dissolving followed by quenching.
- the dissolving is preferably carried out at a temperature between 510 ° C and 570 ° C.
- Quenching is typically carried out by immersion or spraying of cold water. Said sheet thus dissolved and quenched is then relaxed by controlled traction with a permanent elongation of 1 to 5%, preferably 1.5 to 3%.
- the stress relieving step is essential to obtain low internal stresses and therefore low deformations during machining. Controlled tensile stress relief is limited to geometries of constant cross section to ensure homogeneous plastic deformation and therefore does not apply to forged products with complex shapes.
- tempering is carried out, typically at a temperature of between 150 ° C. and 210 ° C., to preferably obtain a T6, T651 or T7 state.
- said sheet thus returned is finally machined to obtain a sheet of final thickness at least equal to 8 mm.
- at least 1 mm is machined, preferably at least 1.5 mm or preferably at least 2 mm per face so as to obtain a precision sheet.
- the sheets capable of being obtained by the process according to the invention have particularly advantageous properties.
- the sheets according to the invention have an elastic limit Rp 0.2 (TL) of at least 240 MPa, preferably at least 250 MPa and preferably at least 260 MPa, and / or a breaking strength Rm (TL) of at least 280 MPa, preferably at least 290 MPa and preferably at least 300 MPa and / or an elongation at break A% of at least 8%, preferably d at least 10% and preferably at least 12%.
- TL elastic limit
- the sheets according to the invention have a low level of internal stresses.
- the product of the maximum deflection deviation in the L and TL directions multiplied by the rolling exit thickness is less than 4 and preferably less than 3.
- the deflection deviations considered to obtain the value of the maximum deflection deviation are on the one hand the deflection difference between the measured deflection bar dimension 400 mm x 30 mm x rolling exit thickness and the deflection measured for this same bar after machining 1 ⁇ 4 of its thickness, and on the other hand the deflection difference between the deflection measured for the previous bar, c 'that is to say the bar after machining 1 ⁇ 4 of the thickness with respect to the rolling exit thickness, and the deflection measured for this previous bar after additional machining of% of its thickness, all deflection measurements being carried out with the bar placed on two supports 390 mm apart and the arrows being expressed in mm, all the measurements being carried out before the optional final machining step and in both L and TL directions.
- the texture of the products according to the invention is also advantageous.
- the crystallographic texture can be described by a mathematical function in 3 dimensions. This function is known in the trade as Orientation Density Function (FDO). It is defined as the volume fraction of the material dV / V having an orientation g up to dg: where ( ⁇ 1, ⁇ , ⁇ 2) are the Euler angles describing the orientation g.
- FDO Orientation Density Function
- the FDO of each sheet is measured by the spherical harmonics method from four pole figures measured by X-ray diffraction on a traditional texture goniometer.
- the measurements of the pole figures were carried out on samples cut at the mid-thickness of the sheets.
- the information contained in the FDO has been simplified, as known to those skilled in the art, in order to describe the texture in a proportion of grains contained in a discretized Euler space.
- the Taylor factor is a geometric factor used to describe the propensity of a crystal to deform plastically by sliding dislocations. H takes into account the crystalline orientation as well as the state of deformation imposed on the material. This factor can be seen as a multiplicative factor of the yield strength, a large value of the Taylor factor indicating a "hard” grain requiring the activation of many slip systems unlike a low value of the Taylor factor which will indicate a grain 'soft', easy to deform.
- an average Taylor factor representative of the plastic behavior of all the grains. From the texture measurements, the Taylor factor for a given stress direction was calculated according to the method described by Taylor (Gl Taylor Plastic Strain in metals, J. Inst. Metals, 62, 307-324; 1938). Many methods derived from the initial Taylor model exist to calculate the Taylor factor and can give significantly different Taylor factor values. In order to overcome these differences, the inventors compared Taylor factor ratios rather than absolute values.
- the ratio between the Taylor factor in the longitudinal direction measured at 1/12 th of the thickness and 1/2 of the thickness is between 0.90 and 1.10, preferably between between 0.92 and 1.08 and preferably between 0.95 and 1.05, the measurements being taken before the optional final machining step.
- sheets according to the invention are used as precision sheet, in particular to produce a reference sheet, a control tool or a jig.
- the sheets according to the invention exhibit improved dimensional stability, in particular during the machining steps, while having sufficient static mechanical properties, and excellent aptitude for anodization.
- alloy rolling plates were prepared, the composition of which is given in Table 1.
- Alloy A is a reference alloy while alloys B and C are alloys according to the invention.
- the plates were homogenized at 535 ° C and hot rolled to a thickness of 20 to 35 mm as appropriate.
- the hot rolling inlet temperature was between 390 and 410 ° C, the end of rolling temperature was kept at a value of at least 340 ° C.
- the highest reduction during one pass of hot rolling, which corresponded to the last pass, is given in Table 2.
- the sheets thus obtained were put in solution at 540 ° C, quenched, tensioned by controlled traction. and returned to obtain a T651 status.
- the tempering conditions were 8 hours at 165 ° C. In the last step, machining of 5 mm (2.5 mm per face) was made so that the final thickness was 5 mm less than the end of rolling thickness.
- the static mechanical properties in tension in other words the tensile strength Rm, the conventional yield strength at 0.2% elongation Rp0.2, and the elongation at break A%, were determined. by a tensile test according to standard NF EN ISO 6892-1 (2016) in the long transverse direction (TL), the sampling and the direction of the test being defined by standard EN 485 (2016). The sample is taken before the last machining step. The characterizations were carried out in the transverse long direction.
- the residual stresses were evaluated on the sheet before machining by measuring the average deflection on bars machined in the L or TL direction at% and at 1 ⁇ 2 thickness. Two full thickness bars are taken, in the L and TL direction, by sawing before the final machining of the sheet.
- the sampling dimensions are:
- TL direction bar 450mm (TL direction) x 35mm (L direction) x thickness.
- the as-rolled L-TL faces are not machined so that the thickness of the machined bars remains the thickness of the sheet.
- the bar is placed on two supports 390 mm apart (the supports are represented by triangles 1 in Figure 3 -A).
- a displacement sensor (represented by an arrow 22 in FIG. 3A) is used to measure the deflection of the bar. The steps are as follows:
- the heating is limited to 10 ° C so as to avoid any influence of the machining conditions on the deflection measurements made.
- the product of the maximum deflection deviation in the L and TL directions multiplied by the rolling exit thickness is greater than 5.1; whereas with the alloy according to the invention this product is always less than 3.
- Figure 1 shows the granular structure after anodic oxidation of alloy A after hot rolling to a thickness of 25 mm.
- Figure 1b shows the granular structure after anodic oxidation of alloy B after hot rolling 25 mm thick.
- a recrystallized zone is observed close to the surfaces while in Figure 1b, this zone is not observed the granular structure is fibrous, that is to say not recrystallized, throughout the thickness of the rolled product. hot.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Metal Rolling (AREA)
- Sliding-Contact Bearings (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1911024A FR3101641B1 (fr) | 2019-10-04 | 2019-10-04 | Tôles de précision en alliage d’aluminium |
PCT/FR2020/051704 WO2021064320A1 (fr) | 2019-10-04 | 2020-09-29 | Toles de precision en alliage d'aluminium |
Publications (1)
Publication Number | Publication Date |
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EP4038214A1 true EP4038214A1 (fr) | 2022-08-10 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP20793025.6A Pending EP4038214A1 (fr) | 2019-10-04 | 2020-09-29 | Toles de precision en alliage d'aluminium |
Country Status (6)
Country | Link |
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US (1) | US20220389557A1 (ko) |
EP (1) | EP4038214A1 (ko) |
KR (1) | KR20220084288A (ko) |
CN (1) | CN114450425B (ko) |
FR (1) | FR3101641B1 (ko) |
WO (1) | WO2021064320A1 (ko) |
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CN113265569B (zh) * | 2021-05-14 | 2022-11-11 | 江苏亚太轻合金科技股份有限公司 | 一种6系列高强度细晶粒锻造汽车控制臂用铝合金棒材的制备方法 |
CN113444933B (zh) * | 2021-07-20 | 2023-06-23 | 中铝瑞闽股份有限公司 | 一种高强度阳极氧化铝薄板及其制备方法 |
FR3136242B1 (fr) | 2022-06-01 | 2024-05-03 | Constellium Valais | Tôles pour éléments de chambres à vide en alliage d’aluminium |
FR3138057B1 (fr) * | 2022-07-22 | 2024-07-19 | Constellium Valais Sa Ag Ltd | Tôles de précision en alliage d’aluminium 7XXX |
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JPH03287738A (ja) * | 1990-04-03 | 1991-12-18 | Kobe Steel Ltd | 真空ろう付け法により組立てられる熱交換器用フィン材及びその製造方法 |
US5776269A (en) * | 1995-08-24 | 1998-07-07 | Kaiser Aluminum & Chemical Corporation | Lead-free 6000 series aluminum alloy |
DE10163039C1 (de) * | 2001-12-21 | 2003-07-24 | Daimler Chrysler Ag | Warm- und kaltumformbares Bauteil aus einer Aluminiumlegierung und Verfahren zu seiner Herstellung |
JP4168066B2 (ja) | 2006-08-11 | 2008-10-22 | 株式会社神戸製鋼所 | プラズマ処理装置に用いられる陽極酸化処理用アルミニウム合金およびその製造方法、陽極酸化皮膜を有するアルミニウム合金部材、ならびにプラズマ処理装置 |
JP4410835B2 (ja) | 2008-03-28 | 2010-02-03 | 株式会社神戸製鋼所 | アルミニウム合金厚板およびその製造方法 |
FR2996857B1 (fr) | 2012-10-17 | 2015-02-27 | Constellium France | Elements de chambres a vide en alliage d'aluminium |
FR3044682B1 (fr) * | 2015-12-04 | 2018-01-12 | Constellium Issoire | Alliage aluminium cuivre lithium a resistance mecanique et tenacite ameliorees |
EP3464659B2 (en) * | 2016-06-01 | 2023-07-12 | Aleris Aluminum Duffel BVBA | 6xxx-series aluminium alloy forging stock material and method of manufacting thereof |
FR3063740B1 (fr) | 2017-03-10 | 2019-03-15 | Constellium Issoire | Elements de chambres a vide en alliage d’aluminium stables a haute temperature |
US11519058B2 (en) * | 2017-12-21 | 2022-12-06 | Constellium Extrusions Decin S.R.O. | 6XXX aluminium alloy extruded forging stock and method of manufacturing thereof |
CN108239712A (zh) | 2018-03-04 | 2018-07-03 | 广西平果百矿高新铝业有限公司 | 一种航空用6082铝合金板材及其生产工艺 |
CN108239713B (zh) | 2018-03-04 | 2020-03-31 | 广西平果百矿高新铝业有限公司 | 一种电子产品外观用铝合金板材及其生产工艺 |
-
2019
- 2019-10-04 FR FR1911024A patent/FR3101641B1/fr active Active
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2020
- 2020-09-29 WO PCT/FR2020/051704 patent/WO2021064320A1/fr unknown
- 2020-09-29 KR KR1020227012016A patent/KR20220084288A/ko active Search and Examination
- 2020-09-29 CN CN202080067910.5A patent/CN114450425B/zh active Active
- 2020-09-29 EP EP20793025.6A patent/EP4038214A1/fr active Pending
- 2020-09-29 US US17/765,345 patent/US20220389557A1/en active Pending
Also Published As
Publication number | Publication date |
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CN114450425B (zh) | 2024-04-05 |
FR3101641A1 (fr) | 2021-04-09 |
FR3101641B1 (fr) | 2022-01-21 |
KR20220084288A (ko) | 2022-06-21 |
WO2021064320A1 (fr) | 2021-04-08 |
CN114450425A (zh) | 2022-05-06 |
US20220389557A1 (en) | 2022-12-08 |
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