EP3004452A1 - Chiffon de nettoyage - Google Patents

Chiffon de nettoyage

Info

Publication number
EP3004452A1
EP3004452A1 EP14721204.7A EP14721204A EP3004452A1 EP 3004452 A1 EP3004452 A1 EP 3004452A1 EP 14721204 A EP14721204 A EP 14721204A EP 3004452 A1 EP3004452 A1 EP 3004452A1
Authority
EP
European Patent Office
Prior art keywords
cleaning cloth
pvf
carrier material
textile carrier
textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14721204.7A
Other languages
German (de)
English (en)
Other versions
EP3004452B1 (fr
Inventor
Volker RITTHALER
Jörg Dunkel
Jörg Hausdorf
Gerrius VROOM
Andreas Eisenhut
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carl Freudenberg KG
Original Assignee
Carl Freudenberg KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carl Freudenberg KG filed Critical Carl Freudenberg KG
Publication of EP3004452A1 publication Critical patent/EP3004452A1/fr
Application granted granted Critical
Publication of EP3004452B1 publication Critical patent/EP3004452B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/16—Cloths; Pads; Sponges
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/04—Processes in which the treating agent is applied in the form of a foam
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics

Definitions

  • the invention relates to a cleaning cloth having a textile carrier material and a coating or impregnation thereon.
  • Cleaning cloth combines in a novel way good cleaning properties with good sliding properties.
  • the cleaning cloth also shows a very good cleaning effect for both hydrophilic and hydrophobic dirt.
  • the cleaning cloths may have a simple structure, for example by being formed from a monolayer textile base body. It is important for the cleaning cloth that it absorbs the dirt from the surface to be cleaned well and returns as completely as possible during the wringing process. In addition, the water absorption and -abgäbe the cloth is important. On the one hand, water is used to dissolve adhering water
  • the cleaning cloth should slide rather easily to achieve a good ergonomics and low effort when wiping.
  • users prefer often wipes with a higher friction, so that adhering dirt can be better removed, or the cleaning process is also haptically detectable.
  • textile carrier materials can be provided with a coating or impregnation.
  • textile materials can be provided with a polyurethane (PU) coating or impregnation.
  • PU polyurethane
  • the application of the PU coating or impregnation mass is carried out according to common practice of the type that the substrate is immersed in a solution of PL ) and dimethylformamide (DMF).
  • Another known method is the coating or impregnation of a textile carrier material consisting of PVA (polyvinyl alcohol) fibers with a PVF microfoam.
  • PVA polyvinyl alcohol
  • Coating material is achieved.
  • the object of the invention is based, a
  • Cleaning cloth should also be achieved a very good cleaning effect.
  • the cleaning cloth should be both hydrophilic and
  • the cleaning cloth the dirt, especially loose dirt particles, when flushing again can easily and easily. As a result, it can be prevented, for example, that recorded sand (eg with quartz components) when cleaning chromed / polished surfaces scratched or damaged.
  • the cleaning cloth is a
  • the coating, or impregnation should show sufficient adhesion to the textile substrate to a corresponding
  • Range of action AB a weight loss of the cleaning cloth of less than 5 wt.% Is present.
  • a cleaning cloth which contains a textile carrier material comprising fibers of a hydrophobic material, in particular micro filaments of a hydrophobic material, wherein the textile carrier material has areas which are provided with a PVF foam, in particular a PVF microfoam such as
  • PVF foam can be present as a coating and / or impregnation.
  • hydrophobic carrier material that can be mixed with both a PVF foam
  • PVF microfoam provided and not provided with a PVF foam, in particular a PVF microfoam regions.
  • PVF foam in particular a PVF microfoam regions.
  • PVF foam provided areas uncoated, or not impregnated before.
  • the PVF (polyvinyl formal) foam can be formed by reacting PVA with formaldehyde, as known to those skilled in the art. This reduces the water solubility of the PVA.
  • the PVF foam preferably has a solubility in water at 100 ° C. of less than 5% by weight.
  • the textile carrier material preferably consists at least proportionally
  • the textile carrier material consists of more than 60% by weight, more preferably 80% by weight to 100% by weight
  • Microfibers This exhibits a high water uptake capacity (e.g., in% over that of the hydrophobic, and hence oleophilic, material because of the capillary action of the knitted microfiber yarns, despite the fibers made of a hydrophobic and thus oleophilic material
  • Oleophilia of the microfiber material by combining with the hydrophilic PVF foam an amphiphilic product can be obtained.
  • the cleaning cloth according to the invention has hydrophobic materials in the form of the fibers of a hydrophobic material in combination with hydrophilic materials (PVF foam) and thus is amphiphilic as a whole. For this reason, the cleaning cloth according to the invention has a high cleaning effect both for oleophilic and for hydrophilic dirt, which makes it suitable for a variety of applications.
  • the cleaning cloth according to the invention also has an excellent
  • PVF polyvinyl styrene foam
  • An advantage of the use of PVF is further that it is particularly absorbent due to the free OH groups per se.
  • the hydrophilicity of the PVF material can be further increased when used in the form of a micro-foam.
  • the microfoam preferably has pore sizes of less than ⁇ . This material has due to the fine porosity of the micro-foam structure on an even higher hydrophilicity.
  • the PVF micro-foam, the fibers and optionally yarns of the textile substrate largely or even completely enveloped whereby a stable mechanical connection between the substrate and
  • Coating / impregnation can be achieved. This is advantageous in that the PVF microfoam actually has no good adhesion to the hydrophobic fiber of the carrier material.
  • a cleaning cloth which comprises a textile carrier material comprising fibers of a hydrophobic material, in particular Contains micro-continuous filaments of a hydrophobic material, wherein the textile carrier material at least partially with a PVF foam,
  • PVF foam in the total weight of the cleaning cloth is at most 50% by weight, preferably less than 30% by weight. Practical tests have shown that due to the low proportion of PVF foam in the cleaning cloth this also has an amphiphilic character.
  • a microfiber-containing carrier material in particular a knitwear, is combined with a PVF microfoam. It is advantageous that by projecting microfibers still a good cleaning performance can be achieved especially in fatty soiling and also the PVF microfoam does not significantly reduce the per se good water absorption capacity of the microfiber-containing carrier material. In addition, in this embodiment recorded dirt particles can be washed out very well.
  • Knitted a high washing stability is further facilitated by the fact that the knitted or knitted base material already in itself a high
  • the PVF coating and / or impregnation advantageously has a basis weight of 10 to 150 g / m 2 , preferably from 50 to 100 g / m 2 .
  • the textile advantageously has a basis weight of 10 to 150 g / m 2 , preferably from 50 to 100 g / m 2 .
  • the textile advantageously has a basis weight of 10 to 150 g / m 2 , preferably from 50 to 100 g / m 2 .
  • the textile advantageously has a basis weight of 10 to 150 g / m 2 , preferably from 50 to 100 g / m 2 .
  • Carrier material advantageously a basis weight of 100 to 250 g / m 2 , preferably from 150 to 200 g / m 2 .
  • hydrophobic As a base material for the textile carrier material fibers of a hydrophobic material are used according to the invention.
  • the term "hydrophobic" is understood according to the invention in the conventional sense.
  • materials are considered to be hydrophobic, in which water has a contact angle of greater than or equal to 90 ° on the surface of a compact body formed from them.
  • Contact angle can be known e.g. be determined with a contact angle measuring device from Krüss.
  • Fibers, in particular microfibers, which contain or consist of the following materials have proven to be particularly suitable: polyamide or polyester, hydrophobized viscose, modified polyesters, polyacrylonitrile, triacetate, acetate, polyolefins such as polyethylene and polypropylene, polyvinyl chloride and / or mixtures thereof.
  • Particularly preferred according to the invention is the use of polyamide, in particular polyamide 6 or 66, polyethylene and / or polyester, in particular PET and / or mixtures thereof.
  • such a textile carrier material contains polyester, in particular PET and / or modified polyester. This can be used either as an exclusive raw material or blended with other polymeric fibers (e.g., polyamide fibers, especially PA6).
  • the used titer of the fiber is preferably in the range between 0.05 and 3 dtex. Most preferably, it is in the range of a microfiber, that is between 0.1 and 1 dtex.
  • the advantage of using the microfibers is that they show good cleaning results, are very soft and thus provide a pleasant feel. Particularly good cleaning results are achieved with microfibers having a titre of 0.05 to 1.0 dtex, preferably 0.1 to 0.7 dtex.
  • the textile substrate comprises multi-component continuous filaments, preferably
  • Bicomponent endless filaments which have a titre of 1, 5 to 3 dtex in the non-split state and the new state of the fabric at least partially, preferably at least 60%, to
  • the sheet has a total basis weight of from 90 to 350 g / m 2 , more preferably from 200 to 300 g / m 2 .
  • the sheet preferably contains the hydrophobic fibers in an amount of 80 to 250 g / m 2 , more preferably 150 to 200 g / m 2 .
  • the hydrophobic fibers used for the production of the textile fabric can be provided inexpensively in a wide variety of designs and colors, and the coating or impregnation can be applied in a simple manner by conventional methods.
  • the textile substrate both on one side and on both sides with a PVA-containing Coated dispersion or a PVA-containing polymer solution, or
  • the cleaning cloth can be inexpensive with on both sides
  • an impregnation preferably takes place.
  • the PVF foam is particularly easy to get inside the textile
  • the sheet can be coated with a full-surface coating, or
  • Coating or impregnation is to be understood that the distance between areas provided with PVF foam and areas which are not provided with PVF foam is on average less than 5 mm.
  • full-surface coating as stated above, have areas that are not provided with a PVF foam.A advantageous in this embodiment is that the full-surface
  • Coating or impregnation solidifies the sheet and thus increases its stability.
  • the removal of a larger amount of liquid from a surface to be cleaned can be accomplished particularly well.
  • Invention is the coating, or impregnation, however, on both sides of the cleaning cloth before, as this the beneficial effects of the invention can be particularly well exploited.
  • At least one surface of the cleaning cloth but preferably both surfaces are designed so that when cleaning a smooth surface with a contact pressure of 0.05 N / cm 2 , in particular from 0.05 N / cm 2 to 0 , 5 N / cm 2 , both the hydrophobic fibers and optional further constituents, for example yarns, of the textile carrier material as well as the applied by coating, or impregnation PVF foam comes into contact with the surface to be cleaned.
  • Cleaning results can be achieved with cleaning cloths according to the invention, in which 1 - 60%, but preferably 5 - 20% of
  • Total surface which is in contact with a smooth surface to be cleaned at a contact pressure of 0.05 N / cm 2 , in particular from 0.05 N / cm 2 to 0.5 N / cm 2 , through the fibers and / or yarns of the textile material and the remaining 99-40%, but preferably 95-80% of the surface in contact with the PVF foam.
  • both consolidated and unconsolidated textile base materials can be used as the textile fabric.
  • the textile substrate is at least partially mechanically, thermally and / or chemically solidified.
  • the consolidation of the randomly arranged or partially aligned fibers can be effected mechanically by needling and / or thermally and / or chemically.
  • the fabric is preferably in the form of a nonwoven fabric, a knitted fabric, a knitted fabric, a fabric, fabric,
  • Braid a knitted fabric, a felt, fleece, a tufted fabric, a fabric, combinations of the like and other planar structures.
  • Knitted fabric has the advantage that fibers in large quantities and with a relatively even distribution in the Fabrics can be introduced.
  • the fibers are in the knitted fabric mechanically stable before and thus require no further attachment to each other.
  • Nonwovens offer the advantage that they can be produced easily and inexpensively.
  • Support material at least partially designed as loops containing knitwear.
  • loops according to the invention is understood to mean that both closed loops and the alternative cut-off loops, so protruding fiber ends instead of curved continuous fibers is included.
  • the loops preferably consist at least partly of microfibers, in particular microfilamentary filaments.
  • the three-dimensional structure of the knitwear can be exploited that the coating, or
  • Impregnation is applied in such an amount that the loops are not completely covered at their respective vertices by the coating, or impregnation.
  • the coating or impregnation.
  • At least partially protrude loops outwards from the center plane of the cleaning cloth are uncoated, at least proportionally, at their respective vertex points, while the loops are at least partially coated in the area of the center plane of the cleaning cloth.
  • Invention is the degree of coverage of the loops at their respective
  • the cleaning cloth thus preferably has a cross-section which has a higher proportion of PVF foam in the middle than in the outer areas. Most preferably, at least 80 %, preferably at least 90% of the cleaning cloth on such a cross section.
  • Coating or impregnating mass can be achieved.
  • Support material on the surface of the coated or impregnated cleaning cloth are subsequently exposed by other methods such as grinding the cloth surfaces.
  • microfibers has appropriate amphiphilic character and is versatile.
  • the fine micro-fibers protruding from the surface contribute to a good cleaning performance of the microfibers
  • the height of the loops may vary depending on the application.
  • loop heights over the Center plane in the range of 0.5 mm to 5 mm, preferably achieved in the range 1 mm to 2 mm.
  • the loop densities in the direction and / or transverse to the courses may vary depending on the application and, for example, in the range of 2 to 9 loops per cm, preferably in the range of 4-7
  • the basis weight of the cleaning cloth can vary depending on the desired application. As suitable for most purposes, basis weights of 90 to 350 g / m 2 have been found.
  • microfibers are used as fibers of a hydrophobic material, they can be produced by splitting.
  • the starting material is preferably spun as a multi-component continuous filament, for example as a bicomponent endless filament with a titer of greater than 1 dtex, preferably 1-3 dtex and then divided into the components (split).
  • a titer of greater than 1 dtex preferably 1-3 dtex and then divided into the components (split).
  • the starting filaments are split into microfilament filaments after being felt and before use.
  • the fibers may be composed of polymers containing additives, such as color pigments, permanently acting
  • the textile carrier material may further comprise colored fibers, wherein the coloring of the multicomponent continuous filaments by spin dyeing
  • a printing pattern of abrasives for example polishing particles, is applied to the PVF foam-coated or impregnated side of the textile fabric.
  • the polishing particles may be formed, for example, by silica. These particles result in a cleaning cloth with a slightly abrasive effect.
  • the scourer can in a simple
  • Printing process can be applied in many varieties on the textile substrate. Thus, an additional cleaning effect as well as a decorative effect for the textile structure can be achieved. For some applications, it may be appropriate if the
  • pretreat the textile substrate e.g. a printing, calendering or partial embossing in question.
  • a colorless PVF foam in particular the
  • the cleaning cloth for example, in the following ways:
  • the textile substrate is already partially or fully colored
  • the PVA solution used to make the PVF foam can also be mixed with a colored pigment.
  • a colorless, and therefore cheaper carrier material can be selected and the color of the cleaning cloth can be omitted entirely or can be selected and adjusted only in the later step of the PVF coating or impregnation.
  • the dye can be chosen so that it is permanently wash stable and introduced in particular without bleeding in the PVF material.
  • a further subject of the present invention comprises a process for producing the cleaning cloth according to the invention, comprising the following steps:
  • a textile base material comprising fibers made of a hydrophobic material, in particular microfibers made of a hydrophobic material, is produced in a manner known per se and optionally solidified.
  • multicomponent fibers are used as starting material multicomponent fibers.
  • PVA is preferably in the form of an aqueous solution, for example by conventional application methods, for example the padding method, a doctor blade method, a spray application, a
  • Pflatatk applied with a slot nozzle or a slot die on the textile base material. It has proven particularly suitable to impregnate the textile base material with an aqueous PVA solution.
  • Impregnation thickness be squeezed off, scraped off, sucked off or otherwise removed.
  • the base material thus treated may be in an aqueous salt solution and / or suspension, for example a
  • the aqueous PVA solution and / or suspension contains further addition substances, such as e.g. Color pigments or other additives or particles, such as the o.g. Abrasives.
  • the PVA solution preferably contains a solids content of PVA between 1 and 10
  • Weight% preferably between 3 and 7 wt .-%.
  • the coating or impregnation does not completely cover the textile carrier material, but rather portions of the carrier material, e.g. protruding from the mid-plane loops on the coating, or impregnation also protrude.
  • PVF Application amount of PVF can be adjusted so that only a part of the surface of the cleaning cloth is coated or impregnated. This can be achieved by a) appropriate metering of the coating, or Impregnation amount of the PVA solution (eg by impregnation, squeezing and / or application of the PVA solution over the entire width using rollers, spray heads, etc. Or b) by distributed over the surface partial application of the PVA solution ("islands Or c) by subsequent sanding of the PVF foam layer located on the two outer sides of the cleaning cloth and associated exposure of the embedded
  • a three-dimensional structure for example a knitted fabric
  • a textile structure can be produced in a simple and highly productive manner, which has a PVF-containing coating or impregnation on one or both sides.
  • the PVF-containing coating or impregnation can penetrate into the textile base material, whereby it is firmly anchored in the textile base material.
  • the textile base material is coated at the same time and on both sides of a plant.
  • the PVF-containing coating, or impregnation can be applied to the textile base material in one operation, whereby a particularly high efficiency in the production of the textile structure is achieved.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Knitting Of Fabric (AREA)

Abstract

L'invention concerne un chiffon de nettoyage, lequel contient un matériau de support textile comprenant des fibres constituées d'un matériau hydrophobe, en particulier des micro-filaments continus constitués d'un matériau hydrophobe. Le matériau de support textile comporte des zones pourvues d'une mousse de polyfluorure de vinyle, en particulier d'une micro-mousse de polyfluorure, ainsi que des zones non pourvues d'une mousse de polyfluorure de vinyle, en particulier d'une micro-mousse de polyfluorure de vinyle, et est caractérisé par une action nettoyante très satisfaisante pour la saleté aussi bien hydrophile qu'hydrophobe.
EP14721204.7A 2013-05-28 2014-04-11 Chiffon de nettoyage Active EP3004452B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013008984.0A DE102013008984A1 (de) 2013-05-28 2013-05-28 Reinigungstuch
PCT/EP2014/000971 WO2014191070A1 (fr) 2013-05-28 2014-04-11 Chiffon de nettoyage

Publications (2)

Publication Number Publication Date
EP3004452A1 true EP3004452A1 (fr) 2016-04-13
EP3004452B1 EP3004452B1 (fr) 2019-02-20

Family

ID=50639414

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14721204.7A Active EP3004452B1 (fr) 2013-05-28 2014-04-11 Chiffon de nettoyage

Country Status (7)

Country Link
EP (1) EP3004452B1 (fr)
KR (1) KR101825180B1 (fr)
CN (1) CN105247133B (fr)
DE (1) DE102013008984A1 (fr)
ES (1) ES2720434T3 (fr)
RU (1) RU2635602C2 (fr)
WO (1) WO2014191070A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021037485A1 (fr) 2019-08-30 2021-03-04 Carl Freudenberg Kg Article de nettoyage à propriétés de résistance à l'encrassement

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Publication number Priority date Publication date Assignee Title
DE102017100368A1 (de) * 2017-01-10 2018-07-12 Vorwerk & Co. Interholding Gmbh Eigenständige Regenerationseinheit zur Regeneration eines Reinigungselementes
DE102017002129A1 (de) * 2017-03-08 2018-09-13 Carl Freudenberg Kg Reinigungsartikel
DE102019123274A1 (de) 2019-08-30 2021-03-04 Carl Freudenberg Kg Reinigungsartikel, der Mikrokapseln enthält
ES1247780Y (es) * 2020-01-22 2020-09-04 Fita Juan Emilio Pastor Textil mejorado para articulos de limpieza

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WO2010065270A2 (fr) * 2008-11-25 2010-06-10 3M Innovative Properties Company Dispositif et procédé pour nettoyer des bandes flexibles

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021037485A1 (fr) 2019-08-30 2021-03-04 Carl Freudenberg Kg Article de nettoyage à propriétés de résistance à l'encrassement

Also Published As

Publication number Publication date
CN105247133B (zh) 2017-04-26
DE102013008984A1 (de) 2014-12-04
EP3004452B1 (fr) 2019-02-20
RU2015155612A (ru) 2017-07-04
KR20160012219A (ko) 2016-02-02
ES2720434T3 (es) 2019-07-22
KR101825180B1 (ko) 2018-02-02
WO2014191070A1 (fr) 2014-12-04
CN105247133A (zh) 2016-01-13
RU2635602C2 (ru) 2017-11-14

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