EP2956422B2 - Vitrage antisolaire - Google Patents
Vitrage antisolaire Download PDFInfo
- Publication number
- EP2956422B2 EP2956422B2 EP14705126.2A EP14705126A EP2956422B2 EP 2956422 B2 EP2956422 B2 EP 2956422B2 EP 14705126 A EP14705126 A EP 14705126A EP 2956422 B2 EP2956422 B2 EP 2956422B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- glazing
- transparent
- solar
- radiation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000010410 layer Substances 0.000 claims description 160
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 107
- 239000011787 zinc oxide Substances 0.000 claims description 54
- 239000002346 layers by function Substances 0.000 claims description 51
- 239000000758 substrate Substances 0.000 claims description 37
- 239000011521 glass Substances 0.000 claims description 33
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 31
- 229910052709 silver Inorganic materials 0.000 claims description 31
- 239000004332 silver Substances 0.000 claims description 31
- 238000000576 coating method Methods 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 17
- 229910052718 tin Inorganic materials 0.000 claims description 17
- 239000011135 tin Substances 0.000 claims description 17
- 238000009736 wetting Methods 0.000 claims description 17
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 16
- 150000004767 nitrides Chemical group 0.000 claims description 16
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 229910052710 silicon Inorganic materials 0.000 claims description 14
- 239000010703 silicon Substances 0.000 claims description 14
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 13
- 229910001120 nichrome Inorganic materials 0.000 claims description 13
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 13
- 229910045601 alloy Inorganic materials 0.000 claims description 12
- 239000000956 alloy Substances 0.000 claims description 12
- -1 silicon nitrides Chemical class 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 238000010521 absorption reaction Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000011241 protective layer Substances 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- ZARVOZCHNMQIBL-UHFFFAOYSA-N oxygen(2-) titanium(4+) zirconium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4] ZARVOZCHNMQIBL-UHFFFAOYSA-N 0.000 claims description 5
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 claims description 4
- 229910010037 TiAlN Inorganic materials 0.000 claims description 3
- 238000009830 intercalation Methods 0.000 claims 4
- 238000002834 transmittance Methods 0.000 claims 2
- 239000004411 aluminium Substances 0.000 claims 1
- 229960001296 zinc oxide Drugs 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 description 51
- 230000005855 radiation Effects 0.000 description 49
- 230000005540 biological transmission Effects 0.000 description 28
- 230000003287 optical effect Effects 0.000 description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 16
- 229910052726 zirconium Inorganic materials 0.000 description 14
- 238000000151 deposition Methods 0.000 description 12
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 11
- 239000012298 atmosphere Substances 0.000 description 11
- 230000008021 deposition Effects 0.000 description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 229910052786 argon Inorganic materials 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000005496 tempering Methods 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 239000011651 chromium Substances 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- 229910052721 tungsten Inorganic materials 0.000 description 7
- 230000002745 absorbent Effects 0.000 description 6
- 239000002250 absorbent Substances 0.000 description 6
- 230000007935 neutral effect Effects 0.000 description 6
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 6
- 239000005361 soda-lime glass Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 230000004888 barrier function Effects 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- KYKLWYKWCAYAJY-UHFFFAOYSA-N oxotin;zinc Chemical compound [Zn].[Sn]=O KYKLWYKWCAYAJY-UHFFFAOYSA-N 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000005452 bending Methods 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 229910052758 niobium Inorganic materials 0.000 description 4
- 239000010955 niobium Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000012300 argon atmosphere Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910001092 metal group alloy Inorganic materials 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 229910006404 SnO 2 Inorganic materials 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000031700 light absorption Effects 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000000135 prohibitive effect Effects 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- NCGICGYLBXGBGN-UHFFFAOYSA-N 3-morpholin-4-yl-1-oxa-3-azonia-2-azanidacyclopent-3-en-5-imine;hydrochloride Chemical compound Cl.[N-]1OC(=N)C=[N+]1N1CCOCC1 NCGICGYLBXGBGN-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 229910003087 TiOx Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- JUVGUSVNTPYZJL-UHFFFAOYSA-N chromium zirconium Chemical compound [Cr].[Zr] JUVGUSVNTPYZJL-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- HLLICFJUWSZHRJ-UHFFFAOYSA-N tioxidazole Chemical compound CCCOC1=CC=C2N=C(NC(=O)OC)SC2=C1 HLLICFJUWSZHRJ-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- AKJVMGQSGCSQBU-UHFFFAOYSA-N zinc azanidylidenezinc Chemical compound [Zn++].[N-]=[Zn].[N-]=[Zn] AKJVMGQSGCSQBU-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
Definitions
- the field of the invention is that of solar control glazing consisting of a glass substrate carrying a multilayer stack, of which at least one functional thin layer reflecting infrared radiation confers solar control properties. Associated with this functional layer are dielectric layers whose role is in particular to adjust the properties of reflection, transmission, tint and protection against mechanical or chemical alterations of the properties of the stack.
- the stack also includes a solar radiation absorbing layer which is intended to enhance the solar control properties conferred by the functional layer reflecting infrared radiation.
- the adjustment of the thickness of this layer absorbing solar radiation allows the adjustment of the light absorption and of the light transmission.
- the invention relates to glazing intended to furnish buildings but also motor vehicles. Depending on these uses, certain required properties may differ.
- the functionalities of solar control glazing are multiple. They relate in particular to the prevention of overheating of the interior of the passenger compartment of a motor vehicle, in particular vis-à-vis solar radiation passing through a transparent roof, or of the premises of a building exposed to solar radiation when this one is intense enough. According to certain embodiments, this prevention of heating can be obtained while maintaining an appropriate light transmission.
- the optical properties are defined for glazing whose substrate is made of ordinary clear “float” glass 4 mm thick.
- the choice of substrate obviously influences these properties.
- the light transmission under 4 mm, in the absence of a coating is approximately 90% and the reflection 8%, measured with a source conforming to the "daylight” illuminant standardized D65 by the CIE and at a solid angle of 2°.
- the energy measurements, for their part, are made according to the EN 410 standard.
- glass is intended to denote an inorganic glass. By this is meant a glass with a thickness at least greater than or equal to 0.5 mm and at most less than or equal to 20.0 mm, preferably at least greater than or equal to 1.5 mm and at most less than or equal to 10.0 mm , comprising silicon as one of the indispensable constituents of the vitreous material.
- the thickness can for example be 1.5 or 1.6 mm, or 2 or 2.1 mm.
- it will for example be around 4 or 6 mm. Clear, extra-clear or mass-coloured silico-soda-lime glasses are preferred.
- the presence of a multi-layer stack can cause color problems. Most often the market requires that the glazings offer, both in transmission and in reflection, a coloring that is as neutral as possible and therefore of a relatively gray appearance. Slightly green or bluish colorations are also possible. However, much more pronounced shades, for example blue or green, are also sometimes requested to satisfy particular aesthetic criteria.
- the multilayer stacks, and in particular the natures, indexes and thicknesses of the dielectric layers surrounding the functional layers, are chosen in particular to control these colorations.
- Automobile glazing in theory, can be multiple in order to give them a better insulation property, in particular thermal insulation, as is generally the case with building glazing.
- automobile glazing bearing a multilayer stack of the type of the invention is laminated, the multilayer stack being arranged inside the laminate.
- the coating systems according to the invention must still lend themselves to shaping glazing.
- Those used in vehicles are in particular the subject of heat treatments during forming, in particular the bending of the glass sheets, or even during tempering intended to give them in particular reinforced mechanical properties.
- Certain glazings for buildings must also often undergo a tempering heat treatment to give them reinforced mechanical properties, in particular to resist thermal shock due to temperature differences between sunny areas and shaded areas of the same glazing installed on the facade of buildings. a building exposed to the sun.
- the layers used according to the invention must withstand these treatments without their properties being degraded or their aesthetic appearance being modified. Treatments of this type require temperatures that exceed 600° C. for about ten minutes. Subjected to these temperatures, the layers must retain their qualities and properties.
- the aesthetic aspect is also of great commercial importance for solar protection glazing.
- the glazing has thermal anti-solar properties, it is required also that it contributes to the aesthetic quality of the whole of which it is part.
- the prior art proposes sunscreen glazing comprising at least one functional layer reflecting infrared radiation and a layer absorbing solar radiation surrounded by dielectric layers.
- the patent application WO 2005/091864 A2 describes a multilayer stack comprising two functional layers based on silver and a layer absorbing solar radiation, in the form of NiCr, which makes it possible to adjust the light transmission of the coated glazing.
- the NiCr absorbent layer is enclosed between two layers of silicon nitride and this assembly is placed between the substrate and the first silver layer, under which is placed a ZnO wetting layer.
- the stack may undergo a tempering heat treatment.
- the patent application WO 2009/032032 A1 describes the same structure consisting of the metal NiCr absorbing solar radiation enclosed between two layers of silicon nitride, but this time arranged between the two functional layers of silver to solve a tint problem when the glazing is observed at oblique incidence.
- Some examples have undergone a heat-tempering treatment with a relatively low ( ⁇ 3) tint variation ( ⁇ E*) in reflection on the substrate side (outside).
- ⁇ E* tint variation
- a ZnO wetting layer is also placed under the silver functional layers.
- the patent application WO 02/48065 A1 describes in some examples a layer absorbing solar radiation formed of a nitride, such as TiN, enclosed between two layers of silicon nitride, the assembly being placed between the two functional layers of silver. A ZnO wetting layer is also placed under the silver layers. Some examples can undergo tempering heat treatment with relatively small optical changes.
- the patent application WO 2010/48065 describes transparent solar control glazing. After heat treatment at high temperature, in particular to carry out thermal toughening, the solar control glazing according to these prior proposals exhibit a veil with unsightly stains, which is not aesthetically acceptable for obtaining a glazing with high optical quality according to commercial demand.
- the object of the invention is in particular to overcome this drawback of the prior art.
- an object of the invention is to provide a glazing provided with a multilayer stack with solar protection property capable of undergoing a heat treatment at high temperature without deterioration of its optical quality.
- An object of the invention is also to provide a glazing provided with a multilayer stack with solar protection and aesthetic properties which is capable of undergoing heat treatment at high temperature, of the tempering and/or bending type, preferably without significant modification of its tint, in particular in reflection on the substrate side, of the total light and energy transmission and of the total light and energy reflection, on the substrate side and on the stacking side, so that a non-heat-treated glazing can be juxtaposed with its heat-treated version without an observer can detect a significant difference in the overall aesthetic appearance.
- the modification of the optical and energy properties is less than 6%, advantageously less than 4%, and ideally less than 2%.
- the invention in at least one of its embodiments, also aims to provide a glazing provided with a multilayer stack having good stability from the thermal, chemical and mechanical point of view.
- the invention relates to a transparent solar control glazing according to claim 1.
- the dielectric coatings, and in particular the interlayer transparent oxide layer must be capable of undergoing the heat treatment imposed on the substrate coated with the multilayer stack without deterioration or significant structural change, and without significant modification of the opto-energetic properties.
- the wetting layer based on zinc oxide has a beneficial effect on the crystal growth of the silver-based infrared radiation-reflecting functional layer and also acts favorably on the recrystallization of this functional layer during the heat treatment at high temperature. .
- the silver-based functional layer and the wetting layer are in the immediate vicinity of each other so that the wetting layer based on of zinc oxide can have a favorable effect on the functional layer, in particular during the deposition of the stack, but also during a heat treatment at high temperature, and in particular a beneficial effect on the crystal structure of silver.
- This therefore does not exclude there being a very thin layer of another material interposed between the wetting layer and the functional layer, for example having a geometric thickness of at most 1 nm.
- the wetting layer is directly in contact with this said functional layer.
- layer absorbing solar radiation for the purposes of the invention is meant a layer which absorbs part of the visible radiation, and which essentially consists of a material whose spectral extinction coefficient k ( ⁇ ) is at least 0 .2, preferably at least 0.3, at the wavelength 500 nm.
- the presence of a layer absorbing solar radiation makes it possible to filter the thermal energy found in the visible part of the spectrum.
- this filtering By associating this filtering with the reflection of the infrared radiation obtained thanks to the functional layer, it is possible to obtain glazing with solar control which is particularly effective in preventing the heating of premises or passenger compartments subjected to intense sunshine.
- the layer absorbing solar radiation cannot lose its absorption power, otherwise the efficiency of solar control will decrease significantly and the optical properties of the glazing will also be modified.
- Heat treatments in particular of the bending/tempering type, can also induce more or less significant modifications of the optical properties and in particular of the tints. Preferably, these variations must be minimized in such a way that the glazings, whether thermally treated or not, have a practically unchanged appearance.
- the light absorption therefore the absorption of solar radiation in the visible part of the spectrum, due to the layer absorbing solar radiation, measured by depositing only this absorbing layer enclosed between its two dielectric layers on ordinary clear glass of 4 mm thick, measured on the glass side, is between 5% and 45%, preferably between 10% and 35%.
- the latter is inserted between two dielectric layers formed of a material chosen from among silicon or aluminum nitrides and their mixture.
- the minimum geometric thickness of each of these dielectric layers is 8 nm.
- the intermediate layer of transparent oxide can for example be formed by SnO 2 or TiO 2 .
- the intermediate layer of transparent oxide is based on an oxide chosen from mixed oxide of zinc and tin or mixed oxide of titanium and zirconium. These two oxides, and in particular the mixed oxide of zinc and tin, as an interlayer oxide, allow to obtain the best results in terms of the elimination of stains in the optical aspect after heat treatment at high temperature, as well as for the conservation, or even the reduction, of the electrical resistance and therefore of the emissivity.
- Zinc-tin mixed oxide comprises between 40% and 60% tin.
- the mixed titanium-zirconium oxide preferably comprises between 25% and 75% zirconium.
- the intermediate layer of transparent oxide has a geometric thickness comprised between 1 and 35 nm, advantageously between 3 and 25 nm, and preferentially comprised between 3 and 12 nm.
- This thickness makes it possible to obtain a favorable effect on the optical quality while preserving the other properties of the stack and easily accommodating manufacturing constraints and the possibilities of the layer deposition device.
- the adequate thickness also depends on the location of the absorbent layer, it must be best adapted to the configuration. For example, when the absorbent layer is in the first dielectric coating, the thickness will be relatively low because the total thickness of the first dielectric coating is generally relatively thin. On the other hand, if the absorbent layer is in the second dielectric coating, its thickness may be a little greater because the space available is greater.
- This intermediate layer of transparent oxide can also be multiple, that is to say formed of two different oxides, for example mixed zinc-tin oxide followed by a very thin layer of mixed titanium-zirconium oxide.
- the dielectric layers enclosing the layer absorbing solar radiation are based on silicon nitride, and advantageously essentially on silicon nitride, that is to say more than 90%, even 95% and even 98%, of silicon nitride.
- silicon nitride can be obtained from a silicon target, optionally doped with aluminum or boron, by cathode sputtering, using a magnetron, in a reactive nitrogen atmosphere. and argon.
- the silicon target is doped to give it the electrical conduction necessary for cathodic sputtering, for example doped with at most 10% by weight of aluminum or boron, for example between 2% and 4%.
- the silicon nitride layers in the finished stack may be slightly oxidized over part of their thickness. These layers of silicon nitrides can also be richer in silicon than the theoretical stoichiometry. They have a minimum geometric thickness of 8 nm.
- the layer absorbing solar radiation is essentially in metallic form.
- the metal may show traces of nitriding due to the deposition atmosphere polluted by the nitrogen of the neighboring deposition zones. These may be nitrogen leaks from the nitride deposition chambers which surround the absorbent layer, or the metal target may be placed in the same deposition chamber as the silicon target intended to form the silicon nitrides, knowing that the nitrogen will be primarily attracted by the silicon.
- the layer absorbing solar radiation is a metal chosen from among the alloys NiCr, NiCrW, WTa, WCr, NbZr, TaNiV, NbCr, CrZr and NiV, advantageously NiCrW and CrZr. It has been found that these metal alloys are particularly suitable in the context of the invention for combining both the optical quality after heat treatment, the energy performance and the chemical and mechanical durability of the stack.
- the NiCrW alloy preferably comprises at least 30% by weight of tungsten, preferably at least 35%, and advantageously at least 37% or at least 40%.
- the proportion of nickel in this alloy is at least 9% by weight, preferably at least 20% by weight and advantageously at least 25% by weight, for example 30, 35 or 40% by weight.
- the proportion Ni relative to Cr is preferably a proportion ranging from 90/10 to 50/50, advantageously around 80% of Ni for 20% of Cr.
- the proportion of NiCr relative to tungsten, in the NiCrW alloy can vary greatly, but preferably it varies between 10% of NiCr for 90% of W and 65% of NiCr for 35% of tungsten, advantageously between 40% of NiCr for 60% of W and 63% of NiCr for 37% of W.
- the CrZr alloy preferably comprises at least 25% by weight of chromium and at least 20% by weight of zirconium.
- the layer comprises at least 35%, and advantageously at least 40% and even at least 45% by weight of zirconium.
- the alloy comprises between 20 and 75% by weight of zirconium, advantageously between 25 and 75% or between 30 and 75% by weight of zirconium, and favorably between 45 and 65% by weight of zirconium
- the layer absorbing solar radiation is a nitride or a sub-nitride, that is to say a sub-stoichiometric nitrogen nitride. Different absorbent nitrides can be used, provided of course that they are not transparent.
- the layer absorbing solar radiation is a nitride chosen from TiN, NiCrWN, NiVN, TaN, CrN, ZrN, CrZrN, TiAlN, TiZrN, WN, SiZrN and SiNiCrN, and advantageously chosen from TiN and NiCrWN. It has also been found that these metal nitrides, and in particular TiN and NiCrWN, are particularly suitable in the context of the invention for combining both the optical quality after heat treatment, the energy performance and the chemical and mechanical durability of the stack. .
- NiCrWN nitride the preferred respective proportions of the various elements Ni, Cr and W are the same as indicated above for the NiCrW metal alloy, disregarding the presence of nitrogen.
- the stack may comprise a single silver-based functional layer.
- the layer absorbing solar radiation is placed between the substrate and said functional layer, the latter being deposited on a wetting layer based on zinc oxide. It is thus possible to obtain a glazing providing effective solar protection of relatively simple manufacture.
- the stack comprises at least two functional layers reflecting silver-based infrared radiation.
- This embodiment makes it possible to obtain a more selective glazing, that is to say which has a low solar factor, and therefore prevents the entry of heat, while maintaining a relatively high light transmission.
- the stack comprises three, or even four, functional layers based on silver.
- the selectivity of the glazings carrying these stacks is thus still significantly improved.
- the layer absorbing solar radiation can be placed either between the substrate and the first functional layer, or between the two functional layers.
- the layer absorbing solar radiation is located between the substrate and the first functional layer.
- the multilayer stack is arranged in position 2, that is to say that the coated substrate is on the outside side of the room and that the solar radiation passes through the substrate then the stack.
- This embodiment makes it possible to obtain high-performance solar control glazing, but it nevertheless has the disadvantage of absorbing heat radiation quite well and therefore tends to heat up. In the case of glazing with low light transmission, this heating may be such that it is necessary to carry out a heat treatment for mechanical reinforcement for each glazing.
- the layer absorbing solar radiation is located between the two functional layers based on silver.
- part of the calorific solar radiation is reflected by the first silver layer and the energy absorption of the stack is lower than in the first embodiment.
- interior light reflection is lower, which reduces the "mirror" effect inside the room and improves visibility through the glazing.
- the stack comprises three functional layers
- the energy absorption AE (according to the EN410 standard) of the glass substrate coated with the multilayer stack is less than 50%, preferably less than 45%, and advantageously less than 40%. We can thus more easily avoid the obligation to soak all the glazing of the same facade or the same building, and to soak only those which are likely to undergo thermal stresses due to shaded areas.
- each dielectric coating may comprise a transparent dielectric layer usually used in the field such as, to name a few, TiO 2 , SiO 2 , Si 3 N 4 , SiO x N y , Al (O)N, Al 2 O 3 , SnO 2 , ZnAlO x , Zn 2 SnO 4 , ITO, a mixed oxide of Ti and Zr or Nb, etc....
- the dielectric layers are generally deposited by sputtering under reduced pressure assisted by magnetic field (magnetron), but they can also be deposited by the well-known technique called PECVD (“Plasma-Enhanced Chemical Vapor Deposition”) or plasma-assisted chemical vapor deposition.
- the first dielectric layer deposited on and in contact with the glass substrate can be a nitride, such as silicon or aluminum nitride.
- the first dielectric layer in contact with the glass substrate is a layer consisting of an oxide, and advantageously an oxide layer of at least one element chosen from Zn, Sn, Ti, Zr and their alloys. It has been found that this in particular improves the chemical durability of the non-heat-treated product. It is for example possible to use a layer of titanium oxide, in particular appreciated for its high refractive index.
- the first dielectric layer, of the first dielectric coating, deposited on the glass substrate, and in contact with it is a layer of mixed zinc-tin oxide, advantageously containing at least 20% tin, more preferably still a zinc-tin mixed oxide layer in which the zinc-tin proportion is close to 50-50% by weight (Zn 2 SnO 4 ).
- This arrangement is advantageous for the resistance to heat treatment at high temperature.
- the mixed zinc-tin oxide forms an excellent barrier to alkaline ions migrating from the glass substrate at the high temperature of the heat treatment, in particular of quenching. It also exhibits and retains good adhesion to the glass substrate.
- the layer consisting of an oxide, in direct contact with the substrate advantageously has a thickness of at least 5 nm, preferably of at least 8 nm, more preferably of at least 10 nm.
- each dielectric coating comprises a layer of mixed zinc-tin oxide.
- This layer in each of the dielectric coatings promotes good resistance of the stack to heat treatment at high temperature.
- the last dielectric layer of the last upper dielectric coating is a layer of silicon nitride or a layer of SiO 2 .
- This layer promotes the chemical insulation, in particular with respect to oxygen, of the stack with respect to the external atmosphere, in particular during a heat treatment at high temperature. This favors the preservation of the optical properties of the stack during the heat treatment.
- this does not exclude placing a thin protective layer on this last layer of silicon nitride or oxide, which practically does not act as a dielectric layer with an interference effect, but which fulfills another purpose, for example mechanical protection, such as a thin layer of mixed titanium-zirconium oxide for example.
- a protective layer, or “barrier” layer is preferably deposited directly on the silver-based functional layer, or on each of the functional layers if there are several.
- It may be a metallic layer, also generally called a "sacrificial layer” in a manner known in the field, for example a thin layer of Ti, NiCr, Nb, Ta, deposited from a metallic target in an atmosphere neutral and intended to preserve the silver during the deposition of the following dielectric layer, when the latter is in oxide, and during the heat treatment.
- It can also be a TiOx layer deposited from a ceramic target in a practically neutral atmosphere, or a NiCrOx layer.
- the protective layer or layers deposited directly on the silver-based functional layer or layers are made of ZnO, optionally doped with aluminum (ZnAlOx), obtained from a ceramic target, or doped with aluminum either sub-stoichiometric or in pure ZnO also called ZnO-intrinsic or iZnO, and deposited in a relatively neutral atmosphere, that is to say an atmosphere of pure argon or possibly with a maximum of 20% oxygen.
- ZnAlOx aluminum
- iZnO iZnO
- Such a protective layer for the functional layer(s) has the advantage of improving the light transmission of the stack and has a beneficial effect on the properties of the silver-based functional layer, in particular as regards the emissivity and mechanical strength.
- Such a protective layer of the functional layer also has the advantage of reducing the risk of modification of the total light transmission during the heat treatment at high temperature.
- Each functional layer based on silver is preferably deposited on a wetting layer based on zinc oxide.
- the crystallographic growth of the functional layer on the wetting layer is thus favorable for obtaining low emissivity and good mechanical strength of the interfaces.
- the total light transmission TL of the transparent glazing bearing the multilayer stack deposited on a glass substrate of ordinary clear soda-lime glass 4 mm thick is between 25% and 72%, preferably between 35% and 68%.
- the glass substrate can be a mass-tinted glass, such as a grey, blue or green glass, to absorb even more solar radiation, or to form a private space with low light transmission in order to conceal the passenger compartment. of the vehicle, or an office in a building, to external view, or to provide a particular aesthetic effect.
- the glass substrate can also be an extra clear glass with very high light transmission. In this case it will only absorb very little solar radiation.
- the invention extends to laminated glazing comprising a transparent glazing according to the invention as described above, the multilayer stack of which may be in contact with the thermoplastic adhesive material connecting the substrates, in general PVB.
- the invention also extends to insulating multiple glazing comprising transparent glazing according to the invention as described above, for example double or triple glazing with the multilayer stack arranged facing the enclosed space inside. multiple glazing.
- the solar factor g measured according to the EN410 standard, is between 12% and 40%, advantageously between 20% and 36%, for a 6/15/4 double glazing in clear glass.
- the double glazing is therefore formed from a first sheet of ordinary clear soda-lime glass 6 mm thick carrying the multilayer stack in position 2, that is to say on the internal face of the double glazing, separated from another sheet of clear glass 4 mm thick, without stacking, by an enclosed space 15 mm thick filled with argon.
- Such double glazing provides very effective solar control.
- the selectivity expressed in the form of the light transmission TL with respect to the solar factor g, is at least 1.4, advantageously at least 1.5, preferentially at least 1, 6.
- a high value of selectivity expresses that despite an effective solar factor which greatly reduces the quantity of heat energy coming from the sun and penetrating into the room via the glazing, the light transmission remains as high as possible to allow the lighting of the room.
- the invention further extends to the use of transparent solar control glazing comprising on at least one of the faces of a glass substrate a transparent multilayer stack as described above, to obtain a glazing provided with the multilayer stack whose variation of the optical properties ⁇ E* in transmission and in reflection on the substrate side following a tempering or bending heat treatment is less than 5, preferably less than 2.5 and advantageously less than 2.
- the layers absorbing solar radiation and the dielectric layers are applied by a sputtering technique under the usual conditions for this type of technique.
- the metal layers are deposited in a neutral argon atmosphere.
- the nitrides are deposited in a reactive atmosphere of nitrogen and argon.
- the AZO layers are deposited, from a ceramic target of zinc oxide doped with 2% aluminum, under a neutral argon atmosphere.
- the other oxides are deposited from a metal target under a reactive atmosphere of oxygen and argon.
- the dielectric layers are applied by the well-known technique called PECVD (“Plasma-Enhanced Chemical Vapor Deposition”) or plasma-enhanced chemical vapor deposition.
- Silicon nitride dielectric layers are produced from metal targets in an atmosphere consisting of a mixture of argon (30-70%) and nitrogen (70-30%) under a total pressure of 4mTorr (0. 53Pa).
- the chromium-zirconium layers (40% by weight of Cr and 60% of zirconium in the CrZr alloy), the nickel-chromium layers (Nickel/Chromium 80/20)-tungsten (50% by weight of NiCr and 50 % W in the NiCrW alloy) are deposited from metal cathodes in an argon atmosphere alone.
- the deposition atmosphere of these CrZr and NiCrW metal alloys comprises a little nitrogen coming from the neighboring deposition zones.
- the CrZr or NiCrW layer formed, while retaining its essentially metallic character contains a little nitrogen. The properties obtained are similar.
- the notations SiN designate the silicon nitrides without representing a chemical formula, it being understood that the products obtained are not necessarily strictly stoichiometric, but are those obtained under the deposition conditions indicated and which are close to the stoichiometric products.
- the SiN layers can contain up to a maximum of about 10% by weight of aluminum originating from the target.
- B represents a barrier layer against the oxidation of silver well known in the field
- AZO represents a barrier layer based on zinc oxide, optionally doped with aluminum, deposited from a ceramic target (cathode) of zinc oxide (i-ZnO, called intrinsic ZnO, or aluminum-doped ZnO) sputtered in an argon-based atmosphere with little or no oxygen
- D represents one or more dielectric layers, in particular based on zinc stannate, doped or undoped ZnO, or another material known in the field and suitable for this type of layer stacking, for example a nitride such as AlN.
- AZO can be replaced by other barriers well known in the field and adapted to the desired properties for the layer system formed, such as for example a Ti oxide, doped or not with niobium or zirconium, preferably obtained from a ceramic target formed from the oxide to be deposited, or pure ZnO.
- the designation “TZO” represents a mixed oxide comprising 50% TiO 2 and 50% ZrO 2 .
- M represents the wetting layer based on ZnO, doped with aluminum or not.
- IR stands for functional layers reflecting infrared radiation.
- ABS represents the solar radiation absorbing layer.
- ZSO5 represents a mixed zinc-tin oxide formed from a cathode of a zinc-tin alloy with 52% by weight of zinc and 48% by weight of tin to form the spinel structure of zinc stannate Zn 2 SnO 4 .
- TZO 65 means a mixed titanium-zirconium oxide with 35% zirconium and 65% titanium, different from TZO (50/50).
- Table 1 gives examples of glazing according to the invention in which the layer absorbing solar radiation of stacks with two functional layers based on silver is in the first dielectric coating. This is a metal as indicated in the table: NiCrW or CrZr.
- a final TZO protection layer 3 nm thick covers the last layer of silicon nitride. The mechanical durability is thus enhanced.
- Table 2 gives examples of glazing according to the invention in which the layer absorbing solar radiation from stacks with two functional layers based on silver is also found in the first dielectric coating, but this time it is a question of a nitride as indicated in the table: TiN or ZrN.
- Table 3 gives an example of glazing according to the invention in which the layer absorbing solar radiation (NiCrW) is also found in the first dielectric coating, but this time it is a stack with three layers of silver.
- the substrate here is an ordinary clear soda-lime glass 6 mm thick.
- Table 4 gives examples of glazing according to the invention in which the layer absorbing solar radiation of stacks with two functional layers based on silver is in the second dielectric coating. This is a metal as indicated in the table: NiCrW or CrZr.
- Table 5 are similar to those in Table 4 but for different nitrides as the solar radiation absorbing layer as shown in the table.
- Table 6 gives an example of three functional layers of silver with the solar radiation absorbing layer (NiCrW) in the second dielectric coating.
- the substrate here is an ordinary clear soda-lime glass 6 mm thick.
- Table 7 gives the different properties of the different examples.
- the light transmission TL and the light reflection are measured with Illuminant D65, 2°.
- the colorimetric coordinates L*, a*, b*, CIE, are also measured before and after heat treatment with Illuminant D65, 10°.
- the angle at which the measurements are made is 8°.
- the value of the solar factor (g), measured according to standard EN 410, is 37 for examples 11, 12 and 37.5 for example 53.
- the samples are subjected to a heat treatment comprising maintaining at 670° C. for 7 min and 30 sec.
- the variations in transmission and reflection in ⁇ E*, either in transmission ⁇ E* Tl , or in reflection on the layer side ( ⁇ E* Rc ), or in reflection on the glass substrate side (AE* Rg ), are also given in table 7.
- Y values (which represent either the total light transmission or the total light reflection) are also indicated (in %) in transmission (TL), in reflection on the glass substrate side (Rg) and in reflection on the layer system side (Rc) after treatment thermal.
- the variation of the total light transmission ( ⁇ TL ), and the variation of the total reflection on the glass substrate side ( ⁇ Rg ) and on the layer system side ( ⁇ Rc ) are also indicated in table 7.
- the Y and L*, a*, b* values are given before heat treatment.
- the spots which appear following the heat treatment and which are prohibitive for the marketing of a quality product are areas with a diameter of approximately 5 to 10 mm which are visible to the naked eye at a distance of approximately 60cm. These are stains of a different shade from the rest of the stack which gives an unsightly and unpleasant appearance to the eye. When they are visible to the naked eye at a distance of 60 cm, the coated glazing is downgraded and unacceptable for sale.
- the specific electrical resistance of the stack is also higher for comparative example C2 compared to example 41 which has a similar structure but without the intermediate transparent oxide layer.
- the specific electrical resistance Rs expressed in ohms per square, is 1.74 ⁇ / ⁇ after heat treatment whereas it is 1.55 ⁇ / ⁇ before heat treatment.
- the resistance Rs of example 41 before heat treatment is 1.51 ⁇ / ⁇ and it is reduced to 1.12 ⁇ / ⁇ after heat treatment.
- electrical resistance specific Rs of Example 11 before heat treatment is 1.13 ⁇ / ⁇ ; that of Example 53 is 1.3 ⁇ / ⁇ .
- Table 8 below gives the optical and thermal properties of some examples installed in double glazing (6/15/4).
- This double glazing is formed of a first outer sheet of ordinary clear soda-lime glass 6 mm thick carrying the multilayer stack in position 2, that is to say on the internal face of the double glazing, separated from another sheet of clear glass 4 mm thick, without stacking, by an enclosed space 15 mm thick filled with argon.
- the multilayer stack has not undergone any heat treatment.
- table 8 also gives the solar factor g, according to the EN140 standard, the energy absorption AE, the energy transmission TE, according to the EN410 standard, and the selectivity S expressed according to the ratio of the light transmission TL to the solar factor g.
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MY169126A (en) * | 2013-05-30 | 2019-02-18 | Agc Glass Europe | Low-emissivity and anti-solar glazing |
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CN104267499B (zh) | 2014-10-14 | 2016-08-17 | 福耀玻璃工业集团股份有限公司 | 一种抬头显示*** |
FR3030494B1 (fr) * | 2014-12-19 | 2021-09-03 | Saint Gobain | Vitrage de controle solaire ou bas emissif comprenant une couche de protection superieure |
FR3030495B1 (fr) * | 2014-12-19 | 2016-12-23 | Saint Gobain | Vitrage utilise comme un element constitutif d'un dispositif chauffant |
EP3310727B1 (fr) * | 2015-06-19 | 2022-12-21 | AGC Glass Europe | Substrat revêtu pour contrôle solaire |
CN105015107B (zh) * | 2015-07-22 | 2017-04-26 | 赛柏利安工业技术(苏州)有限公司 | 一种可调色低辐射节能玻璃及其制备方法 |
MX2018011150A (es) * | 2016-03-14 | 2019-03-28 | Guardian Glass Llc | Articulo revestido tratable termicamente de color verde que tiene un valor de factor solar bajo. |
MY191639A (en) * | 2016-03-15 | 2022-07-05 | Guardian Glass Llc | Blue colored heat treatable coated article having low solar factor value |
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US20180257980A1 (en) * | 2017-03-07 | 2018-09-13 | Guardian Industries Corp. | Coated article having low-e coating with ir reflecting layer(s) and doped titanium oxide bi-layer film dielectric and method of making same |
FR3072957B1 (fr) * | 2017-10-30 | 2019-10-18 | Saint-Gobain Glass France | Substrat muni d'un empilement a proprietes thermiques |
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MX2021011429A (es) | 2019-03-28 | 2021-10-13 | Vitro Flat Glass Llc | Articulo que tiene un alto reflejo de luz visible y un color neutro. |
GB201910980D0 (en) | 2019-08-01 | 2019-09-18 | Pilkington Group Ltd | coated Substrate |
CN110642527B (zh) * | 2019-09-21 | 2020-11-03 | 精电(河源)显示技术有限公司 | 抗龟裂ito导电玻璃的制作方法 |
FR3101278B1 (fr) * | 2019-09-30 | 2023-11-24 | Saint Gobain | Vitrage feuillete a basse transmission lumineuse et haute selectivite |
WO2022053507A1 (en) | 2020-09-10 | 2022-03-17 | Agc Glass Europe | Temperable uv reflecting coated glass sheet |
FR3117928A1 (fr) * | 2020-12-18 | 2022-06-24 | Saint-Gobain Glass France | Materiau comportant un empilement a sous-couche dielectrique fine d’oxide a base de zinc et procede de depot de ce materiau |
US20240253330A1 (en) | 2021-07-27 | 2024-08-01 | Agc Glass Europe | Glazing for preventing bird collisions |
CN118354985A (zh) * | 2021-12-16 | 2024-07-16 | 旭硝子欧洲玻璃公司 | 低发射率和抗阳光嵌装玻璃 |
WO2024028175A1 (en) * | 2022-08-05 | 2024-02-08 | Agc Glass Europe | Low-emissivity and anti-solar glazing |
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US5821001A (en) * | 1996-04-25 | 1998-10-13 | Ppg Industries, Inc. | Coated articles |
US6899953B1 (en) * | 1998-05-08 | 2005-05-31 | Ppg Industries Ohio, Inc. | Shippable heat-treatable sputter coated article and zinc cathode sputtering target containing low amounts of tin |
US6398925B1 (en) * | 1998-12-18 | 2002-06-04 | Ppg Industries Ohio, Inc. | Methods and apparatus for producing silver based low emissivity coatings without the use of metal primer layers and articles produced thereby |
DE10040222A1 (de) | 2000-08-17 | 2002-02-28 | Marconi Comm Gmbh | Verfahren zum Betreiben eines Nachrichten-Empfängers |
FR2818272B1 (fr) * | 2000-12-15 | 2003-08-29 | Saint Gobain | Vitrage muni d'un empilement de couches minces pour la protection solaire et/ou l'isolation thermique |
US6852419B2 (en) | 2003-02-21 | 2005-02-08 | Guardian Industries Corp. | Heat treatable coated article with niobium chromium nitride IR reflecting layer and method of making same |
US7294402B2 (en) | 2004-03-05 | 2007-11-13 | Guardian Industries Corp. | Coated article with absorbing layer |
CA2608172C (en) * | 2005-05-12 | 2014-01-14 | Agc Flat Glass North America, Inc. | Low emissivity coating with low solar heat gain coefficient, enhanced chemical and mechanical properties and method of making the same |
FR2898122B1 (fr) | 2006-03-06 | 2008-12-05 | Saint Gobain | Substrat muni d'un empilement a proprietes thermiques |
US7597965B2 (en) | 2006-09-18 | 2009-10-06 | Guardian Industries Corp. | Coated article with low-E coating having absorbing layer designed to neutralize color at off-axis viewing angles |
GB0712447D0 (en) * | 2007-06-27 | 2007-08-08 | Pilkington Group Ltd | Heat treatable coated glass pane |
US7648769B2 (en) | 2007-09-07 | 2010-01-19 | Guardian Industries Corp. | Coated article with low-E coating having absorbing layer designed for desirable bluish color at off-axis viewing angles |
CN102015565A (zh) * | 2008-04-30 | 2011-04-13 | 旭硝子欧洲玻璃公司 | 阳光控制玻璃 |
FR2940271B1 (fr) * | 2008-12-22 | 2011-10-21 | Saint Gobain | Substrat muni d'un empilement a proprietes thermiques et a couche(s) absorbante(s) |
US8734920B2 (en) * | 2009-04-29 | 2014-05-27 | Guardian Industries Corp. | Coated article with low-E coating having titanium oxide layer and/or NiCr based layer(s) to improve color values and/or transmission, and method of making same |
US9028956B2 (en) * | 2010-04-22 | 2015-05-12 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article having low-E coating with absorber layer(s) |
US8337988B2 (en) * | 2010-04-22 | 2012-12-25 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article having low-E coating with absorber layer(s) |
US9150003B2 (en) * | 2012-09-07 | 2015-10-06 | Guardian Industries Corp. | Coated article with low-E coating having absorbing layers for low film side reflectance and low visible transmission |
US9242895B2 (en) * | 2012-09-07 | 2016-01-26 | Guardian Industries Corp. | Coated article with low-E coating having absorbing layers for low film side reflectance and low visible transmission |
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2014
- 2014-02-14 EP EP14705126.2A patent/EP2956422B2/fr active Active
- 2014-02-14 ES ES14705126T patent/ES2691038T5/es active Active
- 2014-02-14 MX MX2015010549A patent/MX2015010549A/es unknown
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- 2014-02-14 UA UAA201508782A patent/UA117475C2/uk unknown
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- 2014-02-14 JP JP2015557444A patent/JP6444891B2/ja active Active
- 2014-02-14 US US14/768,058 patent/US9919960B2/en active Active
- 2014-02-14 WO PCT/EP2014/052945 patent/WO2014125083A1/fr active Application Filing
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- 2014-02-14 PL PL14705126.2T patent/PL2956422T5/pl unknown
- 2014-02-14 HU HUE14705126A patent/HUE040638T2/hu unknown
- 2014-02-14 BR BR112015019497-4A patent/BR112015019497B1/pt active IP Right Grant
- 2014-02-14 AU AU2014217832A patent/AU2014217832B2/en active Active
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Also Published As
Publication number | Publication date |
---|---|
PL2956422T3 (pl) | 2018-12-31 |
JP2016513062A (ja) | 2016-05-12 |
TR201814989T4 (tr) | 2018-11-21 |
BR112015019497A2 (pt) | 2017-07-18 |
PL2956422T5 (pl) | 2023-03-20 |
MY193204A (en) | 2022-09-26 |
JP6444891B2 (ja) | 2018-12-26 |
AU2014217832B2 (en) | 2017-05-25 |
MX2015010549A (es) | 2016-03-04 |
EA030587B1 (ru) | 2018-08-31 |
WO2014125083A1 (fr) | 2014-08-21 |
EP2956422B1 (fr) | 2018-07-18 |
PH12015501775A1 (en) | 2015-12-07 |
US9919960B2 (en) | 2018-03-20 |
BR112015019497B1 (pt) | 2021-12-28 |
ES2691038T3 (es) | 2018-11-23 |
HUE040638T2 (hu) | 2019-03-28 |
EA201591314A1 (ru) | 2015-12-30 |
SG11201506371QA (en) | 2015-09-29 |
UA117475C2 (uk) | 2018-08-10 |
CN104995151B (zh) | 2018-12-28 |
SA515360896B1 (ar) | 2018-09-25 |
CN104995151A (zh) | 2015-10-21 |
AU2014217832A1 (en) | 2015-10-01 |
EP2956422A1 (fr) | 2015-12-23 |
US20160023942A1 (en) | 2016-01-28 |
ES2691038T5 (es) | 2023-04-26 |
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