EP2704838B1 - Dispositif de broyage par impact et de production de matériaux, en particulier de bois, en plusieurs fractions - Google Patents

Dispositif de broyage par impact et de production de matériaux, en particulier de bois, en plusieurs fractions Download PDF

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Publication number
EP2704838B1
EP2704838B1 EP12719366.2A EP12719366A EP2704838B1 EP 2704838 B1 EP2704838 B1 EP 2704838B1 EP 12719366 A EP12719366 A EP 12719366A EP 2704838 B1 EP2704838 B1 EP 2704838B1
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EP
European Patent Office
Prior art keywords
sieve
mesh size
ejection
screen
inclination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP12719366.2A
Other languages
German (de)
English (en)
Other versions
EP2704838A2 (fr
Inventor
Ralf Schaefer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Proactor Schutzrechtsverwaltungs GmbH
Original Assignee
Proactor Schutzrechtsverwaltungs GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Proactor Schutzrechtsverwaltungs GmbH filed Critical Proactor Schutzrechtsverwaltungs GmbH
Publication of EP2704838A2 publication Critical patent/EP2704838A2/fr
Application granted granted Critical
Publication of EP2704838B1 publication Critical patent/EP2704838B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C13/00Disintegrating by mills having rotary beater elements ; Hammer mills
    • B02C13/26Details
    • B02C13/286Feeding or discharge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C13/00Disintegrating by mills having rotary beater elements ; Hammer mills
    • B02C13/14Disintegrating by mills having rotary beater elements ; Hammer mills with vertical rotor shaft, e.g. combined with sifting devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C13/00Disintegrating by mills having rotary beater elements ; Hammer mills
    • B02C13/26Details
    • B02C13/282Shape or inner surface of mill-housings
    • B02C13/284Built-in screens
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/08Separating or sorting of material, associated with crushing or disintegrating
    • B02C23/10Separating or sorting of material, associated with crushing or disintegrating with separator arranged in discharge path of crushing or disintegrating zone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B1/00Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
    • B07B1/28Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B13/00Grading or sorting solid materials by dry methods, not otherwise provided for; Sorting articles otherwise than by indirectly controlled devices
    • B07B13/14Details or accessories
    • B07B13/16Feed or discharge arrangements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B2201/00Details applicable to machines for screening using sieves or gratings
    • B07B2201/04Multiple deck screening devices comprising one or more superimposed screens

Definitions

  • the invention relates to a device for impact crushing and spreading of materials, in particular of wood, in several fractions, according to the preamble of claim 1.
  • a method and an apparatus for processing components of mixtures, in particular mixed plastics known in which a baffle reactor, which is accommodated in a cylindrical body, having a rotatable by a drive motor rotor.
  • the height-adjustable in the base body rotor is made of wear-resistant steel and has at its ends releasably received baffle elements, which crush the introduced components by the resulting impact impact stress in different sized fragments, which can then be separated from each other.
  • the cited document gives no indication that the comminuted particles are deposited in several fractions with different particle sizes by means of downstream sieves arranged one above the other, which are directly downstream of the ejection opening of the impact reactor.
  • a baffle device for crushing wood is made WO2004024331 known.
  • a device for comminuting material in particular of wood, comprises a baffle reactor which has a substantially cylindrical basic body in whose closed interior a rotor driven by a motor rotates with at least one baffle element which contacts the material and produces a crushed high momentum transfer into partial components.
  • the device further comprises an ejection box which is connected to the interior of the cylindrical base body via an ejection opening, and a first auger arranged in the ejection box below the ejection opening for conveying the comminuted material from the ejection box.
  • the device according to the invention is characterized in that below the ejection opening a first sieve with a first mesh width is arranged which, viewed from the ejection opening, extends inclined towards the first auger relative to the horizontal, and that below the first sieve one relative to the horizontal inclined sliding surface or a relative to the horizontal inclined second sieve is arranged, which has a relation to the first mesh size reduced second mesh size.
  • the sliding surface, or the second sieve, extending from the cylindrical base body to a second screw conveyor, which is arranged below the first screw conveyor.
  • the ejection box of the device according to the invention can be kept comparatively compact in terms of its dimensions, since the required footprint for the sieves - which is determined by the vertical projection of the sieves - by the inclined arrangement of the same against their effectively reduced effective screen area.
  • the particles remaining on this remaining particles which do not pass downwards through the sieve meshes, slip downwards in the direction of the feed screw due to their own weight and thereby the sieve surface in the region of the ejection opening for the following to release the particle mixture emerging from the ejection opening.
  • the second sieve which is preferably arranged at the same angle of inclination as the first sieve on a plane extending substantially parallel to the sieve surface of the first sieve, below the first sieve.
  • a sliding surface may be provided, which is a falling out of the passing through the first sieve particles, which are also referred to below as undersize, down from the Ejector box prevented. Since the sliding surface, which closes the collecting container in this case preferably downwards dust-tight, all the particles passing through the first sieve particles to the second screw out, occurs in this embodiment of the invention, the entire sub-grain in the screw conveyor, whereby the formation of dust in Compared to the use of an immediately below the first screen surface set up open collection container is significantly reduced.
  • the ejection opening can be closed by a third sieve which has an enlarged mesh size compared to the mesh size of the first sieve.
  • the ejection opening can be closed by a flap or a slide, whereby the possibility of a discontinuous transfer of the comminuted material from the baffle space into the ejection box is created in an advantageous manner.
  • This alternative embodiment has the advantage that the supply amount of crushed material controlled in the ejection box to regulate, if desired, the amount of shredded material on the first and / or second screen. As a result, it is possible in particular to effectively prevent overflowing or overshooting of the sieves and clogging of the conveying screws.
  • the additional advantage that the removal of the crushed material from the baffle out can be made controlled by other parameters, for example, based on the located in the crushed particles, or in the baffle moisture, which to avoid a lump formation and an associated clogging of the sieves must not be too high.
  • a sliding surface inclined relative to the horizontal or one or more further screens inclined relative to the horizontal are arranged, which have a reduced mesh size compared to the mesh size of the second screen.
  • the one or more screens each extend from the cylindrical base body with the same angle of inclination as the first and second screens to a respective further conveyor screw, which is preferably arranged directly below the second conveyor screw.
  • the screw conveyors preferably extend in one and the same vertical plane, which extends in particular parallel to the axis of rotation of the rotor outside the baffle space.
  • the first and / or the second screw conveyor are rotatably mounted within an open at its top tubular tube trough, in which screen openings are formed, the have one of the mesh size of each adjacent screen corresponding opening size.
  • the use of a snail trough equipped with sieve openings has the advantage that particles with a smaller diameter in relation to the mesh size of a sieve, which inadvertently get into the worm trough associated with the sieve in question, still pass through the sieve openings in the worm trough below lying sieve or fall into the underlying screw trough and thereby be applied according to their size in the correct sieve fraction. This is additionally promoted by the rotating conveying movement of the screws in the screw trough and the resulting mixing and circulation of the particles in the screw trough.
  • the third sieve has a mesh size in the range of 20 mm, the first sieve a mesh width in the range of 15 mm and the second sieve a mesh width in the range of 5 mm.
  • the wood particles must be present in different sizes to a particle board on the one hand the smoothest possible surface and on the other hand a high To give resilience.
  • the load-receiving middle layer preferably larger and flatter particles are used, which ensure a more uniform surface distribution of the forces acting on the plate.
  • the smooth cover layer on the top and bottom of the chipboard however, the smallest possible particles are applied.
  • a different assignment of the mesh sizes of the sieves can also be carried out, so that, for example, by approximating the mesh sizes of the first and second sieve advantageously with a reduction of the statistical portion of the corresponding size range undesirable, too large or too small particles, the purity of the variety the material particle is increased.
  • the amount of particles above the desired area can also be reduced because, on the one hand, the particles stay longer in the baffle space to be sufficiently crushed and, on the other hand, through a narrower range between the mesh sizes of the first and third screen, the proportion of too large particles in the particle mixture is reduced, which passes through the third sieve.
  • horizontally extending barrier strips can be arranged on the first screen, which reduce the speed of the comminuted material emerging from the ejection opening as it moves along the inclined screen.
  • the first and / or the second sieve each have a sieve bottom or an effective sieve surface which is inclined relative to the horizontal at an angle in the range of 20 ° and 70 °, in particular in the range of 30 ° to 45 ° is, and which can be advantageously changed within these limits.
  • a high ejection speed of the particles passing through the ejection opening onto the first screen e.g. may be required for the separation of mixtures by a corresponding peripheral speed of the rotor, can be compensated by an appropriate choice of the inclination of the sieve plate of the first sieve.
  • the first auger is in this case located below the discharge opening in the region near the outer wall of the impact reactor, and the second sieve is located in the same direction of inclination or the opposite direction of inclination in the manner previously described below the first sieve.
  • the first and / or second sieve and / or optionally the further sieve has one or more unbalance motors through which the respective sieve can be set in vibration.
  • the first and second sieve preferably via vibration-damped elastic Suspensions or buffers attached to the peripheral surfaces of the ejection box and are, for example, via a coupled to the respective screen, offset by a motor in rotation, eccentrically mounted flywheel vibrated.
  • the excitation of the first and second sieve to oscillations advantageously results in that the particle mixture is fluidized on the respective sieve, whereby with a corresponding choice of the oscillation frequency and the type of oscillation, the larger particles on the sieve upwards and the smaller particles migrate downwards, which additionally supports the screening process and improves the quality of the fractions obtained.
  • the device 1 of the invention comprises an outwardly closed ejection box 14 which is arranged on the outer wall of the cylindrical base body 4 and communicates with the interior 6 of the cylindrical base body 4 via an ejection opening 16 in fluid communication.
  • the ejection opening 16 according to the preferred embodiment of the invention, a continuous third screen 20c with a mesh size of preferably 20 mm.
  • the sieve 20c can be covered by a flap 18a or a slide 18b which can be folded, for example, along the double arrow shown, in such a way that the ejection opening 16 is partially or completely closed and the passage of comminuted material is prevented.
  • the third screen 20c inserted in the ejection port 16 fractionates the particles circulating in the interior 6 of the impingement reactor 2 by allowing such particles smaller than the mesh size of the third screen 20c of preferably 20 mm to enter the ejection box 14, and larger particles and pieces from not yet sufficiently comminuted material in the interior 6 of the impingement reactor 2 withholds to supply them there to a further crushing process.
  • flap 18a the influx of crushed particles in the ejection box 14 by the flap 18a - or the in Fig. 3 shown two-piece slide 18b - is locked, for example, in a partially open position and thus the relative passage area of the discharge opening 16 can be continuously reduced.
  • the discharge chute 14 it is also possible for the discharge chute 14 to be charged batchwise with comminuted material by cyclically opening and closing the flap 18a or the slide 18b.
  • the mesh size of the first screen 20a is hereby preferably smaller than the mesh width of the third screen 20c, whereby a further fractionation of the comminuted material corresponding to the mesh width of preferably 15 mm takes place with this first plane.
  • the first screw trough 26a has screen openings 28 whose mesh width substantially corresponds to the mesh width of the first screen 20a. This makes it possible for particles which erroneously pass into the first screw trough 26a by passing the first sieve 20a to pass through the sieve openings 28 and still be separated from the larger particles according to the mesh size of the first sieve 20a.
  • FIG. 1 further shows that below the first screen plane consisting of the first screen 20a and the first scroll trough 26a, one of the first screen plane is arranged structurally substantially equal to the second screen plane comprising a second screen 20b inclined relative to the horizontal and a second conveyor screw 24b second screw trough 26b includes.
  • the second wire 20b has a second mesh size of preferably 5 mm, which is smaller than the mesh size of the first screen 20a, preferably 15 mm, in order to separate the particles having a size in the range of 5 to 15 mm, which has passed through the first screen 20a, from those components having a size of less than 5 mm own.
  • the particles remaining above the second screen 20b and having a diameter in the range of 5 to 15 mm are guided into the second screw trough 26b and conveyed out of the ejection box 14 by the second conveyor worm 24b.
  • the second screw trough 26b which may consist of a tube in the same way as the first screw trough 26a, which has an upwardly facing opening only within the discharge box 14 in the connection region of the screen plane, preferably also screen openings are introduced which have an opening width which substantially corresponds to the mesh size of the second screen 20b.
  • vibration dampers or buffers 34 over which the first and second wires 20a, 20b are preferably supported on the side walls of the ejection box 14, are preferably arranged in the region of the edge facing the respective first and second screw troughs 26a, 26b so as to be able to oscillate about the wires store and at the same time to reduce the oscillation amplitude in the region of the first and second scroll troughs 26a, 26b.
  • the vibrations of the sieves are decoupled from each other and also from the outwardly closed housing of the ejection box 14 and the screw conveyors 24a, 24b, whereby the vibration modes and amplitudes for each sieve can be optimally adapted to the material to be shredded.
  • the other components, such as in particular the screw conveyor are not affected by the vibrations, so that increases their life in an advantageous manner.
  • a relative to the horizontal inclined sliding surface 22 is provided, which preferably also substantially parallel to the first and second wire 20a, 20b from the cylindrical base body 4 to a below the second screw conveyor 24b arranged third screw conveyor 24c extends, which is in a closed down third screw trough 26c - ie a screw trough, which in contrast to the screw troughs 26a and 26b has no screen openings 28 - is added.
  • the second screen 24b preferably has the same angle of inclination to the horizontal as the first screen 24a, which is advantageously variable and, for example, in the range of 30 to 50 °.
  • FIG. 2 shows a schematic spatial side view of the impact reactor with the ejection box 14, in which the side walls are not shown for better representation of the screen planes, and the different mesh sizes are to be indicated by the different patterns of the first, second and third screen 20a, 20b, 20c. It can also be seen from this illustration that the barrier strips 30 extend over the entire width of the first screen 20a.
  • Fig. 3 a schematic plan view of the device 1 according to the invention shown.
  • the ejection opening 16 can be closed by the slide 18b, which comprises two slide parts and is shown in a partially opened position, by sliding the slide parts along the two double arrows.
  • the slider 18b is made of a single slide plate, which can be moved or pivoted, for example by a vertical, for example upward sliding movement, to open the ejection opening 16.
  • the slider 18b may also have an arcuate shape adapted to the rounding of the outer surface of the impingement reactor 2, and may be slidable in the circumferential direction or in the vertical direction to expose the ejection port 16.
  • the resulting due to the rounding of the outer wall of the baffle reactor 2 and the preferably rectilinear terminal edge of the first screen 20a intermediate region 21 is preferably formed as a closed and inclined sliding surface, along which the at low speed from the discharge opening 16 emerging shredded material, which is not from the front impinges on the screen surface of the first screen 20a, can slide in the direction of the first screen out.
  • a delivery pipe 38 in the axial extension of the first auger 24a is shown, which is received on the outside of the discharge box 14 in order to promote the material transported by the first screw conveyor 24a, for example, to a collecting container not shown further.
  • the screw conveyor 24a is - in the same way as the other aforementioned screw conveyors - driven by a screw motor 36 shown by way of example in this illustration.

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  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Disintegrating Or Milling (AREA)
  • Crushing And Pulverization Processes (AREA)
  • Combined Means For Separation Of Solids (AREA)

Claims (8)

  1. Dispositif (1) de broyage de matériau, en particulier de bois, comprenant un broyeur à impact (2), qui comporte un corps de base (4) sensiblement cylindrique, dans l'espace intérieur (6) fermé duquel tourne un rotor (8) doté d'au moins un élément d'impact (10), qui vient en contact avec le matériau et le broie en éléments partiels en générant un transfert d'impulsion élevé, et comprenant un bac d'éjection (14), qui est relié à l'espace intérieur (6) du corps de base (4) cylindrique par le biais d'une ouverture d'éjection (16), ainsi qu'un premier transporteur à vis sans fin (24a) disposé dans le bac d'éjection (14) sous l'ouverture d'éjection (16) pour transporter le matériau broyé hors du bac d'éjection (14),
    caractérisé en ce que
    sous l'ouverture d'éjection (16) est disposé un premier crible (20a) doté d'une première ouverture de maille, qui s'étend, incliné par rapport à l'horizontale, de l'ouverture d'éjection (16) au premier transporteur à vis sans fin (24a), et en ce qu'une surface de glissement (22) inclinée par rapport à l'horizontale ou un deuxième crible (20b) incliné par rapport à l'horizontale doté d'une deuxième ouverture de maille réduite par rapport à la première ouverture de maille, est disposé(e) sous le premier crible (20a), qui s'étend du corps de base (4) cylindrique à un deuxième transporteur à vis sans fin (24b) disposé sous le premier transporteur à vis sans fin (24a).
  2. Dispositif selon la revendication 1, caractérisé en ce que l'ouverture d'éjection (16) peut être fermée par un troisième crible (20c) doté d'une ouverture de maille agrandie par rapport à l'ouverture de maille du premier crible (20a) et/ou un volet (18a) et/ou une vanne (18b).
  3. Dispositif selon l'une des revendications 1 ou 2,
    caractérisé en ce que
    sous le deuxième crible (20b), sont disposés une surface de glissement (22) inclinée par rapport à l'horizontale ou un ou plusieurs autres cribles inclinés par rapport à l'horizontale dotés d'une ouverture de maille réduite par rapport à la deuxième ouverture de maille, qui s'étendent respectivement du corps de base (4) cylindrique à d'autres transporteurs à vis sans fin disposés respectivement sous le deuxième transporteur à vis sans fin (24b).
  4. Dispositif selon l'une des revendications 1 à 3,
    caractérisé en ce que
    le premier et/ou le deuxième transporteur à vis sans fin (24a, 24b) tournent dans un bac de transporteur à vis (26a, 26b) tubulaire ouvert sur son côté supérieur, dans lequel sont formées des ouvertures de crible (28), qui possèdent une taille d'ouverture correspondant à l'ouverture de maille du crible (20a, 20b) adjacent.
  5. Dispositif selon l'une des revendications 1 à 4,
    caractérisé en ce que
    le troisième crible (20c) possède une ouverture de maille de l'ordre de 20 mm, le premier crible (20a) une ouverture de maille de l'ordre de 15 mm et le deuxième crible (20b) une ouverture de maille de l'ordre de 5 mm.
  6. Dispositif selon l'une des revendications 1 à 5,
    caractérisé en ce que
    sur le premier crible (20a) sont disposées des barres de barrage (30) horizontales qui diminuent la vitesse du matériau broyé sortant de l'ouverture d'éjection (16) lors de son déplacement le long du crible (20a) incliné.
  7. Dispositif selon l'une des revendications 1 à 6,
    caractérisé en ce que
    le premier et/ou le deuxième crible (20a, 20b) comportent respectivement un fond de crible, qui est disposé incliné par rapport à l'horizontale selon un angle compris entre 20° et 70°, en particulier compris entre 30° et 45 °.
  8. Dispositif selon l'une des revendications 1 à 7,
    caractérisé en ce que
    le premier et/ou le deuxième crible (20a, 20b) et/ou l'autre crible comportent des moteurs déséquilibrés (32) pour faire vibrer le crible respectif.
EP12719366.2A 2011-05-02 2012-05-02 Dispositif de broyage par impact et de production de matériaux, en particulier de bois, en plusieurs fractions Not-in-force EP2704838B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011100240A DE102011100240A1 (de) 2011-05-02 2011-05-02 Vorrichtung zur Prallzerkleinerung und Ausbringung von Materialien, insbesondere von Holz, in mehreren Fraktionen
PCT/EP2012/058055 WO2012150273A2 (fr) 2011-05-02 2012-05-02 Dispositif de broyage par impact et de production de matériaux, en particulier de bois, en plusieurs fractions

Publications (2)

Publication Number Publication Date
EP2704838A2 EP2704838A2 (fr) 2014-03-12
EP2704838B1 true EP2704838B1 (fr) 2018-02-28

Family

ID=46044694

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12719366.2A Not-in-force EP2704838B1 (fr) 2011-05-02 2012-05-02 Dispositif de broyage par impact et de production de matériaux, en particulier de bois, en plusieurs fractions

Country Status (8)

Country Link
US (1) US20140091164A1 (fr)
EP (1) EP2704838B1 (fr)
CN (1) CN103596691B (fr)
BR (1) BR112013027747A2 (fr)
CA (1) CA2833069A1 (fr)
CL (1) CL2013003152A1 (fr)
DE (1) DE102011100240A1 (fr)
WO (1) WO2012150273A2 (fr)

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CN114308641A (zh) * 2022-01-13 2022-04-12 诸暨华匠工程设计咨询有限公司 一种土木工程用建筑材料多层级筛沙设备
CN114918030A (zh) * 2022-05-19 2022-08-19 浙江华铁建设工程有限公司 一种矿山工程用石块破碎筛分机
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CN115888886B (zh) * 2022-10-24 2024-06-04 安徽沙丰新材料有限公司 一种硬脂酸锌研磨筛分装置

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CN103596691A (zh) 2014-02-19
WO2012150273A3 (fr) 2013-01-10
EP2704838A2 (fr) 2014-03-12
DE102011100240A1 (de) 2012-11-08
CA2833069A1 (fr) 2012-11-08
US20140091164A1 (en) 2014-04-03
CL2013003152A1 (es) 2014-07-11
BR112013027747A2 (pt) 2017-06-20
WO2012150273A2 (fr) 2012-11-08
RU2013153269A (ru) 2015-06-10
CN103596691B (zh) 2016-01-20

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