EP2531302A2 - Device and method for producing a fine-grained fuel by drying and impact crushing - Google Patents
Device and method for producing a fine-grained fuel by drying and impact crushingInfo
- Publication number
- EP2531302A2 EP2531302A2 EP11705431A EP11705431A EP2531302A2 EP 2531302 A2 EP2531302 A2 EP 2531302A2 EP 11705431 A EP11705431 A EP 11705431A EP 11705431 A EP11705431 A EP 11705431A EP 2531302 A2 EP2531302 A2 EP 2531302A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- reactor
- gas
- impact
- energy
- drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001035 drying Methods 0.000 title claims abstract description 50
- 239000000446 fuel Substances 0.000 title claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 239000002245 particle Substances 0.000 claims abstract description 35
- 239000007787 solid Substances 0.000 claims abstract description 14
- 239000007789 gas Substances 0.000 claims description 73
- 238000000034 method Methods 0.000 claims description 19
- 239000002994 raw material Substances 0.000 claims description 19
- 235000011837 pasties Nutrition 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 8
- 238000010304 firing Methods 0.000 claims description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 239000003085 diluting agent Substances 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 239000003546 flue gas Substances 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 230000008878 coupling Effects 0.000 claims description 2
- 238000010168 coupling process Methods 0.000 claims description 2
- 238000005859 coupling reaction Methods 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000002918 waste heat Substances 0.000 claims description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims 1
- 239000002028 Biomass Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 4
- 238000002309 gasification Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000000035 biogenic effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000009996 mechanical pre-treatment Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000009997 thermal pre-treatment Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/033—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment comminuting or crushing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C13/00—Disintegrating by mills having rotary beater elements ; Hammer mills
- B02C13/14—Disintegrating by mills having rotary beater elements ; Hammer mills with vertical rotor shaft, e.g. combined with sifting devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C13/00—Disintegrating by mills having rotary beater elements ; Hammer mills
- B02C13/26—Details
- B02C13/288—Ventilating, or influencing air circulation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/18—Adding fluid, other than for crushing or disintegrating by fluid energy
- B02C23/24—Passing gas through crushing or disintegrating zone
- B02C23/26—Passing gas through crushing or disintegrating zone characterised by point of gas entry or exit or by gas flow path
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/04—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment drying
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/44—Details; Accessories
- F23G5/46—Recuperation of heat
Definitions
- the invention relates to the thermal and mechanical pretreatment substances which may be present in pasty or viscous form and are referred to hereinafter as solid or pasty energy resources, including, for example, biogenic and other highly reactive fuels, fossil fuels and residues count in one baffle reactor.
- solid or pasty energy resources including, for example, biogenic and other highly reactive fuels, fossil fuels and residues count in one baffle reactor.
- solids and liquid fractions are mixed together, examples of which are sewage sludge and industrial residues, either on an aqueous basis or on the basis of solvents or energy-containing liquids, such as lubricants.
- the synthesis gas thus produced is the feedstock for downstream chemical syntheses, such as for Fischer-Tropsch, methanol or ammonia synthesis.
- Typical grain sizes are for hard coal e.g. in the range ⁇ 100 microns.
- this particle size may also be significantly larger depending on the process parameters, also is a
- Ventilation methods are listed as technical drying devices, in which a promotion of the material to be dried, the rotary reversing dryer, belt dryer and rotary dryer. These mentioned devices have in common that no comminution of the particles takes place.
- the object of the invention is therefore to provide a device simpler apparatus and a more energy-efficient method available, with which the drying and crushing can be done in an apparatus, wherein the solid or pasty energy raw materials are pretreated so that they are for a
- the invention solves the problem by means of a device for producing a fine-grained fuel, in particular from solid, pasty or aqueous energy by drying and comminution, comprising
- At least one further hot gas feed device in the bottom area of the impact reactor • a feeding device for solid or pasty energy raw materials in
- Hot-drying gas supply device in the bottom area of the impact reactor, wherein large amounts of drying gas are to be introduced.
- distributed over the circumference holes are provided.
- the holes are made inclined in the radial direction and that the bores are aligned tangentially to the direction of rotation of the baffle elements.
- the outlet direction of the holes can be aligned with or against the direction of rotation of the rotor of the Praiireaktors.
- the procedurally more favorable solution depends on the interaction of the properties of the material to be comminuted and the
- hot drying gas can be added in the bottom region of the baffle reactor by distributed over the circumference slit-shaped openings.
- the slots may also have a radial inclination.
- the slots can also be formed by overlapping mounting of floor panels.
- Circuit circuit provided with a gas circuit, having in addition
- At least one pressure-increasing device in the recycle gas stream • at least one diluent gas addition device in the
- the object of the invention is also achieved by a method for producing a fine-grained fuel from solid, pasty or aqueous energy raw materials by drying and impact crushing using a
- Impingement reactor with a rotor and baffles, in which
- Hot drying gas is supplied both in the bottom area of the impact reactor and via a labyrinth seal in the area of the rotor shaft of the impact reactor,
- the energy raw materials in the impact reactor are comminuted and dried, and comminuted and dried energy raw material particles in a mixture containing them
- Gas stream are guided out of the impingement reactor in a particle separator.
- drying gas is fed together with the energy raw materials through its supply device into the reactor, in this case it is important to ensure that the drying gas is introduced into the supply device sufficiently cool.
- Feeding device is heated indirectly. Due to the drying effect, the drying gas cools during passage through the feeder. The heating counteracts this cooling. For heating, the hot drying gas can be used, which itself cools and then passed through the feeder. About a screw conveyor, which is open to the impact reactor, the
- Drying gas can be introduced freely into the baffle reactor. It is advantageous in this case if the energy raw materials and the drying gas are passed in co-current through the screw conveyor. With a rotary valve, which connects the silo with the screw conveyor, a backflow into the silo can be prevented.
- All types of feed for drying gas can also be used additively. It is thus possible to introduce drying gas both via the labyrinth seal, as well as the feed device for energy resources, as well as holes and slots in the bottom region of the impact reactor in the baffle reactor and thus process technology to respond to a variety of raw materials, which is an advantage of the invention.
- a suitable impact reactor is described for example in DE 196 00 482 A1.
- This apparatus is surprisingly capable of producing biomass, e.g. Straw or green waste, in the same way as the one described there
- Drum dryer or belt dryer for biomass here takes place simultaneously a crushing by the baffle effect. It will be in contact with the
- Impingement elements preferably the already partially dried outer
- FIG. 1 shows the device within a circulatory operation
- FIG. 2 shows a detailed detail in the area of the rotor shaft of the impingement reactor. From the storage tank 1, the biomass 2 on the
- the comminuted and dried particles 11 are withdrawn via a separator 6, which is preferably a motor-operated rotary separator, with the gas stream 9 from the impingement reactor 5 and into the particle separator 10, shown here as a filtering separator. Another withdrawal takes place through the side outlet 6a, wherein the withdrawn gas 9a also for
- Particle separator 10 is passed.
- the size of the exiting with the gas stream 9 particles can be adjusted by the use of the classifier 6. It may also be advantageous to dispense with the motor-driven rotary separator and to use screens or perforated plates, by which the particle size of the solids contained in the gas stream 9 can be influenced.
- the target particle size of the dried particles 11 is defined by various requirements of the gasification or incineration plant. These are e.g. Requirements for the interaction of reactivity and particle size, on the transport properties or further, may be advantageous for different sof a different particle size or particle size distribution. Therefore, they are different
- Pre-separation methods such as sifters or sieves make sense.
- a mass separator or a cyclone separator may be used sensibly as a particle separator 10.
- Verfarhens Republice can also be a cleaning with other inert gases or with carbon dioxide, air or with oxygen-depleted air.
- a partial flow 17 is previously branched off, and mixed by means of the blower 18 with hot gas, which is obtained from the burner 19 from air 20 and fuel gas 21.
- the resulting drying gas 22 is with
- drying gas 8a there it is divided as the drying gas 8a via a labyrinth seal and drying gas 8b via bottom openings as described above as in the
- Screw conveyor 4 is via a heating medium with Hammerschzulauf 24 and
- FIG. 2 is a fragmentary detail view of
- Baffle reactor 5 shown in the region of the rotor shaft 34, via which the rotor 7 is driven by a motor not shown in detail. As the illustration of Fig. 2 can be taken here, located at the front end of the
- Rotor shaft 34 has a rotor receptacle 35, in the underside of a circumferential recess or groove 36 is introduced, for example, has a rectangular cross-section.
- a circumferential projection 37 which is preferably arranged on the bottom plate 38 of the baffle reactor 5.
- the projection 37 has a width which is smaller than the width of the recess 36, and does not extend completely with its top to the bottom of the recess, so that between the outer surface of the projection 37 and the inner surface of the recess 36, a labyrinth seal 33rd with a
- Labyrinthgang 33a formed through which the full amount of the drying gas (8a + 8b) or a subset (6a) or other gas is introduced into the interior of the impingement reactor 5.
- the labyrinth passage may have a width in the range of 2mm to 20mm. According to a not shown
- the labyrinth seal 33 viewed in the radial direction to improve the sealing effect also have two or more projections 37 which extend into corresponding recesses 36, which are adapted in shape to the shape of the projections.
- the supply of the drying gas 8a via the labyrinth seal 33 is preferably carried out by one or more below the bottom plate 38 in the
- This can be further improved by the use of one or more, the labyrinth passage 33a fluidly downstream Schleuderangn 41.
- the supply of the further drying gas 8b is carried out by one or more located in the bottom plate 38 openings 42.
- These openings 42 can be performed as a plurality of holes over the circumference or as one or more slots. It is also conceivable to provide oblique bores in order to impart to the gas 8b, as it flows into the impingement reactor 5, a flow direction advantageous in terms of process technology.
Landscapes
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Processing Of Solid Wastes (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Treatment Of Sludge (AREA)
- Drying Of Solid Materials (AREA)
- Crushing And Pulverization Processes (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL11705431T PL2531302T3 (en) | 2010-02-04 | 2011-01-26 | Device and method for producing a fine-grained fuel by drying and impact crushing |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102010006916A DE102010006916A1 (en) | 2010-02-04 | 2010-02-04 | Apparatus and method for producing a fine-grained fuel by drying and impact crushing |
PCT/EP2011/000336 WO2011095295A2 (en) | 2010-02-04 | 2011-01-26 | Device and method for producing a fine-grained fuel by drying and impact crushing |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2531302A2 true EP2531302A2 (en) | 2012-12-12 |
EP2531302B1 EP2531302B1 (en) | 2013-12-18 |
Family
ID=44175999
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11705431.2A Not-in-force EP2531302B1 (en) | 2010-02-04 | 2011-01-26 | Device and method for producing a fine-grained fuel by drying and impact crushing |
Country Status (16)
Country | Link |
---|---|
US (1) | US20130199424A1 (en) |
EP (1) | EP2531302B1 (en) |
KR (1) | KR20130009757A (en) |
CN (1) | CN102834179A (en) |
AU (1) | AU2011212726B2 (en) |
CA (1) | CA2786797A1 (en) |
DE (1) | DE102010006916A1 (en) |
DK (1) | DK2531302T3 (en) |
ES (1) | ES2464277T3 (en) |
MX (1) | MX2012009040A (en) |
PL (1) | PL2531302T3 (en) |
RU (1) | RU2012135070A (en) |
TW (1) | TW201134553A (en) |
UA (1) | UA105407C2 (en) |
WO (1) | WO2011095295A2 (en) |
ZA (1) | ZA201204799B (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011080375A1 (en) * | 2011-08-03 | 2013-02-07 | Vescon System Ag | Method and device for producing organic fibrous materials or granules |
CN102607904B (en) * | 2012-03-29 | 2013-11-13 | 浙江大学 | High temperature corrosion atmosphere monitoring device for boiler water wall |
AT515772B1 (en) * | 2014-11-27 | 2015-12-15 | A Tec Holding Gmbh | Process for the treatment of substitute fuels |
LU92916B1 (en) * | 2015-12-17 | 2017-07-13 | Wurth Paul Sa | Grinding and drying plant |
DE102016115714A1 (en) | 2016-08-24 | 2018-03-01 | Schäfer E. Technik u. Sondermaschinen GmbH | baffle reactor |
IT201900006959A1 (en) * | 2019-05-17 | 2020-11-17 | Waste Processing Tech Srl | Plant and method for waste treatment |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1105997A (en) * | 1954-06-09 | 1955-12-09 | Babcock & Wilcox France | Process for using solid fuels and its applications |
GB828515A (en) * | 1957-03-06 | 1960-02-17 | Babcock & Wilcox Ltd | Improvements in or relating to pulverisers |
US3484948A (en) * | 1967-08-09 | 1969-12-23 | John Campbell Whelan | Apparatus for exchanging heat between a gas and a particulate matter |
DE3341857C2 (en) * | 1983-11-19 | 1994-09-08 | Kloeckner Humboldt Deutz Ag | Cone crusher |
JP2913263B2 (en) * | 1995-07-07 | 1999-06-28 | 株式会社山和エンヂニアリング | Solids grinding and drying equipment |
US5680996A (en) * | 1995-09-14 | 1997-10-28 | The United States Of America Is Represented By The Dept. Of Energy | Gas fluidized-bed stirred media mill |
DE19625105A1 (en) * | 1996-01-09 | 1998-01-08 | Ralf Schaefer | Comminutor-agglomerator processing variety of waste materials e.g. vehicle shreddings |
DE19600482A1 (en) | 1995-11-11 | 1997-05-15 | Schaefer Elektrotechnik Sonder | Recycling process for mixed plastics including other materials |
AU7622696A (en) * | 1995-11-11 | 1997-06-05 | Schafer Elektrotechnik - Sondermaschinen | Process and device for the processing of components from mixed materials and other building materials mixed therewith and the use thereof |
EP1616625B1 (en) * | 2004-07-14 | 2011-05-18 | CTU Clean Technology Universe AG | Comminution device and method of operating the same |
US7100853B2 (en) * | 2004-07-27 | 2006-09-05 | Wark Rickey E | Deflector for coal pulverizer/classifier |
EP1747814A1 (en) * | 2005-07-25 | 2007-01-31 | Claudius Peters Technologies GmbH | Dry mill and method of drying of mill feed |
DE102005055620B4 (en) | 2005-11-22 | 2019-01-31 | Proactor Schutzrechtsverwaltungs Gmbh | Device for processing components from mixtures of substances |
DE102006006096A1 (en) * | 2006-02-10 | 2007-08-16 | Altenburger Maschinen Jäckering GmbH | Apparatus and method for feeding moist and / or sticky products, in particular cellulose, in an air vortex mill |
FR2904405B1 (en) * | 2006-07-31 | 2008-10-31 | Inst Francais Du Petrole | PROCESS FOR PREPARING A BIOMASS-CONTAINING LOAD FOR SUBSEQUENT GASIFICATION |
US20080028634A1 (en) * | 2006-08-07 | 2008-02-07 | Syntroleum Corporation | Method for using heat from combustion turbine exhaust to dry fuel feedstocks |
US7594941B2 (en) * | 2006-08-23 | 2009-09-29 | University Of New Brunswick | Rotary gas cyclone separator |
DE102007056170A1 (en) * | 2006-12-28 | 2008-11-06 | Dominik Peus | Substance or fuel for producing energy from biomass, is manufactured from biomass, which has higher carbon portion in comparison to raw material concerning percentaged mass portion of elements |
CN201322515Y (en) * | 2008-12-23 | 2009-10-07 | 岳正喜 | Rotary harrow flying and fast-crushing dryer and heat-division crushing dryer |
-
2010
- 2010-02-04 DE DE102010006916A patent/DE102010006916A1/en not_active Ceased
-
2011
- 2011-01-26 EP EP11705431.2A patent/EP2531302B1/en not_active Not-in-force
- 2011-01-26 WO PCT/EP2011/000336 patent/WO2011095295A2/en active Application Filing
- 2011-01-26 CN CN2011800070719A patent/CN102834179A/en active Pending
- 2011-01-26 ES ES11705431.2T patent/ES2464277T3/en active Active
- 2011-01-26 US US13/577,306 patent/US20130199424A1/en not_active Abandoned
- 2011-01-26 DK DK11705431.2T patent/DK2531302T3/en active
- 2011-01-26 AU AU2011212726A patent/AU2011212726B2/en not_active Ceased
- 2011-01-26 PL PL11705431T patent/PL2531302T3/en unknown
- 2011-01-26 RU RU2012135070/13A patent/RU2012135070A/en not_active Application Discontinuation
- 2011-01-26 UA UAA201207985A patent/UA105407C2/en unknown
- 2011-01-26 MX MX2012009040A patent/MX2012009040A/en not_active Application Discontinuation
- 2011-01-26 CA CA2786797A patent/CA2786797A1/en not_active Abandoned
- 2011-01-26 KR KR1020127022810A patent/KR20130009757A/en not_active Application Discontinuation
- 2011-02-01 TW TW100103868A patent/TW201134553A/en unknown
-
2012
- 2012-06-27 ZA ZA2012/04799A patent/ZA201204799B/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2011095295A2 * |
Also Published As
Publication number | Publication date |
---|---|
CN102834179A (en) | 2012-12-19 |
ES2464277T3 (en) | 2014-06-02 |
DK2531302T3 (en) | 2014-03-31 |
MX2012009040A (en) | 2012-11-29 |
UA105407C2 (en) | 2014-05-12 |
RU2012135070A (en) | 2014-03-10 |
AU2011212726A1 (en) | 2012-07-19 |
PL2531302T3 (en) | 2015-01-30 |
ZA201204799B (en) | 2014-03-26 |
WO2011095295A2 (en) | 2011-08-11 |
DE102010006916A1 (en) | 2011-08-04 |
TW201134553A (en) | 2011-10-16 |
US20130199424A1 (en) | 2013-08-08 |
EP2531302B1 (en) | 2013-12-18 |
KR20130009757A (en) | 2013-01-23 |
AU2011212726B2 (en) | 2014-07-10 |
CA2786797A1 (en) | 2011-08-11 |
WO2011095295A3 (en) | 2011-12-29 |
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