EP2481825B1 - Alliage de magnésium contenant des métaux de terres rares - Google Patents
Alliage de magnésium contenant des métaux de terres rares Download PDFInfo
- Publication number
- EP2481825B1 EP2481825B1 EP11152827.9A EP11152827A EP2481825B1 EP 2481825 B1 EP2481825 B1 EP 2481825B1 EP 11152827 A EP11152827 A EP 11152827A EP 2481825 B1 EP2481825 B1 EP 2481825B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- magnesium
- alloys
- rare earth
- present
- magnesium alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C23/00—Alloys based on magnesium
- C22C23/04—Alloys based on magnesium with zinc or cadmium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C23/00—Alloys based on magnesium
- C22C23/06—Alloys based on magnesium with a rare earth metal as the next major constituent
Definitions
- the present invention relates to cast and wrought single-phase solid solution magnesium alloys with high mechanical properties, formability and corrosion resistance.
- Magnesium alloys have not yet been widely accepted by car manufacturers. Most of the technical barriers preventing magnesium alloys from widespread applications arise from the low ductility and toughness at low temperatures, poor corrosion and creep resistance at high temperatures. Their present commercial products are normally fabricated by high pressure die casting. The use of wrought magnesium alloys is limited because of its poor formability and corrosion resistance.
- Mg-Al magnesium-aluminium
- Mg-Zn magnesium-zinc
- WE43 magnesium-4.1Y-2.2Nd-1HRE-0.5Zr
- WE54 magnesium-5.2Y-1.7Nd-1.7HRE-0.4Zr
- the alloys of magnesium-aluminium series are the most commonly used in wrought applications for their relative ease of extrusion and adequate mechanical properties, but they suffer from both a pronounced asymmetry in the yield behaviour and a relatively narrow processing window. Due to the lower eutectic temperature 437°C for magnesium-aluminium alloys, the hot processing temperatures are normally selected below 350°C and the processing speeds are not so high. If selecting high temperatures more than 350°C with high processing speeds, the eutectic phases dissolve again, leading to the occurrence of hot cracking and bad surface quality of the products. In addition, until now, the methods for refining the as-cast microstructures of magnesium-aluminium alloys are not satisfying and not widely accepted by the industry.
- magnesium-zinc series contain no aluminium, their as-cast microstructure can be effectively refined by the addition of zirconium.
- these magnesium-zinc alloys still have very limited applications because they are susceptible to microporosity during casting.
- the addition of zinc in magnesium increases the susceptibility to hot tearing.
- due to the high content of zinc it was considered that these alloys are difficult to be welded.
- AZ31 (Mg-2.9Al-0.8Zn) alloy is used in industry to an significant extent.
- AZ31 (Mg-2.9Al-0.8Zn) alloy exhibits some problems with recrystallisation during the hot working and has insufficient mechanical and corrosion properties.
- the present invention provides a magnesium alloy as defined in claim 1.
- the solid solution strengthening depends on the contents of alloying elements in the matrix of magnesium and the difference in atomic radius between the alloying elements and magnesium such that a high content of alloying elements and large difference in atomic radius increase the effect of solid solution strengthening.
- rare earth elements can purify the melt during casting.
- the addition of rare earth elements can remove impurity elements such as hydrogen, oxygen, chlorine, etc.
- impurity elements such as hydrogen, oxygen, chlorine, etc.
- they interact with iron, cobalt, nickel or copper elements during melting, and these elements are removed by the formation of intermetallic compounds which settle at the bottom of the ingot.
- the decrease of impurities in the matrix also contributes to the high corrosion resistance.
- the magnesium alloy of the present invention further comprises an element selected from the group consisting of Zr, Ca, Zn, and mixtures thereof.
- the stress corrosion of magnesium alloys could be alleviated by the addition of zirconium (Zr) and rare earth elements. Zirconium (Zr) can be used as an element to decrease the stress corrosion cracking.
- the magnesium alloys according to the present invention contain no aluminium; therefore, their as-cast microstructure can effectively be refined by the addition of zirconium or calcium.
- rare earth elements can be classified in periodic table: light rare earth elements and heavy rare earth elements.
- rare earth elements have the similar chemical and physical properties. Due to the similar properties of yttrium and scandium to heavy rare earth elements, for the purposes of the present invention Y and Sc are treated as they were heavy rare earth elements.
- the light rare earth elements include samarium, lanthanum, cerium, neodymium, and praseodymium, and the heavy rare earth elements include gadolinium, yttrium and dysprosium.
- zirconium and/or calcium are preferably added as a grain refiner.
- the total content of rare earths is maintained below 5 wt.%, mainly for economical reasons.
- the content of grain refiner calcium and/or zirconium is preferably in the range of 0.05-0.6% by weight.
- the manufacturing processes of the magnesium alloys according to the present invention are not restricted.
- the alloys can be prepared by die casting, permanent casting, chill casting, semi-solid processes, continuous casting or continuous twin roll casting.
- the magnesium alloys according to the present invention exhibit excellent room temperature ductility with a value of about 25%.
- Table 1 lists the compositions of the investigated alloys.
- All alloys were prepared by zone solidification. Their optical microstructures are shown in Figure 1 .
- the average grain size decreases with the increment in the content of rare earths. Compared to the gadolinium and dysprosium, the yttrium element is the most effective element to decrease the grain size.
- the average grain sizes of E and H alloys containing zirconium are 55 ⁇ m and 67 ⁇ m.
- the average grain size of Mg-3Al-1Zn (AZ31 is 480 ⁇ m. Table 1.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Continuous Casting (AREA)
- Forging (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Claims (7)
- Alliage de magnésium composé de (a) Mg ; (b) 0,5 % en poids à moins de 5,0 % en poids d'au moins deux éléments choisis parmi Y, Gd et Dy ; et (c) éventuellement Zr, Ca et/ou Zn, la proportion, par rapport au poids total de l'alliage, de chacun desdits éléments Y, Gd et Dy, éventuellement présent, étant de 0,05 à 2,0 % en poids, et la proportion, par rapport au poids total de l'alliage, de chacun desdits éléments choisis parmi Zr, Ca et Zn, éventuellement présent, étant de 0,05 à 0,6 % en poids, le reste étant du magnésium.
- Alliage de magnésium selon la revendication 1, dans lequel Gd est présent à raison de 0,05 à 2,0 % en poids.
- Alliage de magnésium selon l'une quelconque des revendications précédentes, dans lequel Y est présent à raison de 0,05 à 2,0 % en poids.
- Alliage de magnésium selon l'une quelconque des revendications précédentes, dans lequel Dy est présent à raison de 0,05 à 2,0 % en poids.
- Alliage de magnésium selon l'une quelconque des revendications précédentes, dans lequel Ca est présent à raison de 0,05 à 0,4 % en poids.
- Alliage de magnésium selon l'une quelconque des revendications précédentes, dans lequel Zr est présent à raison de 0,2 à 0,6 % en poids.
- Utilisation des alliages de magnésium selon l'une quelconque des revendications 1 à 6 comme alliages de magnésium de fonderie, alliages de magnésium de forge ou biomatériaux dégradables.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11152827.9A EP2481825B1 (fr) | 2011-02-01 | 2011-02-01 | Alliage de magnésium contenant des métaux de terres rares |
ES11152827T ES2423354T3 (es) | 2011-02-01 | 2011-02-01 | Aleación de magnesio que contiene metales de tierras raras |
US13/352,595 US20120195787A1 (en) | 2011-02-01 | 2012-01-18 | Single-phase solid solution cast or wrought magnesium alloys |
CA2765484A CA2765484A1 (fr) | 2011-02-01 | 2012-01-25 | Moule d'une solution solide monophasee ou alliages de magnesium forge |
CN201210022436.1A CN102628134B (zh) | 2011-02-01 | 2012-02-01 | 单相固溶铸造或锻造镁合金 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11152827.9A EP2481825B1 (fr) | 2011-02-01 | 2011-02-01 | Alliage de magnésium contenant des métaux de terres rares |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2481825A1 EP2481825A1 (fr) | 2012-08-01 |
EP2481825B1 true EP2481825B1 (fr) | 2013-05-08 |
Family
ID=45715076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11152827.9A Not-in-force EP2481825B1 (fr) | 2011-02-01 | 2011-02-01 | Alliage de magnésium contenant des métaux de terres rares |
Country Status (5)
Country | Link |
---|---|
US (1) | US20120195787A1 (fr) |
EP (1) | EP2481825B1 (fr) |
CN (1) | CN102628134B (fr) |
CA (1) | CA2765484A1 (fr) |
ES (1) | ES2423354T3 (fr) |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102009025511A1 (de) * | 2009-06-19 | 2010-12-23 | Qualimed Innovative Medizin-Produkte Gmbh | Implantat mit einem vom Körper resorbierbaren metallischen Werkstoff |
CN103820689B (zh) * | 2012-11-19 | 2016-01-20 | 北京有色金属研究总院 | 含两系稀土的高强耐热镁合金及其制备加工方法 |
CN103014467A (zh) * | 2012-12-20 | 2013-04-03 | 常熟市东方特种金属材料厂 | 一种镁-钬合金 |
CN103014469A (zh) * | 2013-01-08 | 2013-04-03 | 哈尔滨工程大学 | 一种抗冲击的高强镁合金材料及制备方法 |
CN103060649A (zh) * | 2013-01-16 | 2013-04-24 | 燕山大学 | 一种低温高韧性镁合金薄板 |
JP6439683B2 (ja) * | 2013-04-15 | 2018-12-19 | 国立大学法人 熊本大学 | 難燃マグネシウム合金及びその製造方法 |
CN104690236A (zh) * | 2013-12-10 | 2015-06-10 | 陕西宏远航空锻造有限责任公司 | 一种控制耐热钢晶粒度的生产方法 |
IL230631A (en) * | 2014-01-23 | 2016-07-31 | Dead Sea Magnesium Ltd | High performance creep resistant magnesium alloys |
RU2554269C1 (ru) * | 2014-03-03 | 2015-06-27 | Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" (ФГУП "ВИАМ") | Сплав на основе магния и изделие, выполненное из него |
CN104004936A (zh) * | 2014-05-21 | 2014-08-27 | 上海交通大学 | 一种锆细化复合低温浇注制备稀土镁合金半固态浆料的方法 |
CN104131204B (zh) * | 2014-08-19 | 2017-01-25 | 中国科学院长春应用化学研究所 | 一种镁合金、镁合金复合材料及其制备方法 |
CN104195483B (zh) * | 2014-08-19 | 2016-06-01 | 中国科学院金属研究所 | 一种提高Mg-Zn-Y-Zr镁合金耐腐蚀性的热处理工艺 |
CN104278185A (zh) * | 2014-11-03 | 2015-01-14 | 北京汽车股份有限公司 | 一种汽车用含SiC颗粒的高强高模量稀土镁基复合材料 |
CN105525172A (zh) * | 2014-11-13 | 2016-04-27 | 比亚迪股份有限公司 | 一种镁合金及其制备方法和应用 |
CN104630895B (zh) * | 2014-12-30 | 2017-10-13 | 中国兵器科学研究院宁波分院 | 一种单晶镁合金生物降解材料及其制备方法 |
CN106148785A (zh) * | 2015-04-20 | 2016-11-23 | 中国科学院金属研究所 | 一种室温高延展性变形镁合金及其制备方法 |
CN105568103A (zh) * | 2016-01-04 | 2016-05-11 | 青岛工学院 | 一种可降解生物医用镁合金 |
CN106367649A (zh) * | 2016-09-30 | 2017-02-01 | 肖旅 | 易于制备和塑性成形的镁合金及其构件制造方法 |
CN106399784A (zh) * | 2016-10-31 | 2017-02-15 | 上海航天精密机械研究所 | 一种近无共晶凝固相的铸造镁合金及其铸件的制造方法 |
CN106591659A (zh) * | 2016-12-29 | 2017-04-26 | 中国科学院长春应用化学研究所 | 一种高强高韧铸造稀土镁合金及其制备方法 |
CN107354357B (zh) * | 2017-06-28 | 2019-10-25 | 中国科学院长春应用化学研究所 | 一种变形镁合金及其制备方法 |
CN107354356B (zh) * | 2017-06-28 | 2019-12-27 | 中国科学院长春应用化学研究所 | 一种砂型铸造镁合金及其制备方法 |
CN107829004A (zh) * | 2017-10-26 | 2018-03-23 | 安徽恒利增材制造科技有限公司 | 一种锌镁合金铸锭及其制备方法 |
CN107974599A (zh) * | 2017-11-16 | 2018-05-01 | 上海航天精密机械研究所 | 一种低成本稀土铸造镁合金及其铸件的制造方法 |
CN109666832A (zh) * | 2019-02-22 | 2019-04-23 | 中国科学院长春应用化学研究所 | 高强耐热变形镁合金及其制备方法 |
CN111155014B (zh) * | 2020-02-08 | 2021-09-07 | 苏州轻金三维科技有限公司 | 一种三维打印用高强度合金及其制备方法 |
CN112746210B (zh) * | 2021-02-01 | 2021-10-12 | 太原理工大学 | 一种多元微合金化镁合金及其制法和板材挤压成形工艺 |
CN112941385B (zh) * | 2021-02-03 | 2022-05-20 | 中南大学 | 一种低稀土含量高疲劳性能镁合金板材及其制备方法 |
CN113088778B (zh) * | 2021-04-02 | 2022-02-08 | 北京理工大学 | 一种高强高刚度镁合金及其制备方法 |
CN113249602B (zh) * | 2021-05-28 | 2022-01-28 | 西南大学 | 一种耐腐蚀的铸造镁合金及其制备方法 |
CN113373361A (zh) * | 2021-06-22 | 2021-09-10 | 河北钢研德凯科技有限公司 | 高强铸造镁合金及其制备方法和应用 |
CN114574743A (zh) * | 2022-03-02 | 2022-06-03 | 东北大学 | 一种中强高塑性的Mg-Ce-Sm系板材及其预拉伸强化方法 |
CN114892055B (zh) * | 2022-05-25 | 2023-09-05 | 鹤壁海镁科技有限公司 | 一种高强韧Mg-Al-Zn镁合金及其制备方法 |
CN115029595A (zh) * | 2022-06-13 | 2022-09-09 | 镁高镁诺奖(铜川)新材料有限公司 | 一种镁合金丝材及其制备方法 |
CN115233061B (zh) * | 2022-06-30 | 2023-05-09 | 上海航天精密机械研究所 | 一种超高塑性稀土变形镁合金板材及其制备方法 |
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AUPS311202A0 (en) * | 2002-06-21 | 2002-07-18 | Cast Centre Pty Ltd | Creep resistant magnesium alloy |
KR100605741B1 (ko) * | 2004-04-06 | 2006-08-01 | 김강형 | 내식성과 도금성이 우수한 마그네슘합금 단련재 |
US20080138236A1 (en) * | 2005-03-08 | 2008-06-12 | G. Alloy Technology Co, Ltd. | Mg Alloys Containing Misch Metal Manufacturing Method of Wrought Mg Alloys Containing Misch Metal, and Wrought Mg Alloys Thereby |
DE112006001375T5 (de) * | 2005-05-26 | 2008-04-10 | Cast Centre Pty., Ltd., St. Lucia | Hochdruckguss-Magnesiumlegierung |
WO2009039581A1 (fr) * | 2007-09-28 | 2009-04-02 | Cast Crc Limited | Alliage de magnésium moulé en coquille |
US20100310409A1 (en) * | 2008-01-09 | 2010-12-09 | Cast Crc Limited | Magnesium based alloy |
GB0817893D0 (en) * | 2008-09-30 | 2008-11-05 | Magnesium Elektron Ltd | Magnesium alloys containing rare earths |
PT2493523E (pt) * | 2009-10-30 | 2014-08-05 | Acrostak Corp Bvi Tortola | Dispositivos médicos biodegradáveis implantáveis formados a partir de material à base de magnésio ultra puro |
CN101787472B (zh) * | 2010-03-18 | 2011-04-20 | 上海交通大学 | 耐热锻压镁稀土合金及其制备方法 |
-
2011
- 2011-02-01 ES ES11152827T patent/ES2423354T3/es active Active
- 2011-02-01 EP EP11152827.9A patent/EP2481825B1/fr not_active Not-in-force
-
2012
- 2012-01-18 US US13/352,595 patent/US20120195787A1/en not_active Abandoned
- 2012-01-25 CA CA2765484A patent/CA2765484A1/fr not_active Abandoned
- 2012-02-01 CN CN201210022436.1A patent/CN102628134B/zh not_active Expired - Fee Related
Non-Patent Citations (2)
Title |
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HONMA ET AL: "Effect of Zn additions on the age-hardening of Mg-2.0Gd-1.2Y-0.2Zr alloys", ACTA MATERIALIA, ELSEVIER, OXFORD, GB, vol. 55, no. 12, 8 June 2007 (2007-06-08), pages 4137 - 4150, XP022110797, ISSN: 1359-6454, DOI: 10.1016/J.ACTAMAT.2007.02.036 * |
YAMADA KENTARO ET AL: "Precipitate microstructures of high strength Mg-Gd-Y- Zn - Zr alloys", 1 January 2006, ADVANCED MATERIALS RESEARCH,, PAGE(S) 417 - 420, ISSN: 1022-6680, XP009092939 * |
Also Published As
Publication number | Publication date |
---|---|
CN102628134B (zh) | 2016-06-29 |
ES2423354T3 (es) | 2013-09-19 |
CA2765484A1 (fr) | 2012-08-01 |
CN102628134A (zh) | 2012-08-08 |
EP2481825A1 (fr) | 2012-08-01 |
US20120195787A1 (en) | 2012-08-02 |
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