EP2480359A1 - Method for producing a green compact - Google Patents
Method for producing a green compactInfo
- Publication number
- EP2480359A1 EP2480359A1 EP10765568A EP10765568A EP2480359A1 EP 2480359 A1 EP2480359 A1 EP 2480359A1 EP 10765568 A EP10765568 A EP 10765568A EP 10765568 A EP10765568 A EP 10765568A EP 2480359 A1 EP2480359 A1 EP 2480359A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- working space
- subset
- partial
- green compact
- partial green
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- 239000000126 substance Substances 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 33
- 238000005304 joining Methods 0.000 claims description 29
- 238000004590 computer program Methods 0.000 claims description 24
- 238000003825 pressing Methods 0.000 claims description 21
- 239000000956 alloy Substances 0.000 claims description 10
- 229910045601 alloy Inorganic materials 0.000 claims description 10
- 238000007906 compression Methods 0.000 claims description 5
- 230000006835 compression Effects 0.000 claims description 4
- 238000012546 transfer Methods 0.000 claims description 4
- 241001464837 Viridiplantae Species 0.000 claims description 3
- 241001417941 Hexagrammidae Species 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 6
- 238000005245 sintering Methods 0.000 description 8
- 238000005056 compaction Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000005352 clarification Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 230000000754 repressing effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
- B22F3/03—Press-moulding apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/06—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
- B22F7/062—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools involving the connection or repairing of preformed parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B11/00—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses
- B30B11/02—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses using a ram exerting pressure on the material in a moulding space
Definitions
- the invention relates to a method for producing a green compact, wherein the green compact comprises at least two partial green compacts.
- EP 399 630 B1 discloses a process for the production of a green compact wherein powder material is precompressed into a first green compact and subsequently a second, separately precompacted green compact or a solid part is inserted into a cavity of the first green compact in the press. Thereafter, the composite green compact is final compressed.
- the object of the invention is to provide an improved process for producing a green compact.
- a method for producing a green compact is proposed, wherein the green compact comprises at least two partial green compacts, wherein the partial green compacts are each pressed and joined at least from one pulverulent substance in one operation.
- the partial green compacts are each pressed and joined at least from one pulverulent substance in one operation.
- two, three, four or more than four partial green compacts can be pressed and joined or pressed, brought together and joined in one single operation.
- the proposed method is much faster than a separate compaction of all partial green compacts to be joined with a subsequent assembly of the partial green compacts.
- the partial green compacts are pressed in the same tool.
- at least one partial green compact can be precompressed and subsequently compacted or densified before or after the joining.
- the joined green compact is preferably densified or densified in the same tool.
- all partial green compacts to be joined are compacted before or during joining in such a way that re-compaction does not have to be carried out after joining.
- a further embodiment provides that the powdery material is supplied in a first step at least one filling space of a tool and in a second step, the powdery substance is separated into at least two subsets.
- a first subset of the powdery substance is fed to a first working space and a second subset is supplied to a second working space.
- Under working space are in particular cavities in a pressing tool to understand, which can be filled with a powder and in which a pressing operation or a compression of the powder can be made.
- the work spaces are limited at least by a ram.
- the working space is bounded by at least two press dies and / or by one die.
- the working space may be designed to be movable, so that, for example, a pressing operation of the pulverulent substance or of the subset which is arranged in the working space can be carried out during a movement of the entire working space. Also, the movement of the working space and arranged in this subset of the powdery substance is provided without compacting the same in one embodiment.
- the filling space is a space in which the powdery substance is filled. This can in particular include at least one workspace. In particular, it is provided that in each case a filling space is provided for at least two subsets. An embodiment also provides that a first subset of the powdery substance is filled into a first filling space and a second quantity of the powdered substance is filled into a second filling space.
- the pulverulent substance is filled into exactly one filling space and is separated, for example, into at least two subsets by means of at least one pressing punch, preferably an upper punch and / or a lower punch.
- the subsets are preferably transferred by means of the press ram into separate working spaces of the same tool.
- the method further offers an advantage if the partial green compacts are first pressed separately in a tool, then brought together and then joined.
- the separated subsets of the powdery substance are pressed in the tool to two separate partial green bodies and brought together in a subsequent step in the tool.
- Separate pressing can mean that the subsets of the powdery material are spaced apart from each other in the tool so that two separate, spaced-apart working spaces are formed in the tool, in which separate green compacts, which are then called partial green bodies, are produced. It is also possible that during the pressing of the partial green compacts the ram of the adjacent working space forms a working space for each other compact or partial green.
- a pressing die arranged in the center of the tool can form a cavity in a first working space for a first partial green body, while the outer pressing dies for the first partial green compact have an outer Make working space for a second Opera essenceling, which is formed by means of the middle press ram.
- the embodiment is not limited to the fact that the two partial green compacts are pressed only separately, but it is also possible to first press a partial green compact in a first separate spaced working space and to transfer this partial green compact in the second working space for the second part green. Subsequently, during the pressing of the second partial green compact, the first partial green compact is held in its working space so that the first partial green compact is immediately joined with the resulting second partial green compact. The merging of the first and second Opera indispensableling is thus moved in a working phase of the tool in which the second part green compact is pressed.
- Press punch is the generic term for lower punch and upper punch.
- powdered material can be pressed, that is to say compacted, and a combination of partial green bodies can be carried out by means of a press punch.
- a joining space is kept free.
- this joining space is at least partially limited by a further subset of the powdery substance.
- a joining space is to be understood as meaning the space within a subset or a partial green part into which a further sub-greening is joined.
- the subsets of the powdered substance are pressed in the first working space to a first partial green body and in the second working space to a second partial green body.
- a variant provides that at least one first partial green compact is joined with a second partial green compact before or during demoulding from the tool.
- the partial green bodies are joined and demolded in a subsequent step.
- the partial green compacts can be joined at the same time as the green compact is removed, wherein, for example, the second green part is moved out of the mold in an ejection direction, which is transferred into the first green part, preferably into its joining space.
- the one or more press dies that have joined the second part greening in the first part green come to a standstill.
- the second subset is pressed to form a second sub green item and the second sub green item is transferred into the first working space.
- an embodiment provides that the first subset is compressed in the first working space, after the second sub green sheet has been transferred to the first working space. Furthermore, too the first subset is compressed in the first working space, while the second sublingue is transferred to the first working space.
- Sintered components are susceptible to cracking during the actual compaction as well as the demoulding and the subsequent handling at cross-sectional transitions inter alia by density inhomogeneities or axial and radial stresses in the tool.
- the risk of cracking at the cross-sectional transitions are avoided by the proposed method, since the at least two partial green compacts are compacted independently of each other without interference at cross-sectional transitions and then joined in one operation.
- a particularly preferred fit between the parts to be joined is achieved by keeping the joining space free by at least one ram.
- the green compact is sintered following removal from the mold and, if appropriate, after further processing steps of the green compact, the high accuracy of fit results in sintering at the contact surfaces of the partial green compacts.
- the partial green compacts are joined in a press fit.
- first subset and the second subset have different alloys. Furthermore, it is provided in one embodiment that the first subset and the second subset have a same alloy.
- the partial green compacts may have the same alloy or have an alloy which has substantially the same or exactly the same shrinkage behavior.
- the proposed method is no longer necessary to achieve a sufficient connection of the green parts, for example a press fit by sintering in particular different materials or materials with different shrinkage behavior, but the compound of the green parts is sufficient for a firm grip already after the pressing process.
- the mechanical interlocking of the partial green compacts after demolding is sufficiently high to ensure oven transport to the sintering, preferably of the part of the green compacts a surface pressure in at least a partial region of the contact surfaces of 0.1 N / mm 2 to 100N / mm 2, further preferably 1 N / mm 2 to 50 N / mm 2 , more preferably 2 N / mm 2 to 30 N / mm 2 .
- the partial green plants After sintering, in particular in the case of intersectoral sintering between the partial green bodies, the partial green plants have a strength which corresponds almost to that of the residual microstructure, in particular a strength of 70% to 99% of the residual microstructure, furthermore preferably 90% to 100% of the residual microstructure.
- the powdery substance is filled into a filling space of a tool, wherein the tool has at least a first lower punch, a second lower punch, a first upper punch and a second upper punch, wherein a first working space at least through the first upper punch and the first Lower stamp is limited and is preferably part of the filling space.
- the second lower punch and the second upper punch transfer a subset of the powdered substance into a second working space, wherein the second working space is delimited at least by the second upper punch and the second lower punch and is preferably arranged outside the first working space.
- the subsets of the powdery substance are pressed at least in the first working space to a first partial green body and in the second working space to a second partial green body.
- the second partial green compact is moved into the first working space before, during or after a compression of the first partial green compact to add the partial green compacts.
- the working spaces before and / or during pressing of at least one of the partial green bodies have no contact surfaces, so that a compression of the powdery substance occurs at least partially and / or at least in a working space separately.
- a further aspect of the invention is a tool for a press for pressing and joining at least two partial green compacts, wherein the tool has at least a first and a second upper punch and a first and a second lower punch, wherein at least the first lower punch and the first upper punch independent of the second lower punch and the second upper punch is movable.
- a first working space can be formed at least by means of the first upper punch and the first lower punch
- a second work space can be formed, at least by means of the second upper punch and the second lower punch.
- the second working space is also at least partially limited or at least partially defined by the first upper punch or the first lower punch.
- first working space and / or the second working space is at least partially limited or defined by at least one die. It is also provided in one embodiment that at least a third press die at least partially limit or define the first and / or the second working space.
- a variant provides that at least by means of the second upper punch or the second lower punch a Fügeraum in the first working space is vorhaltbar, in which the second Opera indispensableling is transf erierbar.
- the press die which holds the joining space, in particular has a slightly smaller diameter than the part green, which is joined in the joining space. The difference or the excess corresponds to the punch clearance between the first lower punch and the second Upper temple. Stamp games are between about 0.005 and about 0.025mm.
- the force for joining the partial green bodies depends on the contact surface between the partial green bodies to be joined, that is, the larger the contact area, the greater the force applied to the partial green body.
- the portion of green compact is in particular with a force of about 1 N / mm 2 to Loon / mm 2, preferably pre-pressed in the joining area between about 10 N / mm 2 and 50 N / mm 2.
- a further aspect of the invention provides for use of a tool as described above for a method as described above.
- a further aspect of the invention provides a computer program product for a press for pressing and joining at least two partial green compacts in one operation, the press having at least a first upper punch, a first lower punch, a second upper punch and a second lower punch, the press being actuated in this manner is that after filling a filling space with at least one powdery substance, at least a second sub-punch and a second upper punch a second subset of the powdered substance separated from a first subset.
- the press is controlled such that a first subset of the powdery substance is supplied to a first working space and a second subset is supplied to a second working space.
- the control takes place in such a way that a first press ram at least partially serves as a die of the second working space, that is to say that the second work space is arranged at least partially within the first upper punch or the first lower punch.
- the press is controlled in such a way that a first part green compact is pressed in a first working space and a second part green compact is pressed in a second working space.
- the computer program product preferably controls the press in such a way that the first partial green compact and the second partial green compact are joined before demoulding.
- a computer program product offers an advantage when the computer program product controls the press such that the separate subsets are pressed into partial greenhouses, then merged and then joined.
- a separate pressing of the partial quantities of the pulverulent substance in separate spaced work spaces can first be controlled before a merging, that is, a superimposition or telescoping of the partial green bodies takes place.
- the joining subsequently controls the computer program product such that the two partial green compacts are brought together and joined with or without repressing.
- a control by means of the computer product is also possible to the effect that in a first step in a first working space, a first partial green body is formed, then subsequently in a second step, the first partial green body formed in the working space of the second partial green compact is moved and finally in a third step the second partial green compact is pressed.
- An ejection of the joined partial green bodies then takes place by means of an opening of the tool and a removal or ejection of the joined partial green compacts for further processing.
- the computer program product controls the press by means of a route control or path control.
- Preferred is a closed loop for controlling the press.
- the computer program product controls the press in such a way that the press punches apply a predetermined force to the powdery substance or perform a predetermined work on the powdery substance.
- a combination of displacement and force control is provided.
- a closed loop for controlling the press is provided in one embodiment.
- a further aspect of the invention is a control device for a press, in particular with a tool described above, the control device having a computer program product described above.
- the control device has a closed loop for a travel control and / or a force control of the press.
- Another aspect of the invention relates to a green compact comprising at least two partial green compacts which are joined by means of a method described above.
- the partial green plants are fitted accurately.
- the green compact can be joined in one embodiment of two, three, four or more than four partial green. It is also provided in one embodiment that the green compact has one or more than one alloy. In particular, all partial green compacts have the same alloy. Furthermore, it is provided in one embodiment that at least two partial green bodies have a different alloy.
- Fig. 3 shows a selection embodiments of mated partial green
- FIG. 4 shows a micrograph of a sintered green body consisting of two partial green bodies.
- FIG. 1 shows a sequence A to E of compacting and joining two partial green compacts in one operation.
- At least a first upper punch 1, a first lower punch 2, a second upper punch 3, a second lower punch 4 and a die 5 form a tool 6.
- the tool 6 is opened for filling with a powdery substance 11 and, as shown in step A, who - The first lower punch 2 and the second lower punch 4 process such that a filling space 16 is formed. In the filling space 16 of the powdery substance is filled.
- step B it can be seen that the tool is closed and in particular a first upper punch 1 and a second punch 3 delimits the filling space, in particular upwards. Furthermore, step B shows that the second upper punch 3 and the second lower punch 4 are moved such that a first subset 7 of the powdery substance 11 is separated from a second subset 9 of the powdery substance 11. In particular, the second subset 9 is transferred into a second working space 10, wherein a first subset remains in a first working space 8.
- the filling space 16 comprises the first working space 8.
- step C the press dies go together. It can be seen that the first upper punch 1 and the first lower punch 2 press the first subset 7 in the first working space 8 to form a first partial green 12. Furthermore, the second subset 9 is pressed in the second working space 10 by means of the second upper punch 3 and the second lower punch 4 to a second partial green compact 13. By means of the second upper punch 3, a joining space 15 within the first working space 8 is kept free in this embodiment. In particular, the joining space 15 is at least partially bounded by the first partial green body 12 after the pressing process.
- Step D shows the merging, that is, how the second upper punch 3 and the second lower punch 4 move the second partial green compact 13 into the joining space 15 and thus join the first partial green 12 and the second green 13.
- the first partial green compact 12 is moved in such a way by means of the first upper punch 1 and the first lower punch 2 that the partial green bodies 12, 13 are joined.
- the partial green bodies 12, 13 are again compacted after the joining by means of the press dies 1, 2, 3, 4.
- the finished green compact 14 is formed from the tool 6.
- the green body 14 is calibrated after shaping and / or subjected to a machining operation.
- the green compact 14 is sintered after molding.
- FIG. 2 shows an alternative embodiment of pressing and joining partial green bodies.
- step A the powdery substance 11 is filled into the filling space 16.
- the first lower punch 2, the second lower punch 4, the die 5 form the filling chamber 16 in this embodiment.
- step B similar to the method step shown in step B of FIG. 1, a second subset 9 is moved into a second working space 10, while a first subset 7 remains in the first working space 8.
- step C it can be seen that the second subset 9 is compressed to form a second sub green 13.
- the first subset 7 is not or only slightly compressed.
- the compression process begins during or after compaction of the second partial green compact 13, wherein this is not completed after compaction of the second partial green compact 13.
- step D the second partial green compact 13 is transferred, moved or moved into the joining space 15, which was kept free by the second upper punch 3.
- the pressing process of the first subset 7 to the first partial green compact 12 is started.
- Step E shows the finished joined and pressed green compact 14 in the tool 6.
- the second partial green compact 13 is moved relative to the matrix 5 in the exemplary embodiment shown.
- the first upper punch 1 and the second upper punch 3 are moved synchronously, preferably also the second lower punch relatively.
- step F the finished green compact 14 is removed from the mold.
- Fig. 3 shows a not complete selection of embodiments of the green body 14.
- the geometric shape is selected here purely by way of example; Various shapes, not shown here, can be realized. It is also provided to combine the embodiments shown here with each other and / or with other shapes not shown here to further embodiments.
- Embodiment A shows a green body 14 having a first partial green 12 and a second partial green 13.
- the second partial green 13 protrudes beyond the first partial green 12 so that the green compact 14 has a cross-sectional change 16, which is formed in particular medially.
- Embodiment B shows a green body 14, the second partial green body 13 is formed as a pipe or hollow part. Furthermore, it can be seen in embodiment C that the first partial green 12 is formed as a hollow part and in particular projects beyond the second partial green 13. The cross-sectional change 16 is formed laterally here.
- Embodiment D shows a further variant of a lateral cross-sectional change 16.
- the second partial green compact 13, which projects beyond the first partial green compact 12, is only partially enclosed by the first partial green compact 12 in a cross section.
- Embodiment E shows that the second partial green body 13 projects beyond the first partial green body 12 on both sides. Furthermore, it can be seen in embodiment F that more than two partial green bodies can be joined. In particular, in embodiment F, four partial green compacts are joined. However, it is provided in further embodiments that three, five or more than five partial green compacts are added.
- FIG. 4 shows an etched micrograph of a joined and sintered green compact 14 made of a first partial green compact 12 and a second partial green compact 13.
- An interface 17 can be recognized between the partial green bodies 12, 13 and extended by means of a dashed line for clarification. However, it can also be seen from FIG. 4 that a grain-spanning sintering 18 has taken place across borders.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Powder Metallurgy (AREA)
- Forging (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009042598A DE102009042598A1 (en) | 2009-09-23 | 2009-09-23 | Process for producing a green body |
PCT/EP2010/005595 WO2011035862A1 (en) | 2009-09-23 | 2010-09-13 | Method for producing a green compact |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2480359A1 true EP2480359A1 (en) | 2012-08-01 |
EP2480359B1 EP2480359B1 (en) | 2021-12-22 |
Family
ID=43301764
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10765568.0A Active EP2480359B1 (en) | 2009-09-23 | 2010-09-13 | Method for producing a green compact apparatus for the manufacture thereof and computer programm |
Country Status (8)
Country | Link |
---|---|
US (1) | US9662708B2 (en) |
EP (1) | EP2480359B1 (en) |
JP (1) | JP6043628B2 (en) |
CN (2) | CN105772717A (en) |
DE (1) | DE102009042598A1 (en) |
ES (1) | ES2907455T3 (en) |
IN (1) | IN2012DN03053A (en) |
WO (1) | WO2011035862A1 (en) |
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JP5601578B2 (en) * | 2010-10-29 | 2014-10-08 | 日立化成株式会社 | Molding device for micro parts |
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DE102011118054A1 (en) * | 2011-11-09 | 2013-05-16 | Dorst Technologies Gmbh & Co. Kg | Method and press for pressing a compact of at least two different metallic and / or ceramic powder and / or granular materials |
DE102012103115A1 (en) * | 2012-04-11 | 2013-10-17 | PMCtec GmbH | Forming low density molded article e.g. gear, by adding phenolic resin having binding agent to base material to form mixture, pressing mixture into pressed part using stamper, and solidifying agent by chemical reaction to form article |
KR101552018B1 (en) * | 2012-11-07 | 2015-09-09 | 오씨아이 주식회사 | Apparatus for molding core of vacuum insulation panel and vacuum insulation panel manufactured thereby |
DE102014003726A1 (en) * | 2014-03-18 | 2015-09-24 | Gkn Sinter Metals Engineering Gmbh | Press for producing dimensionally stable green compacts and method for manufacturing |
DE102014008169A1 (en) | 2014-06-10 | 2015-12-17 | Gkn Sinter Metals Engineering Gmbh | Method and press for producing a green composite with a predetermined breaking point |
AT515961B1 (en) | 2014-06-18 | 2017-04-15 | Miba Sinter Austria Gmbh | Method and device for pressing a green compact |
DE102015201873A1 (en) | 2015-02-03 | 2016-08-18 | Gkn Sinter Metals Engineering Gmbh | Silent gear |
DE112016001673T5 (en) * | 2015-04-10 | 2017-12-28 | Gkn Sinter Metals, Llc. | A method of forming a composite component using dimensional change by densification |
DE102015207748A1 (en) | 2015-04-28 | 2016-11-03 | Gkn Sinter Metals Engineering Gmbh | fluid pump |
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JP6811566B2 (en) * | 2016-08-16 | 2021-01-13 | 株式会社ダイヤメット | Manufacturing equipment and manufacturing method for multi-layer molded products |
DE102016123580B4 (en) | 2016-12-06 | 2021-09-09 | Gkn Sinter Metals Engineering Gmbh | Rotor part of a rotor for a camshaft adjuster and pressing tool for its powder-metallurgical production |
DE102016125659B4 (en) | 2016-12-23 | 2020-12-03 | Gkn Sinter Metals Engineering Gmbh | Green compact of a stator cover unit |
CN107812949A (en) * | 2017-10-30 | 2018-03-20 | 中国有色桂林矿产地质研究院有限公司 | A kind of ring shaped tyre of welded type drill bit and preparation method thereof |
CN107812950B (en) * | 2017-10-30 | 2019-11-05 | 中国有色桂林矿产地质研究院有限公司 | The method that thin diamond wall jacking grooved bit monoblock type bores tooth is prepared using pressureless sintering method |
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- 2009-09-23 DE DE102009042598A patent/DE102009042598A1/en not_active Ceased
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2010
- 2010-09-13 EP EP10765568.0A patent/EP2480359B1/en active Active
- 2010-09-13 JP JP2012530150A patent/JP6043628B2/en active Active
- 2010-09-13 CN CN201610222811.5A patent/CN105772717A/en active Pending
- 2010-09-13 IN IN3053DEN2012 patent/IN2012DN03053A/en unknown
- 2010-09-13 CN CN201080042511.XA patent/CN102762321B/en active Active
- 2010-09-13 ES ES10765568T patent/ES2907455T3/en active Active
- 2010-09-13 WO PCT/EP2010/005595 patent/WO2011035862A1/en active Application Filing
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Also Published As
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US20120216654A1 (en) | 2012-08-30 |
EP2480359B1 (en) | 2021-12-22 |
DE102009042598A1 (en) | 2011-03-24 |
WO2011035862A1 (en) | 2011-03-31 |
CN102762321B (en) | 2016-05-11 |
CN102762321A (en) | 2012-10-31 |
JP6043628B2 (en) | 2016-12-14 |
ES2907455T3 (en) | 2022-04-25 |
CN105772717A (en) | 2016-07-20 |
JP2013505360A (en) | 2013-02-14 |
IN2012DN03053A (en) | 2015-07-31 |
US9662708B2 (en) | 2017-05-30 |
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