EP2459281A2 - Agent cosmétique - Google Patents

Agent cosmétique

Info

Publication number
EP2459281A2
EP2459281A2 EP10731758A EP10731758A EP2459281A2 EP 2459281 A2 EP2459281 A2 EP 2459281A2 EP 10731758 A EP10731758 A EP 10731758A EP 10731758 A EP10731758 A EP 10731758A EP 2459281 A2 EP2459281 A2 EP 2459281A2
Authority
EP
European Patent Office
Prior art keywords
group
monomer
formula
methacrylate
integer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP10731758A
Other languages
German (de)
English (en)
Inventor
Thorsten Knappe
Marcus Noll
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP2459281A2 publication Critical patent/EP2459281A2/fr
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the present invention relates to cosmetic compositions containing a specific combination of polymers and the use of these agents, in particular for the temporary deformation of keratinous fibers.
  • keratinic fibers in principle, all animal hair, e.g. Wool, horsehair, angora hair, furs, feathers and products or textiles made from them.
  • animal hair e.g. Wool, horsehair, angora hair, furs, feathers and products or textiles made from them.
  • the keratinic fibers are human hairs.
  • polymers in various cosmetic products is widespread. They are found in agents for the treatment of the skin as well as in means for the treatment of hair, in agents which are washed off or washed off again immediately after use, so-called rinse-off products, as well as in compositions which are applied to the skin or skin Hair remains, so-called leave-on remedies.
  • the polymers are used for various reasons and in each case exploited certain properties of the polymers.
  • agents for skin treatment in shampoos, hair conditioners and hair treatments, the thickening or care properties of the polymers are often in the foreground.
  • styling agents in addition to these properties, above all film-forming and / or strengthening effects are required.
  • polymers also serve as an aid to improve the deposition and fixation of other active ingredients and ingredients on the skin or hair or make it possible.
  • rubbing fastness and the stability of the dyeing can be increased.
  • cosmetic products contain individual polymers that are specially tailored to achieve a very specific effect. If different effects are to be achieved, the addition of several polymers is required. However, using too many different polymers can bring a number of disadvantages. Thus, formulation problems may arise, for example because the polymers react with each other or with other ingredients of the composition and precipitates or decomposes. Certain polymers also tend to deposit so consistently on the skin, and more particularly on the hair, that they are no longer completely removed in an ordinary wash and there is an undesirable accumulation of the polymer and thus ultimately stress on the skin or hair.
  • styling agents it is necessary for the polymers used to give the treated hair the strongest possible hold.
  • styling agents must meet a whole range of other requirements. These may be broadly subdivided into properties on the hair, properties of the particular formulation, eg properties of the foam, of the gel or of the sprayed aerosol, and of properties relating to the handling of the styling agent, whereby the properties on the hair are of particular importance. Particularly noteworthy are moisture resistance, low tackiness and a balanced conditioning effect.
  • a styling agent should be universally applicable as possible for all hair types. If the styling agent is a gel or a paste, the polymers should also have thickening properties.
  • the object of the present invention was therefore to provide suitable polymer combinations which confer optimized properties on cosmetic agents even without the addition of further active ingredients.
  • cosmetic products with the o.g. Polymer combination can be thickened storage stable and at the same time have good film-forming and / or strengthening properties.
  • Styling agents containing the polymers should have a very high degree of retention without the need for flexibility and good moisture resistance - especially welding and water resistance - would have to be omitted.
  • the production of stable viscous and stable transparent cosmetic compositions with this polymer combination should be made possible.
  • a first subject of the present invention is therefore a cosmetic agent containing in a cosmetically acceptable carrier
  • At least one monomer A1 selected from acrylic acid, methacrylic acid, alkyl acrylates and alkyl methacrylates, and at least one amphoteric monomer A2 selected from (meth) acryloylalkylaminoxiden of the formula A2-I
  • R 1 is H or CH 3 ,
  • R 2 and R 3 each independently represent optionally branched d.-io-alkyl and
  • n stands for an integer from 1 to 20
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * wherein x is an integer from 5 to 35, a group * - (CH 2 CHMeO) y - * where y is an integer of 5 to 35 or a group * - (CH 2 CH 2 ⁇ ) x - (CH 2 CHMeO) y - * wherein the sum x + y is an integer from 5 to 35 and x and y are greater than zero,
  • R 8 is a (C 6 to C 30 ) alkyl group.
  • Film-forming amphoteric and / or strengthening amphoteric polymers B are known. The same applies to copolymers A and their use as film-forming and / or setting polymers.
  • the cosmetic compositions according to the invention contain at least one copolymer A.
  • copolymers A which are formed from the monomers mentioned are understood to mean only those copolymers which, in addition to polymer units resulting from the incorporation of the stated monomers A1 and A2 into the copolymer, have a maximum of 5% by weight, preferably at most 1% by weight of polymer units due to incorporation of other monomers.
  • the copolymers A are composed exclusively of polymer units resulting from the incorporation of said monomers A1 and A2 into the copolymer.
  • Preferred monomers A1 are acrylic acid, methacrylic acid, acrylic acid C
  • Monomer A1 is particularly preferably selected from acrylic acid, methacrylic acid, methyl acrylate, methyl acrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate, isopropyl acrylate, lauryl acrylate, lauryl methacrylate, cetyl acrylate, cetyl methacrylate, stearyl acrylate and stearyl methacrylate, very particularly preferably from acrylic acid, methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, lauryl acrylate, lauryl methacrylate, stearyl acrylate and stearyl methacrylate.
  • Preferred monomers A2 are (meth) acryloylalkylaminoxide of the formula A2-I and / or (meth) acryloylalkylbetaine of the formula A2-II, wherein R 2 and R 3 are each independently methyl, ethyl, propyl, isopropyl, butyl, isobutyl or tert. -Butyl, particularly preferably methyl.
  • Preferred monomers A2 are furthermore selected from at least one monomer from the group which is formed from (meth) acryloylalkylamine oxides of the formula A2-I and / or (meth) acryloylalkylbetaines of the formula A2-II, where n is in each case an integer from 1 to 5, preferably represents an integer from 1 to 3 and particularly preferably 2.
  • monomers A2 selected from at least one monomer from the group which is formed from (meth) acryloylalkylaminoxiden of the formula A2-I and / or (meth) acryloylalkylbetaines of the formula A2-II, where R 1 is in each case CH 3 .
  • the monomers A2 are particularly preferably selected from at least one monomer from the group which is formed from (meth) acryloylalkylamine oxides of the formula A2-I and / or (meth) acryloylalkylbetaines of the formula A2-II, where R 2 and R 3 are each independently of one another is methyl, ethyl, propyl, isopropyl, butyl, isobutyl or tert-butyl, particularly preferably methyl, n is in each case an integer from 1 to 5, preferably an integer from 1 to 3 and particularly preferably 2, and Each R 1 is CH 3 .
  • monomer A2 selected from at least one monomer from the group formed from (meth) acryloylalkylamine oxides of the formula A2-I and / or (meth) acryloylalkylbetaines of the formula A2-II, where R 1 , R 2 and R 3 each represents CH 3 and n represents 2.
  • the copolymer (A) is (in particular exclusively) formed from at least one monomer of the formula (A1) and at least one monomer corresponding to the respective embodiment of the formula (A2-I).
  • the agent according to the invention contains at least one
  • Copolymer A which is formed from
  • Methacrylic acid ethyl ester propyl acrylate, propyl methacrylate,
  • Diaformer Z-400 is known, for example, under the names Diaformer Z-400, Diaformer Z-AT, Diaformer Z-301 N, Diaformer Z-SM and Diaformer ZW from Clariant and under the names Yukaformer 202, Yukaformer 204, Yukaformer 206 and Yukaformer 301 from Mitsubishi available, with the use of Diaformer Z-301 N is particularly preferred.
  • the agent according to the invention comprises at least one copolymer A, which is formed from
  • the first monomer is selected from acrylic acid, methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate and isopropyl methacrylate
  • copolymers are also known and obtainable, for example, under the name Diaformer Z-632 from Clariant, the use of diaformer Z-632 being particularly preferred.
  • the agent according to the invention contains at least one
  • Copolymer A which is formed from
  • the first monomer being selected from acrylic acid, methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate,
  • the second monomer is selected from acryloyl acrylate and methacrylic acid lauryl ester
  • the third monomer is selected from stearyl acrylate and stearyl methacrylate
  • Corresponding copolymers are likewise known, for example under the names Diaformer Z-611, Diaformer Z-612, Diaformer Z-613, Diaformer Z-631, Diaformer Z-633, Diaformer Z-651, Diaformer Z-711 N, Diaformer Z-712N and Diaformer Z-731 N available from the company Clariant, wherein the use of Diaformer Z-712N and Diaformer Z-651 is preferred.
  • agents according to the invention comprise a mixture of at least two of the copolymers A which are used according to the three preferred embodiments just described.
  • compositions of the invention contain the copolymer A preferably in an amount of 0.01 to 20 wt .-%, particularly preferably 0.05 to 10 wt .-% and most preferably 0.1 to 5 wt .-%, based on the entire means.
  • the agents according to the invention may also comprise a plurality of copolymers A, but the total amount of copolymer A is preferably at most 20% by weight.
  • copolymers A can be prepared by means of the known polymerization of the monomers mentioned and are usually commercially available.
  • the means for the temporary deformation of keratinic fibers according to the invention comprise at least one film-forming and / or setting amphoteric polymer B other than copolymer A.
  • the film-forming and / or setting amphoteric polymer B is preferably selected from the group of copolymers of monomers having carboxy and / or sulfone groups, in particular acrylic acid, methacrylic acid, itaconic acid and monomers having amino groups, in particular monoalkylaminoalkylacrylates, dialkylaminoalkylacrylates, monoalkylaminoalkylmethacrylates, dialkylaminoalkylmethacrylates, monoalkylaminoalkylacrylamides, dialkylaminoalkylacrylamides , Monoalkylaminoalkylmethacrylamides, dialkylaminoalkylmethacrylamides, and the copolymers of N-octylacrylamide, methyl methacrylate, hydroxy
  • the inventive agent comprises as film-forming and / or setting amphoteric polymer B is a N-octylacrylamide / acrylic acid / tert-butylaminoethyl copolymer, particularly preferably, the copolymer of the (by the company National Starch under the name Amphomer ® INCI name: Octylacrylamide / Acrylates / butylaminoethyl methacrylate copolymer).
  • the film-forming and / or setting amphoteric polymer B is preferably in an amount of 0.01 to 20 wt .-%, preferably 0.1 to 15 wt .-%, particularly preferably 1, 0 to 10 wt .-%, based on the entire remedy, included.
  • a plurality of film-forming and / or setting amphoteric polymers B may be present, the total amount of film-forming and / or setting amphoteric polymers B preferably being, however, not more than 20% by weight.
  • the agent In order to obtain the desired properties of the agent according to the invention, the agent must contain both copolymer A and a film-forming and / or setting amphoteric polymer B other than copolymer A.
  • the desirable for styling agent combination of very strong hold and excellent moisture resistance can be obtained. It has been found that an optimum property profile results when the composition comprises the copolymer A and the film-forming and / or setting amphoteric polymer B in a weight ratio of from 1:50 to 20: 1, preferably from 1:30 to 10: 1, more preferably from 1:20 to 5: 1, most preferably from 1:10 to 2: 1.
  • An excess of copolymer A thereby improves the thickening properties of the polymer mixture.
  • the third compulsive component of the present invention contains at least one amphiphilic anionic polymer C.
  • This amphiphilic anionic polymer C is different from the copolymer A and the film-forming amphoteric and / or setting amphoteric polymer B.
  • amphiphilic the skilled artisan generally understands the fact that one and the same molecule comprises hydrophilic structural elements and lipophilic structural elements
  • An “amphiphilic polymer” is understood as meaning a polymer having hydrophilic structural elements adjacent to the polymer backbone and lipophilic structural elements adjacent to the polymeric backbone ,
  • the radical -A 1 -R 8 of the itaconic ester monomer of the formula (C2) of course binds via the carbon atom from A 1 to the remainder of the molecule, R 8 binds to the oxygen terminus of A 1 .
  • Preferred amphiphilic anionic polymers C are formed exclusively from at least one said monomer of formula (C1) and at least one monomer of said formula (C2).
  • Preferred amphiphilic anionic polymers C are those in which at least one of R 6 and R 7 is a group * -A 1 -R 8 and the other is a hydrogen atom, wherein A 1 and R 8 are as defined above.
  • Particularly preferably usable amphiphilic anionic polymers C are characterized in that they are formed from at least one monomer of the formula (C1), and at least one itaconic ester monomer of the formula (C2),
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • At least one radical of R 6 and R 7 is a group -A 1 -R 8 and the other for a
  • a 1 is a group * - (CH 2 CH 2 O) x - * where x is an integer from 5 to 35 (in particular an integer from 10 to 30),
  • R 8 is a (C 6 to C 30 ) alkyl group
  • M + represents one equivalent of a physiologically acceptable cation.
  • amphiphilic anionic polymers C are preferably selected from at least one polymer which is formed the group of acrylates / ceteth-20 itaconate copolymer (such as available as Structure ® 3001 from the company Akzo Nobel) / Palmeth-25 itaconate copolymer (, Acrylates obtainable, for example (as Polygel W30 ® or Polygel W40 ® by the company 3V Sigma), Acrylates / steareth-20 itaconate copolymer, for example, available as Structure ® 2001 by the company Akzo Nobel).
  • Preferred agents are characterized in that they have a viscosity of 1000 to 500,000 mPa s, preferably from 5000 to 300,000 mPas, particularly preferably from 10,000 to 150,000 mPa s (each measured with Brookfield RVDV II + with Heilpath, spindle TE, 5 rpm, 2O 0 C).
  • Preferred agents contain the amphiphilic, anionic polymers C in an amount of 0.1 to 10 wt .-%, based on the weight of the composition.
  • At least one monomer A1 selected from acrylic acid, methacrylic acid, alkyl acrylates and alkyl methacrylates, and
  • amphoteric monomer A2 selected from (meth) acryloylalkylaminoxiden of the formula A2-I
  • R 1 is H or CH 3 (in particular CH 3 ),
  • R 2 and R 3 each independently represent optionally branched d.-io-alkyl and
  • n is an integer from 1 to 4 (especially 2), and b) at least one different from copolymer A film-forming amphoteric and / or strengthening amphoteric polymer B selected from octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer, and
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * wherein x is an integer from 5 to 35, a group * - (CH 2 CHMeO) y - * where y is an integer of 5 to 35 or a group * - (CH 2 CH 2 O) x - (CH 2 CHMeO) y - * wherein the sum x + y is an integer from 5 to 35 and x and y are greater than zero,
  • R 8 is a (C 6 to C 30 ) alkyl group.
  • the first monomer is selected from acrylic acid, methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate and isopropyl methacrylate
  • the second monomer is selected from stearyl acrylate and stearyl methacrylate
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * wherein x is an integer from 5 to 35, a group * - (CH 2 CHMeO) y - * where y is an integer of 5 to 35 stands or a group * - (CH 2 CH 2 ⁇ ) x - (CH 2 CHMeO) y - * where the sum x + y is a whole
  • R 8 is a (C 6 to C 30 ) alkyl group.
  • At least one monomer A1 selected from acrylic acid, methacrylic acid, alkyl acrylates and alkyl methacrylates, and
  • amphoteric monomer A2 selected from (meth) acryloylalkylaminoxiden of the formula A2-I
  • R 1 is H or CH 3 (in particular CH 3 ),
  • R 2 and R 3 are each independently optionally branched
  • n is an integer from 1 to 4 (especially 2), and b) at least one different from copolymer A film-forming amphoteric and / or strengthening amphoteric polymer B selected from octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer and
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * where x is an integer of
  • R 8 represents a (C 6 to C 30 ) alkyl group.
  • a particularly preferred embodiment of the present invention is again a cosmetic agent comprising in a cosmetically acceptable carrier
  • the first monomer is selected from acrylic acid, methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate and isopropyl methacrylate
  • the second monomer is selected from stearyl acrylate and stearyl methacrylate
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * where x is an integer of
  • R 8 represents a (C 6 to C 30 ) alkyl group.
  • a particularly preferred embodiment of the present invention is therefore a cosmetic agent having a viscosity of 1000 to 500,000 mPa s, preferably from 5000 to 300,000 mPa s, more preferably from 10,000 to 150,000 mPa s (each measured with Brookfield RVDV II + with Heilpath, spindle TE , 5 rpm, 2O 0 C) containing, in a cosmetically acceptable carrier
  • At least one monomer A1 selected from acrylic acid, methacrylic acid, alkyl acrylates and alkyl methacrylates, and at least one amphoteric monomer A2 selected from (meth) acryloylalkylaminoxiden of the formula A2-I
  • R 1 is H or CH 3 (in particular CH 3 ),
  • R 2 and R 3 are each independently optionally branched
  • n is an integer from 1 to 4 (especially 2), and b) at least one different from copolymer A film-forming amphoteric and / or strengthening amphoteric polymer B selected from octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer, and
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * wherein x is an integer from 5 to 35, a group * - (CH 2 CHMeO) y - * where y is an integer of 5 to 35 or a group * - (CH 2 CH 2 ⁇ ) x - (CH 2 CHMeO) y - * wherein the sum x + y is an integer from 5 to 35 and x and y are greater than zero,
  • R 8 is a (C 6 to C 30 ) alkyl group.
  • a particularly preferred embodiment of the present invention is again a cosmetic agent having a viscosity of 1000 to 500,000 mPa s, preferably from 5000 to 300,000 mPa s, more preferably from 10,000 to 150,000 mPa s (each measured with Brookfield RVDV II + with Heilpath, spindle TE , 5 rpm, 2O 0 C) containing, in a cosmetically acceptable carrier a) at least one copolymer A formed from
  • the first monomer is selected from acrylic acid, methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate and isopropyl methacrylate
  • the second monomer is selected from stearyl acrylate and stearyl methacrylate
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * wherein x is an integer from 5 to 35, a group * - (CH 2 CHMeO) y - * where y is an integer of 5 to 35 or a group * - (CH 2 CH 2 ⁇ ) x - (CH 2 CHMeO) y - * wherein the sum x + y is an integer from 5 to 35 and x and y are greater than zero,
  • R 8 is a (C 6 to C 30 ) alkyl group.
  • a particularly preferred embodiment of the present invention is again a cosmetic agent having a viscosity of 1000 to 500,000 mPa s, preferably from 5000 to 300,000 mPa s, more preferably from 10,000 to 150,000 mPa s (each measured with Brookfield RVDV II + with Heilpath, spindle TE , 5 rpm, 2O 0 C) containing, in a cosmetically acceptable carrier
  • amphoteric monomer A2 selected from (meth) acryloylalkylaminoxiden of the formula A2-I
  • R 1 is H or CH 3 (in particular CH 3 ),
  • R 2 and R 3 each independently represent optionally branched d.-io-alkyl and
  • n is an integer from 1 to 4 (especially 2), and b) at least one different from copolymer A film-forming amphoteric and / or strengthening amphoteric polymer B selected from octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer and
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * where x is an integer of
  • R 8 represents a (C 6 to C 30 ) alkyl group.
  • a particularly preferred embodiment of the present invention is again a cosmetic agent having a viscosity of 1000 to 500,000 mPa s, preferably from 5000 to 300,000 mPa s, more preferably from 10,000 to 150,000 mPa s (each measured with Brookfield RVDV II + with Heilpath, spindle TE , 5 rpm, 2O 0 C) containing, in a cosmetically acceptable carrier
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * where x is an integer of
  • R 8 represents a (C 6 to C 30 ) alkyl group.
  • All the aforementioned preferred embodiments are again preferably transparent.
  • the agents may furthermore contain all other known film-forming and / or setting polymers.
  • These film-forming and / or setting polymers may be both permanent and temporary cationic, anionic or nonionic.
  • Film-forming polymers are polymers which leave a continuous film on the skin, the hair or the nails when drying.
  • Such film formers can be used in a wide variety of cosmetic products, such as for example face masks, make-up, hair fixatives, hair sprays, hair gels, hair waxes, hair treatments, shampoos or nail varnishes.
  • Particular preference is given to those polymers which have sufficient solubility in alcohol or water / alcohol mixtures in order to be present in completely completely dissolved form in the agent according to the invention.
  • the film-forming polymers may be of synthetic or natural origin.
  • film-forming polymers are understood as meaning polymers which, when used in 0.01 to 20% strength by weight aqueous, alcoholic or aqueous-alcoholic solution, are capable of depositing a transparent polymer film on the hair.
  • Suitable further synthetic, film-forming, hair-fixing polymers are, for example, homopolymers or copolymers which are composed of at least one of the following monomers: vinylpyrrolidone, vinylcaprolactam, vinyl esters such as vinyl acetate, vinyl alcohol, acrylamide, methacrylamide, alkyl- and dialkylacrylamide, alkyl- and dialkylmethacrylamide, Alkyl acrylate, alkyl methacrylate, propylene glycol or ethylene glycol, wherein the alkyl groups of these monomers are preferably C 1 - to C 7 alkyl groups, more preferably C 1 - to C 3 alkyl groups.
  • Examples include homopolymers of vinylcaprolactam, vinylpyrrolidone or N-vinylformamide.
  • Further suitable synthetic film-forming, hair-fixing polymers are copolymers of vinyl pyrrolidone and vinyl acetate, terpolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate, polyacrylamides, for example, under the trade designations Akypomine ® P 191 by the company CHEM-Y, Emmerich or Sepigel ® 305 by the company Seppic be distributed; Polyvinyl alcohols, which are marketed under the trade names Elvanol.RTM ® from DuPont or Vinol ® 523/540 by Air Products as well as polyethylene glycol / polypropylene glycol copolymers, for example, Ucon ® Union Carbide sold under the trade names.
  • Suitable natural film-forming polymers include cellulose derivatives, eg. B. hydroxypropyl cellulose having a molecular weight of 30,000 to 50,000 g / mol, which is sold for example under the trade name Nisso Sl ® from Lehmann & Voss, Hamburg.
  • Firming polymers contribute to the maintenance and / or build-up of the hair volume and hair fullness of the overall hairstyle.
  • These so-called consolidating polymers are at the same time film-forming polymers and therefore generally typical substances for shaping hair treatment compositions such as hair fixatives, hair foams, hair waxes, hair sprays.
  • the film formation can be quite selective and connect only a few fibers.
  • Substances which further impart hydrophobic properties to the hair are preferred because they reduce the tendency of the hair to absorb moisture, that is, water. As a result, the limp drooping of the hair strands is reduced, thus ensuring a long-lasting hairstyle structure and preservation. As a test method for this, the so-called curl retention test is often used.
  • These polymeric substances can also be successfully incorporated into leave-on and rinse-off hair treatments or shampoos. Since polymers are often multifunctional, that is, show several applications-wise desirable effects, numerous polymers can be found in several groups on the mode of action, as well as in the CTFA Handbook.
  • the agents according to the invention contain further film-forming and / or setting polymers, they are preferably used in an amount of from 0.01 to 20% by weight, preferably from 0.1 to 15% by weight, based on the total hair-setting agent.
  • the total amount of further film-forming and / or setting polymers preferably being, however, not more than 20% by weight.
  • At least one monomer A1 selected from acrylic acid, methacrylic acid, alkyl acrylates and alkyl methacrylates, and
  • amphoteric monomer A2 selected from (meth) acryloylalkylaminoxiden of the formula A2-I
  • R 1 is H or CH 3 (in particular CH 3 ),
  • R 2 and R 3 each independently represent optionally branched d.-io-alkyl and
  • n is an integer from 1 to 4 (especially 2), and b) at least one different from copolymer A film-forming amphoteric and / or strengthening amphoteric polymer B selected from octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer, and
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * wherein x is an integer from 5 to 35, a group * - (CH 2 CHMeO) y - * where y is an integer of 5 to 35 or a group ⁇ (CH 2 CH 2 O) x - (CH 2 CHMeO) x - * wherein the sum x + y is an integer from 5 to 35 and x and y are greater than zero,
  • R 8 is a (C 6 to C 30 ) alkyl group
  • the first monomer is selected from acrylic acid, methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate and isopropyl methacrylate
  • the second monomer is selected from stearyl acrylate and stearyl methacrylate
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * wherein x is an integer from 5 to 35, a group * - (CH 2 CHMeO) y - * where y is an integer of 5 to 35 or a group * - (CH 2 CH 2 ⁇ ) x - (CH 2 CHMeO) y - * wherein the sum x + y is an integer from 5 to 35 and x and y are greater than zero,
  • R 8 is a (C 6 to C 30 ) alkyl group
  • At least one monomer A1 selected from acrylic acid, methacrylic acid, alkyl acrylates and alkyl methacrylates, and
  • amphoteric monomer A2 selected from (meth) acryloylalkylaminoxiden of the formula A2-I
  • R 1 is H or CH 3 (in particular CH 3 ),
  • R 2 and R 3 are each independently optionally branched
  • n is an integer from 1 to 4 (especially 2), and b) at least one different from copolymer A film-forming amphoteric and / or strengthening amphoteric polymer B selected from octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer and
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * where x is an integer of
  • R 8 is a (C 6 to C 30 ) -alkyl group
  • the first monomer is selected from acrylic acid, methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate and isopropyl methacrylate
  • the second monomer is selected from stearyl acrylate and stearyl methacrylate
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * where x is an integer of
  • R 8 is a (C 6 to C 30 ) -alkyl group
  • a particularly preferred embodiment of the present invention is therefore a cosmetic agent having a viscosity of 1000 to 500,000 mPa s, preferably from 5000 to 300,000 mPa s, more preferably from 10,000 to 150,000 mPa s (each measured with Brookfield RVDV II + with Heilpath, spindle TE , 5 rpm, 2O 0 C) containing, in a cosmetically acceptable carrier
  • At least one monomer A1 selected from acrylic acid, methacrylic acid, alkyl acrylates and alkyl methacrylates, and
  • amphoteric monomer A2 selected from (meth) acryloylalkylaminoxiden of the formula A2-I
  • R 1 is H or CH 3 (in particular CH 3 ),
  • R 2 and R 3 are each independently optionally branched
  • n is an integer from 1 to 4 (especially 2)
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * wherein x is an integer from 5 to 35, a group * - (CH 2 CHMeO) y - * where y is an integer of 5 to 35 or a group * - (CH 2 CH 2 ⁇ ) x - (CH 2 CHMeO) y - * wherein the sum x + y is an integer from 5 to 35 and x and y are greater than zero,
  • R 8 is a (C 6 to C 30 ) alkyl group
  • a particularly preferred embodiment of the present invention is again a cosmetic agent having a viscosity of 1000 to 500,000 mPa s, preferably from 5000 to 300,000 mPa s, more preferably from 10,000 to 150,000 mPa s (each measured with Brookfield RVDV II + with Heilpath, spindle TE , 5 rpm, 2O 0 C) containing, in a cosmetically acceptable carrier
  • the first monomer is selected from acrylic acid, methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate and isopropyl methacrylate
  • the second monomer is selected from stearyl acrylate and stearyl methacrylate
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * wherein x is an integer from 5 to 35, a group * - (CH 2 CHMeO) y - * where y is an integer of 5 to 35 or a group * - (CH 2 CH 2 ⁇ ) x - (CH 2 CHMeO) y - * wherein the sum x + y is an integer from 5 to 35 and x and y are greater than zero,
  • R 8 is a (C 6 to C 30 ) alkyl group
  • a particularly preferred embodiment of the present invention is again a cosmetic agent having a viscosity of 1000 to 500,000 mPa s, preferably from 5000 to 300,000 mPa s, more preferably from 10,000 to 150,000 mPa s (each measured with Brookfield RVDV II + with Heilpath, spindle TE , 5 rpm, 2O 0 C) containing, in a cosmetically acceptable carrier
  • At least one monomer A1 selected from acrylic acid, methacrylic acid, alkyl acrylates and alkyl methacrylates, and
  • amphoteric monomer A2 selected from (meth) acryloylalkylaminoxiden of the formula A2-I
  • R 1 is H or CH 3 (in particular CH 3 ),
  • R 2 and R 3 are each independently optionally branched
  • Ci-io-alkyl and n is an integer from 1 to 4 (especially 2), and b) at least one different from copolymer A film-forming amphoteric and / or strengthening amphoteric polymer B selected from octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer and
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * where x is an integer of
  • R 8 is a (C 6 to C 30 ) -alkyl group
  • a particularly preferred embodiment of the present invention is again a cosmetic agent having a viscosity of 1000 to 500,000 mPa s, preferably from 5000 to 300,000 mPa s, more preferably from 10,000 to 150,000 mPa s (each measured with Brookfield RVDV II + with Heilpath, spindle TE , 5 rpm, 2O 0 C) containing, in a cosmetically acceptable carrier
  • the first monomer is selected from acrylic acid, methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate and isopropyl methacrylate
  • the second monomer is selected from stearyl acrylate and stearyl methacrylate
  • a film-forming amphoteric and / or strengthening amphoteric polymer B selected from octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer and
  • R 4 is a hydrogen atom or a methyl group
  • R 5 represents a hydrogen atom or a (C 1 to C 4 ) -alkyl group
  • R 6 and R 7 represent a hydrogen atom, with the proviso that at least one of R 6 and R 7 is a group -A 1 -R 8 wherein
  • a 1 is a group * - (CH 2 CH 2 O) x - * where x is an integer of
  • R 8 is a (C 6 to C 30 ) -alkyl group
  • All the aforementioned preferred embodiments are again preferably transparent.
  • compositions of the invention contain the polymers in a cosmetically acceptable carrier.
  • Preferred cosmetically acceptable carriers are aqueous, alcoholic or aqueous-alcoholic media with preferably at least 10% by weight of water, based on the total agent.
  • alcohols it is possible in particular to include the lower alcohols having 1 to 4 carbon atoms usually used for cosmetic purposes, such as, for example, ethanol and isopropanol.
  • Particularly suitable as additional co-solvents are unbranched or branched hydrocarbons such as pentane, hexane, isopentane and cyclic hydrocarbons such as cyclopentane and cyclohexane.
  • particularly preferred water-soluble solvents are glycerol, ethylene glycol and propylene glycol in an amount of up to 30% by weight, based on the total agent.
  • the agents preferably have a pH of 4.5 to 6.9. Particularly preferred is the pH range between 6 and 6.9.
  • the pH values refer to the pH at 25 ° C. for the purposes of this document, unless otherwise stated. Agents with these preferred pH values have a particularly good moisture resistance of the fixed hairstyle.
  • compositions of the invention may further contain the auxiliaries and additives which are usually added to the respective cosmetic products.
  • auxiliaries and additives are care substances. These are used both in skin and hair treatment application and can be incorporated with a suitable choice of the care substance, for example in creams, shampoos, hair conditioners, hair treatments, gels, pump and aerosol sprays and show m.
  • compositions of the invention may further contain the auxiliaries and additives which are usually added to conventional styling.
  • auxiliaries and additives in particular additional care substances are mentioned.
  • a silicone oil and / or a silicone gum can be used as a care material.
  • Silicone oils or silicone gums which are suitable according to the invention are in particular dialkyl and alkylaryl siloxanes, for example dimethylpolysiloxane and methylphenylpolysiloxane, and also their alkoxylated, quaternized or else anionic derivatives. Preference is given to cyclic and linear polydialkylsiloxanes, their alkoxylated and / or aminated derivatives, dihydroxypoly-dimethylsiloxanes and polyphenylalkylsiloxanes.
  • Silicone oils cause a wide variety of effects. For example, at the same time they influence the dry and wet combability, the grip of dry and wet hair and the shine.
  • the term "silicone oils” is understood by the person skilled in the art as meaning several structures of silicon-organic compounds. Initially, this is understood to mean the dimethiconols.
  • Examples of such products include the following commercial products: Botanisil NU-150M (Botanigenics), Dow Coming 1-1254 Fluid, Dow Corning 2-9023 Fluid, Dow Corning 2-9026 Fluid, Ultrapure Dimethiconol (Ultra Chemical), Unisil SF- R (Universal Preserve), X-21-5619 (Shin- Etsu Chemical Co.), Abil OSW 5 (Degussa Care Specialties), ACC DL-9430 Emulsion (Taylor Chemical Company), AEC Dimethiconol & Sodium Dodecylbenzenesulfonate (A & E Connock (Perfumery & Cosmetics) Ltd.), BC Dimethiconol Emulsion 95 (Basildon Chemical Company, Ltd.), Cosmetic Fluid 1401, Cosmetic Fluid 1403, Cosmetic Fluid 1501, Cosmetic Fluid 1401 DC (all aforementioned Chemsil Silicones, Inc.), Dow Corning 1401 Fluid, Dow Corning 1403 Fluid, Dow Corning 1501 Fluid, Dow Corning 1784 HVF Em
  • Dimethicones form the second group of silicones which may be present according to the invention. These may be both linear and branched as well as cyclic or cyclic and branched.
  • Dimethicone copolyols form another group of silicones that are suitable.
  • Corresponding dimethicone copolyols are commercially available and are sold, for example, by Dow Corning under the name Dow Corning® 5330 Fluid.
  • the teaching according to the invention also encompasses the fact that the dimethiconols, dimethicones and / or dimethicone copolymers can already be present as an emulsion.
  • the corresponding emulsion of dimethiconols, dimethicones and / or dimethicone copolyols can be prepared both after the preparation of the corresponding dimethiconols, dimethicones and / or dimethicone copolyols from these and the conventional methods of emulsification known to the person skilled in the art.
  • both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions.
  • the emulsions of dimethiconols, dimethicones and / or dimethicone copolyols can also be prepared directly by an emulsion polymerization process. Such methods are also well known to the person skilled in the art.
  • the droplet size of the emulsified particles is according to the invention 0.01 to 10000 microns, preferably 0.01 to 100 .mu.m, more preferably 0.01 to 20 microns and most preferably 0 , 01 to 10 ⁇ m.
  • the particle size is determined by the method of light scattering.
  • branched dimethiconols, dimethicones and / or dimethicone copolyols are used, it is to be understood that the branching is greater than a random branching, which occurs randomly due to impurities of the respective monomers.
  • branched dimethiconols, dimethicones and / or dimethicone copolyols are therefore to be understood as meaning that the degree of branching is greater than 0.01%.
  • a degree of branching is greater than 0.1%, and most preferably greater than 0.5%.
  • the degree of branching is determined by the ratio of the unbranched monomers to the branching monomers, that is, the amount of tri- and tetrafunctional siloxanes determined. According to the invention, both low-branched and highly branched dimethiconols, dimethicones and / or dimethicone copolyols can be very particularly preferred.
  • Particularly suitable silicones are amino-functional silicones, in particular the silicones, which are summarized under the INCI name Amodimethicone. It is therefore preferred according to the invention if the agents according to the invention additionally contain at least one amino-functional silicone. These are silicones which have at least one, optionally substituted, amino group. These silicones are referred to as amodimethicone according to the INCI nomenclature and are available for example in the form of an emulsion as a commercial product Dow Corning ® 939 or as a commercial product Dow Corning ® 949 in a mixture with a cationic and a nonionic surfactant.
  • those amino-functional silicones are used which have an amine number above 0.25 meq / g, preferably above 0.3 meq / g and especially preferably above 0.4 meq / g.
  • the amine number stands for the milliequivalents of amine per gram of the amino-functional silicone. It can be determined by titration and also expressed in mg KOH / g.
  • the agents contain the silicones preferably in amounts of from 0.01% by weight to 15% by weight, particularly preferably from 0.05 to 2% by weight, based on the total agent.
  • the agent may contain, for example, at least one protein hydrolyzate and / or one of its derivatives.
  • Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins). According to the invention, the term protein hydrolyzates also means total hydrolyzates as well as individual amino acids and their derivatives as well as mixtures of different amino acids.
  • the molecular weight of the protein hydrolysates which can be used according to the invention is between 75, the molecular weight for glycine, and 200,000, preferably the molecular weight is 75 to 50,000 and very particularly preferably 75 to 20,000 Da Ito n.
  • protein hydrolysates of both vegetable and animal or marine or synthetic origin can be used.
  • Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein hydrolysates, which may also be present in the form of salts.
  • Such products are, for example, under the trademarks Dehylan ® (Cognis), Promois® ® (Interorgana) Collapuron ® (Cognis), Nutrilan® ® (Cognis), Gelita-Sol ® (German Gelatinefabriken Stoess & Co), Lexein ® (Inolex) sericin (Pentapharm) and kerasol tm ® (Croda) sold.
  • the protein hydrolysates are present in the agents according to the invention, for example, in concentrations of from 0.01% by weight to 20% by weight, preferably from 0.05% by weight to 15% by weight and completely particularly preferably in amounts of 0.05 wt .-% up to 5 wt .-%, each based on the total application preparation included.
  • the agent according to the invention may further comprise at least one vitamin, a provitamin, a vitamin precursor and / or one of their derivatives.
  • vitamins, provitamins and vitamin precursors are preferred, which are usually assigned to groups A, B, C, E, F and H.
  • the agents according to the invention preferably contain vitamins, provitamins and vitamin precursors from groups A, B, C, E and H. Panthenol, pantolactone, pyridoxine and its derivatives as well as nicotinamide and biotin are particularly preferred.
  • the addition of panthenol increases the flexibility of the polymer film formed using the composition of the present invention.
  • the compositions according to the invention may contain panthenol instead of or in addition to glycerol and / or propylene glycol.
  • the agents according to the invention contain panthenol, preferably in an amount of 0.05 to 10% by weight, particularly preferably 0.1 to 5% by weight, in each case based on the total agent.
  • compositions according to the invention may further contain at least one plant extract.
  • these extracts are produced by extraction of the whole plant. However, it may also be preferred in individual cases, the extracts exclusively from flowers and / or
  • compositions according to the invention mixtures of several, especially two, different plant extracts.
  • Mono- or oligosaccharides can also be used as a care substance in the compositions according to the invention.
  • Both monosaccharides and oligosaccharides can be used.
  • the use of monosaccharides is preferred according to the invention.
  • those compounds which contain 5 or 6 carbon atoms are preferred.
  • Suitable pentoses and hexoses are, for example, ribose, arabinose, xylose, lyxose, allose, altrose, glucose, mannose, gulose, idose, galactose, talose, fucose and fructose.
  • Arabinose, glucose, galactose and fructose are preferably used carbohydrates; Very particular preference is given to using glucose which is suitable both in the D - (+) or L - (-) configuration or as a racemate.
  • sugars are gluconic acid, glucuronic acid, sugar acid, mannose acid and mucic acid.
  • Preferred sugar alcohols are sorbitol, mannitol and dulcitol.
  • Preferred glycosides are the methylglucosides.
  • the monosaccharides or oligosaccharides used are usually obtained from natural raw materials such as starch, they usually have the configurations corresponding to these raw materials (for example D-glucose, D-fructose and D-galactose).
  • the mono- or oligosaccharides are preferably present in the compositions according to the invention in an amount of from 0.1 to 8% by weight, particularly preferably from 1 to 5% by weight, based on the total application preparation.
  • the agent may further contain at least one lipid as a care substance.
  • Lipids which are suitable according to the invention are phospholipids, for example soya lecithin, egg lecithin and cephalins, and also the substances known by the INCI names linoleneamidopropyl PG-dimonium chlorides phosphates, cocamidopropyl PG-dimonium chlorides phosphates and stearamidopropyl PG-dimonium chlorides phosphates. These are sold, for example, by the company Mona under the trade names Phospholipid EFA® , Phospholipid PTC® and Phospholipid SV® .
  • the agents according to the invention preferably contain the lipids in amounts of from 0.01 to 10% by weight, in particular from 0.1 to 5% by weight, based on the total application preparation.
  • oil bodies are suitable as a care substance.
  • the natural and synthetic cosmetic oil bodies include, for example: vegetable oils.
  • vegetable oils examples include sunflower oil, olive oil, soybean oil, rapeseed oil, almond oil, jojoba oil, orange oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil.
  • triglyceride oils such as the liquid portions of beef tallow as well as synthetic triglyceride oils.
  • Ester oils are to be understood as meaning the esters of C 6 - C 30 fatty acids with C 2 - C 30 fatty alcohols.
  • the monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred.
  • isopropyl myristate IPM Rilanit ®
  • isononanoic acid C16-18 alkyl ester Cetiol ® SN
  • 2-ethylhexyl palmitate Cegesoft ® 24
  • stearic acid-2-ethylhexyl ester (Cetiol ® 868)
  • cetyl oleate glycerol tricaprylate, Kokosfettalkohol- caprate / caprylate (Cetiol ® LC), n-butyl stearate, oleyl erucate (Cetiol ® J 600), isopropyl palmitate (IPP Rilanit ®),
  • Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate
  • diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2- ethylhexanoate), propylene glycol diisostearate,
  • Fatty acid partial glycerides which are understood to mean monoglycerides, diglycerides and their technical mixtures. With the use of technical products production reasons may still contain small amounts of triglycerides.
  • the partial glycerides preferably follow the formula (D4-I),
  • R 1 , R 2 and R 3 independently of one another represent hydrogen or a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22, preferably 12 to 18, carbon atoms, with the proviso that at least one of these groups represents a Acyl radical and at least one of these groups is hydrogen.
  • the sum (m + n + q) is 0 or numbers from 1 to 100, preferably 0 or 5 to 25.
  • R 1 is an acyl radical and R 2 and R 3 are hydrogen and the sum (m + n + q) is 0.
  • Typical examples are mono- and / or diglycerides based on caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic , Elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures.
  • oleic acid monoglycerides are used.
  • the amount used of the natural and synthetic cosmetic oil bodies in the inventive compositions is usually 0.1 to 30 wt.%, Based on the total application preparation, preferably 0.1 to 20 wt .-%, and in particular 0.1 to 15 wt .-%.
  • UV filters are not subject to any general restrictions with regard to their structure and their physical properties. On the contrary, all UV filters which can be used in the cosmetics sector and whose absorption maximum lies in the UVA (315-400 nm), in the UVB (280-315 nm) or in the UVC ( ⁇ 280 nm) range are suitable. UV filters with an absorption maximum in the UVB range, in particular in the range from about 280 to about 300 nm, are particularly preferred.
  • the UV filters preferred according to the invention can be selected, for example, from substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylic acid esters, cinnamic acid esters, salicylic acid esters, benzimidazoles and o-aminobenzoic acid esters.
  • the UV filters are usually contained in amounts of 0.01-5 wt .-%, based on the total application preparation. Amounts of 0.1-2.5 wt .-% are preferred.
  • the composition according to the invention also contains one or more substantive dyes. This allows the treated keratin fiber not only to be temporarily patterned when the agent is applied, but also dyed at the same time. This may be particularly desirable if only a temporary dyeing is desired, for example, with eye-catching fashion colors, which can be removed again by simple washing from the keratinic fiber.
  • Direct dyes are usually nitrophenylenediamines, nitroaminophenols, azo dyes, anthraquinones or indophenols.
  • Preferred substantive dyes are those having the international designations or trade names HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 12, Acid Yellow 1, Acid Yellow 10, Acid Yellow 23, Acid Yellow 36, HC Orange Disperse Orange 3, Acid Orange 7, HC Red 1, HC Red 3, HC Red 10, HC Red 11, HC Red 13, Acid Red 33, Acid Red 52, HC Red BN, Pigment Red 57: 1, HC Blue 2, HC Blue 11, HC Blue 12, Disperse Blue 3, Acid Blue 7, Acid Green 50, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Acid Violet 43, Disperse Black 9, Acid Black 1, and Acid Black 52 known compounds as well as 1,4-diamino-2-nitrobenzene, 2-amino-4-nitrophenol, 1,4-bis- ( ⁇ -hydroxyethyl) -amino-2-nitrobenzene, 3-nitro
  • aromatic systems substituted with a quaternary nitrogen group such as Basic Yellow 57, Basic Red 76, Basic Blue 99, Basic Brown 16 and Basic Brown 17, as well as
  • the dyes which are also known by the names Basic Yellow 87, Basic Orange 31 and Basic Red 51 are very particularly preferred cationic substantive dyes of group (c).
  • the cationic direct dyes, which are sold under the trademark Arianor ®, according to the invention are also very particularly preferred cationic direct dyes.
  • the agents according to the invention according to this embodiment preferably contain the substantive dyes in an amount of 0.001 to 20 wt .-%, based on the total agent.
  • the agents according to the invention are free of oxidation dye precursors.
  • Oxidation dye precursors are classified into so-called developer components and coupler components.
  • the developer components form the actual dyes under the influence of oxidizing agents or of atmospheric oxygen with one another or with coupling with one or more coupler components.
  • the agent according to the invention may be necessary for them to further contain at least one surfactant. This is especially true for skin cleansers and shampoos. But other means, such as hair rinses, hair treatments and certain styling agents, in particular styling foams, may contain surfactants.
  • cationic surfactants can be used, as described above as suitable care agents. With respect to the preferred cationic surfactants and the amounts used, the above statements apply accordingly.
  • the agents may contain other surfactants or emulsifiers, with both anionic and ampholytic and nonionic surfactants and all types of known emulsifiers being suitable in principle.
  • the group of ampholytic or too Amphoteric surfactants include zwitterionic surfactants and ampholytes. The surfactants may already have emulsifying effect.
  • Suitable anionic surfactants are in principle all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts having 2 to 4 C atoms in the alkanol group,
  • Ethercarbon Acid the formula RO- (CH2-CH2 ⁇ ) ⁇ -CH2-COOH, in which R is a linear
  • Alkyl group having 8 to 30 C atoms and x 0 or 1 to 16,
  • Alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 carbon atoms are alpha-sulfofatty acids having 8 to 30 carbon atoms.
  • Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH 2 -CH 2 O) x -OSO 3 H, in which R is a preferably linear alkyl group having 8 to 30 C atoms and x 0 or 1 to 12,
  • esters of tartaric acid and citric acid with alcohols the addition products of about 2-15
  • R 1 is preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms
  • R 2 is hydrogen, a radical (CH 2 CH 2 O) n R 1 or X, n is from 1 to 10 and X is hydrogen, an alkali or alkaline earth metal or NR 3 R 4 R 5 R 6 , where R 3 to R 6 independently of one another represent hydrogen or a C 1 to C 4 hydrocarbon radical,
  • R 7 CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, Alk for CH 2 CH 2 , CHCH 3 CH 2 and / or CH 2 CHCH 3 , n for numbers from 0.5 to 5 and M is a cation, as described in DE-OS 197 36 906,
  • Condensation products of C 8 - C 30 - fatty alcohols with protein hydrolysates and / or amino acids and their derivatives which are known to the skilled person as protein fatty acid condensates, such as Lamepon ® - types Gluadin ® - types Hostapon ® KCG or Amisoft ® - types.
  • Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids having 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule, sulfosuccinic acid mono- and dialkyl esters having 8 to 18 C atoms in the alkyl group and sulfosuccinic acid monoalkylpolyoxyethylester with 8 to 18 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, Monoglycerdisulfate, alkyl and Alkenyletherphosphate and Eiweissfettkladensate.
  • Zwitterionic surfactants are those surface-active compounds which carry at least one quaternary ammonium group and at least one -COO () or -SO 3 () group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyl dimethylammonium glycinate, N-acylaminopropyl N, N-dimethylammonium glycinates, for example cocoacylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxymethyl-3-hydroxyethyl-imidazolines having in each case 8 to 18 C atoms in the alkyl or acyl group, and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name
  • Ampholytes are understood as meaning those surface-active compounds which, apart from a C 8 -C 24 -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO 3 H group and are capable of forming internal salts.
  • ampholytes are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 C-atoms in the alkyl group.
  • Particularly preferred ampholytes are N-cocoalkylaminopropionate, cocoacylaminoethyl aminopropionate and C 2 - C 8 - sarcosine.
  • Nonionic surfactants contain as hydrophilic group e.g. a polyol group, a polyalkylene glycol ether group, or a combination of polyol and polyglycol ether groups.
  • hydrophilic group e.g. a polyol group, a polyalkylene glycol ether group, or a combination of polyol and polyglycol ether groups.
  • Such compounds are, for example
  • Polyol fatty acid esters such as the commercial product Hydagen ® HSP (Cognis) or
  • R 1 CO for a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms
  • R 2 is hydrogen or methyl
  • R 3 is linear or branched
  • R 4 is an alkyl or alkenyl radical having 4 to 22 carbon atoms
  • G is a
  • the alkylene oxide adducts of saturated linear fatty alcohols and fatty acids having in each case 2 to 100 mol Ethylene oxide per mole of fatty alcohol or fatty acid proven. Preparations with excellent properties are also obtained when they contain as nonionic surfactants C 2 -C 30 fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide with glycerol and / or addition products of 5 to 60 moles of ethylene oxide with castor oil and hydrogenated castor oil ,
  • the agents according to the invention as surfactant very particularly preferably contain at least one addition product of from 15 to 100 mol of ethylene oxide, in particular from 15 to 50 mol of ethylene oxide, to a linear or branched (in particular linear) fatty alcohol having from 8 to 22 carbon atoms.
  • ethylene oxide in particular from 15 to 50 mol of ethylene oxide
  • linear or branched (in particular linear) fatty alcohol having from 8 to 22 carbon atoms.
  • These are very particularly preferably Ceteareth-15, Ceteareth-25 or Ceteareth- 50, which are marketed as Eumulgin ® CS 15 (Cognis), Cremophor A25 (BASF SE) or Eumulgin ® CS 50 (Cognis).
  • compositions according to the invention can be carried out in all forms customary for cosmetic compositions, for example in the form of solutions which can be applied to the skin or hair as facial or hair tonic or pump or aerosol spray, in the form of creams, emulsions, waxes , Gels or surfactant-containing foaming solutions or other preparations which are suitable for use on the skin or hair.
  • the agents according to the invention are preferably in gel form or in cream form, with transparent gels being particularly preferred.
  • the agents of the invention are means for temporarily deforming keratinic fibers, i. to styling agent.
  • Preferred styling agents are styling gels and styling creams, with transparent styling gels being particularly preferred.
  • a second subject of the invention is the use of the agents according to the invention of the first subject of the invention for the temporary deformation of keratinous fibers.
  • compositions according to the invention and products which contain these agents are distinguished in particular by the fact that they give treated hair a very strong and moisture-resistant hairstyle hold.
  • the hold of the deformation also called hairstyle hold, as well as flexibility, elasticity and
  • Plasticity are determined according to the present invention according to the omega-loop method.
  • the quality of transparency of a composition of the invention can be visual
  • the styling gels E1 to E5 according to the invention were prepared according to the following table.
  • Polyvinylpyrrolidone (about 20% solids in water, conserved with about 250 ppm polyaminopropyl biguanide, INCI name: PVP) (BASF SE)

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention concerne un agent cosmétique, notamment un agent coiffant sous forme de gel ou de crème, qui contient, dans un excipient cosmétiquement acceptable, a) au moins un copolymère A comprenant au moins un monomère A1 sélectionné parmi les constituants suivants; acide acrylique, acide méthacrylique, alkylesters d'acide acrylique et alkylesters d'acide méthacrylique, et au moins un monomère amphotère A2 sélectionné parmi les constituants suivants: oxydes de (méth)acryloylalkylamine de formule (A2-I), et bétaïnes de (méth)acryloylalkylamine de formule (A2-II), dans la formule A2-I et dans la formule A2-II, R1 désignant H ou CH3, R2 et R3 désignant respectivement indépendamment l'un de l'autre alkyle C1-10 éventuellement ramifié et n désignant un nombre entier compris entre 1 et 20, et b) au moins un polymère B amphotère filmogène et/ou amphotère fixant, différent du copolymère A, et c) au moins un polymère anionique amphiphile C, comprenant au moins un monomère de formule (C1) et au moins un monomère ester d'acide itaconique de formule (C2), où R4 désigne un atome d'hydrogène ou un groupe méthyle, R5 désigne un atome d'hydrogène ou un groupe alkyle(C1 à C4)-, R6 et R7 désignent un atome d'hydrogène, sous réserve qu'au moins un reste issu de R6 et R7 désigne un groupe -A1-R8, A1 désignant un groupe *-(CH2CH2O)x-* où x représente un nombre entier compris entre 5 et 35, un groupe *-(CH2CHMe0)y-* où y désigne un nombre entier compris entre 5 et 35 ou un groupe *-(CH2CH2O)x-(CH2CHMeO)y-*, où la somme x + y représente un nombre entier compris entre 5 et 35 et x et y sont supérieurs à zéro, R8 désignant un groupe alkyle(C6 bis C30). L'invention concerne également l'utilisation desdits agents pour la mise en forme temporaire de la chevelure.
EP10731758A 2009-07-28 2010-07-16 Agent cosmétique Ceased EP2459281A2 (fr)

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DE102009028054A DE102009028054A1 (de) 2009-07-28 2009-07-28 Kosmetisches Mittel
PCT/EP2010/060296 WO2011012464A2 (fr) 2009-07-28 2010-07-16 Agent cosmétique

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US9370191B2 (en) 2012-08-07 2016-06-21 Pardis Kelly Cosmetic formulation
FR3014444B1 (fr) * 2013-12-10 2017-03-03 Commissariat Energie Atomique Utilisation d'un copolymere a blocs amphiphile pour l'obtention d'un materiau presentant des proprietes de resistance a l'humidite ameliorees
DE102015204154A1 (de) 2015-03-09 2016-09-15 Henkel Ag & Co. Kgaa Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern
DE102015225203A1 (de) 2015-12-15 2017-06-22 Henkel Ag & Co. Kgaa "Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern"
DE102015225207A1 (de) 2015-12-15 2017-06-22 Henkel Ag & Co. Kgaa "Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern"
DE102015225199A1 (de) 2015-12-15 2017-06-22 Henkel Ag & Co. Kgaa "Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern"
DE102015225211A1 (de) 2015-12-15 2017-06-22 Henkel Ag & Co. Kgaa Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern
DE102015225198A1 (de) 2015-12-15 2017-06-22 Henkel Ag & Co. Kgaa "Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern"
DE102015225214A1 (de) 2015-12-15 2017-06-22 Henkel Ag & Co. Kgaa Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern
DE102017211852A1 (de) * 2017-07-11 2019-01-17 Henkel Ag & Co. Kgaa Wasserbeständige kosmetische Mittel zur temporären Farbveränderung von keratinhaltigen Materialien II
DE102019219305A1 (de) * 2019-12-11 2021-06-17 Henkel Ag & Co. Kgaa Haarstylingzusammensetzung und deren Verwendung

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JP3620165B2 (ja) * 1996-09-18 2005-02-16 三菱化学株式会社 毛髪化粧料組成物
JP3045402B2 (ja) * 1996-11-04 2000-05-29 ザ、プロクター、エンド、ギャンブル、カンパニー ヘアスタイリング組成物
DE19736906A1 (de) 1997-08-25 1999-03-04 Henkel Kgaa Verfahren zur Herstellung von sulfatierten Fettsäurealkylenglykolestern
DE19738866A1 (de) 1997-09-05 1999-03-11 Henkel Kgaa Schaumarme Tensidmischungen mit Hydroxymischethern
US5972356A (en) * 1997-11-05 1999-10-26 The Procter & Gamble Company Personal care compositions
DE19756454C1 (de) 1997-12-18 1999-06-17 Henkel Kgaa Verwendung von Glycerincarbonat
FR2785183B1 (fr) 1998-11-04 2002-04-05 Oreal COMPOSITION TINCTORIALE CONTENANT UN COLORANT DIRECT CATIONIQUE ET UNE PYRAZOLO-[1,5-a]- PYRIMIDINE A TITRE DE BASE D'OXYDATION, ET PROCEDES DE TEINTURE
JP2002097119A (ja) * 2000-09-20 2002-04-02 Mitsubishi Chemicals Corp 毛髪化粧料
DE102004001522A1 (de) * 2004-01-10 2005-08-04 Clariant Gmbh Haarfärbemittel
JP4136964B2 (ja) * 2004-02-23 2008-08-20 花王株式会社 毛髪化粧料
DE102004018723A1 (de) * 2004-04-17 2005-11-03 Wella Ag Itaconsäuremonoester/Acrylat Copolymer und Polystyrolsulfonat enthaltende Haarbehandlungsmittel
DE102006051729A1 (de) 2006-10-30 2008-05-08 Henkel Kgaa Kosmetisches Mittel

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DE102009028054A1 (de) 2011-02-10
JP5771202B2 (ja) 2015-08-26
US20120128619A1 (en) 2012-05-24
WO2011012464A3 (fr) 2013-03-28
JP2013505895A (ja) 2013-02-21
US9132077B2 (en) 2015-09-15
WO2011012464A2 (fr) 2011-02-03

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