EP2396088B1 - Article pour le nettoyage de la peau - Google Patents

Article pour le nettoyage de la peau Download PDF

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Publication number
EP2396088B1
EP2396088B1 EP10707097.1A EP10707097A EP2396088B1 EP 2396088 B1 EP2396088 B1 EP 2396088B1 EP 10707097 A EP10707097 A EP 10707097A EP 2396088 B1 EP2396088 B1 EP 2396088B1
Authority
EP
European Patent Office
Prior art keywords
substrate
water
item
skin
cleansing composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP10707097.1A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2396088A2 (fr
Inventor
Anne-Gaëlle Clermont
Philippe Gregoire
Bernard Louis Dit Picard
Bruno Bret
Alexandra Da Silva
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Essity Operations France SAS
Original Assignee
Essity Operations France SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Essity Operations France SAS filed Critical Essity Operations France SAS
Priority to PL10707097T priority Critical patent/PL2396088T3/pl
Publication of EP2396088A2 publication Critical patent/EP2396088A2/fr
Application granted granted Critical
Publication of EP2396088B1 publication Critical patent/EP2396088B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

Definitions

  • the present invention relates to a method of manufacturing an article for cleaning the skin, disposable after use, and to a skin cleaning article obtained by this method.
  • the article comprises a pad made of a fibrous substrate material and a lotion having a substantially dry feel on the substrate.
  • a fibrous pad based on cotton blended optionally with other synthetic or artificial fibers on which is deposited a lotion or emulsion, appropriate, cleaning or make-up remover as appropriate.
  • the present invention relates to such articles in which the lotion has a substantially dry appearance and feel on the substrate, i.e. the article generally contains a small amount of water, less than 25%. It is not used in this form.
  • the lotion is activated by moistening it with water.
  • the lotion contains agents by which a cleaning foam is formed when the article undergoes a mechanical action, such as deformation or rubbing.
  • the pad impregnated with wet foam is then applied to the areas of the skin that one wishes to clean.
  • the buffers forming the substrate which are also referred to as formats, are available in many forms.
  • the invention relates to buffers obtained from a sheet of fibrous material made of cotton alone or mixed with other fibers and in which they are cut.
  • the fibers of the web are bonded so as to form a non-woven to the mechanical strength greater or less depending on the needs of keeping the article.
  • the shape can be circular, oval, polygonal or different, for sizes ranging from 25 to more than 100 cm 2 .
  • the grammages are generally between 100 and 300 g / m 2 .
  • a fibrous pad for such an application is chosen to have several characteristics. It is thick enough to hold well when wet. It absorbs and wipes off impurities. It retains its integrity, during use, with friction. It does not lint and leaves no fibers on the skin.
  • the invention relates to a fibrous substrate preferably obtained according to this second technique.
  • the hydrolysis process reduces the propensity for the formation of pilling on the surface and increases the tensile strength of the web.
  • This purely mechanical process makes it possible to manufacture webs with a composition of up to 100% of cotton fibers.
  • the loss of resistance is not desired because we want to avoid disintegration and destruction of the buffer when the user rubs the skin or other surface.
  • the Applicant has set itself the goal of producing a skin cleaning article with a cleaning composition that is activated by wetting with water followed by a mechanical action, and incorporated into a fibrous substrate whose fibers are mechanically bonded, which, when wet, retains its strength properties before wetting or does not see them significantly reduced or sees them improved.
  • the Applicant has also set as an objective an article which has wet surface resistance, after wetting, sufficient to limit the formation of pilling to rubbing.
  • the active ingredients of the composition are all elements with the exception of water.
  • the substrate has a basis weight of between 150 and 250 g / m 2 , more particularly between 160 and 200 g / m 2 .
  • the article preferably comprises from 0.2 to 0.72 grams of active material of said composition per gram of substrate.
  • Said composition comprises from 15 to 35% of said surfactant or surfactant mixture expressed as a percentage of active ingredient of the composition and from 55 to 75% of said humectant expressed as a percentage of active ingredient of the composition.
  • the resistance running direction of the article between its state before wetting and wet state, after wetting undergoes an increase of at least 10%.
  • the composition comprises a gelling agent in an amount of less than 0.2%.
  • the amount of active material of the gelling agent is preferably less than 0.12%.
  • the composition comprises at least one additive such as a preserving agent, a dye, a perfume, an acidity regulator, a treatment agent for the skin, etc.
  • the substrate is made of 100% cotton fibers.
  • the substrate may however contain a certain percentage, from 5 to 30% and more particularly from 15 to 20% of other natural fibers, of synthetic or artificial fibers in substitution for cotton fibers.
  • the substrate may be obtained from a web of fibers such as bleached cotton, pneumatically formed, carded or a combination of these techniques.
  • the layers are for example card webs.
  • one embodiment is to fold back on itself, by means of of a lapping spreader, a web of carding weight preferably between 30 and 60 g / m 2 at a lay angle between 0 and 90 °.
  • Several layers are then superimposed to obtain the desired grammage.
  • the substrate may also be formed of a plurality of layers of different nature.
  • the substrate may be formed from a web obtained by pneumatically depositing fibers between two or more webs.
  • the substrate comprises on one side an exfoliating means for the skin.
  • it is a buffer manufactured according to the technique disclosed in the patent application WO200501699 which relates to the incorporation, immediately below the surface of the stamp, of exfoliating elements.
  • the substrate comprises from 5 to 50 g / m 2 of exfoliating elements.
  • These are natural organic elements such as strawberry achenes, apricot kernels, organic bamboo silica or pumpkin cellulose, minerals such as silica balls, artificial ones such as cellulose and methylcellulose spheres or else still synthetic such as polyethylene, nylon, polypropylene or EVA polymers.
  • fibers of larger diameter and fairly stiff are mixed with the cotton fibers. This mixture is carded to form a veil which constitutes the surface veil of the sheet to be obtained.
  • the rigid fibers are selected from hemp, flax, sisal or yuka fibers. Depending on the effectiveness of the exfoliant and the nature of the fiber, 25 to 75% of these stiffer fibers are incorporated into the blend.
  • This method allows an application of the lotion in the mass or only at the surface, but requires a drying step.
  • a hydrolysis mode comprises the treatment of a face with an energy input between 4 and 8x10-3kWh / m 2 and 1 and 3x10 -3kWh / m 2 on the other side.
  • the following is a non-limiting method of manufacturing a fibrous web for producing a buffer forming the substrate according to the invention.
  • a laminated cotton web is produced according to the tablecloth manufacturing technique mentioned in the patent EP 0 681 621 B1 .
  • This layer composed of three superimposed layers is then chemically treated to render it hydrophilic and white.
  • the web thus formed is then driven by an endless support mat, permeable to liquids, to the various continuous line treatment stations.
  • the web is impregnated by gravity discharge of a scouring solution containing sodium hydroxide on the web, in the form of a liquid blade transverse to the direction of displacement thereof.
  • a suction slot placed under the fabric, a depression is created sufficient to allow at least part of the solution to cross the tablecloth.
  • the quantity of liquor supplied to the sheet is controlled by adjusting the vacuum created at the suction slot.
  • the sheet is introduced into a vaporizer heated to a temperature of 100 ° C in which it remains, while remaining continuous, for a given time in particular depending on the material flow.
  • the tablecloth is then rinsed.
  • the scouring juice is extracted by means of a second liquid slide and a vacuum slot associated with a mean vacuum.
  • the impure and hydrophilic web is impregnated with a bleach solution containing hydrogen peroxide, in the same manner as for the scouring treatment.
  • the web is then introduced into a vaporizer heated to a temperature of about 100 ° C for bleaching to be effective.
  • the sheet is then rinsed by means of a succession of liquid blades associated with suction slots.
  • This treatment of the web gives an adhesion between the layers constituting it and a very good cohesion to the assembly.
  • This technique makes it possible to manufacture webs of grammage between 80 and 600 g / m 2 .
  • the jets are produced by injectors as used in the hydrodynamic bonding technology of nonwovens.
  • Each injector comprises, for example, an elongated chamber, closed along its length by a perforated plate, in one or more rows, with a large number of small diameter holes, of the order of 80 to 200 microns.
  • the chamber is fed with pressurized liquid which escapes through the orifices in the form of parallel fine jets of corresponding diameter.
  • the level of energy to be supplied depends on the thickness of the sheet and its weight.
  • the consolidation of the web allows its transformation into absorbent pad or cleansing pad by a simple cut and packaging.
  • This rinsing treatment applied to the layered layer of three layers described above has the additional advantage of not reducing the thickness of the layer while reinforcing the surface layers.
  • An example of treatment comprises the bonding of a first face by a plurality of jets of water spaced 2.5 mm, providing an energy of 5 to 7x10 -3 kWh / m 2 .
  • the bonding of the second face is achieved by means of a plurality of jets of water spaced 0.6 mm, providing an energy of 2.08x10 -3 kWh / m 2 .
  • After bonding the web is dried and cut into pads in the desired format by appropriate cutting means.
  • humectant agent that is to say a hygroscopic agent for retaining water and thus improve skin hydration
  • another polyol such as propylene glycol, butylene glycol, sorbitol, pentylene glycol or hexylene glycol.
  • the nonionic surfactant is preferably selected from alkyl polyglucosides such as for example Decyl Glucoside.
  • amphoteric surfactant is preferably one or more of the following agents, according to the classification according to "Handbook of Surfactants” MR Porter, 2nd Edition, Blackie A & P ;
  • Amino propionate derivatives such as alkyl aminopropionates, alkyl ampho polycarboxy propionates, ampho propionates, ampho carboxy propionates, alkyl imino dipropionates, amino alkanoates, beta-N-alkylalanines, alkyl amino propionates, alkyl iminodipropionates, imino dialkanoate propionates.
  • Betaine derivatives for example cocamidopropyl betain, alkyl such as alkyl betaines, alkyl bisbetaines, alkyl dimethyl betaines, alkyl amido betaines, alkyl amido propyl betaines, alkyl amido propyl dimethyl betaine, alkyl amido propyl dimethyl sulphobetaines, alkyl amido propyl hydroxy sultaines; ; sulpho amido betaines; sulpho betaines.
  • alkyl such as alkyl betaines, alkyl bisbetaines, alkyl dimethyl betaines, alkyl amido betaines, alkyl amido propyl betaines, alkyl amido propyl dimethyl sulphobetaines, alkyl amido propyl hydroxy sultaines; ; sulpho amido betaines; sulpho betaines.
  • Glycinates such as alkyl glycinates, alkyl amino carboxylic acids, alkyl amphomonoacetates, alkyl amphodiacetates, alkyl carboxy glycinates, alkyl ampho polycarboxy glycinates, alkyl imino diglycinates, alkyl polyaminocarboxylates, amino alkanoates, ampho glycinates, ampho carboxy glycinates, carboxy glycinates, alpha N-alkyl amino acetic acids.
  • a tampon impregnated with a lotion whose composition is as follows: Glycerin 43.27 Water 35.94 Anionic Surfactant - Laureth Sodium Sulfate 11.52 Amphoteric Surfactant: Cocamido Propyl Betain 1.92 Perfume 1.8 Nonionic TA-Decyl Glucoside 2.26 Conservative - 1.30 Potassium Sorbate : 0.29 Citric Acid : 0.18 Seaweed extract 1.50 Dye : 0.02 Total : 100
  • the active ingredients of the composition are all elements with the exception of water.
  • a sample N2 is prepared by depositing the above lotion on the substrate at a rate of 0.56 grams of lotion per gram of substrate.
  • the lotion being relatively viscous, the deposit is made by means of a lip nozzle.
  • the article obtained has a sufficient dryness rate so as not to have to dry it.
  • a sample N3 is prepared with a lotion of the same composition as above, diluted 4 times in water. The deposit is made by padding, followed by drying. The final active ingredient impregnation rate is the same as for N2.
  • the tensile strength values were measured on samples of the dimensions specified in the test on which a longitudinal tensile force was applied at a constant rate of increase.
  • the sample was folded in half in its middle, the fold being perpendicular to the length of the sample.
  • the area of the fold on a centimeter is soaked for a second in distilled water, without dripping.
  • the sample is unfolded for measurement.
  • Pellets formed on the nonwoven are counted and measured by optical analysis.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Cosmetics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
EP10707097.1A 2009-02-13 2010-02-12 Article pour le nettoyage de la peau Active EP2396088B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL10707097T PL2396088T3 (pl) 2009-02-13 2010-02-12 Wyrób do czyszczenia skóry

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0950954A FR2942133B1 (fr) 2009-02-13 2009-02-13 Article pour le nettoyage de la peau
PCT/FR2010/000119 WO2010092261A2 (fr) 2009-02-13 2010-02-12 Article pour le nettoyage de la peau

Publications (2)

Publication Number Publication Date
EP2396088A2 EP2396088A2 (fr) 2011-12-21
EP2396088B1 true EP2396088B1 (fr) 2018-12-19

Family

ID=41130367

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10707097.1A Active EP2396088B1 (fr) 2009-02-13 2010-02-12 Article pour le nettoyage de la peau

Country Status (9)

Country Link
US (1) US20110302734A1 (pl)
EP (1) EP2396088B1 (pl)
CA (1) CA2750929A1 (pl)
ES (1) ES2712966T3 (pl)
FR (1) FR2942133B1 (pl)
PL (1) PL2396088T3 (pl)
RU (1) RU2521302C2 (pl)
TR (1) TR201900072T4 (pl)
WO (1) WO2010092261A2 (pl)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022073601A1 (en) * 2020-10-07 2022-04-14 Essity Hygiene And Health Aktiebolag Skin-cleansing pad treated with a self-emulsifying cleansing lotion suitable for makeup removal
EP4225258A1 (en) 2020-10-07 2023-08-16 Essity Hygiene and Health Aktiebolag Skin-cleansing pad treated with a cleansing lotion suitable for makeup removal

Family Cites Families (25)

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FR2081133B1 (pl) * 1970-03-09 1974-07-12 Serviere Hubert De
SU499350A1 (ru) * 1973-05-08 1976-01-15 Способ обработки хлопка-сырца
US5091102A (en) * 1988-11-15 1992-02-25 Nordico, Inc. Method of making a dry antimicrobial fabric
FR2701040B1 (fr) * 1993-01-29 1996-06-28 Kaysersberg Sa Nappe de coton hydrophile et produits obtenus a partir de la transformation d'une telle nappe.
CA2151774C (en) * 1994-06-27 1999-04-06 Minh Quang Hoang Skin disinfecting formulations
FR2730248B1 (fr) 1995-02-03 1997-03-21 Kaysersberg Sa Procede de traitement d'une nappe de fibres cellulosiques
US5919471A (en) * 1996-12-13 1999-07-06 Saferstein; Lowell Substantially anhydrous antiseptic wipes
US6042815A (en) * 1998-10-21 2000-03-28 Revlon Consumer Products Corporation Water and oil emulsion solid cosmetic composition
FR2795100B1 (fr) 1999-06-16 2001-09-14 Fort James France Produit de coton hydrophile comportant une face douce et une face grattante
EP1106723B1 (fr) 1999-12-07 2003-03-12 Georgia-Pacific France Tampon de coton hydrophile destiné aux soins de la peau et comportant deux faces externes différentes
KR100755104B1 (ko) * 2000-04-17 2007-09-04 유니레버 엔.브이. 개선된 거품형성능 및 습윤 가요성을 갖는 실질적으로건조한 세정 제품
US20030194425A1 (en) * 2002-04-11 2003-10-16 L'oreal Moist cleansing, skin care or cosmetic article
US20040068849A1 (en) * 2002-10-11 2004-04-15 Polymer Group, Inc. Differentially entangled nonwoven fabric for use as wipes
US8877316B2 (en) * 2002-12-20 2014-11-04 The Procter & Gamble Company Cloth-like personal care articles
US20040176002A1 (en) * 2003-03-04 2004-09-09 Siegwart Kathleen Ann Disposable skin cleansing implement
DE10328906A1 (de) 2003-06-26 2005-01-13 Endress + Hauser Process Solutions Ag Feldbusverteilereinheit
US20080168748A1 (en) * 2003-07-31 2008-07-17 Edmak Limited Cleansing Pad
FR2858757B1 (fr) * 2003-08-12 2005-10-21 Georgia Pacific France Tampon pour les soins de la peau
FR2860525B1 (fr) * 2003-10-02 2006-02-10 Georgia Pacific France Procede de fabrication de tampons pour le soin de la peau
US8017145B2 (en) * 2003-12-22 2011-09-13 Conopco, Inc. Exfoliating personal care wipe article containing an array of projections
US20050148260A1 (en) * 2003-12-24 2005-07-07 Kopacz Thomas J. Highly textured non-woven composite wipe
FR2882068B1 (fr) * 2005-02-14 2011-04-08 Georgia Pacific France Tampon fibreux impregne
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Title
None *

Also Published As

Publication number Publication date
EP2396088A2 (fr) 2011-12-21
CA2750929A1 (en) 2010-08-19
FR2942133A1 (fr) 2010-08-20
FR2942133B1 (fr) 2012-12-14
RU2521302C2 (ru) 2014-06-27
RU2011134685A (ru) 2013-03-20
PL2396088T3 (pl) 2019-04-30
TR201900072T4 (tr) 2019-02-21
ES2712966T3 (es) 2019-05-16
US20110302734A1 (en) 2011-12-15
WO2010092261A2 (fr) 2010-08-19
WO2010092261A3 (fr) 2011-05-19

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