EP2225520B1 - Device for extracting metals or metal compounds from a material containing the metal or the metal compound - Google Patents
Device for extracting metals or metal compounds from a material containing the metal or the metal compound Download PDFInfo
- Publication number
- EP2225520B1 EP2225520B1 EP08861906.9A EP08861906A EP2225520B1 EP 2225520 B1 EP2225520 B1 EP 2225520B1 EP 08861906 A EP08861906 A EP 08861906A EP 2225520 B1 EP2225520 B1 EP 2225520B1
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- European Patent Office
- Prior art keywords
- metal
- furnace
- furnace vessel
- electrode
- electrodes
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/52—Manufacture of steel in electric furnaces
- C21C5/5229—Manufacture of steel in electric furnaces in a direct current [DC] electric arc furnace
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/52—Manufacture of steel in electric furnaces
- C21C5/5241—Manufacture of steel in electric furnaces in an inductively heated furnace
- C21C5/5247—Manufacture of steel in electric furnaces in an inductively heated furnace processing a moving metal stream while exposed to an electromagnetic field, e.g. in an electromagnetic counter current channel
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/52—Manufacture of steel in electric furnaces
- C21C5/5252—Manufacture of steel in electric furnaces in an electrically heated multi-chamber furnace, a combination of electric furnaces or an electric furnace arranged for associated working with a non electric furnace
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
- F27B3/08—Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces heated electrically, with or without any other source of heat
- F27B3/085—Arc furnaces
Definitions
- the invention relates to a device for recovering metals or metal compounds, from a material containing the metal or the metal compound according to the preamble of patent claim 1.
- a device of this kind is from the EP 1375628 A2 known.
- the field of application of the invention is the purification of slags from the iron and non-ferrous production and from the precious metal extraction, as well as the improvement of the metal removal in slag-based ferroalloying processes.
- an apparatus for recovering a metal from a slag containing the metal comprising a first furnace designed as an AC electric furnace and a second furnace constructed as a DC electric furnace, wherein a melt-bonding means is provided between the first furnace and the second furnace, so that the melt after heating in the first furnace can be brought into the second furnace.
- the object of the invention is to integrate the previously provided only in a separate downstream furnace slag cleaning by DC - field and magnetic field in the well-known industrial object SAF (Submerged Arc Furnance), also the efficiency of the classic furnace technology in only one stage and only one unit and the bundling of the competence in only one aggregate, as well as a more uncomplicated handling. This is to make it possible to dispense with the need for two units and the reduction of electrothermal losses.
- SAF Submerged Arc Furnance
- the furnace vessel 3 or 6 arranged in series or on a pitch circle electrodes protrude and the furnace vessel is formed round or square.
- a transverse bulkhead separating the regions is provided between the region of the furnace vessel in which the electrodes protrude and the region in which the additional electrode projects.
- a simplification of conventional ovens taking into account the core idea of the invention can be achieved in that, dispensing with the additional electrode, the existing electrodes can be switched to DC operation with the bottom electrode.
- the essence of the solution according to the invention is that the basic principle of the magnetic field directed transversely to a DC current flow is integrated into the concept of a standard SAF. It achieves a consistent gradual treatment of slag depending on the metallurgical processes, the process of slag treatment is not interrupted, temperature losses are avoided, the overall system is much smaller, the electrical equipment can be bundled, the handling of the exhaust gas is easier.
- This version includes the combination of a classic round or angular electric reduction oven (SAF), usually operated with alternating current (AC), and a DC reduction oven with anode and cathode, supplemented by a transversely to it aligned permanent or electromagnet.
- SAF classic round or angular electric reduction oven
- AC alternating current
- DC DC reduction oven with anode and cathode, supplemented by a transversely to it aligned permanent or electromagnet.
- the furnace thus combines the known electric reduction furnace and an intensive slag cleaning furnace in one unit in terms of process technology and design.
- This per se conventional "Enforced slag cleaning furnace", which has been designated 15, usually has 3 or 6 arranged in series or on a pitch circle electrodes 1 in a round or square running furnace vessel 2.
- the medium (slag) 14 is supplied with the energy required for reduction, melting and settling.
- the oven is now designed in such a way that a space 16 remains in the area of the slag tap, in which at least one further electrode 4, with the function of an anode, can be arranged.
- the furnace is designed with a bottom electrode as the cathode 5.
- a variant of the invention provides a switchability of the classical z. B. 3-6 electrodes in conjunction with a kind of batch process.
- the otherwise operating in the AC mode electrodes 1 would be switched to DC operation and in this case could be dispensed with the additional electrode 4.
- the interconnection of the electrodes 1 would thus be temporarily changed to a DC operation with the bottom electrode 5. That is, either a classical reduction furnace process would be operated OR a DC furnace process was operated with 3-6 parallel connected electrodes and bottom electrode and superimposed by the magnetic field as described. In this way existing ovens could be retrofitted even easier.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Furnace Details (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Description
Die Erfindung betrifft eine Vorrichtung zur Gewinnung von Metallen oder Metallverbindungen, aus einem das Metall oder die Metallverbindung enthaltenden Material gemäß dem Oberbegriff des Patentanspruchs 1.The invention relates to a device for recovering metals or metal compounds, from a material containing the metal or the metal compound according to the preamble of
Eine Vorrichtung dieser Art ist aus der
Das Anwendungsgebiet der Erfindung ist die Reinigung von Schlacken aus der Eisen- und Nichteisengewinnung sowie aus der Edelmetallgewinnung, sowie die Verbesserung des Metallausbringens bei schlackenbasierten Ferrolegierungsprozessen.The field of application of the invention is the purification of slags from the iron and non-ferrous production and from the precious metal extraction, as well as the improvement of the metal removal in slag-based ferroalloying processes.
Aus der
Die intensive Schlackenreinigung mittels DC - Technologie mit einer oder mehrerer Elektroden und Bodenelektrode(n) und quer gerichtetem Magnetfeld ist bereits vorgeschlagen worden. Der runde oder rechteckige Elektroreduktionsofen ist ein bewährtes Standard -Aggregat zur Reinigung von z.B. Kupferschlacken.
Nachteile:
- Eine Anlage zur intensiven Schlackenreinigung erfordert demzufolge 2 hintereinander geschaltete Aggregate. Dies erfordert entsprechend Platz, eine entsprechende Logistik, verbindende Rinnen, eine doppelte Ausführung von Teilen wie z.B. Steuerung oder Abgäskaminen. Zwischen den beiden Aggregaten kommt es zur Abkühlung der Schlacke und somit zu thermischen Verlusten. Standardofen und nachgeschalteter Ofen könnten von unterschiedlichen Lieferanten bezogen werden.
Disadvantage:
- A system for intensive slag cleaning therefore requires two units connected in series. This requires appropriate space, a corresponding logistics, connecting gutters, a double execution of parts such as control or Abgäskaminen. Between the two aggregates, the slag cools and thus thermal losses. Standard oven and downstream oven could be sourced from different suppliers.
Aufgabe der Erfindung ist die bislang nur in einem separaten nachgeschalteten Ofen vorgesehenen Schlackenreinigung mittels DC - Feld und Magnetfeld in das bekannte industrielle Objekt SAF (Submerged Arc Furnance) zu integrieren, ferner die Effizienzsteigerung der klassischen Ofentechnologie in nur einer Stufe und nur einem Aggregat und
die Bündelung der Kompetenz in nur einem Aggregat, sowie ein unkomplizierteres Handhabung.
Damit soll der Verzicht auf die Notwendigkeit von zwei Aggregaten und die Reduzierung der elektrothermischen Verluste ermöglicht werden.The object of the invention is to integrate the previously provided only in a separate downstream furnace slag cleaning by DC - field and magnetic field in the well-known industrial object SAF (Submerged Arc Furnance), also the efficiency of the classic furnace technology in only one stage and only one unit and
the bundling of the competence in only one aggregate, as well as a more uncomplicated handling.
This is to make it possible to dispense with the need for two units and the reduction of electrothermal losses.
Gelöst wird diese Aufgabe erfindungsgemäß durch eine Vorrichtung zur Gewinnung von Metallen oder Metallverbindungen, aus einem das Metall oder die Metallverbindung enthaltenden Material, mit einem Ofengefäß, mit einem ersten Einlass für die Zuführung des Materials, einem ersten Auslass zum Abführen von Abgas, einem Elektro-Reduktionsofen Bereich, mit einer oder mehreren üblicher Weise im AC Betrieb arbeitenden,optional auf DC Betrieb umschaltbaren Elektroden zum Schmelzen und/oder Reduzieren des zugeführten Materials, die in das Ofengefäß ragen, einem im Bereich des Schlackenabstichs vorgesehenen, als Absetzzone dienenden Raum, mit einer als Kathode ausgebildeten Bodenelektrode, zwischen der und einer Elektrode oder den optional auf DC Betrieb umschaltbaren Elektroden ein DC Stromfluß erzeugbar ist, und mit einem Elektrooder Permanentmagneten, der derart am Ofengefäß platziert ist, dass der im Ofengefäß erzeugterDC Stromfluss vom einem Magnetfeld gekreuzt wird, so dass mittels der überlagerten Strom- und Magnetfelder und der daraus resultierenden Kräfte, das im Ofen befindliche Medium derart in Bewegung versetzt wird, dass sich in Kombination der Effekte eine Rührwirkung ergibt, sowie mit einem Abstich zur Entnahme von dem geschmolzenen Metall oder der Metallverbindung und einem Überlauf oder Abstich für die Schlacke, dadurch, dass die Elektrode im Bereich des als Absetzzone dienenden Raumes angeordnet ist.This object is achieved according to the invention by a device for recovering metals or metal compounds, from a material containing the metal or the metal compound, with a furnace vessel, with a first inlet for the supply of the material, a first outlet for the discharge of exhaust gas, an electric Reduction furnace region, with one or more commonly operating in AC mode, optionally switchable to DC operation electrodes for melting and / or reducing the supplied material, which protrude into the furnace vessel, provided in the slag tap, serving as a settling zone, with a formed as a cathode bottom electrode, between which and an electrode or the optionally switchable to DC operation electrodes, a DC Stromfluß is generated, and with an electric or permanent magnet, which is placed on the furnace vessel, that the DC flow generated in the furnace vessel is crossed by a magnetic field, so that by means of the superimposed current and magnetic fields and the resulting forces, the medium in the oven is set in motion such that a combination of the effects results in a stirring effect, as well as with a tap for removal of the molten metal or metal compound and an overflow or tapping for the slag, characterized in that the electrode is arranged in the region of serving as the settling zone space.
Nach einer Ausgestaltung ist vorgesehen, dass in das Ofengefäß 3 oder 6 in Reihe oder auf einem Teilkreis angeordnete Elektroden ragen und das Ofengefäß rund oder eckig ausgebildet ist.According to one embodiment it is provided that in the
Vorzugsweise ist zwischen dem Bereich des Ofengefäßes, in den die Elektroden ragen, und dem Bereich, in den die zusätzliche Elektrode ragt, ein die Bereiche trennender Querschott vorgesehen.Preferably, a transverse bulkhead separating the regions is provided between the region of the furnace vessel in which the electrodes protrude and the region in which the additional electrode projects.
Eine Vereinfachung üblicher Öfen unter Berücksichtigung der Kernidee der Erfindung lässt sich dadurch erreichen, dass unter Verzicht auf die zusätzliche Elektrode die vorhandenen Elektroden auf DC Betrieb mit der Bodenelektrode umschaltbar sind.A simplification of conventional ovens taking into account the core idea of the invention can be achieved in that, dispensing with the additional electrode, the existing electrodes can be switched to DC operation with the bottom electrode.
Der Kern der erfindungsgemäßen Lösung besteht darin, dass das Grundprinzip des quer zu einem DC - Stromfluss gerichteten Magnetfeldes in das Konzept eines Standard - SAF integriert wird. Man erzielt eine konsequente schrittweise Behandlung der Schlacke in Abhängigkeit der metallurgischen Prozesse, der Prozess der Schlackenbehandlung wird nicht unterbrochen, Temperaturverluste werden vermieden, die Gesamtanlage wird deutlich kleiner, die elektrische Ausrüstung kann gebündelt werden, das Handling des Abgases wird einfacher.The essence of the solution according to the invention is that the basic principle of the magnetic field directed transversely to a DC current flow is integrated into the concept of a standard SAF. It achieves a consistent gradual treatment of slag depending on the metallurgical processes, the process of slag treatment is not interrupted, temperature losses are avoided, the overall system is much smaller, the electrical equipment can be bundled, the handling of the exhaust gas is easier.
Hieraus ergeben sich eine Reihe von Vorteilen:
- Der Prozess der intensiven Schlackenreinigung kann gezielt in einem Ofengefäß gesteuert werden.
- Die Überlagerung der verschiedenen elektrischen Größen kann optimal aufeinander abgestimmt werden.
- Es wird weniger Platz benötigt und
- es entfällt ein Transportschritt durch den Wegfall von einem zusätzlichen Ofengefäß.
- The process of intensive slag cleaning can be specifically controlled in a furnace vessel.
- The superimposition of the different electrical quantities can be optimally matched to one another.
- It takes less space and
- it eliminates a transport step by the elimination of an additional furnace vessel.
Eine Ausführung der Erfindung ist in der Figur schematisch dargestellt und soll nachfolgend beschrieben werden.An embodiment of the invention is shown schematically in the figure and will be described below.
Diese Ausführung beinhaltet die Kombination eines klassischen rund oder eckig ausgeführten Elektro - Reduktionsofens (SAF), üblich mit Wechselstrom (AC) betrieben, und einem DC- Reduktionsofen mit Anode und Kathode, ergänzt um einen quer dazu ausgerichteten Dauer- oder Elektromagneten. Der Ofen vereint somit den bekannten Elektro - Reduktionsofen und einen Intensiv - Schlackenreinigungs - Ofen prozesstechnisch und ausführungsmäßig in einem Aggregat.This version includes the combination of a classic round or angular electric reduction oven (SAF), usually operated with alternating current (AC), and a DC reduction oven with anode and cathode, supplemented by a transversely to it aligned permanent or electromagnet. The furnace thus combines the known electric reduction furnace and an intensive slag cleaning furnace in one unit in terms of process technology and design.
Dieser an sich übliche Ofen ("Enforced slag cleaning furnace"), der mit 15 bezeichnet worden ist, besitzt in der Regel 3 oder 6 in Reihe oder auf einem Teilkreis angeordnete Elektroden 1 in einem rund oder eckig ausgeführten Ofengefäß 2. Mittels dieser Elektroden, die üblicherweise im AC Betrieb arbeiten, wird dem Medium (Schlacke) 14 die zur Reduktion, zum Schmelzen und zum Absetzen erforderliche Energie zugeführt.
Der Ofen wird nun im Gegensatz zu den bekannten Öfen jedoch in der Art ausgeführt, dass im Bereich des Schlackenabstichs ein Raum 16 verbleibt, in dem mindestens eine weitere Elektrode 4, mit der Funktion einer Anode, angeordnet sein kann. Außerdem wird der Ofen mit einer Bodenelektrode als Kathode 5 ausgeführt. Von dieser / diesen zusätzlichen Elektrode(n) ausgehend wird nun eine Spannung zur Bodenelektrode angelegt, so dass ein zusätzlicher Stromfluss (DC) durch das Medium entsteht. Der Kern eines Elektro- oder Permanentmagneten 6 wird nun so am Ofengefäß platziert, dass der DC Stromfluss im rechten Winkel (oder mit ähnlicher Wirkung) vom Magnetfeld gekreuzt wird. Mittels dieser überlagerten Strom- und Magnetfelder und der daraus resultierenden Kräfte (3-Finger-Regel) wird im Ofen das Medium (die Schlacke) in Bewegung versetzt, so dass sich in Kombination der Effekte eine Rührwirkung ergibt, die die Wirkung des klassischen Ofenprozesses unterstützt, indem insbesondere das Absetzen noch in der Schlacke vorhandener kleiner Metallteilchen verbessert wird.This per se conventional "Enforced slag cleaning furnace", which has been designated 15, usually has 3 or 6 arranged in series or on a
However, in contrast to the known ovens, the oven is now designed in such a way that a
Über das DC - System wird dabei in der Regel nur die Leistung zugeführt, die für die forcierten Prozesse erforderlich ist. Das Magnetfeld erzielt seine Wirkung auch bei geringen magnetischen Feldstärken < 100 Gauss. In Kombination aller 3 Energieeintragungsarten (AC, DC, Magnetfeld) lassen sich die einzelnen Anteile noch optimieren.As a rule, only the power required for the forced processes is supplied via the DC system. The magnetic field achieves its effect even at low magnetic field strengths <100 Gauss. By combining all three types of energy input (AC, DC, magnetic field), the individual components can be optimized.
Denkbar für spezielle Prozesse sind auch Varianten mit einer zusätzlichen DC -Elektrode (Anode) im Bereich des Schlackeneinlaufs.Also conceivable for special processes are variants with an additional DC electrode (anode) in the area of the slag inlet.
Während im Bereich der Anoden eine Schüttung 13 z.B. in einer Höhe gleich dem Elektrodendurchmessers und somit vergleichsweise hoch erwünscht ist, um eine Leiterplatte auf der Schlacke darzustellen (also die Anode zu vergrößern), ist diese hohe Schüttung im Bereich der üblichen Elektroden eher unerwünscht, da sie zu elektrischen Querströmen führen kann. Sollte sich zwischen diesen beiden entgegengerichteten Aspekten im Einzelfall kein Kompromiss finden lassen, so ist der Einbau eines Querschottes 7 zur Trennung der Prozessräume oberhalb des Schlackenbades ähnlich wie bei Kivcet - Öfen möglich.While in the region of the anodes a
Eine Variante der Erfindung stellt eine Umschaltbarkeit der klassischen z. B. 3-6 Elektroden dar in Verbindung mit einer Art Batch - Prozess. In diesem Falle würden die sonst im AC Betrieb arbeitenden Elektroden 1 auf DC Betrieb umgeschaltet werden und in diesem Fall könnte auf die zusätzliche Elektrode 4 verzichtet werden. Die Verschaltung der Elektroden 1 würde somit zeitweilig auf einen DC - Betrieb mit der Bodenelektrode 5 gewechselt werden. Das heißt, es würde entweder ein klassischer Reduktionsofenprozess betrieben ODER es würde ein DC - Ofenprozess mit 3-6 parallel geschalteten Elektroden und Bodenelektrode betrieben und dieser vom Magnetfeld überlagert, wie beschrieben. Auf diese Art ließen sich bestehende Öfen noch leichter nachrüsten.A variant of the invention provides a switchability of the classical z. B. 3-6 electrodes in conjunction with a kind of batch process. In this case, the otherwise operating in the
Hinsichtlich der übrigen Bezugszeichen sei bemerkt, dass in der Zeichnung mit 8 der Abstich für das Metall bzw. die Metallverbindung bezeichnet ist, das/die sich unten im Ofengefäß unter der Schlacke 14 bei 9 angesammelt hat.
Die Abgase werden durch den Kamin 10 abgeführt.
Zum Entfernen der Schlacke 14 aus dem Ofengefäß dient der Schlackenabstich 12.With respect to the remainder of the reference numerals, it should be noted that in the drawing at 8, the tap for the metal or metal compound has been accumulated at the bottom of the furnace vessel below the
The exhaust gases are discharged through the
To remove the
Claims (3)
- Device for extraction of metal or metal compounds from a material containing the metal or metal compound, comprising
a furnace vessel (2) with a first inlet for feed of the material,
a first outlet (10) for discharge of waste gas,
an electric reduction furnace area with one or more electrodes (1), which usually operate in alternating-current operation and are optionally switchable over to direct-current operation and which project into the furnace vessel, for melting and/or reducing the fed material,
a space (16) provided in the region of the slag tap (12) and serving as a settling zone,
a base electrode (5) which is constructed as a cathode and between which and an electrode (4) or the electrode (1) optionally switchable over to direct-current operation a direct-current flow can be generated,
an electromagnet or permanent magnet (6) which is so positioned at the furnace vessel that the direct-current flow generated in the furnace vessel is crossed by the magnetic field thereof so that by means of the superimposed current and magnetic fields and the forces resulting therefrom the medium present in the furnace is set in motion in such a way that a stirring action results from the combination of the effects, and
a tap (8) for removal of the molten metal or the metal compound and an overflow or tap (12) for the slag,
characterised in that
the electrode (4) is arranged in the region of the space (16) serving as a settling zone. - Device according to claim 1, wherein three or six electrodes (1) arranged in a row or on a pitch circle project into the furnace vessel (3) and the furnace vessel (2) is formed to be round or polygonal.
- Device according to any one of the preceding claims, wherein provided between the region of the furnace vessel into which the electrodes (1) project and the space (16) serving as settling zone and into which the electrode (4) extends is a transverse bulkhead (7) separating the regions.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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DE102007061025 | 2007-12-18 | ||
DE102008021886 | 2008-05-02 | ||
DE102008058605A DE102008058605A1 (en) | 2007-12-18 | 2008-11-19 | Apparatus for recovering metals or metal compounds from a material containing the metal or metal compound |
PCT/DE2008/002125 WO2009076945A1 (en) | 2007-12-18 | 2008-12-17 | Device for extracting metals or metal compounds from a material containing the metal or the metal compound |
Publications (2)
Publication Number | Publication Date |
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EP2225520A1 EP2225520A1 (en) | 2010-09-08 |
EP2225520B1 true EP2225520B1 (en) | 2017-07-12 |
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Application Number | Title | Priority Date | Filing Date |
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EP08862095.0A Not-in-force EP2235461B1 (en) | 2007-12-18 | 2008-12-11 | Device and method for obtaining metals or metal compounds |
EP08861906.9A Not-in-force EP2225520B1 (en) | 2007-12-18 | 2008-12-17 | Device for extracting metals or metal compounds from a material containing the metal or the metal compound |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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EP08862095.0A Not-in-force EP2235461B1 (en) | 2007-12-18 | 2008-12-11 | Device and method for obtaining metals or metal compounds |
Country Status (9)
Country | Link |
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EP (2) | EP2235461B1 (en) |
CN (2) | CN101903730B (en) |
BR (2) | BRPI0820788B1 (en) |
CL (2) | CL2008003748A1 (en) |
DE (1) | DE102008058605A1 (en) |
PE (2) | PE20091616A1 (en) |
RU (2) | RU2455599C2 (en) |
WO (2) | WO2009077114A1 (en) |
ZA (2) | ZA201003734B (en) |
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CN102679718A (en) * | 2011-03-15 | 2012-09-19 | 孙晓冰 | Novel transferred arc plasma furnace structural design |
DE102011090072A1 (en) * | 2011-12-29 | 2013-07-04 | Sms Siemag Ag | A method for recovering a metal from a slag containing the metal and apparatus for recovering the metal |
DE102014015302A1 (en) | 2014-10-13 | 2016-04-14 | Sms Group Gmbh | Apparatus and method for cleaning slags |
RU2624880C2 (en) * | 2015-10-12 | 2017-07-07 | Сергей Федорович Павлов | Method of processing oxidised of nickel ores |
DE102016207798A1 (en) * | 2015-11-19 | 2017-05-24 | Sms Group Gmbh | Settling furnace and method of its operation |
CN106082342B (en) * | 2016-08-16 | 2017-12-08 | 浙江海鸿工业产品设计有限公司 | Molybdenum trisulfide production reaction unit |
CN107218800B (en) * | 2017-06-20 | 2019-07-19 | 青岛大学 | A kind of direct current electric arc furnace |
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CH688325A5 (en) * | 1994-11-25 | 1997-07-31 | Holderbank Financ Glarus | Process for the treatment of solid residues from waste incineration plants and apparatus for Drchfuehrung the process. |
CN1154411A (en) * | 1995-07-24 | 1997-07-16 | 亚瑞亚·勃朗勃威力有限公司 | Melting equipment |
AUPP554098A0 (en) * | 1998-08-28 | 1998-09-17 | Technological Resources Pty Limited | A process and an apparatus for producing metals and metal alloys |
EP1375628A3 (en) * | 2000-01-21 | 2004-12-08 | Integrated Environmental Technologies, Llc. | Methods and apparatus for treating waste |
JP2001279313A (en) * | 2000-03-30 | 2001-10-10 | Midrex Internatl Bv | Method for producing molten metallic iron |
RU2207476C2 (en) * | 2001-05-14 | 2003-06-27 | Коршунов Евгений Алексеевич | Melting unit |
US6689182B2 (en) * | 2001-10-01 | 2004-02-10 | Kobe Steel, Ltd. | Method and device for producing molten iron |
RU2235258C1 (en) * | 2003-02-28 | 2004-08-27 | Федеральное государственное унитарное предприятие "Институт Гинцветмет" | Technogenious material processing electric furnace |
DE102006022779A1 (en) | 2005-06-08 | 2006-12-21 | Sms Demag Ag | Method and apparatus for recovering a metal from a slag containing the metal |
-
2008
- 2008-11-19 DE DE102008058605A patent/DE102008058605A1/en not_active Withdrawn
- 2008-12-11 CN CN2008801215573A patent/CN101903730B/en not_active Expired - Fee Related
- 2008-12-11 EP EP08862095.0A patent/EP2235461B1/en not_active Not-in-force
- 2008-12-11 WO PCT/EP2008/010490 patent/WO2009077114A1/en active Application Filing
- 2008-12-11 BR BRPI0820788-7A patent/BRPI0820788B1/en not_active IP Right Cessation
- 2008-12-11 RU RU2010129916/02A patent/RU2455599C2/en not_active IP Right Cessation
- 2008-12-16 CL CL2008003748A patent/CL2008003748A1/en unknown
- 2008-12-17 RU RU2010129525/02A patent/RU2455600C2/en not_active IP Right Cessation
- 2008-12-17 EP EP08861906.9A patent/EP2225520B1/en not_active Not-in-force
- 2008-12-17 CN CN2008801211642A patent/CN101903729B/en not_active Expired - Fee Related
- 2008-12-17 PE PE2008002085A patent/PE20091616A1/en not_active Application Discontinuation
- 2008-12-17 WO PCT/DE2008/002125 patent/WO2009076945A1/en active Application Filing
- 2008-12-17 BR BRPI0821164-7A patent/BRPI0821164B1/en not_active IP Right Cessation
- 2008-12-18 PE PE2008002113A patent/PE20091533A1/en not_active Application Discontinuation
- 2008-12-18 CL CL2008003801A patent/CL2008003801A1/en unknown
-
2010
- 2010-05-26 ZA ZA2010/03734A patent/ZA201003734B/en unknown
- 2010-06-10 ZA ZA2010/04163A patent/ZA201004163B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP2225520A1 (en) | 2010-09-08 |
BRPI0820788B1 (en) | 2017-06-13 |
CN101903730A (en) | 2010-12-01 |
RU2010129525A (en) | 2012-01-27 |
RU2010129916A (en) | 2012-01-27 |
WO2009076945A1 (en) | 2009-06-25 |
WO2009077114A1 (en) | 2009-06-25 |
RU2455599C2 (en) | 2012-07-10 |
CL2008003801A1 (en) | 2009-10-16 |
CN101903729A (en) | 2010-12-01 |
CN101903730B (en) | 2013-12-25 |
ZA201003734B (en) | 2011-03-30 |
EP2235461B1 (en) | 2017-05-31 |
BRPI0820788A2 (en) | 2015-06-16 |
DE102008058605A1 (en) | 2009-07-02 |
EP2235461A1 (en) | 2010-10-06 |
BRPI0821164A2 (en) | 2015-06-16 |
BRPI0820788A8 (en) | 2016-10-11 |
RU2455600C2 (en) | 2012-07-10 |
PE20091533A1 (en) | 2009-10-03 |
ZA201004163B (en) | 2011-02-23 |
CN101903729B (en) | 2013-07-17 |
BRPI0821164B1 (en) | 2018-01-02 |
CL2008003748A1 (en) | 2009-05-15 |
PE20091616A1 (en) | 2009-11-07 |
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