EP2094456B1 - Panneau de fibres et son procédé de fabrication - Google Patents
Panneau de fibres et son procédé de fabrication Download PDFInfo
- Publication number
- EP2094456B1 EP2094456B1 EP07857475.3A EP07857475A EP2094456B1 EP 2094456 B1 EP2094456 B1 EP 2094456B1 EP 07857475 A EP07857475 A EP 07857475A EP 2094456 B1 EP2094456 B1 EP 2094456B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fibers
- fiberboard
- proportion
- recycled material
- plant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011094 fiberboard Substances 0.000 title claims description 23
- 238000000034 method Methods 0.000 title claims description 21
- 238000004519 manufacturing process Methods 0.000 title description 11
- 239000000835 fiber Substances 0.000 claims description 98
- 239000000463 material Substances 0.000 claims description 25
- 239000011230 binding agent Substances 0.000 claims description 20
- 239000000654 additive Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 239000000123 paper Substances 0.000 claims description 5
- 239000011111 cardboard Substances 0.000 claims description 3
- 239000011087 paperboard Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000000417 fungicide Substances 0.000 claims description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- 229920000877 Melamine resin Polymers 0.000 claims 1
- 239000004640 Melamine resin Substances 0.000 claims 1
- 229920001807 Urea-formaldehyde Polymers 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims 1
- 239000002482 conductive additive Substances 0.000 claims 1
- 125000005442 diisocyanate group Chemical group 0.000 claims 1
- 238000004079 fireproofing Methods 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229920001568 phenolic resin Polymers 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- ZJHHPAUQMCHPRB-UHFFFAOYSA-N urea urea Chemical compound NC(N)=O.NC(N)=O ZJHHPAUQMCHPRB-UHFFFAOYSA-N 0.000 claims 1
- 238000004078 waterproofing Methods 0.000 claims 1
- 239000002699 waste material Substances 0.000 description 18
- 239000000126 substance Substances 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- 235000013311 vegetables Nutrition 0.000 description 5
- 238000004026 adhesive bonding Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000010893 paper waste Substances 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 241000209134 Arundinaria Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241000208202 Linaceae Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 fumed silicas Chemical compound 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 235000019731 tricalcium phosphate Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/007—Manufacture of substantially flat articles, e.g. boards, from particles or fibres and at least partly composed of recycled material
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/10—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
- E04C2/16—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of fibres, chips, vegetable stems, or the like
Definitions
- the invention relates to a fiberboard, in particular based on cellulosic fibers.
- MDF Medium Density Fiberboard
- HDF boards High Density Fiberboard
- HDF panels are increasingly needed because they increasingly substitute other products as panels for paneling walls, ceilings and floors.
- fibreboards are increasingly in demand due to their excellent machinability and favorable coating properties.
- the invention therefore has the technical problem of providing a method for producing a fiberboard, with which it is possible to provide a fiberboard in an economical manner, which meets the requirements usually made.
- a fiberboard based on cellulosic fibers is produced, the cellulosic fibers of which consist of a proportion of fibers made from vegetable raw materials and at least one further fraction of fibers made available or recovered from waste materials.
- the fibers are scattered in several layers to a nonwoven fabric, wherein in the different layers different proportions of a waste fibers and plant-derived fibers.
- Cellulosic fibers from waste materials are contained in particular in paper, cardboard, paperboard or pulp. These old substances, which can be summarized under the name waste paper, today form the most important raw material for the paper industry itself.
- waste paper In some cases very expensive wet process, the respectively required Cellulose fiber quality recovered from the waste, freed from impurities and added depending on the desired paper quality, in a certain proportion in papermaking.
- cellulosic fibers in a purely mechanical way in a dry process.
- Such fibers are also suitable for the process according to the invention since there are lower to no requirements with regard to any impurities.
- dyes as compulsorily contained in waste paper have no disadvantageous properties for the plate according to the invention and its production.
- the treatment of the cellulose-containing fibers, which are obtained from a waste by a multi-stage drying process. It has proved to be advantageous in this regard in a first stage with a hammer mill pressed into bales crushed waste paper, so that a pourable granules with a particle size of several millimeters to a few centimeters is formed.
- This material is then readily observed in a subsequent step to eliminate large foreign matter.
- the remaining portion is then ground into fibers using a mill or a refiner.
- a proportion of cellulosic fibers from existing substances of 1% to 80%, preferably a proportion of 10% to 65%, particularly preferably a proportion of 20% to 50%, based respectively on the dry mass of the finished plate, proved suitable.
- a modification of the cellulosic fibers is provided from a waste. This can be done in various ways and can also be provided for the achievement of a variety of objectives.
- Suitable as flow aids are known from the prior art substances such as diatomaceous earth, fumed silicas, tricalcium phosphate, etc.
- the modification of the cellulosic fibers provided from a waste can be carried out in the form of a hydrophobic treatment.
- a hydrophobic treatment By hydrophobing the cellulosic fibers provided from a waste, the resistance of a panel to moisture can be substantially improved.
- Addition of hydrophobizing agents in the production of MDF and HDF boards is well known, but it has surprisingly been found that addition of such substances to the pulp-derived cellulosic fibers is substantially more effective than simultaneous addition to the binder, such as in the production of conventional fiberboard is usually the case.
- Another type of modification may be the separate sizing of the cellulosic fibers obtained from a waste and the cellulosic plant-based fibers. This makes it possible in a simple manner to add to the different fractions specially adapted binders and / or specially adapted binder amounts.
- a further preferred embodiment is the possibility of utilizing the modification of the cellulosic fibers obtained from a waste material to achieve the addition of certain additives and / or auxiliaries in a particularly good distribution of these substances in the plate.
- the generally relatively dry fibers are able to absorb larger amounts of said liquid substances, whereby an increase in the desired effects can be achieved.
- additives and / or auxiliaries for example, substances for improving the electrical conductivity, dyes, emission scavengers or substances for flame and fire protection are meant.
- the reaction partners provided for the crosslinking reaction of the binder such as a hardener or an accelerator, and the binder itself are added separately to the different proportions of fibers provided from a recycled material and of fibers provided on a vegetable basis.
- the reactants can be added to the recovered fibers from a waste and the binder to the plant-derived fibers.
- the binder is added to the recovered fibers from a waste and the reactants to the plant-derived fibers. This advantageously achieves that these components only come into intimate contact with each other during the course of pressing, whereby an early and thus ineffective crosslinking reaction of the binder is prevented.
- the method described above can be carried out in a simple manner on plants for the production of fiberboard by the dry process. Only simple devices for providing the cellulosic fibers obtained from a waste material and optionally devices for modifying these fibers are required.
- the addition of the cellulosic fibers from a waste to the cellulosic fibers on a vegetable basis can take place at various points in the production process.
- wood chips from deciduous and / or softwood are shredded after their washing and a hydrothermal digestion in refiners.
- These fibers produced in this way pass from there via the so-called blow-line, in which binders and auxiliaries and additives can be added, via a fiber dryer into a fiber bunker, from which the feed of a spreading station then takes place. This then forms a nonwoven, which deflected in a cycle press or as an infinite strand in one continuously working double belt press or a calender press is pressed.
- the desired plate formats are deflected before or after the press.
- auxiliaries and additives are understood, for example, hardeners and accelerators, water repellents or fire protection and fungicidal agents.
- binder and auxiliaries and additives in the blow-line it is also possible to add these between the fiber dryer and the fiber bunker. According to the already dry state of the fibers one speaks then of a dry gluing.
- the addition of binder and auxiliaries and additives in the region of the entry of the fibers into the dryer can take place. Since very high transport speeds and optionally also turbulent flow conditions are present, this ensures a very good mixing of the various fiber fractions.
- the cellulosic fibers obtained from a waste material are already in a moisture range suitable for the pressing process, they can also be added after the fiber dryer, for example before the fiber bunker which is provided immediately before the scattering station.
- a dry gluing device ie a device with which the fibers are glued only after they have been dried, is used for the gluing of the fibers, it is advantageously possible to add the cellulosic fibers provided from a recycled material in front of this dry gluing device.
- the entirety of the fibers are provided with binder, whereby reduced equipment costs can be achieved.
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Architecture (AREA)
- Manufacturing & Machinery (AREA)
- Forests & Forestry (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Paper (AREA)
Claims (15)
- Procédé de fabrication d'un panneau de fibres,- dans lequel des fibres contenant de la cellulose sont fournies à partir d'un matériau végétal,- dans lequel des fibres contenant de la cellulose sont fournies à partir d'un matériau recyclé,- dans lequel un liant est ajouté,- dans lequel un non-tissé fibreux est formé et- dans lequel un non-tissé fibreux est comprimé en un panneau,
caractérisé en ce que- les fibres sont répandues en plusieurs couches en un non-tissé et- dans les différentes couches, différentes teneurs de fibres fournies à partir d'un matériau recyclé et fibres fournies à partir d'un matériau végétal sont ajoutées,- dans lequel la teneur en fibres fournies à partir d'un matériau recyclé dans la couche centrale du plateau est plus élevée que dans la couche de couverture. - Procédé selon la revendication 1,
dans lequel les fibres sont fournies à partir d'un matériau recyclé sélectionné dans le groupe du papier, du carton, du carton mince et de la cellulose. - Procédé selon la revendication 1 ou 2,
dans lequel les fibres fournies à partir d'un matériau recyclé sont extraites au cours d'un procédé sec, en particulier en plusieurs étapes. - Procédé selon l'une des revendications 1 à 3,
dans lequel les fibres fournies à partir d'un matériau recyclé sont ajoutées avec une teneur de 1 % à 80 %, de préférence une teneur de 10 % à 65 %, particulièrement de préférence une teneur de 20 % à 50 %, rapporté respectivement à la masse sèche du panneau fabriqué. - Procédé selon l'une des revendications 1 à 4,
dans lequel les fibres fournies à partir d'un matériau recyclé sont modifiées dans une étape séparée. - Procédé selon l'une des revendications 1 à 5,
dans lequel un liant à base de résine urée-formaldéhyde ou de résine urée-mélamine ou de résine phénol-formaldéhyde ou de résine tanin-formaldéhyde ou de diisocyanate ou à base de mélange de ceux-ci est employé. - Procédé selon l'une des revendications 1 à 6,
dans lequel l'ajout du liant aux fibres fournies à partir d'un matériau recyclé est effectué séparément de l'ajout du liant aux fibres fournies à base d'un matériau végétal, dans lequel en particulier une composante de liant est ajoutée aux fibres fournies à partir d'un matériau recyclé et une autre composante de liant est ajoutée aux fibres fournies à partir d'un matériau végétal. - Procédé selon la revendication 6,
dans lequel le liant est ajouté aux fibres fournies à partir d'un matériau recyclé et aux fibres fournies à partir d'un matériau végétal conjointement dans un dispositif pour l'encollage à sec. - Panneau de fibres à base de fibres contenant de la cellulose,- dans lequel les fibres contenant de la cellulose sont composées d'une teneur en fibres fournies à partir d'un matériau végétal, et- dans lequel les fibres contenant de la cellulose sont composées d'une teneur en fibres fournies à partir d'un matériau recyclé,
caractérisé en ce- qu'un montage multicouches est prévu et- que les différentes couches contiennent différentes teneurs de fibres fournies à partir d'un matériau recyclé et de fibres fournies à partir d'un matériau végétal, et- que la teneur en fibres fournies à partir d'un matériau recyclé dans la couche centrale du plateau est plus élevée que dans la couche de couverture. - Panneau de fibres selon la revendication 9,
caractérisé en ce que
les fibres fournies à partir d'un matériau recyclé sont fournies à partir d'un matériau recyclé sélectionné dans le groupe du papier, du carton, du carton mince et de la cellulose. - Panneau de fibres selon la revendication 9 ou 10,
caractérisé en ce que
les fibres fournies à partir d'un matériau recyclé ont une teneur de 1 % à 80 %, de préférence une teneur de 10 % à 65 %, particulièrement de préférence une teneur de 20 % à 50 %, rapporté respectivement à la masse sèche du panneau fabriqué. - Panneau de fibres selon l'une des revendications 9 à 11,
caractérisé en ce que
les fibres extraites d'un matériau recyclé sont modifiées. - Panneau de fibres selon l'une des revendications 9 à 12,
caractérisé en ce que
les fibres fournies à partir d'un matériau recyclé sont modifiées par ajout d'un additif, qui est en particulier un additif conducteur et/ou un agent agissant comme ignifuge et fongicide. - Panneau de fibres selon la revendication 13,
caractérisé en ce que
le panneau de fibres présente un agent d'hydrophobisation. - Panneau de fibres selon la revendication 13 ou 14,
caractérisé en ce que
le panneau de fibres présente un colorant.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL07857475T PL2094456T3 (pl) | 2006-12-22 | 2007-12-12 | Płyta pilśniowa i sposób jej wytwarzania |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006062285A DE102006062285B4 (de) | 2006-12-22 | 2006-12-22 | Faserplatte und Verfahren zu deren Herstellung |
PCT/EP2007/063812 WO2008077793A1 (fr) | 2006-12-22 | 2007-12-12 | Panneau de fibres et son procédé de fabrication |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2094456A1 EP2094456A1 (fr) | 2009-09-02 |
EP2094456B1 true EP2094456B1 (fr) | 2016-10-26 |
Family
ID=39146840
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07857475.3A Active EP2094456B1 (fr) | 2006-12-22 | 2007-12-12 | Panneau de fibres et son procédé de fabrication |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP2094456B1 (fr) |
DE (1) | DE102006062285B4 (fr) |
ES (1) | ES2605155T3 (fr) |
HU (1) | HUE030748T2 (fr) |
PL (1) | PL2094456T3 (fr) |
WO (1) | WO2008077793A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1019736A3 (fr) * | 2010-04-09 | 2012-12-04 | Unilin Bvba | |
DE102011052301A1 (de) * | 2011-07-29 | 2013-01-31 | Topalit GmbH | Formteil und Verfahren zu dessen Herstellung |
CN104191472B (zh) * | 2014-08-28 | 2016-04-27 | 潘建朋 | 一种减少有害气体的人造板 |
WO2019117799A1 (fr) * | 2017-12-15 | 2019-06-20 | Nsr Ab | Panneau de particules avec résine hybride |
IT201900014682A1 (it) | 2019-08-12 | 2021-02-12 | Fantoni Arredamenti Spa | Pannello in fibra di legno e relativo impianto e metodo di realizzazione |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2117872C3 (de) | 1971-04-13 | 1979-07-19 | Kataflox S.A., Genf (Schweiz) | Verfahren zur Wiederverwendung von aus Abwasserschlämmen gewonnenen Fasern |
DE2811833B2 (de) * | 1978-03-17 | 1980-04-17 | Bison-Werke Baehre & Greten Gmbh & Co Kg, 3257 Springe | Überwiegend aus Fasermaterial und mindestens einem Bindemittel bestehende Platte sowie Verfahren zu deren Herstellung |
DE2845117C2 (de) * | 1978-10-17 | 1985-03-07 | Casimir Kast Gmbh & Co Kg, 7562 Gernsbach | Verfahren und Anlage zur Herstellung von zu Formteilen verpreßbarem Plattenmaterial |
DE4020969C1 (en) * | 1989-10-05 | 1991-07-18 | Mayer, Frank, Prof. Dr., 3400 Goettingen, De | Moulding with improved mechanical properties and density - comprises mixt. of wood or cellulose material shavings and potato pulp, waste paper and binder |
DE4124355A1 (de) * | 1991-07-23 | 1993-01-28 | Rolf Schlotterhausen | Verfahren zum wiederverwerten von abfaellen aus harzgetraenktem papier u. dgl. |
DE4342678A1 (de) * | 1993-12-15 | 1995-06-22 | Karl Schedlbauer | Strang- oder strangrohrgepreßte Formteile, insbesondere Platten |
FR2737141A1 (fr) * | 1995-07-24 | 1997-01-31 | Carle Alain | Agglomeres destines au recyclage des dechets ligneux, des papiers et cartons de recuperation des excedents d'amidon, de resines ou de gommes organiques et toutes substances a combustion non polluante |
DE29603564U1 (de) * | 1996-02-27 | 1996-07-25 | Vollmer, Sven, 83024 Rosenheim | Verbundwerkstoff |
SE513336C2 (sv) * | 1998-10-14 | 2000-08-28 | Tetra Laval Holdings & Finance | Fiberskiva av MDF-typ, sätt att framställa densamma, samt användning av återvunna cellulosafibrer för tillverkning av sådana fiberskivor |
DE10006982A1 (de) * | 2000-02-16 | 2001-08-23 | Gert H Weihe | Werkstoff und Verfahren zu dessen Herstellung |
-
2006
- 2006-12-22 DE DE102006062285A patent/DE102006062285B4/de not_active Revoked
-
2007
- 2007-12-12 PL PL07857475T patent/PL2094456T3/pl unknown
- 2007-12-12 HU HUE07857475A patent/HUE030748T2/hu unknown
- 2007-12-12 EP EP07857475.3A patent/EP2094456B1/fr active Active
- 2007-12-12 ES ES07857475.3T patent/ES2605155T3/es active Active
- 2007-12-12 WO PCT/EP2007/063812 patent/WO2008077793A1/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
ES2605155T3 (es) | 2017-03-13 |
WO2008077793A1 (fr) | 2008-07-03 |
PL2094456T3 (pl) | 2017-05-31 |
DE102006062285A1 (de) | 2008-06-26 |
EP2094456A1 (fr) | 2009-09-02 |
DE102006062285B4 (de) | 2009-05-28 |
HUE030748T2 (hu) | 2017-05-29 |
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