EP2029713A1 - Compositions détergentes liquides comprenant des polymères d'acide polyacrylique de faible polydispersité - Google Patents

Compositions détergentes liquides comprenant des polymères d'acide polyacrylique de faible polydispersité

Info

Publication number
EP2029713A1
EP2029713A1 EP07784463A EP07784463A EP2029713A1 EP 2029713 A1 EP2029713 A1 EP 2029713A1 EP 07784463 A EP07784463 A EP 07784463A EP 07784463 A EP07784463 A EP 07784463A EP 2029713 A1 EP2029713 A1 EP 2029713A1
Authority
EP
European Patent Office
Prior art keywords
units
formula
mixtures
backbone
liquid detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP07784463A
Other languages
German (de)
English (en)
Inventor
Robb Richard Gardner
Jeffrey Scott Dupont
Kenneth Nathan Price
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of EP2029713A1 publication Critical patent/EP2029713A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate

Definitions

  • Typical builders such as citrates and fatty acids
  • polymer additives such as polyacrylates, and higher molecular weight/high charge density molecules
  • Typical builders such as citrates and fatty acids
  • polymer additives such as polyacrylates, and higher molecular weight/high charge density molecules
  • Typical builders such as citrates and fatty acids
  • polymer additives such as polyacrylates, and higher molecular weight/high charge density molecules
  • Typical builders such as citrates and fatty acids
  • polymer additives such as polyacrylates, and higher molecular weight/high charge density molecules
  • a fully non-branched linear modified polyamine according to the present invention has the formula
  • R4 is CJ-CJ 2 alkylene, C4-C12 alkenylene, Cg-Cj 2 arylalkylene, Cg-CjQ arylene, preferably CJ-CJQ alkylene, Cg-Cj 2 arylalkylene, more preferably C 2 -Cg alkylene, most preferably ethylene or butylene.
  • 20 E units are selected from the group consisting of -(CH 2 )pCO 2 M, -(CH 2 )q-S ⁇ 3M, -
  • indices have the following values: p has the value from 1 to 6; q has the value from 0 to 6; r has the value 0 or 1; w has the value 0 or 1; x has the value from 1 to 100; y has the value from 0 to 100; z has the value 0 or 1; k has the value from 0 to about 20; m has the value from 4 to about 400; n has the value from 0 to about 200; preferably m + n has the value of at least 5.
  • [J-R] n -J wherein the [J-R] units represent the amino units which comprise the main backbone and any branching chains.
  • the zwitterionic polyamines prior to modification, mter alia, quaternization, substitution of an amino unit hydrogen with an alkyleneoxy unit have backbones which comprise from 2 to about 100 amino units.
  • the index n which describes the number of backbone units present is further described herein below.
  • the anionic groups of the present invention include both units which are covalently attached to the polymer, as well as, external anions which are present to achieve charge neutrality.
  • Non-limiting examples of anions suitable for use include halogen, inter alia, chloride; methyl sulfate; hydrogen sulfate, and sulfate.
  • the formulator will recognize by the herein described examples that the anion will typically be a unit which is part of the quaternizing reagent, inter alia, methyl chloride, dimethyl sulfate, benzyl bromide.
  • Non-limiting examples of backbones according to the present invention include 1,9- diamino-3,7-dioxanonane; 1 , 10-diamino-3,8-dioxadecane; 1 , 12-diamino-3,10-dioxadodecane; l,14-diamino-3,12-dioxatetradecane.
  • backbones which comprise more than two nitrogens may comprise one or more repeating units having the formula:
  • the formulator may form zwitterionic polymers which have an excess of charge or an equivalent amount of charge type.
  • An example of a preferred zwitterionic polyamine according to the present invention which has an excess of backbone quaternized units, has the formula:

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne des compositions détergentes liquides comprenant un polymère comprenant des monomères d'acide polyacrylique ayant une masse moléculaire moyenne en nombre faible, comprise entre environ 1 000 et environ 10 000 amu, et une très faible polydispersité, inférieure à environ 5. Selon l'invention, le détergent liquide comprend une quantité inférieure à environ 50 % de solvants non-aminofonctionnels quelconques. L'invention concerne également des compositions détergentes liquides comprenant des mélanges avantageux des polymères à base d'acide polyacrylique de faible masse moléculaire et de très faible polydispersité avec des polymères spécifiques.
EP07784463A 2006-06-19 2007-06-18 Compositions détergentes liquides comprenant des polymères d'acide polyacrylique de faible polydispersité Ceased EP2029713A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US81493806P 2006-06-19 2006-06-19
PCT/US2007/071441 WO2007149806A1 (fr) 2006-06-19 2007-06-18 Compositions détergentes liquides comprenant des polymères d'acide polyacrylique de faible polydispersité

Publications (1)

Publication Number Publication Date
EP2029713A1 true EP2029713A1 (fr) 2009-03-04

Family

ID=38577489

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07784463A Ceased EP2029713A1 (fr) 2006-06-19 2007-06-18 Compositions détergentes liquides comprenant des polymères d'acide polyacrylique de faible polydispersité

Country Status (6)

Country Link
EP (1) EP2029713A1 (fr)
JP (1) JP2009542896A (fr)
BR (1) BRPI0712934A2 (fr)
CA (1) CA2652467A1 (fr)
MX (1) MX2008016448A (fr)
WO (1) WO2007149806A1 (fr)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9376648B2 (en) 2008-04-07 2016-06-28 The Procter & Gamble Company Foam manipulation compositions containing fine particles
WO2009148983A1 (fr) 2008-06-06 2009-12-10 The Procter & Gamble Company Composition détergente comprenant un variant de xyloglucanase de la famille 44
EP2674488A1 (fr) 2008-06-06 2013-12-18 Novozymes A/S Variants de xyloglucanase de la famille 44
US20110150817A1 (en) * 2009-12-17 2011-06-23 Ricky Ah-Man Woo Freshening compositions comprising malodor binding polymers and malodor control components
EP2501792A2 (fr) 2009-12-29 2012-09-26 Novozymes A/S Polypeptides amplifiant la detergence
MX369096B (es) 2010-02-10 2019-10-29 Novozymes As Variantes y composiciones que comprenden variantes con alta estabilidad en presencia de un agente quelante.
EP2357220A1 (fr) 2010-02-10 2011-08-17 The Procter & Gamble Company Compositions de nettoyage comprenant des variantes de l'amylase de grande stabilité en présence d'un agent chélateur
WO2011104339A1 (fr) 2010-02-25 2011-09-01 Novozymes A/S Variants d'un lysozyme et polynucléotides pour les coder
US8492325B2 (en) * 2010-03-01 2013-07-23 The Procter & Gamble Company Dual-usage liquid laundry detergents comprising a silicone anti-foam
US20130266554A1 (en) 2010-09-16 2013-10-10 Novozymes A/S Lysozymes
MX2013009178A (es) 2011-02-16 2013-08-29 Novozymes As Composiciones detergentes que comprenden metaloproteasas.
JP2014511409A (ja) 2011-02-16 2014-05-15 ノボザイムス アクティーゼルスカブ 金属プロテアーゼを含む洗剤組成物
WO2012110564A1 (fr) 2011-02-16 2012-08-23 Novozymes A/S Composition de détergent comprenant des métalloprotéases m7 ou m35
WO2014029819A1 (fr) 2012-08-22 2014-02-27 Novozymes A/S Métalloprotéase dérivée de exiguobacterium
MX2015002212A (es) 2012-08-22 2015-05-08 Novozymes As Composiciones detergentes que comprenden metaloproteasas.
WO2014029821A1 (fr) 2012-08-22 2014-02-27 Novozymes A/S Métalloprotéases dérivées de alicyclobacillus sp.
DE102013216776A1 (de) * 2013-08-23 2015-02-26 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
WO2016066369A1 (fr) * 2014-10-29 2016-05-06 Unilever Plc Réduction de la détérioration des couleurs pendant le procédé de lavage du linge
US20210171927A1 (en) 2016-01-29 2021-06-10 Novozymes A/S Beta-glucanase variants and polynucleotides encoding same
WO2018224544A1 (fr) 2017-06-08 2018-12-13 Novozymes A/S Compositions comprenant des polypeptides ayant une activité cellulase et une activité amylase et leurs utilisations dans des compositions de nettoyage et détergentes
US11746310B2 (en) 2017-10-02 2023-09-05 Novozymes A/S Polypeptides having mannanase activity and polynucleotides encoding same
EP3692148A1 (fr) 2017-10-02 2020-08-12 Novozymes A/S Polypeptides présentant une activité mannanase et polynucléotides codant pour ces polypeptides
EP3701001A1 (fr) 2017-10-24 2020-09-02 Novozymes A/S Compositions comprenant des polypeptides présentant une activité mannanase
WO2020070199A1 (fr) 2018-10-03 2020-04-09 Novozymes A/S Polypeptides ayant une activité de dégradation de l'alpha-mannane et polynucléotides codant pour ceux-ci
EP3947619A1 (fr) 2019-04-03 2022-02-09 Novozymes A/S Polypeptides ayant une activité bêta-glucanase, polynucléotides codant pour celles-ci et leur utilisation dans des compositions nettoyantes et détergentes
EP4097226A1 (fr) 2020-01-31 2022-12-07 Novozymes A/S Variants de mannanase et polynucléotides codant pour ceux-ci
EP4097227A1 (fr) 2020-01-31 2022-12-07 Novozymes A/S Variants de mannanase et polynucléotides codant pour ceux-ci
WO2023247348A1 (fr) 2022-06-21 2023-12-28 Novozymes A/S Variants de mannanase et polynucléotides codant pour ceux-ci

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0969024A2 (fr) * 1998-07-02 2000-01-05 Nippon Shokubai Co., Ltd. Adjuvant de détergence, procédé de sa préparation et polymère d'acide (meth)acrylique (ou sel) et son usage
US20030008995A1 (en) * 2001-05-01 2003-01-09 Shigeru Yamaguchi Acrylic acid (salt) polymer, its production process and uses

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* Cited by examiner, † Cited by third party
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GB8428985D0 (en) * 1984-11-16 1984-12-27 Allied Colloids Ltd Water soluble polymers
US7442749B2 (en) * 2002-08-29 2008-10-28 Nippon Shokubai Co., Ltd. Sulfur-containing poly (unsaturated carboxylic acid) and its uses and production process
CA2494131C (fr) * 2002-09-12 2013-03-19 The Procter & Gamble Company Solutions de polymeres et produits de nettoyage contenant celles-ci

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0969024A2 (fr) * 1998-07-02 2000-01-05 Nippon Shokubai Co., Ltd. Adjuvant de détergence, procédé de sa préparation et polymère d'acide (meth)acrylique (ou sel) et son usage
US20030008995A1 (en) * 2001-05-01 2003-01-09 Shigeru Yamaguchi Acrylic acid (salt) polymer, its production process and uses
US6794473B2 (en) * 2001-05-01 2004-09-21 Nippon Shokubai Co., Ltd. Acrylic acid (salt) polymer, its production process and uses

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2007149806A1 *

Also Published As

Publication number Publication date
JP2009542896A (ja) 2009-12-03
BRPI0712934A2 (pt) 2013-03-26
CA2652467A1 (fr) 2007-12-27
MX2008016448A (es) 2009-01-22
WO2007149806A1 (fr) 2007-12-27

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