EP1866469B1 - Non-tisse lie thermiquement - Google Patents
Non-tisse lie thermiquement Download PDFInfo
- Publication number
- EP1866469B1 EP1866469B1 EP06707417.9A EP06707417A EP1866469B1 EP 1866469 B1 EP1866469 B1 EP 1866469B1 EP 06707417 A EP06707417 A EP 06707417A EP 1866469 B1 EP1866469 B1 EP 1866469B1
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- EP
- European Patent Office
- Prior art keywords
- nonwoven fabric
- sheath
- core
- shrinkage
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000463 material Substances 0.000 title description 2
- 239000000835 fiber Substances 0.000 claims description 81
- 239000004745 nonwoven fabric Substances 0.000 claims description 72
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 29
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 29
- 229920000728 polyester Polymers 0.000 claims description 16
- 229920000642 polymer Polymers 0.000 claims description 15
- -1 polybutylene terephthalate Polymers 0.000 claims description 11
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 238000005452 bending Methods 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000011112 polyethylene naphthalate Substances 0.000 claims description 2
- 239000000306 component Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 6
- 230000004927 fusion Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000003490 calendering Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000036316 preload Effects 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 229920006125 amorphous polymer Polymers 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000009960 carding Methods 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000010705 motor oil Substances 0.000 description 2
- WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical group O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 description 1
- ZVSXNPBSZYQDKJ-UHFFFAOYSA-N 3,8-dioxabicyclo[8.3.1]tetradeca-1(14),10,12-triene-2,9-dione Chemical group O=C1OCCCCOC(=O)C2=CC=CC1=C2 ZVSXNPBSZYQDKJ-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 206010049040 Weight fluctuation Diseases 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
- D04H1/5412—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres sheath-core
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
- D04H1/43825—Composite fibres
- D04H1/43828—Composite fibres sheath-core
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
- D04H1/5418—Mixed fibres, e.g. at least two chemically different fibres or fibre blends
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/542—Adhesive fibres
- D04H1/55—Polyesters
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/74—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/2495—Thickness [relative or absolute]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/603—Including strand or fiber material precoated with other than free metal or alloy
- Y10T442/607—Strand or fiber material is synthetic polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
- Y10T442/641—Sheath-core multicomponent strand or fiber material
Definitions
- the invention relates to a thermally bonded nonwoven fabric having improved thermal and chemical stability.
- the invention further relates to a use of this nonwoven fabric.
- melt-bondable fibers and non-woven fabrics made therefrom are known.
- the melt-bondable fibers are bicomponent fibers comprised of a first at least partially crystalline polymer component and a second component adhered to the surface of the first component having a compatible blend of polymers, at least one amorphous polymer and at least one at least partially crystalline polymer.
- the melting temperature of the second component should be at least 30 ° C below the first component, but at least equal to or greater than 130 ° C.
- the weight ratio of the amorphous polymer of the second component to the at least partially crystalline polymer of the second component in the range of 15: 85 to 90: 10 and be sized so that the bonding of the bicomponent fibers is prevented with a similar bicomponent fiber and that the first component of the core and the second component of the shell in the form of a sheath Core configuration forms spun bicomponent fiber.
- This bicomponent fiber is blended with conventional polyester fibers and thermally bonded to a nonwoven fabric which is made into a nonwoven abrasive web by application of abrasive particles.
- heat-bondable conjugate fibers which have a sheath-core configuration and whose core consists of a polyester containing polyethylene terephthalate (PET) as the main component and whose sheath is made of a copolymerized polyester or a side-by-side conjugate fiber consisting of a polyester Polyethylene terephthalate and a copolymerized polyester.
- PET polyethylene terephthalate
- the copolymerized polyester is the lower melting component and contains butylene terephthalate units and butylene isophthalate units as recurring structural units.
- a nonwoven fabric made from these bicomponent fibers is said to have excellent thermal resistance and fatigue resistance to compressive loads, so it can be used as an alternative material to polyurethane upholstery, especially in the automotive field.
- thermally bonded nonwovens from a mixture of unstretched and stretched PET fibers.
- binding under heat and pressure in a calender is necessary.
- the binding capacity of the unstretched, amorphous PET fibers is not based on a melting process, but on the crystallization process of PET, which starts above 90 ° C, if there are still crystallizable parts.
- Such nonwoven fabrics have a high meet chemical and thermal stability.
- the manufacturing process allows low flexibility. For example, with undrawn PET fibers, it is not possible to activate their binding ability several times, since this is at a process that is irreversible below the melting temperature.
- the object of the invention has been found to provide a thermally bonded nonwoven fabric which shows improved properties in terms of its thermal stability, in particular the tendency to shrink of the resulting nonwoven fabrics.
- the chemical stability compared to fibers the copolymers of monomer mixtures such. Isophthalic acid / terephthalic acid contained, increased.
- thermoplastic bonded nonwoven fabric containing a low-shrinkage core-sheath bicomponent fiber.
- the low-crimp core-sheath bicomponent fiber consists of a crystalline polyester core and a crystalline polyester sheath which melts at least 10 ° C lower and has a hot air shrinkage at 170 ° C of less than 10%, preferably less than 5%.
- a corresponding nonwoven fabric has a thermal dimensional change (shrinkage and Bausch) of less than 2% at temperatures of 150 ° C (1 h).
- crystalline is understood as meaning a polyester polymer which has a melting enthalpy (DSC) of> 40 Joule / g and whose width of the melt peak (DSC) preferably precipitates at ⁇ 40 ° C. at 10 ° C./min.
- the sheath of the low-shrinkage bicomponent fiber consists of a homogeneous polyester polymer prepared from a monomer pair, which is formed to greater than 95% only from a polymer pair. In the case of the polyester described in the claims, this means that the polymer consists of> 95% of a single dicarboxylic acid and a single dialcohol.
- the mass ratio of core and cladding component is typically 50:50, but may vary between 90:10 and 10:90 for specific applications.
- a nonwoven fabric in which the sheath of the low-shrink core-sheath bicomponent fiber is polybutylene terephthalate (PBT), polytrimethylene terephthalate (PTT) or polyethylene terephthalate (PET).
- PBT polybutylene terephthalate
- PTT polytrimethylene terephthalate
- PET polyethylene terephthalate
- nonwoven fabric wherein the core of the low shrink core-sheath bicomponent fiber is polyethylene terephthalate or polyethylene naphthalate (PEN).
- PEN polyethylene naphthalate
- the nonwoven fabric of the present invention may contain other fibers other than the low-shrink core-sheath bicomponent fiber depending on the particular use.
- the nonwoven fabric according to the invention preferably consists of low-shrinkage core-sheath bicomponent fibers having a titer in the range between 0.1 and 15 dtex.
- the nonwoven fabric according to the invention has a basis weight between 20 and 500 g / m 2 .
- the nonwoven fabric according to the invention reaches at a Basis weight of eg 150-190g / m 2 a bending stiffness determined according to ISO 2493 transverse to the machine direction of greater than 1 Nmm.
- the method of making the thermally bonded nonwoven web is to lay the fibers into a nonwoven web, thermally bond and, if necessary, compact immediately thereafter.
- the fibers of the nonwoven fabric according to the invention dwell in a thermofusion oven, which enables uniform tempering of the binder fibers.
- the low-shrink core-sheath bicomponent fibers are wet laid in a paper-laying process and dried or dipped by a carding or airaldisch process, and then bonded at temperatures of 200 to 270 ° C and optionally by a calender or a press shop Roller temperatures which are below the melting point of the sheath polymer, preferably ⁇ 170 ° C, compressed This compression is preferably carried out immediately after the binding process in the dryer with still hot fibers.
- the structure of the fibers also allows subsequent thermal treatments, since the binding process can be activated several times.
- the resulting thermally bonded nonwoven fabrics have shrinkage and bulk values in the range of ⁇ 2%, preferably ⁇ 1%.
- the nonwoven fabrics according to the invention are suitable as a liquid filter medium, membrane support web, gas filter medium, battery separator or nonwoven fabric for the surface of composites due to their high thermal stability, their low shrinkage tendency and their chemical aging stability. This is especially true for use as an oil filter medium for use in automotive engines.
- the bending stiffness is determined according to ISO 2493 in Nmm.
- the sample (DIN A4-sized pattern) is provided with markings in the longitudinal and transverse direction, which have a distance of 200 mm. After storing the sample for 1 hour at 150 ° C in a convection oven and then cooling for 20 minutes at room temperature, the dimensional change is determined. This is given, in each case for the longitudinal and transverse directions in percent relative to the initial value. The signs before the percent value indicate whether the dimensional changes are positive (+) or negative (-). The mean value is formed from at least six individual values (measurements).
- the sample (DIN A4-sized sample) is provided with markings on which the thickness is determined in accordance with ISO 9073/2. After storing the sample for 1 hour at 150 ° C in a convection oven and then cooled for 20 minutes at room temperature, the thickness (ISO 9073/2) is determined again on the markers.
- the mean value is formed from at least six individual values (measurements).
- the fiber is provided with a biasing weight as described below.
- the free fiber end is in one Clamped clamp of a terminal plate.
- the length of the clamped fiber is determined (L 1 ).
- the fiber is tempered freely without hanging for 10 minutes at 170 ° C in a circulating air drying oven. After at least 20 minutes of cooling at room temperature, the same weight piece from the determination of L 1 is again attached to the fiber and the new length determined after the shrinking process (L 2 ).
- Fineness [dtex] Preload weight [mg] Fineness [dtex] Preload weight [mg] to 1.20 100 over 5.40 350 to 8.00 over 1,20 100 over 8,00 500 to 1.60 to 12.00 over 1.60 150 over 12.00 700 to 2.40 to 16.00 over 2.40 200 over 16.00 1000 to 3.60 to 24.00 over 3,60 250 over 24.00 1500 to 5.40 to 36.00
- the fiber In the suspended state, the fiber should appear entreplexed. If the crimping is too strong, the next higher weight should be selected.
- the sample is weighed and heated with a temperature program of 10 ° C / min from 0 ° C to 300 ° C.
- the area under the obtained endothermic melting peaks is related with the weight of fiber and the associated masses of the sheath or core component, the enthalpy of fusion of the respective components in J / g.
- Nonwoven A represents a drained, carded and thermally bonded nonwoven having a basis weight of 190g / m 2.
- This nonwoven fabric consists of 75% of a low shrink PET / PBT bicomponent fiber having a sheath melt point of 225 ° C and a core to sheath ratio of 50: 50 and 25% from conventional PET fibers. The thickness is 0.9 mm and the air permeability 850 l / m 2 s at 200 Pa. 140g / m 2 of the fibers are carded over carding with transverse stretcher, the remaining 50g / m 2 are longitudinally carded.
- the nonwoven fabric is bonded in a thermal fusion furnace at about 240 ° C and calibrated with an initial presser to the target thickness.
- Nonwoven B was produced analogously to nonwoven A The difference is the use of conventional PET / co-PET bicomponent fibers with a Mantelschmeizddling of about 200 ° C and the reduction of the oven temperature to 230 ° C. The resulting basis weight, thickness and air permeability are comparable.
- the nonwoven fabrics C and D represent wet laid, dried and thermally bonded nonwoven fabrics having a basis weight of 198 g / m 2 and 182 g / m 2.
- These nonwoven fabrics consist of 72% of a low-shrinkage PET / PBT bicomponent fiber with a sheath melt point of 225 ° C and a core-shell ratio of 50:50 and 28% of conventional PET-Fasem.
- the fibers are present as dispersible short cut fibers.
- the fibers are laid down in a paper-laying process on a wire belt, dried and thermally bonded in a second dryer.
- the outstanding properties of these nonwovens lie in the very good mechanical test values, as well as their excellent shrinkage behavior (Table 2).
- the low-shrinkage bicomponent fibers according to the invention offer advantages, since these fibers are multiply activatable in comparison to unstretched binder fibers or not fully react in the first drying process.
- the nonwovens A, C, D according to the invention are particularly suitable for use as motor oil filter medium in motor vehicles.
- calendered PET nonwoven fabrics are made of a mixture of stretched and unstretched monofilament PET fibers prior art. Due to the calendering process, there is a risk of surface sealing, especially for heavy nonwovens with basis weights> 150 g / m 2 , since high roll temperatures or slow production speeds are necessary for good penetration of the nonwoven fabric in order to bring the necessary heat into the interior of the nonwoven fabric. Sealed surfaces harbor the risk of film formation, which in turn leads to poor membrane adhesion and lower flow rates (comparative nonwoven fabric E).
- the FIGS. 4 and 5 demonstrate the different surfaces of a conventional nonwoven fabric (comparative example, nonwoven fabric E; FIG. 4 ) and the surface of a nonwoven fabric according to the invention (nonwoven fabric F; FIG. 5 ).
- the nonwovens according to the invention of the corresponding bicomponent fibers overcome both obstacles, since they are low in shrinkage and easily allow food approvals by the construction of homopolymers.
- the enthalpy of fusion is a direct measure of the crystalline proportions in the polymer.
- the core-sheath ratios of the two fibers are 1: 1, resulting in the following melt enthalples of the fiber sheaths: Fiber A 63 y / g Fiber B 29 y / g
- the core of both fibers can serve here, which consists of PET in both.
- the melting enthalpy values obtained are comparable (59 J / g vs. 54 J / g).
- the low peak height and the broader peak base are characteristic of fiber cladding based on copolymers (here CoPET).
- comonomers such as e.g. Isophthalic acid in polyethylene terephthalate, both the melting point and the crystallinity or willingness to crystallize the polymer is reduced.
- the nonwoven fabrics according to the invention are thus based on fibers of the fiber A type.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Multicomponent Fibers (AREA)
Claims (14)
- Utilisation d'un non-tissé lié thermiquement contenant une fibre à deux composants noyau-enveloppe pauvre en retrait, la fibre à deux composants noyau-enveloppe pauvre en retrait étant constituée par un noyau en polyester cristallin et une enveloppe en polyester cristallin fondant à une température inférieure d'au moins 10°C et présentant un retrait thermique à 170°C inférieur à 10% comme milieu de filtration d'un liquide, non-tissé support de membrane, milieu de filtration de gaz, séparateur de batterie ou non-tissé pour la surface de matériaux composites.
- Utilisation selon la revendication 1, le non-tissé étant utilisé comme milieu de filtration d'huile pour moteurs de véhicules à moteur.
- Utilisation selon la revendication 3, caractérisée en ce que l'enveloppe de la fibre à deux composants noyau-enveloppe pauvre en retrait est constituée à raison de > 95% d'un polymère de polyester homogène, qui n'est pas un copolymère.
- Utilisation selon la revendication 1 ou 2, caractérisée en ce que l'enveloppe de la fibre à deux composants noyau-enveloppe pauvre en retrait est constituée de poly(téréphtalate de butylène) (PBT), de poly(téréphtalate de triméthylène) (PTT) ou de poly(téréphtalate d'éthylène) (PET).
- Utilisation selon la revendication 1 ou 2, caractérisée en ce que le noyau de la fibre à deux composants noyau-enveloppe pauvre en retrait est constitué de poly(téréphtalate d'éthylène) (PET) ou de poly(naphtalate d'éthylène) (PEN).
- Utilisation selon l'une quelconque des revendications 1 à 5, caractérisée en ce que la fibre à deux composants noyau-enveloppe pauvre en retrait présente un titre entre 0,1 et 15 dtex.
- Utilisation selon l'une quelconque des revendications 1 à 6, caractérisée en ce que la fibre à deux composants noyau-enveloppe pauvre en retrait présente un rapport noyau-enveloppe entre 10:90 et 90:10, de préférence 50:50.
- Utilisation selon l'une quelconque des revendications 1 à 7, caractérisée en ce qu'elle contient jusqu'à 90% en poids d'une ou de plusieurs fibres.
- Utilisation selon l'une quelconque des revendications 1 à 8, caractérisée en ce que le non-tissé est déposé par voie humide.
- Utilisation selon l'une quelconque des revendications 1 à 8, caractérisée en ce que le non-tissé est déposé par voie sèche.
- Utilisation selon l'une quelconque des revendications 1 à 10, caractérisée en ce que la fibre à deux composants noyau-enveloppe pauvre en retrait présente un titre entre 0,1 et 15 dtex.
- Non-tissé selon l'une quelconque des revendications 1 à 11, caractérisé en ce qu'il présente un poids surfacique entre 20 et 500 g/m2.
- Non-tissé selon l'une quelconque des revendications 1 à 12, caractérisé en ce qu'il présente, à un poids surfacique > 150 g/m2, une résistance à la flexion transversale > 1 Nmm.
- Non-tissé selon l'une quelconque des revendications 1 à 13, caractérisé en ce qu'il présente, après 1 h à 150°C, une modification thermique des dimensions (bombement et retrait) < 2%, de préférence < 1%.
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DE200510015550 DE102005015550C5 (de) | 2005-04-04 | 2005-04-04 | Verwendung eines thermisch gebundenen Vliesstoffs |
PCT/EP2006/001992 WO2006105836A1 (fr) | 2005-04-04 | 2006-03-04 | Non-tisse lie thermiquement |
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EP1866469B1 true EP1866469B1 (fr) | 2013-07-17 |
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EP06707417.9A Active EP1866469B1 (fr) | 2005-04-04 | 2006-03-04 | Non-tisse lie thermiquement |
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US (2) | US8124550B2 (fr) |
EP (1) | EP1866469B1 (fr) |
KR (1) | KR100942879B1 (fr) |
CN (1) | CN101151406B (fr) |
DE (1) | DE102005015550C5 (fr) |
DK (1) | DK1866469T3 (fr) |
ES (1) | ES2429537T3 (fr) |
PL (1) | PL1866469T3 (fr) |
WO (1) | WO2006105836A1 (fr) |
Families Citing this family (20)
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DE102005015550C5 (de) * | 2005-04-04 | 2013-02-07 | Carl Freudenberg Kg | Verwendung eines thermisch gebundenen Vliesstoffs |
EP1964956B1 (fr) | 2007-01-31 | 2010-07-28 | Ivo Ruzek | Support de tufting léger et très résistant et son procédé de fabrication |
JP5497987B2 (ja) * | 2007-06-22 | 2014-05-21 | ユニ・チャーム株式会社 | 不織布およびその製造方法 |
CN102373578B (zh) * | 2010-08-18 | 2014-09-17 | 扬光绿能股份有限公司 | 无纺布及其制造方法、气体燃料的产生装置和产生方法 |
DE102010052466A1 (de) | 2010-11-26 | 2012-05-31 | Carl Freudenberg Kg | Membranträger, dessen Verwendung und Verfahren zur Herstellung flüssig applizierter Polymermembranen mit einem derartigen Membranträger |
MY167349A (en) * | 2010-12-24 | 2018-08-16 | Kao Corp | Method of producing nonwoven fabric, nonwoven fabric and manufacturing apparatus of nonwoven fabric, and a support for producing a nonwoven fabric |
CN102660842A (zh) * | 2012-05-22 | 2012-09-12 | 昆山吉美川纤维科技有限公司 | 床垫用椰棕板的制备方法 |
CN103866485B (zh) * | 2012-12-11 | 2017-07-28 | 东丽纤维研究所(中国)有限公司 | 一种热粘合无纺布及其生产方法和用途 |
CN104424941B (zh) * | 2013-09-05 | 2018-04-03 | 上海泰瑞电子科技有限公司 | 一种吸音材料及其制备方法 |
EP3052688B1 (fr) * | 2013-10-02 | 2019-01-16 | Carl Freudenberg KG | Structure plane présentant une stabilité thermique élevée |
DE102014003418B4 (de) | 2014-03-13 | 2017-01-05 | Carl Freudenberg Kg | Element zur Lichtmanipulation |
DE102014119524A1 (de) * | 2014-12-23 | 2016-06-23 | Coroplast Fritz Müller Gmbh & Co. Kg | "Klebeband, basierend auf einem Nähvlies-Träger mit Bikomponentenfasern" |
EP3078407A1 (fr) * | 2015-04-10 | 2016-10-12 | Carl Freudenberg KG | Support de filtre haute performance et sans liant |
DE202015105210U1 (de) | 2015-10-02 | 2016-11-03 | Ahlstrom Corp. | Filtermedium mit hoher Hitzebeständigkeit |
KR20180097515A (ko) * | 2015-12-22 | 2018-08-31 | 도레이 카부시키가이샤 | 필터용 스펀본드 부직포 및 그 제조방법 |
DE102016220770A1 (de) * | 2016-10-21 | 2018-04-26 | Elringklinger Ag | Abscheidevorrichtung, Motorvorrichtung und Abscheideverfahren |
DE102017003361B4 (de) | 2017-04-06 | 2021-09-30 | Carl Freudenberg Kg | Element zur Lichtmanipulation |
DE102017004481A1 (de) * | 2017-05-11 | 2018-11-15 | Carl Freudenberg Kg | Textiles Flächengebilde für die Elektroisolation |
DE102018110246B4 (de) * | 2018-04-27 | 2020-12-31 | Johann Borgers GmbH | Faservliesformteil |
DE202021106602U1 (de) * | 2020-12-03 | 2022-03-07 | herotec GmbH Flächenheizung | Verlegevorrichtung für Leitungen einer Flächentemperiervorrichtung |
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-
2005
- 2005-04-04 DE DE200510015550 patent/DE102005015550C5/de active Active
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2006
- 2006-03-04 EP EP06707417.9A patent/EP1866469B1/fr active Active
- 2006-03-04 KR KR1020077024939A patent/KR100942879B1/ko active IP Right Grant
- 2006-03-04 CN CN2006800108433A patent/CN101151406B/zh active Active
- 2006-03-04 DK DK06707417.9T patent/DK1866469T3/da active
- 2006-03-04 WO PCT/EP2006/001992 patent/WO2006105836A1/fr active Application Filing
- 2006-03-04 ES ES06707417T patent/ES2429537T3/es active Active
- 2006-03-04 PL PL06707417T patent/PL1866469T3/pl unknown
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Also Published As
Publication number | Publication date |
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CN101151406A (zh) | 2008-03-26 |
KR20070116279A (ko) | 2007-12-07 |
US20080308490A1 (en) | 2008-12-18 |
ES2429537T3 (es) | 2013-11-15 |
PL1866469T3 (pl) | 2013-12-31 |
KR100942879B1 (ko) | 2010-02-17 |
DE102005015550A1 (de) | 2006-10-26 |
DE102005015550C5 (de) | 2013-02-07 |
WO2006105836A1 (fr) | 2006-10-12 |
US8124550B2 (en) | 2012-02-28 |
US20120129032A1 (en) | 2012-05-24 |
DE102005015550B4 (de) | 2009-07-23 |
US8481437B2 (en) | 2013-07-09 |
CN101151406B (zh) | 2011-07-06 |
DK1866469T3 (da) | 2013-10-14 |
EP1866469A1 (fr) | 2007-12-19 |
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