EP1664363A1 - Hard metal or cermet body and method for producing the same - Google Patents
Hard metal or cermet body and method for producing the sameInfo
- Publication number
- EP1664363A1 EP1664363A1 EP04732930A EP04732930A EP1664363A1 EP 1664363 A1 EP1664363 A1 EP 1664363A1 EP 04732930 A EP04732930 A EP 04732930A EP 04732930 A EP04732930 A EP 04732930A EP 1664363 A1 EP1664363 A1 EP 1664363A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mass
- layer
- volume
- carbonitrides
- nitrides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 50
- 239000002184 metal Substances 0.000 title claims abstract description 50
- 239000011195 cermet Substances 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 44
- 150000004767 nitrides Chemical class 0.000 claims abstract description 25
- 239000011230 binding agent Substances 0.000 claims abstract description 23
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 22
- 150000002739 metals Chemical class 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 150000001247 metal acetylides Chemical class 0.000 claims abstract description 13
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 13
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 12
- 230000000737 periodic effect Effects 0.000 claims abstract description 12
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 10
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 8
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 7
- 230000005496 eutectics Effects 0.000 claims abstract description 6
- 239000012299 nitrogen atmosphere Substances 0.000 claims abstract description 6
- 230000007704 transition Effects 0.000 claims abstract description 4
- 238000005245 sintering Methods 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000000758 substrate Substances 0.000 claims description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 2
- 229910017109 AlON Inorganic materials 0.000 claims description 2
- 229910003460 diamond Inorganic materials 0.000 claims description 2
- 239000010432 diamond Substances 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 2
- 238000007669 thermal treatment Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 30
- 238000000034 method Methods 0.000 description 8
- 238000009792 diffusion process Methods 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000009489 vacuum treatment Methods 0.000 description 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- XCUPBHGRVHYPQC-UHFFFAOYSA-N sulfanylidenetungsten Chemical class [W]=S XCUPBHGRVHYPQC-UHFFFAOYSA-N 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1003—Use of special medium during sintering, e.g. sintering aid
- B22F3/1007—Atmosphere
- B22F3/101—Changing atmosphere
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
- C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
- C21D1/76—Adjusting the composition of the atmosphere
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Definitions
- the invention relates to a hard metal or cermet body having a hard material phase of WC and at least one carbide, nitride, carbonitride or oxicarbonitride of at least one of the elements of the IVa or Va group of the periodic table and having a binder phase of Fe, Co and / or Ni whose Proportion is 3-25 mass%, with a single or multiple contiguous surfaces, with a 2-1 OO ⁇ m thick first layer below the single or at least one of the surfaces, having a binder metal content of 2-25 mass% and up to 25% by volume of nitrides or carbonitrides of one or more metals of the IVa group of the Periodic Table and / or up to 10% by volume of carbides and / or carbonitrides of V, Nb, Ta and / or Cr.
- the invention further relates to a method for producing the aforementioned body, which after sintering or during sintering has undergone a first heat treatment to produce the aforesaid layer.
- the nitrogen required for the nitroxide can be converted to the cemented carbide both by a nitrogen atmosphere used and in the form of nitrides or carbonitrides of one of the hard material carbides. be fed mixture approach.
- the sintering is introduced under vacuum so that the gradient zone formation can occur.
- the gradient zone can also be obtained by subjecting the cemented carbide, after sintering in the temperature range from about 1150 to at most 1300 ° C., to a nitrogen treatment under elevated pressure.
- the sintering of the hard metal by dewaxing to 600 ° C, holding, heating to sintering temperature and subsequent vacuum sintering at 0.1 to 100 Pa and then pressure sintering done.
- the sintered body is subjected to a pressure treatment with a nitrogen at 1 to 10 MPa and a subsequent vacuum treatment at 10 to 100 Pa.
- DE 197 52 289 C1 states that a subsequent mechanical finish machining of the substrate body for producing a final contour is accompanied by an at least partial removal of the edge zones, so that the properties of the gradient zones which are assessed to be positive are completely or partially lost again.
- DE 197 52 289 proposes to post-treat the substrate body in a vacuum at about 600-1300 ° C. for a period of up to 150 min after finish-machining.
- a surface marginal zone is formed on the machined surfaces, enriched with binder metals and free of cubic mixed carbide.
- the thickness of this view is 5-35 ⁇ m.
- the wear resistance of such carbide or cermet body is to be improved, which are used as cutting tools.
- the cemented carbide or cermet body has, beneath a 2 to 100 ⁇ m thick first layer with increased binder content and a reduced proportion of mixed carbides, a further 2 to 40 ⁇ m thick second layer which has a higher nitrogen content than the first layer and which consists essentially of nitrides and / or carbonitrides of the metals of the IVa group of the Periodic Table and phase proportions of up to 10% by volume of »carbides, nitrides, carbonitrides or oxycarbonitrides of the elements, Mo, V, Ta, Nb, Cr and / or dissolved in the hard material phase Amounts of up to 5 mass% V, Nb, Ta and up to 2 mass% Cr, Mo, W and contains up to 15 mass% binder.
- this second layer is a transition zone having a thickness of 2 to 100 ⁇ m, in which the composition gradually changes to a homogeneous composition in the interior of the core of the cemented carbide or cermet body.
- a relatively tough and abrasive resistant zone is given with high levels of WC
- underlying layer is a diffusion-resistant, hard layer with high nitride or carbonitride proportions.
- said first layer has only up to 2% by mass of carbides or carbonitrides of at least one of the metals V, Nb, Ta and / or Cr.
- the first layer has a composition consisting of 4 to 15 mass% or 7 to 22 volume% binder metal (s), 80 to 96 mass% or 66 to 93 volume% WC and 0 to 5 mass% or 0 to 12 volume% TiCN and / or TiN.
- the total amount of the aforementioned substances gives 100 mass% or 100 volume%.
- the second layer preferably has 3 to 15 mass% or 2 to 15 volume%
- the nitrogen content in said second layer is from 8 to 22 mass% when the nitrides in that layer are present exclusively as metal nitrides.
- the nitride level decreases in the presence of metal carbonitrides as nitrogen is replaced by carbon.
- the nitrogen content of the second layer is thus preferably minimized to half, ie to 4 to 22 mass%.
- the object is also achieved by a body according to claim 6.
- the binder metal enriched and mixed carbide depleted first layer has been abraded, etched away or removed by other methods on one or more surfaces so that the cemented carbide or cermet body beneath the surface in question has the layer structure of claim 3.
- the hard metal or cermet body can additionally have a single-layer or multi-layer coating on at least one surface.
- This coating may consist of carbides, nitrides, carbonitrides, oxides, oxynitrides of the elements of the IVa-Vla group of the Periodic Table, but also Al 2 O 3 , ZrO 2) HfO 2 , AlON or carbon, preferably as diamond or molybdenum or tungsten sulfides ,
- the number of additional layers applied for example by means of PVD or CVD, and the choice of layer compositions depend on the intended use.
- the process according to claim 8 is used to produce the above-described cemented carbide or cermet body.
- the cemented carbide or cermet body produced by powder metallurgy is subjected to a first heat treatment to produce a binder metal-enriched 2-100 ⁇ m thick layer and then additionally subjected to this heat treatment of a nitrogen atmosphere under a nitrogen pressure of 50 mbar (5 ⁇ 10 3 Pa) to 1 OObar (10 7 Pa) below the eutectic, preferably treated at 1000 ° C to 1200 ° C.
- the binder metal-enriched and mixed-carbide-depleted first layer remains in its composition in the Essentially unchanged.
- the first near-surface layer thus has the effect of a membrane which allows nitrogen to pass in from the outside in, while at the same time inhibiting diffusion of nitrogen-affine metals to the outside.
- this membrane-like effect occurs only in a temperature range below the eutectic, namely at 1000 to 1200 ° C.
- titanium or other nitrogen-affine metals diffuse in the direction of the substrate body surface, where they form corresponding nitrides in the near-surface edge zones.
- the nitrogen diffusion slows down, so that the desired effect of nitrogen enrichment in the second layer practically no longer occurs. Compliance with the temperature limits in the second heat treatment is thus crucial for the success of the method according to the invention.
- the resulting layer below at least one surface by grinding, etching or other methods to remove before the body in a nitrogen atmosphere under a Nitrogen pressure 5 x 10 3 Pa to 10 7 Pa below the eutectic, preferably at temperatures between 1000 ° C and 1200 ° C is treated.
- a nitrogen-enriched, 2 to 40 ⁇ m thick layer with a higher nitrogen content forms immediately below the surface.
- This method can be used, in particular, for substrate bodies which serve as cutting tools, the layer sequences a) to c) described in claim 1 being present underneath the free surface while on the chip surface. surface or at least in the region near the cutting edge of the rake surface only a layer sequence according to b) and c) or claim 3 is present.
- the life in continuous section measured by the wear mark width and the Kolktiefe could be increased by 8 to 10 times.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Powder Metallurgy (AREA)
- Chemical Vapour Deposition (AREA)
- Ceramic Products (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Adornments (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL04732930T PL1664363T3 (en) | 2003-09-12 | 2004-05-14 | Hard metal or cermet body and method for producing the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10342364A DE10342364A1 (en) | 2003-09-12 | 2003-09-12 | Carbide or cermet body and process for its preparation |
PCT/DE2004/001016 WO2005026400A1 (en) | 2003-09-12 | 2004-05-14 | Hard metal or cermet body and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1664363A1 true EP1664363A1 (en) | 2006-06-07 |
EP1664363B1 EP1664363B1 (en) | 2010-08-25 |
Family
ID=34305731
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04732930A Expired - Lifetime EP1664363B1 (en) | 2003-09-12 | 2004-05-14 | Hard metal or cermet body and method for producing the same |
Country Status (8)
Country | Link |
---|---|
US (1) | US7544410B2 (en) |
EP (1) | EP1664363B1 (en) |
JP (1) | JP2007505212A (en) |
CN (1) | CN100439535C (en) |
AT (1) | ATE478969T1 (en) |
DE (2) | DE10342364A1 (en) |
PL (1) | PL1664363T3 (en) |
WO (1) | WO2005026400A1 (en) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101312927B (en) * | 2005-11-17 | 2011-04-06 | 倍锐特有限责任公司 | Laminated hard alloy piece |
JP5187572B2 (en) * | 2008-07-09 | 2013-04-24 | 三菱マテリアル株式会社 | Diamond coated cemented carbide cutting tool |
DE102008048967A1 (en) | 2008-09-25 | 2010-04-01 | Kennametal Inc. | Carbide body and process for its production |
US8663359B2 (en) * | 2009-06-26 | 2014-03-04 | Dimicron, Inc. | Thick sintered polycrystalline diamond and sintered jewelry |
CN102560393B (en) * | 2010-12-27 | 2016-04-06 | 青岛韬谱光学科技有限公司 | Film-coated part |
US8574728B2 (en) | 2011-03-15 | 2013-11-05 | Kennametal Inc. | Aluminum oxynitride coated article and method of making the same |
AT510981B1 (en) * | 2011-03-18 | 2012-08-15 | Boehlerit Gmbh & Co Kg | COATED BODY, USE THEREOF AND METHOD FOR THE PRODUCTION THEREOF |
GB201105150D0 (en) * | 2011-03-28 | 2011-05-11 | Element Six Holding Gmbh | Cemented carbide material and tools comprising same |
WO2013002270A1 (en) * | 2011-06-27 | 2013-01-03 | 京セラ株式会社 | Hard alloy and cutting tool |
US8834594B2 (en) | 2011-12-21 | 2014-09-16 | Kennametal Inc. | Cemented carbide body and applications thereof |
DE102012018067A1 (en) * | 2012-09-13 | 2014-03-13 | Tutec Gmbh | Hexagonal tungsten carbide powder having a specified nitrogen content, useful for making sintered cemented carbide bodies, where nitrogen is located in outer edge zone of tungsten carbide particles with specified particle diameter |
US9138864B2 (en) | 2013-01-25 | 2015-09-22 | Kennametal Inc. | Green colored refractory coatings for cutting tools |
US9017809B2 (en) | 2013-01-25 | 2015-04-28 | Kennametal Inc. | Coatings for cutting tools |
US9427808B2 (en) | 2013-08-30 | 2016-08-30 | Kennametal Inc. | Refractory coatings for cutting tools |
JP6327102B2 (en) * | 2014-10-10 | 2018-05-23 | 新日鐵住金株式会社 | Carbide tool |
US10094005B2 (en) * | 2014-11-27 | 2018-10-09 | Kyocera Corporation | Cermet and cutting tool |
JP6614491B2 (en) * | 2014-12-25 | 2019-12-04 | 三菱マテリアル株式会社 | Composite sintered body cutting tool and surface-coated composite sintered body cutting tool |
CN104862637A (en) * | 2015-05-09 | 2015-08-26 | 芜湖鼎瀚再制造技术有限公司 | Co-ZrO2-HfO2 nano-coating material and preparing method thereof |
US10066277B2 (en) * | 2015-06-12 | 2018-09-04 | Tungaloy Corporation | Cemented carbide and coated cemented carbide |
CN105112756A (en) * | 2015-08-12 | 2015-12-02 | 蔡婷婷 | Titanium carbonitride composited alumina cermet of cutting tool and preparation method thereof |
CN106312048A (en) * | 2016-09-18 | 2017-01-11 | 广东工业大学 | Metal ceramic particle and preparation method and application thereof |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2717842C2 (en) * | 1977-04-22 | 1983-09-01 | Fried. Krupp Gmbh, 4300 Essen | Process for the surface treatment of sintered hard metal bodies |
JPS60238481A (en) * | 1984-05-14 | 1985-11-27 | Sumitomo Electric Ind Ltd | Multilayered coated hard metal |
US4990410A (en) * | 1988-05-13 | 1991-02-05 | Toshiba Tungaloy Co., Ltd. | Coated surface refined sintered alloy |
JPH02131803A (en) * | 1988-11-11 | 1990-05-21 | Mitsubishi Metal Corp | Cutting tool made of abrasion resistant cermet excelling in chipping resistance |
JPH0711048B2 (en) * | 1988-11-29 | 1995-02-08 | 東芝タンガロイ株式会社 | High-strength nitrogen-containing cermet and method for producing the same |
JP2985300B2 (en) * | 1990-12-25 | 1999-11-29 | 三菱マテリアル株式会社 | Hard layer coated cermet |
WO1995030030A1 (en) * | 1994-05-03 | 1995-11-09 | Widia Gmbh | Cermet and process for producing it |
US5750247A (en) * | 1996-03-15 | 1998-05-12 | Kennametal, Inc. | Coated cutting tool having an outer layer of TiC |
DE19752289C1 (en) * | 1997-11-26 | 1999-04-22 | Hartmetall Beteiligungs Gmbh | Sintered hard metal article with a binder-enriched and/or cubic carbide-depleted surface zone |
DE19922057B4 (en) * | 1999-05-14 | 2008-11-27 | Widia Gmbh | Carbide or cermet body and process for its preparation |
US6110603A (en) * | 1998-07-08 | 2000-08-29 | Widia Gmbh | Hard-metal or cermet body, especially for use as a cutting insert |
DE10225521A1 (en) * | 2002-06-10 | 2003-12-18 | Widia Gmbh | Hard tungsten carbide substrate with surface coatings, includes doped metallic binder |
-
2003
- 2003-09-12 DE DE10342364A patent/DE10342364A1/en not_active Withdrawn
-
2004
- 2004-05-14 US US10/572,000 patent/US7544410B2/en not_active Expired - Fee Related
- 2004-05-14 WO PCT/DE2004/001016 patent/WO2005026400A1/en active Application Filing
- 2004-05-14 AT AT04732930T patent/ATE478969T1/en active
- 2004-05-14 PL PL04732930T patent/PL1664363T3/en unknown
- 2004-05-14 JP JP2006525609A patent/JP2007505212A/en not_active Ceased
- 2004-05-14 CN CNB2004800170079A patent/CN100439535C/en not_active Expired - Fee Related
- 2004-05-14 DE DE502004011588T patent/DE502004011588D1/en not_active Expired - Lifetime
- 2004-05-14 EP EP04732930A patent/EP1664363B1/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO2005026400A1 * |
Also Published As
Publication number | Publication date |
---|---|
US20070042222A1 (en) | 2007-02-22 |
DE502004011588D1 (en) | 2010-10-07 |
WO2005026400A1 (en) | 2005-03-24 |
JP2007505212A (en) | 2007-03-08 |
CN1820089A (en) | 2006-08-16 |
EP1664363B1 (en) | 2010-08-25 |
PL1664363T3 (en) | 2011-02-28 |
US7544410B2 (en) | 2009-06-09 |
CN100439535C (en) | 2008-12-03 |
DE10342364A1 (en) | 2005-04-14 |
ATE478969T1 (en) | 2010-09-15 |
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