EP1654154A1 - Verfahren zum transport von gummihalbzeug - Google Patents
Verfahren zum transport von gummihalbzeugInfo
- Publication number
- EP1654154A1 EP1654154A1 EP04743559A EP04743559A EP1654154A1 EP 1654154 A1 EP1654154 A1 EP 1654154A1 EP 04743559 A EP04743559 A EP 04743559A EP 04743559 A EP04743559 A EP 04743559A EP 1654154 A1 EP1654154 A1 EP 1654154A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- semi
- rubber
- processed rubber
- heat
- processed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 108
- 239000005060 rubber Substances 0.000 title claims abstract description 108
- 238000000034 method Methods 0.000 title claims abstract description 39
- 238000002425 crystallisation Methods 0.000 claims abstract description 9
- 239000011810 insulating material Substances 0.000 claims abstract description 7
- 238000007711 solidification Methods 0.000 claims abstract description 4
- 230000008023 solidification Effects 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims description 12
- 244000043261 Hevea brasiliensis Species 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 6
- 229920000126 latex Polymers 0.000 claims description 5
- 239000004816 latex Substances 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- 238000010079 rubber tapping Methods 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 description 4
- 229920001194 natural rubber Polymers 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 3
- 239000002918 waste heat Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 238000007781 pre-processing Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229920003008 liquid latex Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B25/00—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby
- B63B25/02—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods
- B63B25/04—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods solid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B25/00—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby
- B63B25/02—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods
- B63B25/08—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63J—AUXILIARIES ON VESSELS
- B63J2/00—Arrangements of ventilation, heating, cooling, or air-conditioning
- B63J2/12—Heating; Cooling
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C3/00—Treatment of coagulated rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63J—AUXILIARIES ON VESSELS
- B63J2/00—Arrangements of ventilation, heating, cooling, or air-conditioning
- B63J2/02—Ventilation; Air-conditioning
- B63J2/08—Ventilation; Air-conditioning of holds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63J—AUXILIARIES ON VESSELS
- B63J2/00—Arrangements of ventilation, heating, cooling, or air-conditioning
- B63J2/12—Heating; Cooling
- B63J2002/125—Heating; Cooling making use of waste energy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63J—AUXILIARIES ON VESSELS
- B63J3/00—Driving of auxiliaries
- B63J3/02—Driving of auxiliaries from propulsion power plant
Definitions
- This invention relates to transporting goods, for example rubber, particularly, but not exclusively to transporting goods which can alter their state during transportation to become unusable or such that they require processing after transportation to make the goods usable.
- Rubber is produced by tapping the latex of the tree Hevea brasiliensis.
- the latex flows into a collection cup from the tapped tree from where it is passed to a pan where it coagulates to form a cake.
- Water is rolled or pressed from the cake to provide a dewatered cake of fresh rubber which has the consistency of plasticene (RTM).
- the cake which may be called semi-processed rubber, is then transported to the end users for further processing such as cleaning and drying in an oven. Further processes may be used to provide rubber having the technical characteristics necessary for, say, vehicle tyre production and to thereby form the rubber into the end product.
- each major rubber producing country has its own schemes for further differentiating or subdividing the rubbers of the TSR scheme produced therein (SIR - Standard Indonesian Rubber; SMR - Standard Malaysian Rubber; STR - Standard Thai Rubber; SVR - Standard Vietnamese Rubber).
- the TSR scheme requires that the rubber is transported in standardised packaging of 33.3 or 35 kg bales (ca. 330 x 670 x 170 mm) wrapped in polyethylene, with thirty six bales on a crated or shrink-wrapped on a standard pallet to give a crate size of 1260 kg.
- RSS rubber consists of deliberately coagulated rubber sheets, completely dried using smoke. In ADS rubber the sheets are dried in the air. The sheets are then graded into three main grades according to their color, consistency and observed impurities. The purest is 1 RSS S/B, then 2RSS S/B then 3RSS S/B. RSS is transported in standard TSR pack (designated S/B for small bales) consisting of a compressed bale of 33.3 or 35 kg or in conventional big bale of 111.11kg. A crate size is about 1200 or 1260 Kilos. RSS are used when extra tough (due to extensive cross linking) rubber is needed. Some applications are tires, tank liners, industrial products, etc. RSS is generally more difficult to process than TSR.
- Pale crepe consists of carefully collected fresh liquid latex, deliberately coagulated and (sometimes) bleached, milled to produce crepe of a thickness corresponding approximately to standardized thickness, either thin or thick.
- 1X Thick Pale Crepe (1XTPC) while the most popular is 1 Thick Pale Crepe (1TPC).
- 2 Thick Pale Crepe is also available.
- Pale Crepe is usually sold in 25 kg bales with 32 bales packed onto a crated pallet of 800kgs, suitable for Ocean Container shipping. Pale Crepe is used in FDA applications, medical sundries, footwear, cements and adhesives, and any application that requires light color, sweet smell and good properties.
- the rubber cakes cool and harden and crystallisation within the rubber can, and does, occur.
- the rubber is unusable in that state. This process of crystallisation continues or is compounded when the rubber is stored at the destination port in a cold warehouse or factory, before being delivered to the end-user.
- Rubber is a known insulator and, therefore, has a low thermal conductivity, i.e. it losses and gains heat very slowly. In order to alter the rubber back to its usable state, it is necessary to slowly heat the rubber to about 70 to 180 °C over a period of about three days to three weeks depending on the type of rubber. The heating causes the rubber to soften and for the crystals to dissolve.
- a first aspect of the invention provides a method of transporting semi-processed rubber, the method comprising locating the semi-processed rubber in a ship and supplying heat to the semi-processed rubber during transit to prevent solidification of, and/or crystallisation in, the semi-processed rubber.
- sufficient heat is supplied to the semi-processed rubber so that it is held at a temperature above 25 °C, most preferably in a range of from 28 to 35 °C, and even more preferably in a range of from 30 to 33 °C.
- the desired temperature is 32 °C, although variations within the above-identified ranges are acceptable.
- the heat for heating the semi-processed rubber may come from heat recirculated from the ship engine.
- the heat may be provided by a heating blanket placed over, under, around or otherwise adjacent the semi-processed rubber.
- a container, in which the semi-processed rubber is located in the ship, may be a heated container. Heat may be directed from the engine room using the water which is drawn through the engine to cool it. That water may be directed through the ship to where it may flow through pipes or panels to heat the semi-processed rubber. Other waste heat may also be utilised.
- Heat may be directed to a heat exchanger to heat circulating air, the heated air then being circulated into the hold of the ship where the rubber is stored for transport.
- convection heaters for example electrical convection heaters, may be used.
- the method may further comprise storing the semi-processed rubber in a covered warehouse or storage facility at a destination port, the warehouse preferably being maintained at a temperature sufficient to prevent the rubber from solidifying and/or crystallising during storage.
- the method may further comprise transporting the semi-processed rubber to an end user in a state which is usable without requiring further heating.
- a second aspect of the invention provides a method of supplying semi- processed rubber to an end-user in a usable form, the method comprising tapping latex from a rubber tree, forming a cake, transporting the cake to a local processor for semi- processing and subsequently transporting the semi-processed rubber cake to an end user and ensuring that the cake does not harden or that crystals form in the cake during the first and/or second transportation step.
- a third aspect of the invention provides a method of transporting solid goods whose state is prone to alter during transportation, the method comprising maintaining the goods at a temperature of from 25 to 35 °C during transportation by supplying heated air to the goods using heat reclaimed from the prime mover of the means of transportation.
- the goods are semi-processed rubber.
- At least part of said transportation takes place on a ship and said transportation means is a ship.
- a further aspect of the invention provides a method of supplying semi- processed rubber to a user, the method comprising storing the semi-processed rubber in a location which is maintained at a temperature to prevent or at least inhibit the hardening of, or formation of crystals in, the semi-processed rubber.
- a yet further aspect of the invention provides an inflatable bag or bladder sized and dimensioned to be located adjacent the wall of a hold of a ship to insulate said wall.
- the bag or bladder will have a thickness, when inflated of from 5 to 50 cm.
- a plurality of bags may be used to cover the walls of the hold of a ship.
- semi-processed rubber, rubber cakes/bales and the like it will be understood that what is meant is any form of semi- processed rubber which is liable to change its state (e.g. to harden or crystals to form therein) when transported.
- Figure 1 is a perspective view of a part of a hold of a ship; and Figure 2 is a section along line X-X of Figure 1.
- a wall 1 of a ship which defines at least part of a hold 2.
- a plurality of stacked crates 3 each containing rubber.
- a heat exchanger 4 Located at the centre of the stack of crates 3 is a heat exchanger 4.
- an insulating material 5 is located adjacent each wall 1 of the hold 2.
- the insulating material 5 is an inflatable bladder or bag 6 which is filled with a fluid which is usually a gas and is typically air.
- the walls of the bladder or bag 6 will typically be made from a polymer or other material which has a low thermal conductivity.
- the bladder or bag 6 may be inflated using pumps or using the fan or blower associated with the heat exchanger 4.
- the bladder or bag 6 may extend over the whole of the hold 2 or there may be several bladders 6 which cover a section of the hold 2.
- insulating materials 5 may be used such as curtains or drapes and the like, the main characteristic being that the insulating material is removable or collapsible once the goods have been, or before the goods are, removed from the ship's hold 2.
- Hot water from the ship's engine, boiler or engine room (not shown) is pumped to the heat exchanger 4 where it heats air.
- the heated air is then distributed about the hold 2 using the blower or fan (not shown) which is operatively associated with the heat exchanger 4.
- the fan or blower draws air into the heat exchanger 4, as indicated by arrows A, and blows the heated air into the hold 2, as indicated by arrows B. In this way the ambient temperature in the hold 2 is maintained at a temperature which will prevent crystallization in the rubber contained in the crates 3, say above 25°C.
- the position of the heat exchanger 4 is not limited to the centre of the hold 2, as shown. Indeed, it may be easier to place the heat exchanger 4 at the side of the hold 2 which would decrease the complexity of piping the hot or heated water to the heat exchanger 4 and piping the cold or cooled water from the heat exchanger 4. In principle, the heat exchanger 4 will be more efficiently employed if it is at the side of the hold 2 at the closest position to the engine room or other source of heat exchange medium.
- the rubber located within the crates 3, will be loaded into the hold 2 in a conventional manner.
- the inflatable bladder or bag 6 will be inflated and the heat exchanger 4 will commence operation.
- the combination of the heat exchanger 4 and the insulating effect provided by the bladder or bag 6 will prevent the rubber within the crates 3 from experiencing ambient temperatures less than 25 °C, and thereby will prevent crystallization or hardening of the rubber.
- the heat exchanger 4 may be replaced with convection heaters or blowers, for example electrical convection heaters or blowers.
- the water from the engine room or other heat exchange medium may be pumped through or around the crates (for example, above, below and/or between), the pipes or conduits acting as radiators to maintain the temperature of the rubber.
- any suitable means may be used.
- a particularly advantageous method requires capturing waste heat from the engine of a ship and redirecting that heat to heat the rubber.
- the cooling water used to cool the engines is pumped to the hold 2 to act as the heat exchange medium in the heat exchanger 4 to heat the rubber or at least the container in which the rubber is located. Waste heat from the engine exhausts may alternatively or additionally be used.
- Rubber was tapped from a tree and two cakes were formed, as is well known to the skilled addressee.
- the first cake/bale was packed and placed in a shipping container and left for a period of one month at a temperature similar to those found in the holds of ships.
- the second cake/bale was placed in an identical container and had a heating blanket placed under and over it.
- the heating blanket was arranged to keep the rubber at about 32 °C.
- the heat was supplied for from 14 days to 50 days, to simulate corresponding journeys.
- the warehouse was maintained at an ambient temperature of 24 °C.
- the rubber cake/bale was examined. The cake was still in a usable condition. Whilst we do not wish to be limited to any particular theory, it is postulated that due to rubber's low thermal conductivity the rubber retains its heat and therefore does not harden even when left at a lower temperature for a week.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ocean & Marine Engineering (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Packages (AREA)
- Wrappers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0318326.6A GB0318326D0 (en) | 2003-08-05 | 2003-08-05 | Transporting |
PCT/GB2004/003230 WO2005016744A1 (en) | 2003-08-05 | 2004-07-26 | Method for transporting semi-processed rubber |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1654154A1 true EP1654154A1 (de) | 2006-05-10 |
Family
ID=27839668
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04743559A Withdrawn EP1654154A1 (de) | 2003-08-05 | 2004-07-26 | Verfahren zum transport von gummihalbzeug |
Country Status (5)
Country | Link |
---|---|
US (1) | US20060171792A1 (de) |
EP (1) | EP1654154A1 (de) |
JP (1) | JP2007501156A (de) |
GB (2) | GB0318326D0 (de) |
WO (1) | WO2005016744A1 (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2522571A1 (de) * | 2011-05-12 | 2012-11-14 | Mika Jurvanen | Anordnung zur Rückgewinnung der von einem Schiffsmotor produzierten Abwärme |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1109556B (de) * | 1953-01-27 | 1961-06-22 | Casinghini Economizzatori Gree | Heizrohranlage zum Erwaermen von Erdoel, Rohoel u. dgl. in den Tanks der Schiffe |
GB1484252A (en) * | 1973-10-22 | 1977-09-01 | Rubber Res Inst Of Malaysia | Treatment of rubber |
SU623778A1 (ru) * | 1976-12-28 | 1978-09-15 | Предприятие П/Я Г-4488 | Способ уменьшени потерь натурального каучука при транспортировании его в кипах на судах |
JPS63215493A (ja) * | 1987-03-03 | 1988-09-07 | Ishikawajima Harima Heavy Ind Co Ltd | 船舶の推進装置 |
BG48388A1 (en) * | 1989-05-09 | 1991-02-15 | Vissh Khim T I | Method for processing of rubber coagulate |
-
2003
- 2003-08-05 GB GBGB0318326.6A patent/GB0318326D0/en not_active Ceased
-
2004
- 2004-07-26 WO PCT/GB2004/003230 patent/WO2005016744A1/en not_active Application Discontinuation
- 2004-07-26 JP JP2006522388A patent/JP2007501156A/ja active Pending
- 2004-07-26 EP EP04743559A patent/EP1654154A1/de not_active Withdrawn
- 2004-07-26 US US10/566,416 patent/US20060171792A1/en not_active Abandoned
- 2004-07-26 GB GB0600628A patent/GB2419399A/en not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
See references of WO2005016744A1 * |
Also Published As
Publication number | Publication date |
---|---|
GB0318326D0 (en) | 2003-09-10 |
US20060171792A1 (en) | 2006-08-03 |
GB2419399A (en) | 2006-04-26 |
JP2007501156A (ja) | 2007-01-25 |
WO2005016744A1 (en) | 2005-02-24 |
GB0600628D0 (en) | 2006-02-22 |
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Legal Events
Date | Code | Title | Description |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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17P | Request for examination filed |
Effective date: 20060302 |
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AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR |
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DAX | Request for extension of the european patent (deleted) | ||
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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18D | Application deemed to be withdrawn |
Effective date: 20080201 |