EP1409775A1 - Vorrichtung zur herstellung von fasern in einem elektrostatischen spinnverfahren - Google Patents
Vorrichtung zur herstellung von fasern in einem elektrostatischen spinnverfahrenInfo
- Publication number
- EP1409775A1 EP1409775A1 EP02754394A EP02754394A EP1409775A1 EP 1409775 A1 EP1409775 A1 EP 1409775A1 EP 02754394 A EP02754394 A EP 02754394A EP 02754394 A EP02754394 A EP 02754394A EP 1409775 A1 EP1409775 A1 EP 1409775A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- spray
- electrode
- electrodes
- plates
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 17
- 238000010041 electrostatic spinning Methods 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 229920000642 polymer Polymers 0.000 claims abstract description 74
- 238000003860 storage Methods 0.000 claims abstract description 15
- 239000007921 spray Substances 0.000 claims description 124
- 238000005507 spraying Methods 0.000 claims description 16
- 239000002904 solvent Substances 0.000 claims description 10
- 238000009987 spinning Methods 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000012876 carrier material Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 4
- 230000005686 electrostatic field Effects 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000002184 metal Substances 0.000 abstract description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000003570 air Substances 0.000 description 6
- -1 polyoxymethylene Polymers 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920001410 Microfiber Polymers 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003658 microfiber Substances 0.000 description 2
- 239000002121 nanofiber Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Chemical class 0.000 description 1
- 239000004695 Polyether sulfone Chemical class 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Chemical class 0.000 description 1
- 229920002647 polyamide Chemical class 0.000 description 1
- 229920006260 polyaryletherketone Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006393 polyether sulfone Chemical class 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920002635 polyurethane Chemical class 0.000 description 1
- 239000004814 polyurethane Chemical class 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920001289 polyvinyl ether Chemical class 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0069—Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
Definitions
- Such devices are basically known from the prior art.
- a polymer in the form of a polymer melt or in the form of a solution is introduced into an electric field and spun into fibers by the action of the electric field.
- An electrode usually forms a receiving device for the spun fibers, while the counter electrode is designed as a spraying electrode or spray nozzle.
- Spray electrodes or several spray plates arranged side by side, in particular triangular, trapezoidal, square or rounded Are shape. It is preferred here if the spray electrodes or spray plates are arranged next to one another at a distance in the range from 2 to 10 cm. On the one hand, the peak effect is most pronounced and, on the other hand, the nano and / or microfibers produced by the electrostatic spinning process can be deposited into a particularly regular nonwoven with spray electrodes or spray plates. The same applies, of course, in the aforementioned embodiment with a jagged or corrugated design of the spray electrode or the spray plate. The tips of the spikes or the apexes of the waves are spaced from each other in the range of 2 to 10 cm.
- Spray electrodes or spray plates is promoted.
- the surface of the polymer solution or the polymer melt exposed to the environment is kept as small as possible, so that, for example, unnecessary solvent losses are avoided.
- the heat loss is kept low, which advantageously contributes to energy savings when operating the device according to the invention.
- the device according to the invention is closed or encapsulated with a lid such that only the at least one spraying electrode or the at least one spraying plate protrudes from the device. This advantageously further reduces the evaporation of solvents or cooling of the melt.
- the conveying device is formed by one or more lines or line systems for conveying the polymer solution or the polymer melt from the at least one storage vessel to the at least one spray electrode or the at least one spray plate.
- the one or more lines or line systems for conveying the polymer solution or the polymer melt from the at least one storage vessel to the at least one spray electrode or the at least one spray plate.
- the feed device is then actuated either in a predetermined time interval or controlled by an operator and the used spray electrode or the used spray element is released from the device according to the invention and a new spray electrode or a new spray plate is brought into an operating position for electrostatic spinning of a polymer.
- the particular advantage of this embodiment is that additional handling of solvents and a corresponding cleaning of the spray electrodes or spray plates can be omitted, as a result of which a higher level of operational safety is achieved, because the effort to completely clean the spray plates or
- Spray electrodes is comparatively large if the quality of the product, i.e. the fibers or nonwovens produced should be ensured.
- the counter electrode is preferably formed by a rigid sheet, an electrically conductive, circumferential band or a fleece. It is particularly preferred if the counter electrode is formed by an electrically conductive, circumferential band made of wire mesh or metal foil, this band moving in particular with a carrier material on which the fibers produced by the electrostatic spinning are placed. This avoids the application of tensile forces on the carrier material. It is most preferred if the counter electrode is formed from electrospun fibers of opposite polarity. This carrier material is then simultaneously coated on the top and bottom by two spray devices with fibers of opposite polarity. This creates a much more effective filter material, since a higher charge density can be achieved and both the positive and negative charges are firmly fixed in the fibers.
- water-soluble polymers e.g. Polyvinyl alcohol, polyvinyl pyrrolidine, polyethylene oxide and its copolymers, cellulose and its derivatives, starch and mixtures of these polymers.
- Polymers which are soluble in organic solvents can also be spun in the device according to the invention.
- Polystyrene, polycarbonate, polyvinyl chloride, polyacrylate, polymethacrylate, polyvinyl acetate, polyvinyl acetal, polyvinyl ether, polyurethane, polyamide, polysulfone, polyether sulfone, polyacrylonitrile, cellulose derivatives and mixtures of these polymers are particularly worth mentioning here.
- Polymers spinnable from the melt are e.g. Thermoplastics such as polyolefins, polyester, polyoxymethylene, polychlorotrifluoroethylene,
- Figure 2 is a schematic plan view of a conveyor roller with adjacent spray electrodes or spray plates;
- FIG. 3 is a schematic representation of an embodiment in which the
- Spray electrodes or spray plates are arranged on a transport device
- FIG. 4 shows a second embodiment of the present invention, in which the spray electrodes or spray plates are arranged on a transport wheel and pass through a cleaning bath;
- FIG. 1 shows a first embodiment of the device according to the invention for the electrostatic spinning of polymers.
- a conveyor device 1 formed by a conveyor roller is arranged in a storage container for the polymer solution or the polymer melt 2, the conveyor roller 1 conveying polymer solution or polymer melt from the storage vessel and transferring it to the adjacent spraying electrode 3, generally also referred to as a spraying plate.
- a high-voltage generator 4 generates the potential difference required between the spray electrode 3 and the counter electrode 5, so that the polymer contained in the storage vessel 2 is spun into fibers 6 in the electrostatic field.
- a 5% polystyrene solution in dichloromethane is mixed with 0.5 rhodamine G6 and spun at 50 revolutions of the conveyor roller (diameter 7 cm) per minute.
- the spray plates are directly opposite each other at a distance of 20 cm, the carrier fleece (micro-spunbond polypropylene fleece with 60 g / m 2 ) is in the middle at a speed of 0.5 m / min. passed.
- a high voltage of + or - 15 kV is applied to the spray plates.
- the carrier fleece coated in this way has a deposition rate of 50% of the 0.3-0.5 ⁇ m fraction of NaCl. Measured at a flow rate of 50 l / min. and a flow area of 100 cm 2 .
- the air resistance of the carrier fleece was increased under these conditions by the coating from 8 to 16 Pa.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10136256A DE10136256B4 (de) | 2001-07-25 | 2001-07-25 | Vorrichtung zur Herstellung von Fasern in einem elektrostatischen Spinnverfahren |
DE10136256 | 2001-07-25 | ||
PCT/DE2002/002654 WO2003016601A1 (de) | 2001-07-25 | 2002-07-19 | Vorrichtung zur herstellung von fasern in einem elektrostatischen spinnverfahren |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1409775A1 true EP1409775A1 (de) | 2004-04-21 |
EP1409775B1 EP1409775B1 (de) | 2004-12-22 |
Family
ID=7693064
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02754394A Expired - Lifetime EP1409775B1 (de) | 2001-07-25 | 2002-07-19 | Vorrichtung zur herstellung von fasern in einem elektrostatischen spinnverfahren |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1409775B1 (de) |
DE (2) | DE10136256B4 (de) |
WO (1) | WO2003016601A1 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102137962B (zh) * | 2008-06-24 | 2013-05-22 | 斯泰伦博斯大学 | 用于制造精细纤维的方法及装置 |
US8727756B2 (en) | 2012-01-19 | 2014-05-20 | Contipro Biotech S.R.O. | Combined spinning nozzle for the manufacture of nanofibrous and microfibrous materials |
JP2015081391A (ja) * | 2013-10-22 | 2015-04-27 | 積水化学工業株式会社 | 電界紡糸装置 |
US9718012B2 (en) | 2000-09-05 | 2017-08-01 | Donaldson Company, Inc. | Fine fiber media layer |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10310435B3 (de) * | 2003-02-05 | 2004-06-03 | Helsa-Werke Helmut Sandler Gmbh & Co. Kg | Filterelement und Verfahren zu seiner Herstellung |
CZ294274B6 (cs) | 2003-09-08 | 2004-11-10 | Technická univerzita v Liberci | Způsob výroby nanovláken z polymerního roztoku elektrostatickým zvlákňováním a zařízení k provádění způsobu |
CZ299537B6 (cs) * | 2005-06-07 | 2008-08-27 | Elmarco, S. R. O. | Zpusob a zarízení k výrobe nanovláken z polymerního roztoku elektrostatickým zvláknováním |
DE102007027014A1 (de) | 2007-06-08 | 2008-12-18 | Rainer Busch | Vorrichtung zur Herstellung von Nano- und Microfasern durch elektrostatisches Spinnen einer durch Zentrifugalkräften in radialer Richtung aufgeschichteten Polymerlösung |
CZ300345B6 (cs) * | 2007-07-17 | 2009-04-22 | Elmarco, S. R. O. | Zpusob zvláknování kapalné matrice, zarízení pro výrobu nanovláken elektrostatickým zvláknováním kapalné matrice a zvláknovací elektroda pro takové zarízení |
DE102007055409A1 (de) | 2007-11-19 | 2009-05-20 | Helsa-Automotive Gmbh & Co. Kg | Verfahren zur Herstellung von Polyetherimid-Fasern durch Verspinnen von Polyetherimid im elektrischen Feld |
MY153492A (en) | 2007-11-20 | 2015-02-13 | Clarcor Inc | Filtration medias, fine fibers under 100 nanometers, and methods |
US7815427B2 (en) | 2007-11-20 | 2010-10-19 | Clarcor, Inc. | Apparatus and method for reducing solvent loss for electro-spinning of fine fibers |
US7967588B2 (en) | 2007-11-20 | 2011-06-28 | Clarcor Inc. | Fine fiber electro-spinning equipment, filter media systems and methods |
GB2462112B (en) * | 2008-07-24 | 2012-11-07 | Stfc Science & Technology | An apparatus and method for producing fibres |
JP2012520761A (ja) | 2009-03-19 | 2012-09-10 | イー・エム・デイー・ミリポア・コーポレイシヨン | ナノ繊維濾過媒体を用いる、流体資料からの微生物の除去 |
CZ302876B6 (cs) * | 2009-07-01 | 2011-12-28 | Technická univerzita v Liberci | Zpusob a zarízení k výrobe nanovláken preplavovacím elektrostatickým zvláknováním |
CZ308360B6 (cs) * | 2009-08-06 | 2020-06-24 | Elmarco S.R.O. | Rotační zvlákňovací elektroda |
US20110210060A1 (en) | 2010-02-26 | 2011-09-01 | Clarcor Inc. | Expanded composite filter media including nanofiber matrix and method |
CN102312296B (zh) * | 2010-06-30 | 2013-10-30 | 财团法人纺织产业综合研究所 | 滚筒式电纺设备 |
TWI406982B (zh) | 2010-06-30 | 2013-09-01 | Taiwan Textile Res Inst | 滾筒式電紡設備 |
US9623352B2 (en) | 2010-08-10 | 2017-04-18 | Emd Millipore Corporation | Method for retrovirus removal |
CN101985793B (zh) * | 2010-11-22 | 2012-07-25 | 北京化工大学 | 静电纺丝法连续制备无纺布制品的装置 |
CN103459006B (zh) | 2011-04-01 | 2016-01-06 | Emd密理博公司 | 含有纳米纤维的复合材料结构 |
CZ2011273A3 (cs) * | 2011-05-09 | 2012-07-18 | Výzkumný ústav potravinárský Praha, v.v.i. | Zpusob a zarízení pro beztryskovou odstredivou výrobu nanovláken a mikrovláken na povrchu rotujících válcu |
CZ303298B6 (cs) * | 2011-05-18 | 2012-07-18 | Výzkumný ústav potravinárský Praha, v.v.i. | Zpusob a zarízení pro beztryskovou odstredivou výrobu nanovláken a mikrovláken s použitím rotujících válcu s profilovaným povrchem |
CN102925996A (zh) * | 2012-04-10 | 2013-02-13 | 南京理工大学 | 采用特殊滚筒的静电成形方法 |
CN102704192A (zh) * | 2012-06-25 | 2012-10-03 | 天津工业大学 | 一种多辊实心针电极纳米纤维非织造布生产装置 |
CN102704193A (zh) * | 2012-06-25 | 2012-10-03 | 威程(天津)科技有限公司 | 一种多实心针电极纳米纤维非织造布生产装置 |
CN103065543B (zh) * | 2013-01-20 | 2014-09-10 | 青岛大学 | 一种便携式熔体静电纺丝教学演示装置 |
DE102014004631A1 (de) | 2013-05-17 | 2014-11-20 | Mann + Hummel Gmbh | Vorrichtung und Verfahren zum elektrostatischen Verspinnen von Polymerlösungen und Filtermedium |
CN106457079A (zh) | 2014-06-26 | 2017-02-22 | Emd密理博公司 | 具有增强的污垢容纳能力的过滤器结构 |
CN107530639B (zh) | 2015-04-17 | 2021-02-09 | Emd密理博公司 | 使用以切向流过滤模式操作的纳米纤维超滤膜纯化样品中目标生物材料的方法 |
CN104894661A (zh) * | 2015-07-06 | 2015-09-09 | 苏州大学 | 一种静电纺丝装置 |
CN105401233B (zh) * | 2015-11-11 | 2017-09-26 | 佛山轻子精密测控技术有限公司 | 一种尖齿笼状电极静电纺丝装置 |
DE102018103682A1 (de) | 2018-02-19 | 2019-08-22 | Twe Gmbh & Co. Kg | Filtermedium |
CA3116905A1 (en) * | 2018-11-01 | 2020-05-07 | Emd Millipore Corporation | Efficient production of nanofiber structures |
WO2021014413A1 (en) * | 2019-07-24 | 2021-01-28 | Nanoshields Technology Limited | Device and method for applying nanofibers and/or microfibers onto a substrate, and system comprising the devices |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3994258A (en) * | 1973-06-01 | 1976-11-30 | Bayer Aktiengesellschaft | Apparatus for the production of filters by electrostatic fiber spinning |
GB1527592A (en) * | 1974-08-05 | 1978-10-04 | Ici Ltd | Wound dressing |
DE2960875D1 (en) * | 1978-04-19 | 1981-12-10 | Ici Plc | A method of preparing a tubular product by electrostatic spinning |
IL132945A0 (en) * | 1999-06-07 | 2001-03-19 | Nicast Ltd | Filtering material and device and method of its manufacture |
-
2001
- 2001-07-25 DE DE10136256A patent/DE10136256B4/de not_active Expired - Fee Related
-
2002
- 2002-07-19 DE DE50201852T patent/DE50201852D1/de not_active Expired - Lifetime
- 2002-07-19 EP EP02754394A patent/EP1409775B1/de not_active Expired - Lifetime
- 2002-07-19 WO PCT/DE2002/002654 patent/WO2003016601A1/de not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO03016601A1 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9718012B2 (en) | 2000-09-05 | 2017-08-01 | Donaldson Company, Inc. | Fine fiber media layer |
US10272374B2 (en) | 2000-09-05 | 2019-04-30 | Donaldson Company, Inc. | Fine fiber media layer |
US10967315B2 (en) | 2000-09-05 | 2021-04-06 | Donaldson Company, Inc. | Fine fiber media layer |
CN102137962B (zh) * | 2008-06-24 | 2013-05-22 | 斯泰伦博斯大学 | 用于制造精细纤维的方法及装置 |
US8727756B2 (en) | 2012-01-19 | 2014-05-20 | Contipro Biotech S.R.O. | Combined spinning nozzle for the manufacture of nanofibrous and microfibrous materials |
JP2015081391A (ja) * | 2013-10-22 | 2015-04-27 | 積水化学工業株式会社 | 電界紡糸装置 |
Also Published As
Publication number | Publication date |
---|---|
WO2003016601A1 (de) | 2003-02-27 |
DE10136256B4 (de) | 2005-03-31 |
DE10136256A1 (de) | 2003-04-24 |
EP1409775B1 (de) | 2004-12-22 |
DE50201852D1 (de) | 2005-01-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1409775B1 (de) | Vorrichtung zur herstellung von fasern in einem elektrostatischen spinnverfahren | |
DE10136255B4 (de) | Vorrichtung zum Herstellen von Fasern mit verbesserter Anordnung der Absprühelektroden | |
DE2620399C3 (de) | Vorrichtung zum elektrostatischen Versprühen | |
DE69919139T2 (de) | Vorrichtung und Verfahren zur Herstellung eines Filtermaterials | |
DE3788821T2 (de) | Verfahren und Vorrichtung zur Herstellung einer nicht gewebten Faserfolie. | |
DE2511195C3 (de) | Verfahren zum Filtrieren und Filter zur Durchführung des Verfahrens | |
EP2512690B1 (de) | Verfahren und vorrichtung zum elektrostatischen abscheiden von overspray | |
DE102007036553A1 (de) | Vorrichtung zum Abscheiden von Lack-Overspray | |
DE2844163B2 (de) | Verfahren zur Beseitigung der Oberflächenklebrigkeit von aus einer Spinnlösung aus Cellulose in einem Gemisch aus Aminoxyd und Wasser extrudierten Fäden | |
DE10341980A1 (de) | Vorrichtung zum Abtrennen von Lack-Overspray | |
EP0601278B1 (de) | Spinnrotor | |
EP2156901A2 (de) | Herstellungssystem für ein netz- oder gitterartiges Flächenerzeugnis | |
DE4209606A1 (de) | Verfahren und Vorrichtung zum Behandeln mindestens einer Bahn von Fäden aufweisenden Filtermaterial für Zigarettenfilter | |
DE69822127T2 (de) | Verbesserungen zum Herstellen van Vliesstoffen mit einem elektrostatischen geladenen Transportband | |
DE3523998C2 (de) | ||
DE3147808A1 (de) | Vorrichtung zur spritzbehandlung, insbesondere zur spritzlackierung von gegenstaenden | |
DE4425655A1 (de) | Vorrichtung zur elektrostatischen Sprühbeschichtung von Werkstücken | |
DE102004044399A1 (de) | Schmiermittelsäuberungsvorrichtung fürs Trockendrahtziehen | |
DE2852948A1 (de) | Vorrichtung fuer die aufbringung einer zwischenfaserbindemittelfluessigkeit | |
DE4402857A1 (de) | Verfahren zum Herstellen eines Mikrofaser-Vliesstoffs, Mikrofaser-Vliesstoff und dessen Verwendung | |
EP0291443A1 (de) | Verfahren und Vorrichtung zum Auftragen eines flüssigen Behandlungsmittels auf Stahlrohre | |
DE2032072C3 (de) | Elektrostatisches Spinnverfahren zur Herstellung von Filtermaterial | |
DE1242566B (de) | Drehfilter mit fortlaufend erneuerter Filterhilfsschicht | |
DE2615180B2 (de) | Verfahren zum Reinigen von Abgasen und Vorrichtung zur Durchführung des Verfahrens | |
DE4430749A1 (de) | Pulverbeschichtungsanlage, sowie Verfahren zur Rückgewinnung nicht verbrauchten Pulvermaterials |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20031205 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL LT LV MK RO SI |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
17Q | First examination report despatched |
Effective date: 20040406 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): DE FR |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: HELSA-AUTOMOTIVE GMBH & CO. KG |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): DE FR |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: GERMAN |
|
REF | Corresponds to: |
Ref document number: 50201852 Country of ref document: DE Date of ref document: 20050127 Kind code of ref document: P |
|
ET | Fr: translation filed | ||
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
PLAX | Notice of opposition and request to file observation + time limit sent |
Free format text: ORIGINAL CODE: EPIDOSNOBS2 |
|
26 | Opposition filed |
Opponent name: CARL FREUDENBERG KG Effective date: 20050913 |
|
PLAF | Information modified related to communication of a notice of opposition and request to file observations + time limit |
Free format text: ORIGINAL CODE: EPIDOSCOBS2 |
|
PLBB | Reply of patent proprietor to notice(s) of opposition received |
Free format text: ORIGINAL CODE: EPIDOSNOBS3 |
|
RAP2 | Party data changed (patent owner data changed or rights of a patent transferred) |
Owner name: MANN+HUMMEL INNENRAUMFILTER GMBH & CO. KG |
|
PLCK | Communication despatched that opposition was rejected |
Free format text: ORIGINAL CODE: EPIDOSNREJ1 |
|
PLBN | Opposition rejected |
Free format text: ORIGINAL CODE: 0009273 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: OPPOSITION REJECTED |
|
27O | Opposition rejected |
Effective date: 20080527 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 15 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 16 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20210727 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20210721 Year of fee payment: 20 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R071 Ref document number: 50201852 Country of ref document: DE |