EP1346242A1 - Dispositif a guide d'ondes optiques optiquement actif comportant un canal sur un substrat optique - Google Patents

Dispositif a guide d'ondes optiques optiquement actif comportant un canal sur un substrat optique

Info

Publication number
EP1346242A1
EP1346242A1 EP01990613A EP01990613A EP1346242A1 EP 1346242 A1 EP1346242 A1 EP 1346242A1 EP 01990613 A EP01990613 A EP 01990613A EP 01990613 A EP01990613 A EP 01990613A EP 1346242 A1 EP1346242 A1 EP 1346242A1
Authority
EP
European Patent Office
Prior art keywords
substrate
active layer
channel
active
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01990613A
Other languages
German (de)
English (en)
French (fr)
Inventor
Stéphane TISSERAND
Laurent Roux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ion Beam Services SA
Original Assignee
Ion Beam Services SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ion Beam Services SA filed Critical Ion Beam Services SA
Publication of EP1346242A1 publication Critical patent/EP1346242A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/011Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  in optical waveguides, not otherwise provided for in this subclass
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/10Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
    • G02B6/12Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
    • G02B6/122Basic optical elements, e.g. light-guiding paths
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/10Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
    • G02B6/12Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
    • G02B6/13Integrated optical circuits characterised by the manufacturing method
    • G02B6/134Integrated optical circuits characterised by the manufacturing method by substitution by dopant atoms
    • G02B6/1347Integrated optical circuits characterised by the manufacturing method by substitution by dopant atoms using ion implantation
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/10Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
    • G02B6/12Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
    • G02B2006/12035Materials
    • G02B2006/1208Rare earths
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/10Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
    • G02B6/12Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
    • G02B2006/12083Constructional arrangements
    • G02B2006/121Channel; buried or the like
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/10Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
    • G02B6/12Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
    • G02B2006/12133Functions
    • G02B2006/12142Modulator
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24Coupling light guides
    • G02B6/26Optical coupling means
    • G02B6/30Optical coupling means for use between fibre and thin-film device
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/011Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  in optical waveguides, not otherwise provided for in this subclass
    • G02F1/0113Glass-based, e.g. silica-based, optical waveguides
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/0147Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on thermo-optic effects
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/20Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/204Strongly index guided structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/20Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/22Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
    • H01S5/223Buried stripe structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/50Amplifier structures not provided for in groups H01S5/02 - H01S5/30

Definitions

  • the present invention relates to an optically active device comprising a channel on an optical substrate.
  • the field of the invention is that of integrated optics on a substrate, a field to which in particular the active devices which essentially provide an amplification, modulation or switching function of a light signal.
  • active devices include an active waveguide and a control element which modulates one of the characteristics of this signal conveyed by the waveguide, this characteristic generally being either the amplitude or the phase.
  • a guide comprises a core which is produced on the substrate, this core having a higher refractive index than that of the surrounding medium.
  • a first method uses the technology of thin layers.
  • the substrate is either silica or silicon on which a thermal oxide has been grown, so that its upper face, the optical substrate, is made of silicon dioxide.
  • a layer with an index higher than that of silicon dioxide is deposited on the optical substrate using any known technique such as flame hydrolysis deposition ("Flame Hydrolysis Deposition in English terminology) chemical vapor deposition high or low pressure and assisted or not by plasma, evaporation under vacuum, sputtering or deposition by centrifugation.
  • this layer is often silicon dioxide doped with a rare earth such as erbium (signal wavelength 1.55 microns) or neodymium (wavelength signal of 1, 3 microns). If on the other hand it is envisaged to produce a modulator or a switch, the layer is often made of a material having electro-optical properties which is in particular the case of certain polymers. This layer can also have thermo-optical properties, which is for example the case of silicon dioxide.
  • a mask defining the heart is then applied to the deposited layer by means of a photolithography technique.
  • the core is produced by a chemical etching or dry etching process such as plasma etching, reactive ion etching or ion beam etching.
  • the mask is removed after etching and, commonly, a covering layer is deposited on the substrate to bury the heart.
  • This covering layer the refractive index of which is lower than that of the core, is intended to limit the disturbances exerted by the surrounding environment, in particular those due to humidity.
  • the document GB 2 346 706 teaches a heart produced by means of two layers which are etched successively by means of a single mask. This heart therefore takes the form of two superimposed ribbons having the same dimensions in the plane of the substrate.
  • a second method described in document US 4,834,480 uses ion exchange technology.
  • the substrate is a glass having a high concentration of mobile ions (Na for example) at relatively low temperature.
  • the substrate is again provided with a mask and it is then immersed in a bath containing active ions (K for example).
  • the core is thus produced by increasing the refractive index following the exchange of the active ions of the bath with the mobile ions of the substrate.
  • the heart is buried by application of an electric field perpendicular to the face of the substrate.
  • This method is very simple. However, it requires the selection of a particular substrate which does not necessarily have all the desired characteristics.
  • a third method used for the production of passive components implements ion implantation technology.
  • the document “Channel waveguides formed in fused silica and silica on silicon by Si, P and Ge ion implantation - LEECH PW et al - IEEE Proceedings: Optoelectronics, Institution of Electrical Engineers, Stevenage GB - Volume 1 3 n ° 5, pages 281 to 286 ” teaches a device deposited on an optical substrate of silicon dioxide. A germanium doped layer is deposited on the substrate, then a mask is applied and the channel is produced by ion implantation of the deposited layer. This layer produces mechanical stresses which cause deformation of the substrate. The deformation, the greater the thicker the layer, is detrimental to the optical specifications of the waveguide and poses difficulties during the photolithography step.
  • the present invention thus relates to an optically active device having a suitable spatial resolution and a good surface condition.
  • this device comprises a core on an optical substrate and a control element, this core comprising a channel and at least one active layer arranged on the channel, the refractive index of this channel and that of the active layer being greater than that of the substrate; the optical substrate is practically free of mobile ions.
  • the geometric definition of the core only depends on that of the channel because the active layer is not etched.
  • the device comprises at least one covering layer disposed on the active layer, the index of this covering layer being lower than that of the active layer and that of the channel.
  • the channel is integrated into the substrate.
  • the channel projects from the substrate.
  • the index of the active layer is that of the substrate multiplied by a factor greater than 1.001.
  • the thickness of all of the active layers is between 1 and 20 microns.
  • the channel results from an ion implantation in the substrate.
  • the face of the substrate on which the ion implantation is carried out is made of silicon dioxide.
  • the active layer is for example made of silicon dioxide doped with a rare earth, or else in a material which has either electrooptic or thermo-optical properties, this depending on the function of the device.
  • the invention also relates to a method of manufacturing an active device on an optical substrate.
  • this method comprises the following steps: production of a mask on the optical substrate to define the pattern of a channel,
  • the method comprises the following steps:
  • the method comprises a step of annealing the substrate which follows the step of ion implantation.
  • This method is also adapted to the realization of the various characteristics of the device mentioned above.
  • FIG. 1 a sectional diagram of an active waveguide core
  • FIG. 2 the manufacture of the heart according to a first variant
  • FIG. 3 the manufacture of the heart according to a second variant
  • the substrate is made of silicon on which an insulation layer has been produced, either by growth of a thermal oxide, or by deposition of a layer of silicon dioxide SiO 2 or another material such as Si 3 N 4 , AI 2 O 3 , or SiON.
  • silicon dioxide SiO 2 or another material such as Si 3 N 4 , AI 2 O 3 , or SiON.
  • SiO 2 silicon dioxide
  • SiON another material
  • These are dielectric materials commonly used in both electronics and optics. opposition to glasses charged with mobile ions. However, it is impossible to guarantee that these materials have a zero concentration of mobile ions. We can only specify that this concentration is very low, less than 0.01% for example.
  • the substrate thus has an upper face or optical substrate 11, commonly made of silicon dioxide, with a thickness of 5 to 20 microns, for example.
  • the channel 12 produced by ion implantation is here integrated into the optical substrate which is itself covered with an active layer 13.
  • the refractive index of the channel is naturally higher than that of silicon dioxide.
  • the active layer 5 microns thick for example, is made of erbium-doped silicon dioxide and has a refractive index higher than that of the optical substrate, for example 0.3%. It can possibly result from a stack of thin layers.
  • a covering layer 14 which may also consist of a stack of thin layers is provided on the active layer 13. This covering layer, also 5 microns thick, has a lower index than that of the active layer and to that of the canal; in this case it is made of undoped silicon dioxide.
  • the substrate does not have an insulation layer so that it merges with the optical substrate.
  • It is, for example, a III-V type semiconductor compound, for example InP, GaAs, AIGaAs or InGaAsP.
  • the channel is implanted before the deposition of the active layer obtained with a doped material similar to that of the substrate.
  • the various materials commonly used in optics such as silica or lithium niobate can be suitable as an optical substrate.
  • the core formed by the association of the channel 12 and the active layer 13 can support one or more propagation modes whose properties are a function of the optical and geometric characteristics adopted.
  • the extended propagation mode GM extends widely in the active layer 13.
  • the width of the channel 7.5 microns for example, and the thickness of this active layer are chosen so that the GM propagation mode is as close as possible to that of optical fibers.
  • the effective guide mode index is lower than the refraction of the active layer and that of the channel; it is greater than the refractive index of the upper face 11 and that of the covering layer 14.
  • the core can also support a reduced propagation mode PM which extends much less in the active layer 13.
  • the channel index should then be relatively high, 1.90 for example.
  • the width of the channel can be significantly reduced.
  • the effective index of the guided mode is here higher than that of the active layer and lower than that of the channel.
  • the lateral confinement of the reduced PM mode is very important.
  • the technique of ion implantation was chosen because it makes it possible to precisely define a very thin channel, of the order of a few hundred nanometers.
  • the silicon dioxide optical substrate has a refractive index which exhibits little or no variation, it follows that very high accuracy can be obtained on the index of the channel. For example, for an implanted dose of titanium of 10 / cm respectively 10 17 / cm 2 , the precision on the refractive index reaches 10 ⁇ 4 respectively 10 "3. This precision is particularly important when looking for the extended propagation mode GM because the channel index is a parameter which very significantly affects the coupling to the optical fibers.
  • a first method of manufacturing the core comprises a first step which consists in carrying out a mask 16 on the optical substrate 15, this by means of a conventional photolithography process
  • the mask 16 is made of resin, metal or any other material capable of constituting an impassable barrier for ions during implantation.
  • the mask can be obtained by a direct writing process.
  • the channel 17 is produced by ion implantation of the masked substrate.
  • the implantation dose is between 10 16 / cm 2 and 10 18 / cm 2 and the energy is between a few tens and a few hundred KeV.
  • the mask is removed, for example by means of a chemical etching process.
  • the substrate is then annealed to reduce losses from propagation within the heart. Annealing notably makes it possible to eliminate the defects of the crystal structure and the absorbent colored centers, to stabilize the new chemical compounds and to restore the canal stoichiometry.
  • the temperature is between 400 and 500 ⁇ C
  • the atmosphere is controlled or it is open air, while the duration is of the order of a few tens of hours.
  • the active layer 18 is then deposited on the substrate 15 by means of any of the known techniques provided that this leads to a low loss material whose refractive index can be easily controlled .
  • the covering layer 19 is optionally deposited on the active layer 18.
  • this first method has the advantage of defining an active waveguide whose structure is perfectly planar since it does not include an etching step.
  • a second method of manufacturing the wave core comprises a first step which consists in implanting the entire optical substrate 20.
  • the dose and the implantation energy can be identical to the values mentioned in relation to the first method.
  • the next step is to make a mask 21 on the substrate 20.
  • This mask has the same pattern as that used during the first method but it must not undergo the implantation step.
  • the channel 25 is obtained by etching the optical substrate to a depth at least equal to the implantation depth. Any of the known etching techniques is suitable provided that this leads to acceptable geometrical characteristics of the channel, in particular the profile and the surface condition of its sides.
  • the mask is removed and then the substrate is here also subjected to annealing.
  • the active layer 22 and possibly the covering layer 23 are then deposited in accordance with the first method.
  • an amplifier comprises a first rectilinear channel 31 which, associated with the active layer, constitutes the heart of the active waveguide.
  • the control element here takes the form of a second curved channel 32 having a rectilinear coupling section 33 arranged in the immediate vicinity of the first channel 31 and parallel to the latter.
  • the second channel 32 is provided for convey an optical pumping signal. It is produced at the same time as the first channel by means of the mask which in fact defines the two channels.
  • a modulator consists of an so-called "Mach Zehnder" interferometer.
  • the mask now delimits a guide 34 which is subdivided into a first 35 and a second 36 channels, these two channels coming together to reform a single guide.
  • a section of the second channel 36 is surrounded by a pair of elongate electrodes 37 whose connections are not shown in the figure.
  • These electrodes are for example deposited by means of a thin film technology on the active layer.
  • This layer is here made of a material provided with electro-optical properties, that is to say a material whose refractive index is a function of an electric field which is applied to it.
  • the control element consists of the combination of the second channel 36 and the pair of electrodes 37.
  • a switch consists of a coupler having a first 38 and a second 39 parallel channels which approach in a coupling section to move away again. These two channels made with the same mask are coated with the active layer.
  • this layer is made of a material provided with thermooptical properties, ie a material whose refractive index is a function of temperature.
  • an electrode 40 is deposited on the active layer, an electrode whose function is the local heating of this layer.
  • the electrode 40 constitutes the control element.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Nonlinear Science (AREA)
  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Optical Integrated Circuits (AREA)
EP01990613A 2000-12-26 2001-12-21 Dispositif a guide d'ondes optiques optiquement actif comportant un canal sur un substrat optique Withdrawn EP1346242A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0017003A FR2818755B1 (fr) 2000-12-26 2000-12-26 Dispositif optiquement actif comportant un canal sur un substrat optique
FR0017003 2000-12-26
PCT/FR2001/004204 WO2002052312A1 (fr) 2000-12-26 2001-12-21 Dispositif a guide d'ondes optiques optiquement actif comportant un canal sur un substrat optique

Publications (1)

Publication Number Publication Date
EP1346242A1 true EP1346242A1 (fr) 2003-09-24

Family

ID=8858179

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01990613A Withdrawn EP1346242A1 (fr) 2000-12-26 2001-12-21 Dispositif a guide d'ondes optiques optiquement actif comportant un canal sur un substrat optique

Country Status (6)

Country Link
US (1) US20040091225A1 (zh)
EP (1) EP1346242A1 (zh)
CN (1) CN1264032C (zh)
CA (1) CA2432815A1 (zh)
FR (1) FR2818755B1 (zh)
WO (1) WO2002052312A1 (zh)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2818390B1 (fr) * 2000-12-15 2003-11-07 Ion Beam Services Guide d'onde comportant un canal sur un substrat optique
AU2003297337A1 (en) * 2003-12-17 2005-08-03 The Trustees Of Columbia University In The City Of New York Methods for fabrication of localized membranes on single crystal substrate surfaces
FR2871812B1 (fr) * 2004-06-16 2008-09-05 Ion Beam Services Sa Implanteur ionique fonctionnant en mode plasma pulse
ITCZ20040017A1 (it) * 2004-11-08 2005-02-08 Carlo Gavazzi Space Spa Micro-interferometro integrato e metodo di realizzazione
FR2902575B1 (fr) * 2006-06-14 2008-09-05 Ion Beam Services Sa Appareil de caracterisation optique du dopage d'un substrat
CN104950478B (zh) * 2015-05-20 2017-08-01 吉林大学 一种基于有机聚合物材料的有源复合光波导及其制备方法

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FR2818390B1 (fr) * 2000-12-15 2003-11-07 Ion Beam Services Guide d'onde comportant un canal sur un substrat optique
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Also Published As

Publication number Publication date
US20040091225A1 (en) 2004-05-13
CN1483151A (zh) 2004-03-17
CA2432815A1 (fr) 2002-07-04
CN1264032C (zh) 2006-07-12
FR2818755B1 (fr) 2004-06-11
FR2818755A1 (fr) 2002-06-28
WO2002052312A1 (fr) 2002-07-04

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