EP1244768A2 - Preparations de microcapsules et produits detergents et produits nettoyants contenant des microcapsules - Google Patents
Preparations de microcapsules et produits detergents et produits nettoyants contenant des microcapsulesInfo
- Publication number
- EP1244768A2 EP1244768A2 EP01900121A EP01900121A EP1244768A2 EP 1244768 A2 EP1244768 A2 EP 1244768A2 EP 01900121 A EP01900121 A EP 01900121A EP 01900121 A EP01900121 A EP 01900121A EP 1244768 A2 EP1244768 A2 EP 1244768A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- acid
- fragrance
- monomers
- microcapsules
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
Definitions
- fragrances are essential oils, resinoids and resins from a variety of sources such as: B. Peru balsam, olibanum resinidid, ⁇ tyrax, labdanum resin, nutmeg, cassia oil, benzoin resin, coriander and lavandin.
- suitable fragrances are: phenyl ethyl alcohol, terpineol, linalool, linalyl acetate, geraniol, nerol, 2- (1, l-dimethylethyl) cyclohexanol acetate, benzyl acetate and eugenol.
- the core of the microcapsules is formed by the water-emulsifiable hydrophobic material.
- the hydrophobic material also serves as a solvent or dispersant for the monomer mixture used in the manufacture of the capsule shells by polymerization.
- the polymerization then takes place in the oil phase of a stable oil-in-water emulsion.
- This emulsion is obtained by, for example, first dissolving the monomers and a polymerization initiator and, if appropriate, a polymerization regulator in the hydrophobic material and emulsifying the solution thus obtained in an aqueous medium with an emulsifier and / or protective colloid.
- grafted degraded or degraded reduced starches and grafted polyethylene oxides are preferably used, 20 to 80% by weight of monomers, based on the graft component, being used in the graft polymerization.
- a mixture of maleic acid and acrylic acid in a weight ratio of 90:10 to 10:90 is preferably used for the grafting.
- organic cobuilders are polyaspartic acid or cocondensates of aspartic acid with further amino acids, C 4 -C 25 mono- or dicarboxylic acids and / or C 4 -C 25 mono- or diamines.
- Polyaspartic acids modified with C 6 -C 22 mono- or dicarboxylic acids or with C 6 -C mono- or diamines are particularly preferably prepared in acids containing phosphorus.
- microcapsules according to the invention 0.001 to 2% by weight, preferably 0.01 to 0.5% by weight of microcapsules according to the invention
- the agents are usually marketed in the form of aqueous concentrates which are used undiluted or diluted.
Landscapes
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10000223A DE10000223A1 (de) | 2000-01-05 | 2000-01-05 | Mikrokapselzubereitungen und Mikrokapseln enthaltende Wasch- und Reinigungsmittel |
DE10000223 | 2000-01-05 | ||
PCT/EP2001/000048 WO2001049817A2 (fr) | 2000-01-05 | 2001-01-04 | Preparations de microcapsules et produits detergents et produits nettoyants contenant des microcapsules |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1244768A2 true EP1244768A2 (fr) | 2002-10-02 |
EP1244768B1 EP1244768B1 (fr) | 2004-08-18 |
Family
ID=7626803
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01900121A Expired - Lifetime EP1244768B1 (fr) | 2000-01-05 | 2001-01-04 | Preparations de microcapsules et produits detergents et produits nettoyants contenant des microcapsules |
Country Status (6)
Country | Link |
---|---|
US (1) | US6951836B2 (fr) |
EP (1) | EP1244768B1 (fr) |
JP (1) | JP5692948B2 (fr) |
DE (2) | DE10000223A1 (fr) |
ES (1) | ES2225464T3 (fr) |
WO (1) | WO2001049817A2 (fr) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202007010668U1 (de) | 2007-07-30 | 2008-12-18 | Follmann & Co. Gesellschaft Für Chemie-Werkstoffe Und -Verfahrenstechnik Mbh & Co. Kg | Verbesserte Mikrokapseln |
DE102008031212A1 (de) | 2008-07-03 | 2010-01-07 | Henkel Ag & Co. Kgaa | Wasch- und Reinigungsmitteladditiv in Partikelform |
WO2011120799A1 (fr) | 2010-04-01 | 2011-10-06 | Unilever Plc | Procédé de structuration de liquides détergents à l'aide d'huile de ricin hydrogénée |
WO2011120772A1 (fr) | 2010-03-31 | 2011-10-06 | Unilever Plc | Incorporation de microcapsules dans des détergents liquides structurés |
EP2495300A1 (fr) | 2011-03-04 | 2012-09-05 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Structuration de liquides détergents avec de l'huile de ricin hydrogénée |
WO2013160022A1 (fr) | 2012-04-23 | 2013-10-31 | Unilever Plc | Compositions détergentes liquides isotropes aqueuses structurées de façon externe |
WO2013160023A1 (fr) | 2012-04-23 | 2013-10-31 | Unilever Plc | Compositions de détergent pour lessive liquide isotrope aqueux structuré de façon externe |
WO2013160024A1 (fr) | 2012-04-23 | 2013-10-31 | Unilever Plc | Compositions détergentes liquides isotropes aqueuses structurées de façon externe |
US9556405B2 (en) | 2012-11-29 | 2017-01-31 | Conopco, Inc. | Polymer structured aqueous detergent compositions |
WO2018210522A1 (fr) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
WO2018210700A1 (fr) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
WO2018210523A1 (fr) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
WO2018210524A1 (fr) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
US11441106B2 (en) | 2017-06-27 | 2022-09-13 | Henkel Ag & Co. Kgaa | Particulate fragrance enhancers |
Families Citing this family (167)
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---|---|---|---|---|
DE10105801B4 (de) * | 2001-02-07 | 2004-07-08 | Henkel Kgaa | Wasch- und Reinigungsmittel umfassend feine Mikropartikel mit Reinigungsmittelbestandteilen |
DE60212984T2 (de) * | 2001-10-01 | 2007-02-15 | The Procter & Gamble Company, Cincinnati | Shampoo mit hohlen teilchen |
EP1693048B1 (fr) * | 2001-10-01 | 2008-05-28 | The Procter & Gamble Company | Shampooing contenant des particules creuses |
DE10163162A1 (de) | 2001-12-20 | 2003-07-03 | Basf Ag | Mikrokapseln |
JP2005521950A (ja) * | 2002-03-28 | 2005-07-21 | プリキャッシュ インコーポレイテッド | 発行−購読ネットワークにおける、信頼性が高く効率的なコンテンツに基づくルーティング、クエリ及び応答のための方法及び装置 |
US7585824B2 (en) | 2002-10-10 | 2009-09-08 | International Flavors & Fragrances Inc. | Encapsulated fragrance chemicals |
US7125835B2 (en) | 2002-10-10 | 2006-10-24 | International Flavors & Fragrances Inc | Encapsulated fragrance chemicals |
US7226607B2 (en) * | 2003-09-11 | 2007-06-05 | The Procter & Gamble Company | Compositions comprising a dispersant and microcapsules containing an active material and a stabilizer |
BRPI0416701A (pt) * | 2003-11-27 | 2007-03-06 | Unilever Nv | proteìna de fusão, codificação da seqüência dna, composição detergente, e, processo para o fornecimento de um agente de beneficiamento para um tecido |
ES2289571T5 (es) * | 2003-12-19 | 2014-12-16 | Unilever N.V. | Gránulos detergentes y procedimiento para su preparación |
US7531365B2 (en) * | 2004-01-08 | 2009-05-12 | International Flavors & Fragrances Inc. | Analysis of the headspace proximate a substrate surface containing fragrance-containing microcapsules |
US7452547B2 (en) * | 2004-03-31 | 2008-11-18 | Johnson&Johnson Consumer Co., Inc. | Product for treating the skin comprising a polyamine microcapsule wall and a skin lightening agent |
FR2868442B1 (fr) * | 2004-04-01 | 2006-05-26 | Seb Sa | Fer a repasser comportant un reservoir d'additif |
US7704940B2 (en) * | 2004-04-09 | 2010-04-27 | The Sun Products Corporation | Granulate for use in a cleaning product and process for its manufacture |
DE102004040848A1 (de) * | 2004-08-23 | 2006-03-02 | Henkel Kgaa | Reiniger mit Fäkalschmutz-abweisenden Eigenschaften |
EP1773937A4 (fr) * | 2004-12-08 | 2009-01-14 | Lg Chemical Ltd | Additif pour pvc et procede de fabrication correspondant |
BRPI0519188A2 (pt) * | 2004-12-23 | 2008-12-30 | Unilever Nv | composiÇço detergente lÍquida substancialmente nço-aquosa, envelope de polÍmero solével em Água, e, uso de composiÇço ou de envelope |
US20060258557A1 (en) * | 2005-05-11 | 2006-11-16 | Popplewell Lewis M | Hard surface cleaning compositions and methods for making same |
WO2006127453A2 (fr) * | 2005-05-23 | 2006-11-30 | Appleton Papers Inc. | Procédé de fabrication de capsule de type eau dans huile et microcapsules produites selon ce procédé |
EP1767613A1 (fr) * | 2005-09-23 | 2007-03-28 | Takasago International Corporation | Procédé pour la préparation d'une poudre séchée par atomisation |
DE602005024404D1 (de) * | 2005-09-23 | 2010-12-09 | Takasago Perfumery Co Ltd | Kern/Schale-Kapseln enthaltend ein Öl oder einen wachsartigen Feststoff |
CA2625959A1 (fr) * | 2005-09-27 | 2007-04-05 | The Procter & Gamble Company | Microcapsule et son procede de fabrication |
GB0524659D0 (en) * | 2005-12-02 | 2006-01-11 | Unilever Plc | Improvements relating to fabric treatment compositions |
US20070138674A1 (en) * | 2005-12-15 | 2007-06-21 | Theodore James Anastasiou | Encapsulated active material with reduced formaldehyde potential |
US20070191256A1 (en) * | 2006-02-10 | 2007-08-16 | Fossum Renae D | Fabric care compositions comprising formaldehyde scavengers |
US20070202063A1 (en) * | 2006-02-28 | 2007-08-30 | Dihora Jiten O | Benefit agent containing delivery particle |
JP5154029B2 (ja) * | 2006-05-08 | 2013-02-27 | 花王株式会社 | 液体洗浄剤組成物 |
US20070275866A1 (en) * | 2006-05-23 | 2007-11-29 | Robert Richard Dykstra | Perfume delivery systems for consumer goods |
EP1867668B1 (fr) * | 2006-06-13 | 2012-07-04 | Basf Se | Procédé de condensation par vaporisation pour la fabrication de la résine |
BRPI0713074A2 (pt) * | 2006-06-30 | 2012-07-17 | Colgate Palmolive Co | composição, e, método para melhorar a estabilidade de um produto. |
JP5351758B2 (ja) * | 2006-07-13 | 2013-11-27 | ビーエーエスエフ ソシエタス・ヨーロピア | 高分子電解質で変性されたマイクロカプセル |
DE602007011272D1 (de) * | 2006-08-01 | 2011-01-27 | Procter & Gamble | Pflegemittel mit freisetzungspartikel |
CN101528339B (zh) * | 2006-10-17 | 2013-03-27 | 巴斯夫欧洲公司 | 微胶囊 |
BRPI0719594B1 (pt) | 2006-11-22 | 2024-01-09 | The Procter & Gamble Company | Produto destinado ao consumidor compreendendo uma composição de partícula formada por partículas de liberação contendo agente de benefício e método não terapêutico de tratamento e/ou limpeza de um local |
US8076280B2 (en) * | 2006-12-20 | 2011-12-13 | Basf Se | Emulsions containing encapsulated fragrances and personal care compositions comprising said emulsions |
DE102007001115A1 (de) * | 2007-01-04 | 2008-07-10 | Cognis Ip Management Gmbh | Verwendung von wässrigen Emulsionen in Schaumform zum Reload von Textilien |
WO2008100411A1 (fr) * | 2007-02-09 | 2008-08-21 | The Procter & Gamble Company | Systèmes de parfums |
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CA2687560C (fr) | 2007-06-11 | 2013-05-14 | The Procter & Gamble Company | Agent ameliorant contenant des particules de liberation |
EP2070510A1 (fr) * | 2007-12-10 | 2009-06-17 | Takasago International Corporation | Système de nettoyage personnel |
WO2009090169A1 (fr) * | 2008-01-15 | 2009-07-23 | Basf Se | Microcapsules contenant un parfum et à comportement de libération amélioré |
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EP2442901A2 (fr) | 2009-06-15 | 2012-04-25 | Basf Se | Microcapsules contenant des polymères fortement ramifiés en tant que réticulants |
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CN102947432B (zh) | 2010-06-22 | 2015-01-28 | 宝洁公司 | 香料体系 |
JP5759544B2 (ja) | 2010-07-02 | 2015-08-05 | ザ プロクター アンド ギャンブルカンパニー | 活性剤を送達する方法 |
JP5788503B2 (ja) | 2010-07-02 | 2015-09-30 | ザ プロクター アンド ギャンブルカンパニー | ウェブ材料及びその製造方法 |
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RU2541275C2 (ru) | 2010-07-02 | 2015-02-10 | Дзе Проктер Энд Гэмбл Компани | Филаменты, содержащие неароматизированный активный агент, нетканые полотна и способы их получения |
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WO2012003349A2 (fr) | 2010-07-02 | 2012-01-05 | The Procter & Gamble Company | Article présentant une structure en tissu fibreux soluble et contenant des agents actifs |
KR20130100290A (ko) | 2010-08-30 | 2013-09-10 | 프레지던트 앤드 펠로우즈 오브 하바드 칼리지 | 협착성 병변을 위한 전단 제어 방출 및 혈전 용해 치료법 |
EP2611847B1 (fr) | 2010-09-01 | 2018-11-07 | Basf Se | Amphiphile servant à solubiliser des substances actives difficilement solubles |
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US8492001B2 (en) * | 2010-10-01 | 2013-07-23 | Toyota Motor Engineering & Manufacturing North America, Inc. | Self-stratifying coating |
US8936030B2 (en) | 2011-03-25 | 2015-01-20 | Katherine Rose Kovarik | Nail polish remover method and device |
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JP5869663B2 (ja) | 2011-04-07 | 2016-02-24 | ザ プロクター アンド ギャンブルカンパニー | ポリアクリレートマイクロカプセルの付着が増大したシャンプー組成物 |
EP2694031B1 (fr) | 2011-04-07 | 2015-07-08 | The Procter and Gamble Company | Compositions d'après-shampooing à dépôt accru de microcapsules de polyacrylate |
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CN114729286A (zh) | 2019-12-05 | 2022-07-08 | 宝洁公司 | 制备清洁组合物的方法 |
ES2946614T3 (es) | 2020-04-21 | 2023-07-21 | Takasago Perfumery Co Ltd | Composición de fragancia |
EP3900696B1 (fr) | 2020-04-21 | 2023-04-19 | Takasago International Corporation | Composition de parfum encapsulée |
WO2021259722A1 (fr) | 2020-06-24 | 2021-12-30 | Basf Se | Composition de détergent liquide concentrée |
WO2024023598A1 (fr) * | 2022-07-25 | 2024-02-01 | S H Kelkar And Company Limited | Microcapsules et leur encapsulation |
EP4339121A1 (fr) | 2022-09-14 | 2024-03-20 | The Procter & Gamble Company | Produit de consommation |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4145184A (en) * | 1975-11-28 | 1979-03-20 | The Procter & Gamble Company | Detergent composition containing encapsulated perfume |
JPS5425277A (en) * | 1977-07-27 | 1979-02-26 | Fuji Photo Film Co Ltd | Method of producing microcapsule |
JPS56102935A (en) * | 1980-01-22 | 1981-08-17 | Fuji Photo Film Co Ltd | Manufacture of micro capsule |
DE2940786A1 (de) * | 1979-10-08 | 1981-04-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mikrokapseln |
US4574110A (en) * | 1983-07-28 | 1986-03-04 | Mitsui Toatsu Chemicals, Incorporated | Process for producing microcapsules and microcapsule slurry |
JPH0659402B2 (ja) * | 1984-06-27 | 1994-08-10 | 三井東圧化学株式会社 | マイクロカプセルの製造方法 |
DE3532878A1 (de) * | 1985-09-14 | 1987-03-26 | Basf Ag | Kontinuierliches verfahren zur herstellung von mikrokapseln mit waenden aus melamin-formaldehydkondensaten in waessriger dispersion |
JPH05125127A (ja) * | 1985-11-28 | 1993-05-21 | Japan Synthetic Rubber Co Ltd | 単一の内孔を有するポリマー粒子 |
US4946624A (en) * | 1989-02-27 | 1990-08-07 | The Procter & Gamble Company | Microcapsules containing hydrophobic liquid core |
DE4015753A1 (de) * | 1990-05-16 | 1991-11-21 | Basf Ag | Farbbildner enthaltende mikrokapseln |
DE4321205B4 (de) | 1993-06-25 | 2006-06-29 | Basf Ag | Mikrokapseln, Verfahren zu ihrer Herstellung und ihre Verwendung |
US6024943A (en) * | 1996-12-23 | 2000-02-15 | Ness; Jeremy Nicholas | Particles containing absorbed liquids and methods of making them |
FR2774390B1 (fr) | 1998-02-02 | 2002-12-13 | Rhodia Chimie Sa | Parfums encapsules dans des polymeres alcali-hydrosolubles, leur procede de preparation et leur utilisation dans les compositions detergentes |
DE19932144A1 (de) | 1999-07-09 | 2001-01-11 | Basf Ag | Mikrokapselzubereitungen und Mikrokapseln enthaltende Wasch- und Reinigungsmittel |
-
2000
- 2000-01-05 DE DE10000223A patent/DE10000223A1/de not_active Withdrawn
-
2001
- 2001-01-04 US US10/169,075 patent/US6951836B2/en not_active Expired - Lifetime
- 2001-01-04 JP JP2001550347A patent/JP5692948B2/ja not_active Expired - Lifetime
- 2001-01-04 DE DE50103314T patent/DE50103314D1/de not_active Expired - Lifetime
- 2001-01-04 WO PCT/EP2001/000048 patent/WO2001049817A2/fr active IP Right Grant
- 2001-01-04 EP EP01900121A patent/EP1244768B1/fr not_active Expired - Lifetime
- 2001-01-04 ES ES01900121T patent/ES2225464T3/es not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO0149817A2 * |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202007010668U1 (de) | 2007-07-30 | 2008-12-18 | Follmann & Co. Gesellschaft Für Chemie-Werkstoffe Und -Verfahrenstechnik Mbh & Co. Kg | Verbesserte Mikrokapseln |
DE102008031212A1 (de) | 2008-07-03 | 2010-01-07 | Henkel Ag & Co. Kgaa | Wasch- und Reinigungsmitteladditiv in Partikelform |
WO2011120772A1 (fr) | 2010-03-31 | 2011-10-06 | Unilever Plc | Incorporation de microcapsules dans des détergents liquides structurés |
WO2011120799A1 (fr) | 2010-04-01 | 2011-10-06 | Unilever Plc | Procédé de structuration de liquides détergents à l'aide d'huile de ricin hydrogénée |
EP2495300A1 (fr) | 2011-03-04 | 2012-09-05 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Structuration de liquides détergents avec de l'huile de ricin hydrogénée |
WO2013160023A1 (fr) | 2012-04-23 | 2013-10-31 | Unilever Plc | Compositions de détergent pour lessive liquide isotrope aqueux structuré de façon externe |
WO2013160022A1 (fr) | 2012-04-23 | 2013-10-31 | Unilever Plc | Compositions détergentes liquides isotropes aqueuses structurées de façon externe |
WO2013160024A1 (fr) | 2012-04-23 | 2013-10-31 | Unilever Plc | Compositions détergentes liquides isotropes aqueuses structurées de façon externe |
US9556405B2 (en) | 2012-11-29 | 2017-01-31 | Conopco, Inc. | Polymer structured aqueous detergent compositions |
WO2018210522A1 (fr) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
WO2018210700A1 (fr) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
WO2018210523A1 (fr) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
WO2018210524A1 (fr) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
US11441106B2 (en) | 2017-06-27 | 2022-09-13 | Henkel Ag & Co. Kgaa | Particulate fragrance enhancers |
Also Published As
Publication number | Publication date |
---|---|
EP1244768B1 (fr) | 2004-08-18 |
DE50103314D1 (de) | 2004-09-23 |
WO2001049817A2 (fr) | 2001-07-12 |
US20030125222A1 (en) | 2003-07-03 |
JP2003524689A (ja) | 2003-08-19 |
JP5692948B2 (ja) | 2015-04-01 |
ES2225464T3 (es) | 2005-03-16 |
WO2001049817A3 (fr) | 2001-12-13 |
US6951836B2 (en) | 2005-10-04 |
DE10000223A1 (de) | 2001-07-12 |
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