EP1133937A1 - Vorrichtung zum Aufbewahren und Auftragen von Kosmetiska oder Pflegeprodukten - Google Patents
Vorrichtung zum Aufbewahren und Auftragen von Kosmetiska oder Pflegeprodukten Download PDFInfo
- Publication number
- EP1133937A1 EP1133937A1 EP01400671A EP01400671A EP1133937A1 EP 1133937 A1 EP1133937 A1 EP 1133937A1 EP 01400671 A EP01400671 A EP 01400671A EP 01400671 A EP01400671 A EP 01400671A EP 1133937 A1 EP1133937 A1 EP 1133937A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- plastic
- components
- abs
- solvent
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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Classifications
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/02—Casings wherein movement of the lipstick or like solid is a sliding movement
- A45D40/04—Casings wherein movement of the lipstick or like solid is a sliding movement effected by a screw
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/06—Casings wherein movement of the lipstick or like solid is a screwing movement
Definitions
- the present invention relates to the field of packaging devices and application of a cosmetic or care product.
- the invention relates more particularly but not exclusively to a device for packaging and applying lipstick.
- the present invention aims in particular to improve the conservation of the grape.
- the invention aims to improve the preservation of a product cosmetic or care product containing at least one volatile hydrocarbon solvent contained in a tightly closed packaging and application device, comprising at least at least two elements, one of which is made of plastic, these elements being able to be moved relatively to each other to allow application of the product.
- the invention achieves this by virtue of the fact that the plastic material is chosen to so that said element (s) does not undergo mass variation sensitive when it (s) is (are) in prolonged contact with the vapors of said solvent.
- the present invention allows, when the device includes a product drive mechanism as is the case for example for a lipstick case, to avoid any risk of variation dimensional of the plastic components and malfunction of the mechanism after absorption of the volatile hydrocarbon solvent (s) contained in the product, if stored at a relatively high temperature and / or prolonged storage (several years).
- the drive mechanisms from red to lips have parts to be moved precisely by one compared to others and are particularly sensitive to dimensional variations.
- the invention is very particularly advantageous when the solvent is chosen from hydrocarbon oils of 8 to 16 carbon atoms or their mixtures, the solvent being able to be chosen from branched C 8 -C 16 alkanes and their mixtures and consisting of isododecane.
- the plastic components of the non-polyolefinic plastics device Preferably, the plastic components of the non-polyolefinic plastics device.
- styrenics especially polystyrenes and their copolymers (SB, SAN, ABS), polyvinyl chloride and their derivatives, polyacrylic (PMMA), polyoxymethylenes (POM), polyamides (PA) and saturated polyesters thermoplastics, in particular polyethylene terephthalate (PET).
- SB polystyrenes and their copolymers
- PMMA polyacrylic
- POM polyoxymethylenes
- PA polyamides
- PET saturated polyesters thermoplastics, in particular polyethylene terephthalate
- all the plastic components of the device are made of acrylobutadiene-styrene (ABS).
- the device includes an external covering, advantageously to produce this covering of ABS or an ABS / SAN copolymer.
- the device includes a drive mechanism comprising at at least two moving components relative to each other, advantageously used to make these components from different materials, one of the components being made in POM and another component in ABS.
- At least one of said plastic elements not subjected to significant mass variation can belong to a product drive mechanism.
- At least one of said plastic elements not subjected to significant mass variation may not be apparent from outside the device.
- At least one of said plastic elements not subjected to significant mass variation may be in direct contact with the product.
- the case 1 comprises an external covering comprising a body or base 2, a removable cover 3 and a drive mechanism 4 intended for allow the axial displacement of a grape of product P.
- Mechanism 4 has a structure known per se, and it is constituted by the assembly of three elements, namely a sheath 5, a grape cup 6 and a envelope 7.
- the sheath 5 and the cup 6 are made of plastic and the casing 7 has a metal sleeve 8 lined with an inner jacket 9 made of material plastic.
- the cup 6 comprises, in a manner known per se, two lugs 10 diametrically opposed arranged to slide in two guide slots 11 diametrically opposite of the sleeve 5.
- the ends of the lugs 10 engage in helical grooves 12 of the inner liner 9, so that a movement of rotation of the sheath 5 relative to the casing 7 is accompanied by an axial displacement of the cup 6.
- the body 2 includes a chimney 13 which engages in the sheath 5 and which is immobilized in rotation with respect thereto.
- the user turns the envelope 7 relative to the body 2 after removing the closure cover 3.
- FIG. 3 shows a case 1 ′ of lipstick, of structure known and described in French patent application FR-A-2 762 763, to which can advantageously refer.
- the case 1 ' comprises an external covering comprising a body or base 2' and a closing cover 3 ', the latter housing a drive mechanism 4' comprising a envelope 7 ', a sheath 5' and a cup holder 6 '.
- the sheath 5 ' is made in one piece before the body 2' and has two diametrically opposite slots 11 'in which two pins can slide diametrically opposite 10 'of the cup 6'.
- the casing 7 ′ has an external metal sleeve 8 ′ lined with inner jacket 9 'provided with a helical thread 12'.
- the case 1 “comprises an external covering comprising a body or base 2" and a closing cover 3 ", the body 2" and the cover 3 "being for example made of metal.
- the case 1 includes a drive mechanism 4" which includes a 5 “assembly made of plastic fixed with respect to the body 2", a 7 “casing capable of turn relative to the latter and a 6 "grape cup.
- the cup 6 is integral with a threaded rod 20 of engaged plastic material in an element 21 forming a nut belonging to the 5 "assembly.
- the envelope 7 “comprises a metal sleeve 8", which can move in rotation by relative to the body 2 "but fixed in translation, in which is engaged an insert 22 in plastic material.
- the threaded rod 20 has along its length two diametrically flats opposite, not visible in the drawing because they are parallel to the section plane in FIG. 4.
- the insert 22 has two drive surfaces, not shown on the Figure 4, which come to bear on the flats of the rod 20, so that the drive in rotation of the envelope 7 "is accompanied by a displacement in rotation of the rod 20, the latter however being free to move axially relative to the insert 22, the threads of the rod 20 engaging in the element 21.
- closing hood 3 "comprises an insert 23 provided with gadroons 24.
- the plastic components are used to produce the components materials chosen so as not to exhibit any significant mass variation when placed in prolonged contact with the vapors of the volatile solvent (s) contained in the product P.
- volatile solvent is understood, within the meaning of the present invention, a medium non-aqueous liquid at room temperature (25 ° C) and at atmospheric pressure normal (760 mm of mercury), capable of evaporating from the skin or the lips less than an hour.
- Such a solvent can be chosen from media having a vapor pressure, at ambient temperature and normal atmospheric pressure, ranging from 10 -3 to 300 mm of mercury (0.13 Pa to 40,000 Pa).
- the solvents considered are hydrocarbon oils comprising from 8 to 16 carbon atoms or their mixtures.
- Such oils can be chosen from branched C 8 -C 16 alkanes and mixtures thereof.
- Is used for example, C 8 -C 14 isoparaffins, or isododecane, isohexadecane or isohexyl neo-pentanoate, isododecane being preferred.
- the product P contains, in the embodiments described, between 5 and 90% volatile solvents, and preferably at least 20%.
- the product P may for example have one of the following compositions:
- Isododecane (2,2,4,6,6) pentanethyl heptane 20% Phenyltrimethicone 49% Polyethylene wax (PM 500) 20% Pigments and nacres 11% the proportions given above being mass fractions.
- This lipstick is obtained by dispersing the pigments and nacres in the phenyltrimethicone then adding the wax and heating everything to 100 ° C until melting total wax. Isododecane is then added at 80 ° C. The molten mixture is then poured into a suitable mold to form a stick then cools to temperature ambient. The stick obtained is homogeneous, soft and non-greasy. It provides a comfortable film on the lips throughout the day and that does not transfer.
- This lipstick is obtained as in Example 1. A red is obtained. lips which is easily applied and which after evaporation of the isododecane leads to a comfortable film that does not transfer.
- This lipstick is obtained as in Example 1 and has the same properties.
- Particulate phase C is ground in phase A using a grinder three-cylinder.
- the polyethylene wax is then added and the mixture is heated at 100 ° C. until complete dissolution of the wax.
- Phenyltrimethicone and mica are then added to 100 ° C, then isododecane at 80-90 ° C. It can then be poured at 80-85 ° C in molds suitable for obtaining sticks.
- the product P contains a significant proportion of isododecane and the components are chosen plastic of cases 1, 1 'and 1 "in non-polyolefinic thermoplastics.
- styrenics for example polystyrenes (PS) and their copolymers (SB, SAN, ABS), polyvinyl chloride and their derivatives, polyacrylic (PMMA), polyoxymethylenes (POM), polyamides (PA) and saturated polyesters thermoplastics, in particular polyethylene terephthalate (PET).
- PS polystyrenes
- SB SAN
- ABS copolymers
- PMMA polyacrylic
- POM polyoxymethylenes
- PA polyamides
- saturated polyesters thermoplastics in particular polyethylene terephthalate (PET).
- ABS acrylobutadiene-styrene
- the invention applies generally to all lipstick cases known.
- the invention has shown that, in addition to the best conservation of the product, guaranteed dimensional stability of plastic components the case over a long period of time, even when stored at a relatively high temperature high.
- the invention also makes it possible to avoid that following a loss of solvent the the grape dries out, such drying can lead to a shrinking of its diameter and to a detachment of the cup which carries it; in addition, the drying of the grapes is accompanied by a hardening which prevents correct spreading of the product on the lips.
- the invention is not limited to the case where the hydrocarbon solvent contained in the product is isododecane.
- the invention is not limited to lipstick cases but generally applies to all packaging and application devices in which we seek to obtain a tight closure and in which we use plastic components exposed to vapors from hydrocarbon solvents contained in the product.
Landscapes
- Cosmetics (AREA)
- Packages (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0003375 | 2000-03-16 | ||
FR0003375A FR2806273B1 (fr) | 2000-03-16 | 2000-03-16 | Dispositif de conditionnement et d'application d'un produit cosmetique ou de soin |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1133937A1 true EP1133937A1 (de) | 2001-09-19 |
EP1133937B1 EP1133937B1 (de) | 2005-05-11 |
Family
ID=8848162
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01400671A Expired - Lifetime EP1133937B1 (de) | 2000-03-16 | 2001-03-14 | Vorrichtung zum Aufbewahren und Auftragen von Kosmetiska oder Pflegeprodukten |
Country Status (11)
Country | Link |
---|---|
US (2) | US6843611B2 (de) |
EP (1) | EP1133937B1 (de) |
JP (2) | JP4131617B2 (de) |
CN (1) | CN100418453C (de) |
AR (1) | AR027663A1 (de) |
AT (1) | ATE295095T1 (de) |
BR (1) | BR0100997B1 (de) |
CA (1) | CA2341837C (de) |
DE (1) | DE60110665T2 (de) |
ES (1) | ES2239655T3 (de) |
FR (1) | FR2806273B1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008046762A1 (en) * | 2006-10-20 | 2008-04-24 | L'oreal | Cosmetic composition comprising an organopolysiloxane comprising at least one carboxyl group |
US11166537B2 (en) | 2017-08-23 | 2021-11-09 | Tokiwa Corporation | Coating material feeding container |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2806273B1 (fr) * | 2000-03-16 | 2002-10-04 | Oreal | Dispositif de conditionnement et d'application d'un produit cosmetique ou de soin |
FR2833817B1 (fr) | 2001-12-26 | 2004-06-04 | Rexam Reboul | Mecanisme de rouge a levres ou analogue a fin de course reversible |
MXPA03008714A (es) | 2002-09-26 | 2004-09-10 | Oreal | Polimeros secuenciados y composiciones cosmeticas que comprenden tales polimeros. |
JP2004269497A (ja) * | 2002-09-26 | 2004-09-30 | L'oreal Sa | ブロックポリマーを含むマニキュア組成物 |
US7481229B2 (en) | 2002-11-06 | 2009-01-27 | L'oreal | Case with a sealing element |
AU2003300598A1 (en) | 2002-12-12 | 2004-07-09 | L'oreal-Ferrari | Non-transfer cosmetic composition comprising a dispersion of a grafted ethylene polymer |
FR2857257B1 (fr) * | 2003-07-07 | 2007-10-19 | Oreal | Utilisation de derives cellulosiques modifies en tant qu'agent epaississant de la phase organique d'une composition de vernis a ongles. |
FR2860143B1 (fr) | 2003-09-26 | 2008-06-27 | Oreal | Composition cosmetique comprenant un polymere sequence et une huile siliconee non volatile |
FR2860142B1 (fr) * | 2003-09-26 | 2007-08-17 | Oreal | Produit cosmetique bicouche, ses utilisations et kit de maquillage contenant ce produit |
CN1781476B (zh) * | 2004-03-22 | 2013-10-16 | 莱雅公司 | 包含聚甘油化硅氧烷弹性体的化妆品组合物 |
US20050220731A1 (en) * | 2004-03-23 | 2005-10-06 | Philippe Ilekti | Nail varnish composition comprising at least one polymer and at least one plasticizer |
US8728451B2 (en) | 2004-03-25 | 2014-05-20 | L'oreal | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
US20050281769A1 (en) * | 2004-06-11 | 2005-12-22 | Toumi Beatrice | Cosmetic composition comprising a polymer |
US20080138300A2 (en) * | 2004-10-15 | 2008-06-12 | L'oreal S.A. | Composition cosmetique comprenant un polymere acrylique |
US20060159643A1 (en) * | 2004-12-20 | 2006-07-20 | Isabelle Jacquier | Cosmetic composition comprising at least one metallic dyestuff |
FR2881343B1 (fr) | 2005-01-31 | 2007-04-20 | Oreal | Composition cosmetique solide de maquillage et/ou de soin |
FR2892901B1 (fr) * | 2005-11-09 | 2007-12-28 | Oreal | Dispositif de conditionnement et d'application d'un produit sur des fibres keratiniques |
US7883286B2 (en) * | 2005-11-09 | 2011-02-08 | L'oreal | Beauty care product application device |
FR2903603B1 (fr) | 2006-07-13 | 2009-03-20 | Galderma Res & Dev S N C Snc | Combinaison d'adapalene et de peroxyde de benzole dans le traitement de l'acne |
FR2904320B1 (fr) | 2006-07-27 | 2008-09-05 | Oreal | Polymeres sequences, et leur procede de preparation |
FR2917614B1 (fr) | 2007-06-21 | 2009-10-02 | Oreal | Composition cosmetique comprenant un polyester et un compose hydrocarbone ramifie. |
FR2917615B1 (fr) | 2007-06-21 | 2009-10-02 | Oreal | Composition cosmetique comprenant deux polyesters. |
FR2939033B1 (fr) | 2008-12-02 | 2012-08-31 | Oreal | Composition cosmetique de maquillage et/ou de soin des matieres keratiniques, et procede de maquillage |
WO2011065101A1 (ja) * | 2009-11-30 | 2011-06-03 | 株式会社 資生堂 | 唇用化粧料 |
JP5926896B2 (ja) * | 2010-09-17 | 2016-05-25 | 株式会社 資生堂 | 唇用固形化粧料 |
KR101821850B1 (ko) | 2011-05-13 | 2018-01-24 | 마리 케이 인코포레이티드 | 립 스틱 |
KR101554222B1 (ko) * | 2013-02-28 | 2015-09-18 | 인하공업전문대학산학협력단 | 립스틱용 투웨이칼라스틱 제작방법 |
US9185962B2 (en) | 2013-03-15 | 2015-11-17 | Hcp Packaging Usa, Inc. | Elevator cup and dispensing device incorporating the same |
USD735413S1 (en) | 2013-03-15 | 2015-07-28 | The Mentholatum Company | Cosmetic packaging |
USD742593S1 (en) | 2013-10-07 | 2015-11-03 | The Mentholatum Company | Cosmetic container |
EP3096645B1 (de) | 2014-01-24 | 2020-03-18 | HCP Packaging USA, Inc. | Kosmetikspender mit reibungswiderstand |
US9642439B2 (en) | 2014-02-14 | 2017-05-09 | Hcp Packaging Usa, Inc. | Cosmetic dispenser with crenelated wall for frictional resistance |
USD768937S1 (en) | 2014-05-08 | 2016-10-11 | The Mentholatum Company | Cosmetic container |
USD768936S1 (en) | 2014-05-08 | 2016-10-11 | The Mentholatum Company | Cosmetic container |
CN107573607A (zh) * | 2017-08-29 | 2018-01-12 | 浙江阿克希龙舜华铝塑业有限公司 | 口红包装管的中束芯 |
US11382400B2 (en) | 2018-08-10 | 2022-07-12 | Go Products Co. | Material applicator |
JPWO2020203408A1 (de) * | 2019-03-29 | 2020-10-08 | ||
WO2021042313A1 (zh) * | 2019-09-05 | 2021-03-11 | 珠海市鼎荣塑胶制品有限公司 | 具环保功效的化妆容器结构 |
WO2021042312A1 (zh) * | 2019-09-05 | 2021-03-11 | 珠海市鼎荣塑胶制品有限公司 | 具环保功效的口红芯结构 |
US11246394B2 (en) * | 2019-09-17 | 2022-02-15 | Zhuhai Ding Rong Plastic Products Co., Ltd | Environmentally friendly lipstick tube |
US11064787B2 (en) * | 2019-09-17 | 2021-07-20 | Zhuhai Ding Rong Plastic Products Co., Ltd | Environmentally friendly lipstick case |
CN113367465A (zh) * | 2020-02-25 | 2021-09-10 | 珠海市鼎荣塑胶制品有限公司 | 可更换唇膏的容器结构 |
US11297925B2 (en) * | 2020-08-10 | 2022-04-12 | Crystal International (Group) | Refillable lipstick case |
FR3126861B1 (fr) | 2021-09-14 | 2024-01-12 | Oreal | Dispositif de conditionnement d’un rouge à lèvres |
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-
2000
- 2000-03-16 FR FR0003375A patent/FR2806273B1/fr not_active Expired - Lifetime
-
2001
- 2001-03-13 US US09/804,740 patent/US6843611B2/en not_active Expired - Lifetime
- 2001-03-14 EP EP01400671A patent/EP1133937B1/de not_active Expired - Lifetime
- 2001-03-14 ES ES01400671T patent/ES2239655T3/es not_active Expired - Lifetime
- 2001-03-14 AT AT01400671T patent/ATE295095T1/de not_active IP Right Cessation
- 2001-03-14 DE DE60110665T patent/DE60110665T2/de not_active Expired - Lifetime
- 2001-03-15 AR ARP010101201A patent/AR027663A1/es not_active Application Discontinuation
- 2001-03-15 CA CA002341837A patent/CA2341837C/fr not_active Expired - Fee Related
- 2001-03-16 JP JP2001076628A patent/JP4131617B2/ja not_active Expired - Fee Related
- 2001-03-16 CN CNB011096705A patent/CN100418453C/zh not_active Expired - Fee Related
- 2001-03-16 BR BRPI0100997-4A patent/BR0100997B1/pt not_active IP Right Cessation
-
2004
- 2004-07-23 US US10/897,175 patent/US7144171B2/en not_active Expired - Fee Related
-
2005
- 2005-07-12 JP JP2005203378A patent/JP2005343567A/ja active Pending
Patent Citations (12)
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FR2248880A1 (en) | 1973-10-25 | 1975-05-23 | Wennerholm Owe | Spraying device for overhead high voltage units - has pressure vessel for variable volume member containing product |
FR2548880A1 (fr) | 1983-07-11 | 1985-01-18 | Oreal | Cupule porte-raisin d'un baton de rouge a levres, et baton la comportant |
US5342134A (en) * | 1991-06-24 | 1994-08-30 | Elizabeth Arden Co., Division Of Conopco, Inc. | Lipstick article |
EP0815666A1 (de) | 1995-03-24 | 1998-01-07 | Motorola, Inc. | Verfahren und anordnung zur bereitstellung von erinnerungsnachrichten in einem kommunikationssystem |
EP0815766A1 (de) | 1996-06-26 | 1998-01-07 | L'oreal | Stifthalterpfanne für ein Lippenproduktstift und damit ausgestattet Etui |
FR2762763A1 (fr) | 1997-05-05 | 1998-11-06 | Oreal | Dispositif de conditionnement et d'application d'un produit delitable |
EP0876777A1 (de) * | 1997-05-05 | 1998-11-11 | L'oreal | Verpackung zum Aufbewahren und Auftragen eines streichfähigen Produkts |
FR2765800A1 (fr) * | 1997-07-11 | 1999-01-15 | Oreal | Produit cosmetique coule comprenant des huiles volatiles hydrocarbonees |
US5984554A (en) * | 1997-10-21 | 1999-11-16 | Color Access, Inc. | Airtight cosmetic case with bellows |
US5954441A (en) * | 1998-02-02 | 1999-09-21 | Heinz Welschoff | Cosmetic applicator |
EP0981976A2 (de) * | 1998-08-27 | 2000-03-01 | Kotobuki Printing Co., Ltd. | Drehmechanismus für Stiftbewegung |
WO2000041588A2 (en) * | 1999-01-12 | 2000-07-20 | The Procter & Gamble Company | Self cleaning dip-in package for liquids |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008046762A1 (en) * | 2006-10-20 | 2008-04-24 | L'oreal | Cosmetic composition comprising an organopolysiloxane comprising at least one carboxyl group |
US11166537B2 (en) | 2017-08-23 | 2021-11-09 | Tokiwa Corporation | Coating material feeding container |
Also Published As
Publication number | Publication date |
---|---|
FR2806273A1 (fr) | 2001-09-21 |
CA2341837A1 (fr) | 2001-09-16 |
FR2806273B1 (fr) | 2002-10-04 |
US20050002724A1 (en) | 2005-01-06 |
ATE295095T1 (de) | 2005-05-15 |
ES2239655T3 (es) | 2005-10-01 |
CA2341837C (fr) | 2006-05-09 |
DE60110665D1 (de) | 2005-06-16 |
US20020015611A1 (en) | 2002-02-07 |
BR0100997A (pt) | 2001-10-30 |
CN1314293A (zh) | 2001-09-26 |
BR0100997B1 (pt) | 2014-09-16 |
US7144171B2 (en) | 2006-12-05 |
JP2005343567A (ja) | 2005-12-15 |
AR027663A1 (es) | 2003-04-09 |
DE60110665T2 (de) | 2006-03-16 |
US6843611B2 (en) | 2005-01-18 |
EP1133937B1 (de) | 2005-05-11 |
CN100418453C (zh) | 2008-09-17 |
JP2001292830A (ja) | 2001-10-23 |
JP4131617B2 (ja) | 2008-08-13 |
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