EP1105357A2 - Beton et enveloppe de protection contre les radiations - Google Patents

Beton et enveloppe de protection contre les radiations

Info

Publication number
EP1105357A2
EP1105357A2 EP99952354A EP99952354A EP1105357A2 EP 1105357 A2 EP1105357 A2 EP 1105357A2 EP 99952354 A EP99952354 A EP 99952354A EP 99952354 A EP99952354 A EP 99952354A EP 1105357 A2 EP1105357 A2 EP 1105357A2
Authority
EP
European Patent Office
Prior art keywords
concrete
radiation
radiation protection
shielding
aggregate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP99952354A
Other languages
German (de)
English (en)
Inventor
Dieter Vanvor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Areva GmbH
Original Assignee
Siemens AG
Framatome ANP GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG, Framatome ANP GmbH filed Critical Siemens AG
Publication of EP1105357A2 publication Critical patent/EP1105357A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/36—Inorganic materials not provided for in groups C04B14/022 and C04B14/04 - C04B14/34
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C1/00—Reactor types
    • G21C1/30—Subcritical reactors ; Experimental reactors other than swimming-pool reactors or zero-energy reactors
    • G21C1/306—Irradiation loops
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F1/00—Shielding characterised by the composition of the materials
    • G21F1/02—Selection of uniform shielding materials
    • G21F1/04—Concretes; Other hydraulic hardening materials
    • G21F1/042—Concretes combined with other materials dispersed in the carrier
    • G21F1/047—Concretes combined with other materials dispersed in the carrier with metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00862—Uses not provided for elsewhere in C04B2111/00 for nuclear applications, e.g. ray-absorbing concrete
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin
    • Y02E30/30—Nuclear fission reactors

Definitions

  • the invention relates to a radiation protection concrete and a radiation protection jacket for shielding radiation from a radiation source, in particular for / shielding neutron and gamma radiation.
  • a radiation source from which ionizing radiation and / or neutron beams are emitted e.g. B. the radiation in the area of a beam channel of a reactor system
  • a spallation neutron source or the radiation from a medical device steel, cast materials, polyethylene layers, lead, lead alloys and combinations of these materials are usually used as shielding materials.
  • neutron poisons e.g. Boron, in particular Borisotop 10, or cadmium
  • shielding materials of this type are particularly suitable for shielding neutrons.
  • the neutrons are dependent on the selected neutron poison concentration, e.g. Boron concentration, and the neutron energy is absorbed to a greater or lesser extent.
  • the type, size and power of the radiation source largely determine the design, the material selection and the material arrangement of the shield.
  • the required total thickness of the shield is usually determined by the intensity of the radiation at the entrance to the shield and the desired weakening of the intensity via the thickness of the shield and the specific shielding effectiveness of the selected shielding materials.
  • the shielding then exhibits them required high overall thickness usually has a particularly large volume.
  • the protective jacket or the protective barrier is divided into several areas or layers of different materials.
  • the reactor core is cooled and shielded by continuously cooled water as the first layer of the protective jacket.
  • This first layer is usually followed by a second layer of solids, preferably concrete with a comparatively high density.
  • the individual layers of the protective sheath formed from solids must be corrosion-resistant both to liquid and to vaporous water.
  • the solid material selected as the shielding material is predominantly coated or encapsulated with refined metals. This is particularly complex in terms of design and assembly.
  • Another disadvantage is that cavities caused by a complex structure of the radiation source cannot be used, or cannot be used completely, for shielding due to the solid shielding materials. This leads to the fact that the dimensions are particularly large due to the shielding effect to be achieved and prescribed by regulations, and such a protective jacket is particularly expensive.
  • boron-containing substances are, for example, colemanite, boron calcite, boron putty and boron carbide.
  • heavy metal surcharges such as e.g. Iron granules or steel sand.
  • the invention is therefore based on the object of specifying a radiation protection concrete with which a radiation protection jacket with a particularly small volume can be produced, taking into account the highest possible radiation-absorbing shielding effect. This should be achievable with a particularly high level of installation flexibility combined with a particularly low purchase and production effort. A radiation protection jacket should also be specified for this purpose.
  • this object is achieved according to the invention by a radiation protection concrete which, with a content of at least 5.0% by weight, in particular at least 7.8% by weight, contains a first boron-containing additive with a grain size contains up to 1 mm, and which contains a second, metallic aggregate with a grain size of up to 7 mm.
  • the radiation protection concrete of the first embodiment is particularly suitable for shielding strong neutron radiation.
  • a radiation protection concrete which contains a first boron-containing aggregate with a grain size of up to 1 m and which contains between 80 and 90% by weight a second metallic aggregate with a Contains grain size up to 7 mm.
  • boron-containing additive is preferably present in a proportion or content of between 1.0 and 1.5 by weight. "The proportion of the second metallic aggregate is preferably in the interval from 85 to 89% by weight.
  • the radiation protection concrete of the second embodiment is particularly suitable for shielding against strong gamma radiation.
  • the radiation protection concrete according to the invention is particularly suitable for producing radiation protection antels, in which a wall area is formed from the radiation protection concrete at least one of the two embodiments.
  • the invention is based on the consideration that in order to achieve a particularly large shielding effect with a minimal volume, such a shielding material or radiation protection material should be used which can also be emptied into complicated cavities and thus achieves a shielding effect in the immediate vicinity of the radiation source.
  • the composition of the shielding material should be designed in such a way that direct exposure to radiation can be achieved.
  • the shielding should be particularly temperature and radiation-resistant, which means that it can also be used directly at the radiation source and thus under extreme environmental conditions.
  • the potential for self-activation determined by the composition of the shielding material must be taken into account.
  • the radiation protection jacket is made of a concrete, which achieves the desired high shielding effect and low potential for self-activation due to its chemical composition and the grain size of the chemicals used.
  • the ratio of the gamma to the neutron radiation component with the total radiation intensity of the radiation source is decisive. The higher the proportion of cooking radiation, the higher the bulk density of the concrete to be selected in the set state according to DIN 1045.
  • this is achieved by a high proportion of the second, metallic aggregate, which influences the density of the concrete used as a shielding material.
  • the proportion of the first boron-containing additive which acts as a neutron poison is chosen to be particularly high.
  • a minimum bulk density of about 3000 kg / m can also advantageously be set, since otherwise secondary gamma radiation can arise when neutron radiation is absorbed.
  • the radiation protection concretes of the first and second embodiment are advantageously concrete mixtures which contain as a base elements a cement with a high crystal water content and water (so-called / mixing water), the first boron-containing additive as a so-called neutron poison and the second metallic additive to achieve the desired bulk density.
  • a third, metallic or a fourth, mineral additive is preferably used in the radiation protection concretes according to the invention to further increase the bulk density or to increase the water content.
  • a flow agent and / or a retarder are expediently provided as an auxiliary. The addition of flow and retarding agents improves the processability of the Concrete mix, especially from a bulk density of approx. 4000 kg / m 3 .
  • This concrete absorbs almost no water, so that there is almost no corrosion of the metallic aggregates.
  • the fourth mineral additive preferably serpentine
  • Serpentine is characterized by its particularly good binding properties of a particularly large amount of water in the form of crystal water. This results in an improved corrosion resistance compared to standard concrete with at the same time particularly good properties for workability and producibility.
  • the boron mainly serves as a neutron absorber and heats up accordingly.
  • boron is very light, less thermally conductive and less resistant to gamma radiation than many other materials.
  • metals are used as the second additive, which often have a reflective effect on neutron radiation. Therefore, the quantity ratios of the aggregates allow absorption, moderation and reflection of the neutron radiation to be set according to the respective requirements, the density, heat dissipation and gamma absorption being achieved at the same time.
  • a suitable bulk density is achieved by combining the selected additives and a suitable one
  • the respective grain size of the aggregates can be chosen so that the concrete visually the processing and the properties to be achieved, such as. B. moderation and absorption, the highest possible installation flexibility or the most effective shielding effect.
  • the additives preferably have both fine and coarse particles. It has proven to be particularly advantageous that the first, boron-containing additive is more fine-grained than the second, metallic additive, the fine-grained first additive having an average grain diameter of approx. 1 mm and the coarse-grained second additive having an average grain diameter of approx. 7 mm exhibit.
  • the desired shielding effect is preferably achieved with the highest possible proportion of neutron poison in the shielding concrete, which should have a minimum density for shielding the secondary gamma radiation.
  • the radiation protection concrete of the first embodiment is particularly suitable.
  • the desired shielding of gamma radiation is preferably achieved by the highest possible bulk density of the concrete (/ shielding concrete), this AD shielding concrete should have a minimal amount of a neutron poison to shield the residual neutron radiation.
  • the radiation protection concrete of the second embodiment is preferred.
  • the corresponding wall area formed from one of the concretes can be combined in the manner of a layer structure with other shielding layers of the radiation protection jacket each comprising a different concrete mixture.
  • the individual shielding layers differ depending on their composition in the shielding effect achieved. For example, shielding layers can be provided with a lower bulk density and an increased boron content compared to the wall area, in order to obtain a higher protection against neutrons with a longer range.
  • the boron in the first additive is advantageously used in the form of a boron-containing mineral, in particular colemanite containing boron oxide.
  • the boron content in the first additive is at least 20% by weight, preferably between 30 and 50% by weight (calculated as boron oxide).
  • the admixture of cole anit (naturally occurring mineral) with a boron oxide content of up to 41% by weight consequently makes it particularly high
  • iron granules or steel granules are expediently provided as the second metallic additive.
  • the use of steel granulate with a bulk density of up to 7850 kg / m as a coarse-grained material with a grain size of 0.3 mm to 7 mm determines the bulk density of the concrete produced.
  • the selected grain size makes the concrete particularly easy to manufacture and process, even for smaller dimensions of the radiation protection jacket.
  • a third additive in particular barite sand, is preferably used.
  • barite sand which preferably has a grain size of up to 1 mm and is therefore particularly fine-grained.
  • the wall area of the radiation protection jacket is preferably formed from the radiation protection concrete of the first embodiment.
  • This radiation protection concrete is in particular a first concrete that has a minimum cement content between 8 and 9% by weight, a minimum water content (mixing water) between 4.5 and 6.5% by weight, a minimum residual content of the first aggregate ( Colemanite) of at least 7.8% by weight up to the same proportion as the selected proportion of cement, a minimum content of the second aggregate (iron or steel granules) between 30 and 35% by weight and a minimum content of the fourth mineral-containing aggregate ( Serpentine) between 40 and 50 wt .-%.
  • Auxiliaries are not necessary for this first concrete mix.
  • the percentages by weight relate to the sample weight minus the water which can be expelled at 80 ° C.
  • the particularly high proportion of water in the first concrete causes - due to the binding of the mixing water in the form of crystal water - a particularly high deceleration of neutron radiation. This is also reinforced by the colemanite content. In other words, the higher the colemanite and water content, the better this first one will be
  • This first concrete or the radiation protection concrete of one of the two embodiments advantageously has a bulk density of approximately 3000 kg / m 3 .
  • the specified mm minimum density achieved Through the use of iron or steel granules with a certain grain size as the second additive, the specified mm minimum density achieved.
  • the bulk density achieved additionally provides a sufficient shielding effect from the gamma radiation.
  • the crystal water content of the concrete mixture is increased significantly and the bond within the concrete is improved so that it is particularly pressure and splitting tensile. Due to the particularly high proportion of serpentine, the first concrete is referred to below as "serpentine concrete".
  • the third aggregate preferably has a grain size of up to 7 mm. It has proven to be particularly advantageous if the third additive is mixed with two different grain sizes.
  • the minimum content of the third aggregate with a first grain size of up to 3 mm is advantageously between 12 and 16% by weight. With a second grain size between 3 and 7 mm, the minimum content is between 28 and 34% by weight.
  • the specification of the grain size refers to the geometric mean value as it occurs when minerals are crushed or during the corresponding manufacturing process in the bulk material. In particular, however, the specified upper limit can be set by the mesh size of a corresponding sieve.
  • Gamma radiation of the radiation protection jacket, the wall area is preferably formed from the radiation protection concrete of the second embodiment.
  • This radiation protection concrete is in particular a second concrete that has a minimum cement content between 4 and 4.5% by weight, a minimum water content between 1.5 and 2.5% by weight, and a minimum content of the first aggregate (colemanite) between 1 and 1.5% by weight, a minimum content of the second additive (iron or steel granulate) between 85 and 89% by weight, a minimum content of the third additive (barite sand) between 4.5 and 5% by weight and one Has a minimum content of at least one auxiliary from 0.1 to 0.15% by weight.
  • the weight percentages are given on the weight minus the concrete's water which can be expelled at 80 ° C.
  • This second concrete or the radiation protection concrete of one of the two embodiments advantageously has a bulk density of approximately 6000 kg / m 3 .
  • a particularly high bulk density is achieved in particular by using steel granulate with a certain grain size as the second additive, which forms the main component of the concrete.
  • the high bulk density in turn causes a particularly high shielding of the resulting gamma radiation.
  • the concrete has a good absorption property of neutron radiation due to the Colemamt component.
  • the bond within the concrete is improved so that it achieves particularly good compressive and splitting tensile strengths.
  • a flow agent and / or a delaying agent are preferably provided as auxiliary substances.
  • the addition of these auxiliaries depends on the amount of col ⁇ manite added, which has a particularly strong influence on the workability of the second concrete.
  • This second concrete which has iron or steel granules as the main constituent for borderline case b), is referred to as "steel granulate concrete".
  • At least part of the radiation protection jacket comprises a first layer provided with the first concrete (serpentine concrete) and a second layer provided with the second concrete (steel granulate concrete).
  • a radiation protection jacket constructed of concrete in this way is particularly advantageously suitable for indirect and / or direct shielding of a radiation source, X-ray prediction, a room having a radiation source or a radiation channel in a reactor system.
  • the radiation protection jacket is suitable both for the direct shielding of a radiation source in the form of a formwork and for the indirect shielding of a radiation source in a room in the form of a wall or a floor.
  • Darm shows the figure a schematic representation of a radiation protection jacket for the direct shielding of a radiation source.
  • the radiation protection jacket 2 shown in the exemplary embodiment according to the figure and arranged around two beam channels 1 is Part of a radiation source, not shown in detail, for example a reactor core of a nuclear power plant.
  • the two jet channels 1 are, for example, part of a measuring arrangement in the control area of a reactor plant or nuclear power plant.
  • a tank 4 is arranged to shield the reactor core (radiation source), which is not shown. The design of the tank 4 depends on the construction of the system.
  • the reactor basin 6 connects to the tank 4. Depending on the type of system, the tank 4 and the reactor basin 6 can also form a unit.
  • the reactor pool 6 is delimited by a reactor pool wall 8.
  • the two beam channels 1 are arranged in the radiation protection jacket 2 for the controlled removal and guidance of the radiation emanating from the reactor core.
  • the radiation protection jacket 2 is arranged between the tank 4 and the outer wall of the reactor pool wall 8, a casing tube 12, comprising a casing tube 12A, a formwork tube 12B and a compensator tube 12C.
  • the cavity to be filled by the radiation protection jacket 2 is limited by the respective inner wall of the casing tube 12A, the formwork tube 12B, the compensator tube 12C and the inside of a jet tube nose 10 guided in the tank 4.
  • the components or components mentioned are attached to the respective connection piece 16 with fastening elements 14 attached, e.g. screwed.
  • the hollow tube 12 is stepped several times in the axial direction.
  • the tubes forming the casing tube 12 - the casing tube 12A, the switching tube 12B, the compensator tube 12C - have a correspondingly increasing diameter.
  • the casing tube 12, also called the formwork tube, can consist of one element, e.g. Casting element, or consist of several tubes or sub-elements.
  • the outer tube 12 After installation of the radiation protection jacket 2 m, the outer tube 12 is closed on the side of the lining case 12A by means of an / end plate 18. To shield the (laterally scattering) neutron and gamma radiation emerging from the two beam channels 1, the two beam channels 1 are completely enveloped by a metal jacket 19 in cross section.
  • the metal jacket 19 is preferably formed from a rustproof ferritic material and causes the least possible self-activation of the radiation protection jacket 2 arranged subsequently in cross section.
  • the thickness of the metal jacket 19 is determined by the static and dynamic loading of the radiation protection jacket 2.
  • this is divided into a number of wall areas 2a to 2z, each of which completely surrounds the two radiation channels 1 and each of which consists of a radiation protection concrete or concrete 22a to which contains different amounts of additives and thus has different raw densities 22z are formed.
  • the thickness of the wall area 2a to 2z is determined by the respective diameter of the individual elements of the hollow tube 12. Both the number and the respective thickness as well as the respective chemical composition and the respective bulk density of the wall areas 2a to 2z is determined by pre-dimensioning as required.
  • the concretes 22a to 22z forming the wall regions 2a to 2z can thus vary.
  • the concrete 22a to 22z belonging to a wall area 2a to 2z has corresponding proportions of a first boron-containing aggregate with a grain size of up to 1 mm and a second metallic aggregate with a grain size of up to 7 mm.
  • the first fine-grain aggregate is a boron-containing mineral, e.g. B. colemanite.
  • the second aggregate known as coarse-grained because of its grain size, is preferably iron granulate or steel granulate.
  • the proportions of the first and second aggregate for the concrete 22a to 22z are largely determined by the shielding properties to be achieved, in particular gamma absorption and absorption and moderation of neutrons, of the radiation protection jacket 2 in the associated wall area 2a to 2z.
  • the concrete 22a primary that forms the wall region 2a closest to the radiation source, the reactor core is suitable for absorbing neutron radiation due to its high proportion of the first mineral-containing additive - colemanite.
  • the first concrete 22a has a minimum cement content between 8 and 9% by weight, a minimum water content (mixing water) between 4.5 and 6.5% by weight, a minimum content of the first aggregate (colemanite) of 7. 8% by weight up to the weight fraction of cement, a minimum content of the second aggregate (iron or steel granulate) between 30 and 35% by weight and a minimum content of a fourth mineral-containing aggregate (serpentine) between 40 and 50% by weight . Due to the low proportion of the second aggregate - iron or steel granulate - this concrete 22a is only suitable for absorbing the gamma radiation. When set, the first concrete 22a has a minimum bulk density of up to 3000 kg / m.
  • serpentine is used as the fourth, mineral-containing additive.
  • the minimum serpentine content for a first grain size up to 3 mm is between 12 and 16% by weight.
  • the minimum content is between 28 and 34% by weight.
  • This first concrete 22a, which has serpentine as its main component, is called Serpentine concrete, and is particularly pressure and splitting tensile.
  • the wall region 2b which is seen as a second layer from the radiation source, is formed from a second concrete 22b having a different chemical composition than the first concrete 22a.
  • the second concrete 22b forming the second wall region 2b preferably has a minimum content of cement between 4 and 4.5% by weight, a minimum content of water (mixing water) between 1.5 and 2.5% by weight, a minimum content of the first Aggregate (colemanite) between 1 and 1.5 wt .-%, a minimum content of the second aggregate (iron or steel granules) between 85 and 89 wt .-%, a minimum content of a third, in particular metallic, aggregate (barite sand) between 4 , 5 and 5 wt .-% and a minimum content of at least one auxiliary from 0.1 to 0.15 wt .-%.
  • this composition of the second concrete 22b is preferably suitable for a particularly high shielding of the gamma radiation and, due to the colemanite portion, for a lower absorption and moderation of the neutron radiation emanating from the radiation source than the first concrete 22a.
  • a flow agent or a delaying agent is provided as an auxiliary.
  • Such a second concrete 22b formed from the above-mentioned proportions of cement, water, aggregates and auxiliary materials has a bulk density in the set state of up to 6000 kg / m ". This bulk density largely determines the particularly high shielding of the gamma radiation.
  • alumina cement based on calcium alumates is used in particular as cement.
  • the crystal water effects a particularly good deceleration of the neutron radiation.
  • the addition of colemanite with a boron oxide content of up to 41 mass * also achieves a particularly high absorption of thermal neutrons.
  • the two-layer arrangement has proven to be particularly advantageous, since in the first wall area 2a of the radiation protection jacket 2 the fast neutrons emerging from the radiation source and not the two beam channels 1 are moderated particularly well by the high proportion of colemanite in the first concrete 22a be absorbed.
  • a shielding of a considerable proportion of gamma radiation is already achieved.
  • the neutrons emerging laterally from the beam channels 1 due to scattered radiation due to the proportion of the first aggregate (colemanite) analogously to first concrete 22a are moderated and absorbed.
  • further wall areas 2c to 2z can be filled with further suitably chosen concrete 22c to 22z.
  • this has special shielding properties or effects.
  • the bulk density of the concrete 22a can be changed by changing the proportion of the iron or steel granulate can be set to 22z.
  • the boron content of the respective concrete 22a to 22z can be adjusted by changing the content of colemanite.
  • the use of concrete 22a to 22z for certain layers or wall areas 2a to 2z of the radiation protection jacket 2 enables the radiation source to be completely enveloped and thus a particularly high shielding effect of the radiation source even with difficult and complex geometries or constructions.
  • the concrete 22a to 22z enables formwork, e.g. m the hollow tube 12 that cavities are also closed.
  • the wall area 2a of the radiation protection jacket 2 can be designed as a formwork, a wall or em floor of a room or a building.
  • B. is an X-ray device or another radiation source.
  • the table on the description page 20 shows the components which are important for the two limit cases a) and b) described above and for the shielding properties of the first concrete 22a (serpentine concrete) and the second concrete 22b (steel granulate concrete) to be achieved, particularly advantageous minimum and maximum limits.
  • the minimum and maximum limits for the particular grain size of the granulated constituents, which are determined to be particularly advantageous for a particularly simple production and processing of the two concretes 22a and 22b, are also specified. Further mixing ratios between the two concrete mixtures are also possible.
  • the radiation protection jacket 2 em Due to the highly effective radiation shielding provided by the respective composition of the concretes 22a and 22b to 22z, the radiation protection jacket 2 em has particularly good behavior both with regard to self-activation and thermal influences and with regard to absorption and moderation of neutrons and shielding of gamma radiation.
  • the radiation protection jacket 2 is therefore particularly suitable for direct use in radiation sources, for. B. in radiation pipes from research facilities, on the P ⁇ markniklauf a reactor system, etc.
  • the radiation protection jacket 2 can be carried out on the one hand over a large area and in one layer, for example in the form of walls, floors and ceilings.
  • the radiation protection jacket 2 can be constructed from a plurality of layers or wall regions 2a to 2z, each of which has different shielding properties.
  • the radiation shielding structure of the radiation protection jacket 2, which is particularly radiation-shielding, also excludes any significant radiation exposure of the operating personnel.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Plasma & Fusion (AREA)
  • Civil Engineering (AREA)
  • Particle Accelerators (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Building Environments (AREA)
  • Buildings Adapted To Withstand Abnormal External Influences (AREA)
  • Powder Metallurgy (AREA)
  • X-Ray Techniques (AREA)

Abstract

Afin d'obtenir un effet d'écran maximal, absorbant la chaleur et les rayonnements, une enveloppe (1) de protection contre les radiations présente une zone de paroi (2a à 2z) constituée d'un béton (22a à 22z) de protection contre les radiations, qui comprend un premier agrégat renfermant du bore, présentant une grosseur de grain d'au maximum 1 mm, et un deuxième agrégat métallique, présentant une grosseur de grain d'au maximum 7 mm. Dans un premier mode de réalisation de l'invention, la teneur en premier agrégat renfermant du bore, du béton (22a) de protection contre les radiations s'élève à au moins 5,0 % en poids, en particulier au moins 7,8 % en poids. Le béton (22b) de protection contre les radiations présente, dans un deuxième mode de réalisation de l'invention, une teneur en deuxième agrégat métallique comprise entre 80 et 90 % en poids, en particulier entre 85 et 89 % en poids. La teneur en premier agrégat renfermant du bore peut alors se situer dans une plage comprise entre 1,0 et 1,5 % en poids.
EP99952354A 1998-08-21 1999-08-11 Beton et enveloppe de protection contre les radiations Withdrawn EP1105357A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19838134 1998-08-21
DE19838134 1998-08-21
PCT/DE1999/002499 WO2000010935A2 (fr) 1998-08-21 1999-08-11 Beton et enveloppe de protection contre les radiations

Publications (1)

Publication Number Publication Date
EP1105357A2 true EP1105357A2 (fr) 2001-06-13

Family

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Family Applications (1)

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EP99952354A Withdrawn EP1105357A2 (fr) 1998-08-21 1999-08-11 Beton et enveloppe de protection contre les radiations

Country Status (12)

Country Link
US (1) US6630683B2 (fr)
EP (1) EP1105357A2 (fr)
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Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9913188A (pt) * 1998-08-21 2001-05-15 Siemens Ag Concreto protetor de radiação e invólucro protetor de radiação
US6565647B1 (en) 2002-06-13 2003-05-20 Shieldcrete Ltd. Cementitious shotcrete composition
JP4369135B2 (ja) * 2002-07-18 2009-11-18 株式会社神戸製鋼所 組成物、硬化体、コンクリートキャスク、および硬化体の製造方法
FR2850965B1 (fr) * 2003-02-06 2005-04-22 Bouygues Travaux Publics Compositions cimentaires durcissables et applications aux ecrans radiologiques et aux conteneurs de dechets radioactifs
JP2006038467A (ja) * 2004-07-22 2006-02-09 Kumagai Gumi Co Ltd 低放射化コンクリート組成物
KR100910260B1 (ko) * 2004-10-30 2009-08-04 박영웅 저에너지의 방사선 차폐를 수단으로 하는 차폐성능보강방법
US20070102672A1 (en) 2004-12-06 2007-05-10 Hamilton Judd D Ceramic radiation shielding material and method of preparation
CN1303614C (zh) * 2004-12-17 2007-03-07 清华大学 核反应堆实验孔道屏蔽用无轴旋转闸门
ES2618313T3 (es) * 2006-04-25 2017-06-21 Jan Forster Cuerpo estructural para construcciones de protección contra la radiación
JP2008157801A (ja) * 2006-12-25 2008-07-10 Fujita Corp 中性子遮蔽低放射化コンクリートおよびモルタル
CN100999401A (zh) * 2006-12-28 2007-07-18 吕迎智 一种减弱质子辐射强度的防护工程混凝土
US20080203331A1 (en) * 2007-02-12 2008-08-28 Murphy Brent D Mobile radiation treatment facility
ES2322532B1 (es) * 2007-12-21 2010-04-16 Construcciones Tecnicas De Radioterapia S.L. Masa pesada para la ejecucion de barreras de radioproteccion en el ambito de los rayos x.
ES2344290B1 (es) * 2009-02-20 2011-06-17 Construcciones Tecnicas De Radioterapia, S.L Masa para la fabricacion de productos con alta capacidad de radio-proteccion neutronica.
JP5259515B2 (ja) * 2009-07-28 2013-08-07 株式会社東芝 中性子遮蔽材、その製造方法および使用済み燃料用キャスク
US8450707B1 (en) * 2011-03-22 2013-05-28 Jefferson Science Associates, Llc Thermal neutron shield and method of manufacture
US8664630B1 (en) * 2011-03-22 2014-03-04 Jefferson Science Associates, Llc Thermal neutron shield and method of manufacture
ES2395661B1 (es) * 2011-07-08 2014-02-13 Arraela, S.L. Material para la absorción y atenuacion de neutrones.
CN102898081A (zh) * 2012-10-08 2013-01-30 中国核工业华兴建设有限公司 一种用于射线防护结构的混凝土及制备方法
KR101688646B1 (ko) 2014-12-02 2016-12-22 한국과학기술원 고준위 중성자 차폐를 위한 이중 차폐 콘크리트 및 그 제조방법
WO2016202291A1 (fr) * 2015-06-19 2016-12-22 南京中硼联康医疗科技有限公司 Matériau de blindage pour assurer un blindage contre un rayon radioactif et procédé de préparation de celui-ci
US10074449B2 (en) * 2016-06-21 2018-09-11 Raytheon Company Additively manufactured concrete-bearing radiation attenuation structure
RU2648253C1 (ru) * 2016-10-31 2018-03-23 Федеральное Государственное Бюджетное Образовательное Учреждение Высшего Образования "Сибирский Государственный Университет Водного Транспорта" (Фгбоу Во "Сгувт") Электропроводная композиция для защиты от техногенных излучений
CN110785820B (zh) * 2017-06-23 2023-09-05 澳洲快索有限公司 屏蔽x射线辐射装置
DE102017006902A1 (de) * 2017-07-20 2019-01-24 Theodor Pieper GmbH & Co. KG Betonzusammensetzung und Verfahren zum Herstellen einer solchen Betonzusammensetzung
CN108098976B (zh) * 2017-12-14 2019-06-07 东莞理工学院 一种中子防辐射多层混凝土块的注浆成型机构
EP3781533A2 (fr) 2018-04-18 2021-02-24 Fibrobeton Yapi Elemanlari Sanayi Insaat Ve Ticaret Anonim Sirketi Bétons renforcés de fibres étanches imperméables aux rayonnements et étanches au gaz radon
HU231202B1 (hu) * 2018-05-09 2021-10-28 Mirrotron Kft. Betonfal neutronsugárzás elnyelésére, valamint eljárás ilyen betonfal előállítására
CN110870951A (zh) * 2018-08-31 2020-03-10 中硼(厦门)医疗器械有限公司 中子捕获治疗***
CN110870950A (zh) * 2018-08-31 2020-03-10 中硼(厦门)医疗器械有限公司 中子捕获治疗***
CN109320159A (zh) * 2018-10-16 2019-02-12 成都宏基建材股份有限公司 一种低热微膨胀水泥基防辐射混凝土及其制备方法
CN109133803A (zh) * 2018-10-16 2019-01-04 成都宏基建材股份有限公司 一种c40普通硅酸盐水泥基防辐射混凝土及其制备方法
CN109231932A (zh) * 2018-10-16 2019-01-18 成都宏基建材股份有限公司 一种铝酸钡水泥基防辐射混凝土及其制备方法
CN109231933A (zh) * 2018-10-16 2019-01-18 成都宏基建材股份有限公司 一种防辐射混凝土及其制备方法
CN109231931A (zh) * 2018-10-16 2019-01-18 成都宏基建材股份有限公司 一种铝酸钙水泥基防辐射混凝土及其制备方法
CN109231934A (zh) * 2018-10-16 2019-01-18 成都宏基建材股份有限公司 一种快硬硫铝酸钙水泥基防辐射混凝土及其制备方法
CN109320172A (zh) * 2018-10-16 2019-02-12 成都宏基建材股份有限公司 一种快凝快硬氟铝酸钙水泥基防辐射混凝土及其制备方法
CN109231920A (zh) * 2018-10-16 2019-01-18 成都宏基建材股份有限公司 一种c20普通硅酸盐水泥基防辐射混凝土及其制备方法
CN109336496A (zh) * 2018-10-16 2019-02-15 成都宏基建材股份有限公司 一种普通硅酸盐水泥基防辐射混凝土及其制备方法
CN111933322B (zh) * 2020-08-13 2022-11-22 中国核动力研究设计院 一种耐高温中子屏蔽组件及其制备方法
CN112250386A (zh) * 2020-10-26 2021-01-22 华北水利水电大学 一种防辐射超高性能混凝土及其制备方法
CN112557335B (zh) * 2020-11-30 2024-02-02 四川中核艾瑞特工程检测有限公司 一种防辐射混凝土有效屏蔽元素检测方法
CN113121171A (zh) * 2021-04-20 2021-07-16 中国一冶集团有限公司 防辐射自密实混凝土及其制备方法
CN113539535B (zh) * 2021-07-06 2024-04-19 散裂中子源科学中心 中子屏蔽件及其制造方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR475831A (fr) * 1914-07-30 1915-06-17 Charles Van Woumen Controleur d'entrée et de sortie du personnel
GB1105957A (en) * 1964-11-27 1968-03-13 English Electric Co Ltd Radiation shielding materials
US4437013A (en) * 1981-07-06 1984-03-13 The United States Of America As Represented By The Department Of Energy Neutron and gamma radiation shielding material, structure, and process of making structure
FR2534733A1 (fr) * 1982-10-15 1984-04-20 Commissariat Energie Atomique Materiau neutrophage contenant du bore et son procede de fabrication
SE8307035L (sv) * 1983-12-20 1985-06-21 Asea Atom Ab Sett att tillverka en absorbatorplatta for en kokarvattenreaktor
DE8410248U1 (de) 1984-04-03 1984-08-30 Vahlbrauk, Karl Heinz, 3353 Bad Gandersheim Abflussrohrleitung
RO92538B1 (ro) * 1985-06-14 1987-12-31 INSTITUTUL DE CERCETARI îN CONSTRUCTII SI ECONOMIA CONSTRUCTIILOR Beton foarte greu de protectie contra radiatiilor nucleare
US4727257A (en) * 1986-01-22 1988-02-23 Sergio Grifoni Shield against radiations
JPS62180294A (ja) * 1986-01-30 1987-08-07 セルジオ・グリフオニ 放射能に対する遮蔽体
FR2597654B1 (fr) * 1986-04-16 1989-06-30 Aerospatiale Gainage de protection de conducteurs electriques ou optiques, durci vis-a-vis des rayons x
FR2597652B1 (fr) * 1986-04-16 1988-07-29 Aerospatiale Boitier de protection de circuits electroniques, durci vis-a-vis des rayons x
JPS6481846A (en) * 1987-09-24 1989-03-28 Hitachi Chemical Co Ltd Phenolic resin molding material
DE3821684A1 (de) 1988-06-28 1990-02-08 Martin Dr Westarp Baustoff zur herstellung von schutzraumbauten
US5416333A (en) * 1993-06-03 1995-05-16 Greenspan; Ehud Medium density hydrogenous materials for shielding against nuclear radiation
BR9913188A (pt) * 1998-08-21 2001-05-15 Siemens Ag Concreto protetor de radiação e invólucro protetor de radiação

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0010935A2 *

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TW464878B (en) 2001-11-21
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JP3699650B2 (ja) 2005-09-28
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KR20010079675A (ko) 2001-08-22
CA2341206A1 (fr) 2000-03-02
WO2000010935A2 (fr) 2000-03-02
US6630683B2 (en) 2003-10-07
JP2002526746A (ja) 2002-08-20
US20020134951A1 (en) 2002-09-26
AR021779A1 (es) 2002-08-07
CZ2001618A3 (cs) 2002-03-13
BR9913188A (pt) 2001-05-15
CN1314874A (zh) 2001-09-26
AU756455B2 (en) 2003-01-16

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