EP1021684A1 - Verfahren und vorrichtung zur überwachung einer flamme - Google Patents
Verfahren und vorrichtung zur überwachung einer flammeInfo
- Publication number
- EP1021684A1 EP1021684A1 EP98950111A EP98950111A EP1021684A1 EP 1021684 A1 EP1021684 A1 EP 1021684A1 EP 98950111 A EP98950111 A EP 98950111A EP 98950111 A EP98950111 A EP 98950111A EP 1021684 A1 EP1021684 A1 EP 1021684A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- signal
- flame
- evaluation circuit
- output
- monitoring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N5/00—Systems for controlling combustion
- F23N5/02—Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium
- F23N5/12—Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium using ionisation-sensitive elements, i.e. flame rods
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N5/00—Systems for controlling combustion
- F23N5/02—Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium
- F23N5/12—Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium using ionisation-sensitive elements, i.e. flame rods
- F23N5/123—Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium using ionisation-sensitive elements, i.e. flame rods using electronic means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N2231/00—Fail safe
- F23N2231/10—Fail safe for component failures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N5/00—Systems for controlling combustion
- F23N5/02—Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium
- F23N5/08—Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium using light-sensitive elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N5/00—Systems for controlling combustion
- F23N5/24—Preventing development of abnormal or undesired conditions, i.e. safety arrangements
Definitions
- the invention relates to a method for monitoring a flame of a gas or oil burner according to the preamble of claim 1 and a device for monitoring this flame according to the preamble of claim 10.
- Flame monitors are often used to monitor gas flames, which take advantage of the rectifier effect of the flame and which therefore work according to the so-called ionization principle.
- An AC voltage is applied between two electrodes.
- the volume that the flame fills depends on the instantaneous power of the burner.
- the achievable direct current can be very low when the burner output is low and the geometry of the electrodes is not optimal, while the alternating current can be considerably larger depending on the capacitance of the sensor line.
- the flame signal amplifier must therefore be able to filter out the small proportion of direct current in the entire sensor circuit current without the alternating current entering the amplifier input as a result of the inevitable rectifier effects
- the level of the direct current component therefore gives a measure of the intensity of the flame, the absence of a flame corresponding to zero intensity, the detection of which must be determined reliably and promptly in order to prevent unburned gas or oil from escaping into the burner chamber.
- the filtering of the direct current component can be accomplished by an evaluation circuit upstream of the flame signal amplifier, such as, for example, a low-pass filter with a sufficiently low cut-off frequency.
- an evaluation circuit upstream of the flame signal amplifier such as, for example, a low-pass filter with a sufficiently low cut-off frequency.
- the filter property of the low pass goes e.g. B. lost due to a failure of a filter capacitor, the alternating current could pretend the presence of the flame even if it is not present.
- This faulty behavior must be recognized by the flame monitoring or burner control system. This is normally not a problem for burners in intermittent operation because after switching off the fuel supply, which leads to the flame being extinguished, the control system can recognize a pretended flame signal as faulty and prevent the burner from being restarted. This must be the case with burners in continuous operation
- Misconduct can be detected by periodically checking the flame guard without the burner may be put out of operation. In the case of optical flame sensors, this is usually done by interrupting the beam path between the flame and the sensor by means of an aperture, ie a flame failure is briefly simulated during operation, to which the output of the flame signal amplifier must react accordingly.
- the method of signal interruption on the flame sensor can also be used for ionization flame monitoring.
- the ionization circuit is interrupted by means of a suitable switching element.
- this element would have to be attached close to the sensor electrode so that only the flame signal current and not also the alternating current flowing over line capacitances is interrupted, the flame-pretending effect of which should be recognized by the test in the event of a component failure. It would also be conceivable to short-circuit the flame signal lines, as a result of which the flame signal current also becomes zero and the alternating current is even increased.
- a switching element would have to be used which is suitable for the high sensor AC voltage and which itself cannot adopt an error mechanism that leads to undetected flame simulation.
- EP 159 748 discloses a circuit which suggests a high sensitivity if the capacitive load current at the sensor connections caused by line capacitances remains low in relation to the flame signal current. In this respect, this circuit does not meet the requirements for high sensitivity and, at the same time, high resistance to line capacitance. Another requirement that is frequently asked is the display of the flame intensity as a setting aid when starting up a burner and for the timely detection of changes in the flame during operation. The circuit disclosed in EP 159 748 does not offer this possibility.
- EP 0 617 234 also discloses an ionization flame monitor with a circuit arrangement which has a capacitance which is converted by the ionization current from a state charged by the operating voltage to a discharged state, the signal "flame present" being output when a certain threshold is undershot .
- the function of the capacitance can be checked using a test signal.
- the object of the present invention is therefore to specify a method or a device for monitoring a flame, which is used as a flame monitoring method or
- the response sensitivity is significantly improved compared to the prior art, without reducing the compatibility for line capacity, the shutdown ability can be checked periodically during burner operation, as well as provides an output signal that represents a measure of the flame intensity.
- the procedure is also intended to ensure that the monitoring is continuously checked.
- the method according to the invention for monitoring a flame makes use of the known principle that, depending on the presence or intensity of the flame, a second electrical signal (eg DC signal) (I F ) of different size is generated from a first electrical signal (e.g. AC voltage signal). is produced.
- a second electrical signal e.g DC signal
- I F first electrical signal
- ionization electrodes or ultraviolet sensors with a diode connected in series are used, for example, which deliver a corresponding DC signal depending on the intensity of the flame. When the flame goes out, no DC signal is generated.
- the second electrical signal (I F ) is detected by an evaluation circuit, to which the ionization electrodes or the ultraviolet sensors are connected, and converted into a first output signal (A), the conversion being carried out by various further circuit elements in such a way that, depending on the flame intensity, varies dynamic output signals can be obtained.
- the output signal (A) is therefore an output signal which changes in its dynamics when the intensities of the flame change.
- An electrical monitoring signal (alternating voltage signal) is also applied to the evaluation circuit, which can be derived, for example, from the alternating voltage signal made available to the ionization electrodes, which leads to a second output signal (A A ) if the evaluation circuit fails.
- this second output signal is advantageously a static one, so that the monitoring device immediately detects the failure of the evaluation circuit and can cause the fuel supply to be switched off.
- the second electrical signal (I F ) is converted into a control signal (S) and passed on to a flip-flop.
- This flip-flop can, for example. be an operational amplifier, which compares the control signal with a certain threshold and then resets the evaluation circuit via a reset signal (R), so that it can control the flip-flop again.
- the output of the flip-flop is switched between two output signals (Ai, A) depending on the control signal (S).
- the flip-flop switches back and forth at different speeds.
- the control signal (S) can also be conducted via a further evaluation circuit in order to determine the sensitivity of the circuit to the second electrical signal, that is to say, for example. across from to improve the direct current component in the sensor current.
- a further evaluation circuit in order to check this second evaluation circuit, ie to detect a failure, its circuit is connected to the control input of an integrator designed as a charge pump, the output signal of which corresponds to the level of the second electrical signal, such as, for example. of the sensor current reflects.
- a monitoring circuit is used to detect a failure of the first evaluation circuit, which is connected to the monitoring signal via the evaluation circuit, that is to say, for example. an AC voltage signal is applied so that if the evaluation circuit fails, the monitoring circuit is deactivated and this leads to a static output signal (A A ). The output signal of the integrator becomes zero if the second evaluation circuit fails.
- FIG. 1 shows a schematic representation of the flame monitoring circuit
- FIG. 2 shows a block diagram of the flame monitoring circuit
- FIG. 3 shows a detailed circuit diagram of the flame monitoring circuit
- FIG. 4 shows a further development of the flame monitoring circuit
- FIG. 5 shows three time diagrams of the DC signal, the failure test and the
- Ionization electrodes 3 or ultraviolet sensors 4, 4a are fed via a connection terminal 1 with the AC voltage signal from a corresponding source 5 and deliver this from
- evaluation circuit 6 fails, no signal is forwarded to the monitoring circuit 7, so that the flip-flop 9 is transferred to another, static state which interrupts the further message of the flame intensity (output signal A) and then has the output signal A A.
- the failure of the evaluation circuit 6 can thus easily be detected.
- a test signal T can be applied to a switch 11 which simulates the failure of the evaluation circuit 6.
- the circuit for failure detection of the evaluation circuit 6 can in turn be checked, in particular the charge pump and the flip-flop 9.
- FIGS. 2 and 3 show a block diagram or a detailed circuit diagram of a flame monitoring circuit according to the invention.
- the components are shown with the usual symbols and with the usual names.
- the exact wiring is not explained in detail here, it can be seen in FIGS. 2 and 3.
- the flame monitoring circuit is fed bipolar from two operating voltages + Ubl and -Ub2 defined in relation to a reference potential m. It has two connections 1 and 2, either with two ionization electrodes 3 or with the two connections one
- Ultraviolet sensor can be connected, which consists of a gas-filled ultraviolet cell 4 and a diode 4a connected to it in series.
- the first connection 1 serves as an output, which carries an alternating voltage generated by an alternating voltage generator 5 and defined with respect to the reference potential m.
- the second connection 2 serves as an input to which the actual sensor signal is fed.
- the second connection 2 is followed by a first low-pass filter 6 formed from a resistor R1 and a capacitor C1.
- the AC voltage generated by the AC voltage generator 5 is conducted via a limiting resistor R3 and a coupling capacitor C3 to the capacitor C1 and further to the input of a charge pump.
- the signal at the output of the charge pump is conducted via a voltage divider 8 connected to the positive operating voltage to the non-inverting input of an operational amplifier 9 connected as a Schmitt trigger.
- the inverting input of the operational amplifier 9 is connected to the output of the low pass 6.
- the output of the operational amplifier 9 controls a switch 10, via which the Capacitor Cl can be discharged.
- the AC voltage acting on the capacitor C1 which in the example is derived from the AC voltage generated by the AC voltage generator 5, could also be generated by a second AC voltage generator.
- the flame monitoring circuit works as follows: As long as the capacitor C1 is intact, the charge pump 7 has an approximately constant, negative potential Ucs at its output, the absolute value of which is approximately 75-80% of the positive supply voltage + Ubl.
- the resistors R7 and R8 of the voltage divider 8 are dimensioned such that the voltage applied to the non-inverting input of the operational amplifier 9 is then also negative.
- the output of the operational amplifier 9 initially carries the negative operating voltage -Ub2, so that the switch 10 designed as a junction field effect transistor T2 is open. As soon as the flame is present, the direct current flowing between the ionization electrodes 3 or the photocurrent of the ultraviolet sensor 4 charges the capacitor C1, the potential of which becomes increasingly more negative.
- the voltage at the inverting input of the operational amplifier 9 also drops to an increasingly negative potential.
- the output of the operational amplifier 9 carries the positive supply voltage + Ubl, the switch 10 closes and the capacitor C1 begins to discharge. Because of the resistors R5 and R6, the
- Operational amplifier 9 has a certain switching hysteresis, so that the capacitor C1 is partially discharged. If the discharge of the capacitor C1 has progressed sufficiently far, the output of the operational amplifier 9 switches over again and again leads the negative one Supply voltage -Ub2. The game starts over.
- the signal at the output of the operational amplifier 9 is a rectangular signal. Its frequency represents a measure of the intensity of the flame, since the strength of the direct current flowing between the ionization electrodes 3 determines the time it takes to charge the capacitor C1 until the operational amplifier 9 switches over again.
- An interruption of the capacitor C1 leads to the transistor T1 of the charge pump 7 continuously blocking and the charge pump 7 therefore being out of operation.
- the capacitor C5 is charged to the positive supply voltage Ubl, so that the output of the charge pump 7 and the output of the operational amplifier 9 carry a static signal.
- a short circuit of the capacitor C1 causes the charge pump 7 to remain in operation, but the amplitude of the voltage at the inverting input of the operational amplifier 9 remains sufficiently small with respect to the voltage present at the non-inverting input, so that the output of the operational amplifier 9 is again a static one Signal leads.
- the amplitude of the AC voltage generated by the AC voltage generator 5, the resistor R3 and the capacitors C1 and C3 must be matched to one another in such a way that the amplitude of the AC voltage applied to the capacitor C3 and thus also to the inverting input of the operational amplifier 9 is insufficient switched as a Schmitt trigger
- the flame monitoring circuit can be checked whenever the burner is switched off to ensure that no "flame present" signal appears at the output.
- a second switch 11 is provided, with which the input of the charge pump 7 can be connected to the reference potential m. If the switch 11 is closed, then the information "flame not present" must appear at the output of the flame monitoring circuit and / or downstream circuits.
- the switch 11 is preferably controlled by a microprocessor.
- the switch 11 shown in FIG. 3 is an optocoupler controlled via two inputs, which enables galvanically isolated control.
- FIG. 4 shows a further development of the flame monitoring circuit, in which a second low-pass filter 19, formed from a resistor R2 and a capacitor C2, is connected between the capacitor C1 and the input of the operational amplifier 9.
- the switch 10 controls the discharge of the capacitor C2.
- the capacitor C2 must be monitored for a possible interruption in the same way as the capacitor C1.
- the capacitor C2 is therefore connected to the input of an integrator 20, at the output of which there is a DC voltage, the level of which is a measure of the flame intensity.
- the integrator 20 is designed as a charge pump.
- the capacitor C7 is recharged according to the frequency of the charge / discharge cycles of the capacitor C2 via the capacitor C6. The frequency is determined by the sensor current.
- the voltage across the capacitor C7 assumes the value of the reference potential m, which is equivalent to "flame not present".
- the voltage at capacitor C7 is digitized, for example, by means of a voltage / frequency converter and galvanically isolated to an overriding device, e.g. an automatic burner control.
- the advantage of this circuit is that the low-pass filter 19 dampens the AC voltage generated by the AC voltage generator 5 in such a way that a substantially larger ratio between the AC current caused by the sensor line capacitances and the ionization current can be accepted.
- the capacitor C1 of the low pass charges up and, after a certain charging time, causes the flip-flop 9 to switch over.
- the changeover time t u is approximately constant, so that a certain frequency fi is established, which is a measure of the intensity of the flame.
- Each of the frequencies is therefore assigned to one of the direct current signals Ipi, I F2 or I F3 .
- test signal T which is applied between times t 7 and t 8 , can be seen in the middle of the diagrams. If the charge pump 7 is functioning, this leads to a determination of the potential of an input of the amplifier, so that there is no longer a switchover if the trigger circuit is functioning. This can be seen in the output signal diagram between the corresponding times with a small time delay. This output signal A A therefore indicates that the circuit is intact, ie the circuit can also be tested when the burner is operating continuously. Without test signal T, signal A A signals the absence of the flame.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Control Of Combustion (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98950111A EP1021684B1 (de) | 1997-10-10 | 1998-10-08 | Verfahren und vorrichtung zur überwachung einer flamme |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97117731 | 1997-10-10 | ||
EP97117731A EP0908679A1 (de) | 1997-10-10 | 1997-10-10 | Flammenüberwachungsschaltung |
EP98950111A EP1021684B1 (de) | 1997-10-10 | 1998-10-08 | Verfahren und vorrichtung zur überwachung einer flamme |
PCT/EP1998/006392 WO1999019672A1 (de) | 1997-10-10 | 1998-10-08 | Verfahren und vorrichtung zur überwachung einer flamme |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1021684A1 true EP1021684A1 (de) | 2000-07-26 |
EP1021684B1 EP1021684B1 (de) | 2003-02-12 |
Family
ID=8227475
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97117731A Withdrawn EP0908679A1 (de) | 1997-10-10 | 1997-10-10 | Flammenüberwachungsschaltung |
EP98950111A Expired - Lifetime EP1021684B1 (de) | 1997-10-10 | 1998-10-08 | Verfahren und vorrichtung zur überwachung einer flamme |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97117731A Withdrawn EP0908679A1 (de) | 1997-10-10 | 1997-10-10 | Flammenüberwachungsschaltung |
Country Status (8)
Country | Link |
---|---|
US (1) | US6501383B1 (de) |
EP (2) | EP0908679A1 (de) |
JP (1) | JP4124962B2 (de) |
KR (1) | KR20010030982A (de) |
AU (1) | AU742228B2 (de) |
DE (1) | DE59807206D1 (de) |
DK (1) | DK1021684T3 (de) |
WO (1) | WO1999019672A1 (de) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2367172B (en) * | 2000-04-26 | 2004-02-18 | Pektron Group Ltd | Detection apparatus and a method of detection |
DE10023273A1 (de) * | 2000-05-12 | 2001-11-15 | Siemens Building Tech Ag | Messeinrichtung für eine Flamme |
DE10150819A1 (de) * | 2001-10-15 | 2003-04-17 | Dometic Gmbh | Energiebetriebsvorrichtung |
DE10312669B3 (de) * | 2003-03-21 | 2004-10-21 | Honeywell B.V. | Schaltungsanordnung zur Ermittlung des Flammenstromes eines Brenners |
DE10324315A1 (de) * | 2003-05-27 | 2004-12-16 | Siemens Building Technologies Ag | Verfahren zur Überwachung der Qualität eines von einem Reformer für den Betrieb von Brennstoffzellen gelieferten Gasgemisches |
KR100810006B1 (ko) * | 2004-02-06 | 2008-03-07 | 오중산 | 대두 발효 추출물 및 이를 함유하는 화장료 조성물 |
WO2005111556A2 (en) * | 2004-05-07 | 2005-11-24 | Walter Kidde Portable Equipment, Inc. | Flame detector with uv sensor |
EP1719947B1 (de) | 2005-05-06 | 2010-04-14 | Siemens Building Technologies HVAC Products GmbH | Verfahren und Vorrichtung zur Flammenüberwachung |
DE102007018122B4 (de) * | 2007-04-16 | 2013-10-17 | Viessmann Werke Gmbh & Co Kg | Flammenüberwachungsvorrichtung mit einer Spannungserzeugungs- und Messanordnung und Verfahren zum Überwachen eines Brenners mittels der Flammenüberwachungsvorrichtung |
PL2265867T3 (pl) * | 2008-03-07 | 2019-04-30 | Bertelli & Partners Srl | Ulepszony sposób i urządzenie do wykrywania płomienia w palniku działającym na paliwie stałym, płynnym lub gazowym |
CN101614586B (zh) * | 2009-07-21 | 2011-03-30 | 深圳和而泰智能控制股份有限公司 | 一种离子火焰检测装置及其设备 |
US8446204B2 (en) * | 2011-01-27 | 2013-05-21 | Qualcomm Incorporated | High voltage tolerant receiver |
US8680891B2 (en) | 2011-01-27 | 2014-03-25 | Qualcomm Incorporated | High voltage tolerant differential receiver |
ES2536128T3 (es) * | 2011-03-03 | 2015-05-20 | Siemens Aktiengesellschaft | Instalación de quemador |
US9784449B2 (en) * | 2014-05-30 | 2017-10-10 | Jed Margolin | Flame sensing system |
DE102015210507A1 (de) * | 2015-06-09 | 2016-12-15 | Vaillant Gmbh | Flammenüberwachung |
US10890326B2 (en) * | 2016-10-31 | 2021-01-12 | Robertshaw Controls Company | Flame rectification circuit using operational amplifier |
PL3663646T3 (pl) | 2018-12-06 | 2021-09-27 | Siemens Aktiengesellschaft | System sterowania monitorowaniem płomieni |
JP7357220B2 (ja) | 2020-01-27 | 2023-10-06 | パナソニックIpマネジメント株式会社 | フレームロッド回路、水素生成装置、燃料電池システムおよび検知方法 |
JP7357221B2 (ja) * | 2020-01-27 | 2023-10-06 | パナソニックIpマネジメント株式会社 | フレームロッド回路、水素生成装置、燃料電池システムおよび検知方法 |
DE102020108006A1 (de) | 2020-03-24 | 2021-09-30 | Ebm-Papst Landshut Gmbh | Schaltungsvorrichtung und Verfahren zum Überwachen einer Brennerflamme |
DE102022203963B3 (de) | 2022-04-25 | 2023-07-20 | Prüfrex engineering e motion gmbh & co. kg | Schaltungsanordnung zur Flammenüberwachung |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4039844A (en) * | 1975-03-20 | 1977-08-02 | Electronics Corporation Of America | Flame monitoring system |
DE2932129A1 (de) | 1978-08-25 | 1980-02-28 | Satronic Ag | Flammenwaechter an oel- oder gasbrennern |
DE3026787C2 (de) | 1980-06-19 | 1982-08-26 | LGZ Landis & Gyr Zug AG, 6301 Zug | Eigensicherer Flammenwächter |
US4823114A (en) * | 1983-12-02 | 1989-04-18 | Coen Company, Inc. | Flame scanning system |
CH663077A5 (de) * | 1983-12-14 | 1987-11-13 | Landis & Gyr Ag | Selbstueberwachender flammenwaechter. |
NL8401173A (nl) | 1984-04-12 | 1985-11-01 | Philips Nv | Vlambeveiligingsschakeling. |
AU2684888A (en) * | 1988-01-21 | 1989-07-27 | Honeywell Inc. | Fuel burner control system with analog sensors |
GB8906235D0 (en) * | 1989-03-17 | 1989-05-04 | Cambridge Instr Ltd | Flame detection apparatus and method |
US5207276A (en) * | 1991-04-25 | 1993-05-04 | Pem All Fire Extinguisher Corp. | Wire-sensored fire extinguisher with fault-monitoring control system |
DE4309454C2 (de) * | 1993-03-24 | 1997-03-06 | Dungs Karl Gmbh & Co | Ionisationsflammenwächter |
US5439374A (en) * | 1993-07-16 | 1995-08-08 | Johnson Service Company | Multi-level flame curent sensing circuit |
-
1997
- 1997-10-10 EP EP97117731A patent/EP0908679A1/de not_active Withdrawn
-
1998
- 1998-10-08 JP JP2000516189A patent/JP4124962B2/ja not_active Expired - Fee Related
- 1998-10-08 AU AU96299/98A patent/AU742228B2/en not_active Ceased
- 1998-10-08 WO PCT/EP1998/006392 patent/WO1999019672A1/de not_active Application Discontinuation
- 1998-10-08 DK DK98950111T patent/DK1021684T3/da active
- 1998-10-08 KR KR1020007003760A patent/KR20010030982A/ko not_active Application Discontinuation
- 1998-10-08 US US09/508,996 patent/US6501383B1/en not_active Expired - Lifetime
- 1998-10-08 DE DE59807206T patent/DE59807206D1/de not_active Expired - Lifetime
- 1998-10-08 EP EP98950111A patent/EP1021684B1/de not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO9919672A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP1021684B1 (de) | 2003-02-12 |
JP4124962B2 (ja) | 2008-07-23 |
US6501383B1 (en) | 2002-12-31 |
WO1999019672A1 (de) | 1999-04-22 |
DK1021684T3 (da) | 2003-06-10 |
JP2001520361A (ja) | 2001-10-30 |
AU742228B2 (en) | 2001-12-20 |
EP0908679A1 (de) | 1999-04-14 |
AU9629998A (en) | 1999-05-03 |
KR20010030982A (ko) | 2001-04-16 |
DE59807206D1 (de) | 2003-03-20 |
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