EP0994178B1 - Compositions nettoyantes et leur utilisation - Google Patents

Compositions nettoyantes et leur utilisation Download PDF

Info

Publication number
EP0994178B1
EP0994178B1 EP99120336A EP99120336A EP0994178B1 EP 0994178 B1 EP0994178 B1 EP 0994178B1 EP 99120336 A EP99120336 A EP 99120336A EP 99120336 A EP99120336 A EP 99120336A EP 0994178 B1 EP0994178 B1 EP 0994178B1
Authority
EP
European Patent Office
Prior art keywords
cleaning
weight
cleaning agent
agent according
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP99120336A
Other languages
German (de)
English (en)
Other versions
EP0994178A1 (fr
Inventor
Andreas c/o B. Braun Medical AG Arndt
Nadeshda c/o B. Braun Medical AG Arndt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
B Braun Medical AG
Original Assignee
B Braun Medical AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by B Braun Medical AG filed Critical B Braun Medical AG
Publication of EP0994178A1 publication Critical patent/EP0994178A1/fr
Application granted granted Critical
Publication of EP0994178B1 publication Critical patent/EP0994178B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the invention relates to compositions comprising ether carboxylates, nonionic Surfactants and N-alkylpyrrolidones and other auxiliaries.
  • the compositions are characterized by a particular low foam level and at the same time lower Surface tension and high cleaning activity.
  • the compositions do not contain cumene sulfonate as a solubilizer and can if necessary can also be formulated without solvents.
  • the agents according to the invention become mechanical and manual cleaning of hard surfaces, especially of medical devices, surgical instruments, rigid and flexible Endoscopes, inventory and other inanimate surfaces are used.
  • Alkaline cleaners attempt this task by adding active chlorine or to meet active oxygen compounds, which also without the addition of surfactants can dissolve protein soiling from surfaces.
  • the disadvantage here is the high pH and the associated poor quality Material compatibility, especially compared to anodized aluminum, but also Nonferrous metals or special alloys. Therefore, in recent times, have increased mildly alkaline and pH neutral cleaners are suggested based on low-foam nonionic and / or anionic surfactants are built up and Supporting the cleaning effect may contain proteolytic enzymes can.
  • the pH of the agent is preferably between 4.0 and 13.0 between 4.0 and 9.0 and preferred in the case of an enzyme-containing version Values between 4.0 and 8.5 set.
  • the pH is regulated expediently with sodium hydroxide, potassium hydroxide and / or organic alkanolamines, e.g. Triethanolamine or Triisopropanolamin or with the organic acids described above.
  • the surface tension was determined in a process known to the person skilled in the art using a commercially available tensiometer from Krüss a platinum-iridium ring was determined, the sample vessel was thermostated.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (17)

  1. Agent nettoyant, comprenant, en solution aqueuse
    (a) 0,1 à 30 % en poids d'au moins un éthercarboxylate de formule I R1(O-CH2-CH2-)k-OCH2COOM   k = 0-12
    (b) 0,1 à 40 % en poids d'au moins un tensioactif non ionique de formule II
    Figure 00230001
    (c) 0,01 à 20 % en poids d'au moins une N-alkylpyrrolidone
    où
    R1 est un radical alkyle, saturé ou insaturé, linéaire ou ramifié, comportant 4 à 18 atomes de carbone, ou un radical phénylalkyle comportant 10 à 18 atomes de carbone,
    M est un cation métallique monovalent, divalent ou trivalent et/ou un proton (H+),
    R2 et R3 représentent respectivement un radical alkyle, saturé ou insaturé, linéaire ou ramifié, comportant 3 à 18 atomes de carbone, ou un radical phénylalkyle comportant 10 à 18 atomes de carbone,
    la N-alkylpyrrolidone présente un radical alkyle saturé ou insaturé, linéaire ou ramifié, comportant 6 à 18 atomes de carbone,
    et les fractions en poids étant rapportées à la quantité totale de la solution aqueuse.
  2. Agent nettoyant selon la revendication 1, caractérisé en ce que la solution aqueuse comprend au total au moins 1 % en poids des composants (a), (b) et (c).
  3. Agent nettoyant selon la revendication 1 ou 2, caractérisé en ce qu'il contient en outre 0,1 à 30 % en poids d'agents complexants et d'agents de stabilisation de la dureté de l'eau.
  4. Agent nettoyant selon une ou plusieurs des revendications 1 à 3, caractérisé en ce qu'il contient en outre jusqu'à 20 % en poids d'enzymes protéolytiques.
  5. Agent nettoyant selon une ou plusieurs des revendications 1 à 4, caractérisé en ce qu'il contient en outre, dans une forme de réalisation contenant des enzymes, jusqu'à 50 % en poids d'alcools monovalents et/ou polyvalents comportant 2 à 6 atomes de carbone et 1 à 6 groupes hydroxyle.
  6. Agent nettoyant selon une ou plusieurs des revendications 1 à 5, caractérisé en ce qu'il contient en outre jusqu'à 5 % en poids d'inhibiteurs de corrosion, d'agents de conservation, de correcteurs d'odeurs et de colorants.
  7. Agent nettoyant selon une ou plusieurs des revendications 1 à 6, caractérisé en ce qu'il contient en outre jusqu'à 30 % en poids de tensioactifs non ioniques qui ne sont pas sélectionnés dans le groupe défini par la formule II.
  8. Agent nettoyant selon une ou plusieurs des revendications 1 à 7, caractérisé en ce qu'il contient en outre jusqu'à 20 % en poids de tensioactifs anioniques n'entrant pas dans le cadre de la formule I et/ou de tensioactifs amphotères.
  9. Agent nettoyant selon une ou plusieurs des revendications 1 à 8, caractérisé en ce qu'il contient en outre, dans une forme de réalisation contenant des enzymes, jusqu'à 10 % en poids de monoalkyléther d'éthylèneglycol, de monoalkyléther de diéthylèneglycol, de monoalkyléther de propylèneglycol, de monoalkyléther de dipropylèneglycol ou de leurs mélanges, le radical alkyle saturé, linéaire ou ramifié, présentant 1 à 6 atomes de carbone.
  10. Agent nettoyant selon une ou plusieurs des revendications 1 à 9, caractérisé en ce qu'il présente une valeur de pH comprise entre 4,0 et 13,0, et dans le cas d'une forme de réalisation contenant des enzymes, une valeur de pH comprise entre 4,0 et 8,5.
  11. Solution d'application contenant l'agent nettoyant tel que défini dans l'une quelconque des revendications 1 à 10 en solution aqueuse ou aqueuse/alcoolique.
  12. Solution d'application selon la revendication 11, caractérisée en ce qu'on utilise dans la solution aqueuse/alcoolique un alcool monovalent comportant deux ou trois atomes de carbone.
  13. Utilisation de l'agent nettoyant selon l'une quelconque des revendications 1 à 10 et de la solution d'application selon l'une quelconque des revendications 11 ou 12 pour nettoyer des appareils médicaux, des instruments chirurgicaux, des matériaux anesthésiants, des endoscopes rigides et flexibles.
  14. Utilisation selon la revendication 13 pour nettoyer des instruments chirurgicaux, des endoscopes rigides et flexibles dans des automates de nettoyage et de désinfection.
  15. Utilisation selon la revendication 14 pour nettoyer des instruments chirurgicaux, des endoscopes fixes et flexibles dans des automates de nettoyage et de désinfection, où, après l'étape de nettoyage peut être effectuée une désinfection thermique ou chimico-thermique avec les agents désinfectants usuels pouvant être utilisés à cette fin.
  16. Utilisation selon l'une quelconque des revendications 13 à 15 à une température d'application comprise entre 5°C et 95 °C.
  17. Utilisation de l'agent nettoyant selon l'une quelconque des revendications 1 à 10 et de sa solution d'application prête à l'emploi selon les revendications 11 ou 12 pour nettoyer des bâtis de lits, des planchers, du mobilier et d'autres surfaces inanimées.
EP99120336A 1998-10-15 1999-10-12 Compositions nettoyantes et leur utilisation Expired - Lifetime EP0994178B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19847498A DE19847498C2 (de) 1998-10-15 1998-10-15 Reinigungsmittel und deren Verwendung
DE19847498 1998-10-15

Publications (2)

Publication Number Publication Date
EP0994178A1 EP0994178A1 (fr) 2000-04-19
EP0994178B1 true EP0994178B1 (fr) 2003-02-05

Family

ID=7884535

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99120336A Expired - Lifetime EP0994178B1 (fr) 1998-10-15 1999-10-12 Compositions nettoyantes et leur utilisation

Country Status (4)

Country Link
EP (1) EP0994178B1 (fr)
AT (1) ATE232235T1 (fr)
DE (2) DE19847498C2 (fr)
ES (1) ES2192008T3 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108410594A (zh) * 2018-03-06 2018-08-17 北京佳士力科技有限公司 医用泡沫酶保湿剂及其制备方法

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU773446B2 (en) * 1998-12-23 2004-05-27 Huntsman International Llc Herbicidal compositions and surfactant concentrates
GB2392167A (en) * 2002-08-22 2004-02-25 Reckitt Benckiser Inc Composition containing an acid with anionic and nonionic surfactants
WO2004074417A1 (fr) * 2003-02-24 2004-09-02 Unilever Plc Compositions de nettoyage antimicrobiennes
EP2009993B1 (fr) * 2006-04-21 2015-07-22 Kao Corporation Composition d'agent de lutte contre un biofilm
ES2293826B1 (es) 2006-06-07 2008-12-16 Kao Corporation S.A. Composicion detergente.
EP2438904A1 (fr) * 2010-10-05 2012-04-11 Kao Corporation Composition de nettoyage
DE102013218449A1 (de) * 2013-09-13 2015-03-19 Schülke & Mayr GmbH Wässrige Formulierung für die Reinigung von harten Oberflächen
CN105154253A (zh) * 2015-10-09 2015-12-16 湖北穆兰同大科技有限公司 生物多酶清洗剂及其制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2395309A1 (fr) * 1978-03-15 1979-01-19 Chemische Inst Schafer Ag Concentre de nettoyage contenant des tensides ioniques et non-ioniques
DE3639322A1 (de) * 1986-11-17 1988-05-26 Henkel Kgaa Verfahren zur reinigung und desinfektion von endoskopen und mittel zur durchfuehrung des verfahrens
DE3816734A1 (de) * 1988-05-17 1989-11-30 Henkel Kgaa Verfahren zur reinigung und desinfektion von hitze- und korrosionsempfindlichen medizinischen geraeten, insbesondere von endoskopen und mittel zur durchfuehrung des verfahrens
DE4110764A1 (de) * 1991-04-03 1992-10-08 Weigert Chem Fab Verfahren zum entfernen von staerkehaltigen verunreinigungen von geschirr und hierfuer geeignete tensidkonzentrate
DE4208753C2 (de) * 1992-03-19 1999-10-21 Georg Scheidel Jun Gmbh Verwendung einer wäßrigen Zubereitung in flüssiger oder pastöser Form zum Entfernen von Farben und Klebern
GB2292562A (en) * 1994-07-13 1996-02-28 Procter & Gamble Liquid Detergent Compositions
US5614027A (en) * 1994-09-23 1997-03-25 Church & Dwight Co., Inc. Metal cleaner with novel anti-corrosion system
DE19516698C5 (de) * 1995-05-06 2004-02-12 Kao Corp. Gefärbte flüssige Reinigungsmittel
US5814588A (en) * 1996-03-19 1998-09-29 Church & Dwight Co., Inc. Aqueous alkali cleaning compositions
DE59807424D1 (de) * 1997-03-27 2003-04-17 Braun Medical Ag Emmenbruecke Mikrobizides Mittel und dessen Anwendung

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108410594A (zh) * 2018-03-06 2018-08-17 北京佳士力科技有限公司 医用泡沫酶保湿剂及其制备方法
CN108410594B (zh) * 2018-03-06 2020-12-08 北京佳士力科技有限公司 医用泡沫酶保湿剂及其制备方法

Also Published As

Publication number Publication date
EP0994178A1 (fr) 2000-04-19
DE59904212D1 (de) 2003-03-13
DE19847498A1 (de) 2000-04-20
DE19847498C2 (de) 2002-05-08
ES2192008T3 (es) 2003-09-16
ATE232235T1 (de) 2003-02-15

Similar Documents

Publication Publication Date Title
DE69413044T2 (de) Desinfektionsmittel
DE69221922T2 (de) Flüssige Zusammensetzung für Kontaktlinsen und Verfahren zur Reinigung einer Kontaktlinse
EP0977825B1 (fr) Preparation enzymatique liquide et son utilisation
DE69026967T2 (de) Saure, desinfizierende flüssige Allzweckreinigungsmittel
DE69631549T3 (de) Keimtötende saure reinigungsmittel für harte oberflächen
DE69226527T2 (de) Reinigungsmethode für Kontaktlinsen
AT394572B (de) Stark schaeumendes, auf nichtionischen tensiden basierendes fluessiges feinreinigungsmittel und verfahren zu seiner herstellung
DE3788895T2 (de) Antimikrobielle Zusammensetzungen.
DE202010018137U1 (de) Reinigungsmittel mit einem Gehalt an Carbamid und/oder mindestens einem Derivat hiervon
EP0633927B1 (fr) Nettoyants pour surfaces dures
DE69608507T2 (de) Verfahren zur Reinigung und Desinfektion von Kontaktlinsen
EP0994178B1 (fr) Compositions nettoyantes et leur utilisation
DE3048641A1 (de) "tensidhaltiges gemisch zur reinigung harter oberflaechen"
DE19741910A1 (de) Verfahren zur Reinigung und Desinfektion von medizinischen Instrumenten
DE69701225T2 (de) Bodenpflegezusammensetzung
DE19603977A1 (de) Verfahren zur Reinigung und Desinfektion von empfindlichen medizinischen Geräten
EP0721496B1 (fr) Decolorants et desinfectants
DE69722353T2 (de) Reinigungs-, Desinfektions- und Bleichmittelzusammensetzung
DE60123812T2 (de) Tensidsystem
DE69217516T2 (de) Saures, desinfizierendes und Kesselstein entfernendes Reinigungsmittel und Verfahren zu seiner Herstellung
DE69200612T2 (de) Polyphosphonatkomplexbildner enthaltende flüssige, konzentrierte Waschmittelzusammensetzung.
EP0523681A2 (fr) Composition détergente pour le lavage automatique de la vaisselle et méthode pour sa production
DE69725434T3 (de) Zusammensetzung zur behandlung von kontaktlinsen und methode zur anwendung derselben
EP0675945B1 (fr) Produit d'entretien neutre pour sols (i)
DE102006051559A1 (de) Reinigungs- und Desinfektionsmittel mit verbesserter Entkrüstungswirkung für hygienische- medizinische Anwendungen

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

17P Request for examination filed

Effective date: 20000907

AKX Designation fees paid

Free format text: AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

17Q First examination report despatched

Effective date: 20020425

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030205

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030205

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030205

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: GERMAN

REF Corresponds to:

Ref document number: 59904212

Country of ref document: DE

Date of ref document: 20030313

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030505

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030505

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030505

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)
ET Fr: translation filed
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2192008

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: IE

Ref legal event code: FD4D

Ref document number: 0994178E

Country of ref document: IE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20031012

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20031012

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20031031

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20031106

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20131018

Year of fee payment: 15

Ref country code: BE

Payment date: 20131021

Year of fee payment: 15

Ref country code: AT

Payment date: 20131021

Year of fee payment: 15

Ref country code: GB

Payment date: 20131022

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20131029

Year of fee payment: 15

Ref country code: NL

Payment date: 20131021

Year of fee payment: 15

Ref country code: ES

Payment date: 20131022

Year of fee payment: 15

REG Reference to a national code

Ref country code: NL

Ref legal event code: V1

Effective date: 20150501

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 232235

Country of ref document: AT

Kind code of ref document: T

Effective date: 20141012

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20141012

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141031

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141012

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20150630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141012

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141012

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141031

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150501

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20160201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141013

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20181024

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20181025

Year of fee payment: 20

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 59904212

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL