EP0991483B1 - Application of plastic on individual metal parts - Google Patents
Application of plastic on individual metal parts Download PDFInfo
- Publication number
- EP0991483B1 EP0991483B1 EP98936350A EP98936350A EP0991483B1 EP 0991483 B1 EP0991483 B1 EP 0991483B1 EP 98936350 A EP98936350 A EP 98936350A EP 98936350 A EP98936350 A EP 98936350A EP 0991483 B1 EP0991483 B1 EP 0991483B1
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- European Patent Office
- Prior art keywords
- dispersion
- solution
- contact
- brought
- individual parts
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
- B05D7/542—No clear coat specified the two layers being cured or baked together
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
- B05D7/544—No clear coat specified the first layer is let to dry at least partially before applying the second layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
- B05D7/58—No clear coat specified
- B05D7/587—No clear coat specified some layers being coated "wet-on-wet", the others not
Definitions
- the invention relates to a method for applying plastic or plastic-containing layers to metallic individual parts and its use as pretreatment of the individual parts for the subsequent powder coating.
- a wide variety of processes are used in the industrial sector to apply plastic or plastic-containing layers to metallic workpieces.
- the application can be carried out without difficulty or is associated with considerable disadvantages.
- the treatment of tape is possible in a simple manner by using the roller coating method.
- a plastic layer of the required thickness can be produced in one operation.
- the treatment of relatively large, spherical workpieces is also comparatively simple, which is usually done using the electro-dip process or the spray process.
- the coating of individual parts presents difficulties, particularly if they have a spatial extension.
- the term individual parts describes, for example, radiator convection surfaces, shelves, fence elements and guardrails.
- roll request processes are ruled out.
- Spray processes are particularly uneconomical because of the high proportion of over-spray.
- Dipping processes have the disadvantage that drops of the plastic solution or dispersion remain at the drainage points and are visible as a thickening after the subsequent drying. This thickening has a layer thickness that is approximately 30 to 50 times as high as that of the other surface areas. Even after subsequent painting, these thickenings are clearly recognizable.
- the treated parts are - depending on the intended use - practically unusable due to the lack of accuracy of fit.
- the object of the invention is to provide a method for applying plastic or plastic-containing layers to metallic individual parts that avoids the known, in particular the aforementioned disadvantages and also creates layers at the drainage point with a layer thickness that matches the layer thickness of the other surface areas coated with plastic essentially matches.
- Drying on is understood here to mean that the liquid film produced by treatment according to process step a) has completely dried on the surface areas different from the drainage points.
- the polymer solution or dispersion present at the outflow points is slightly concentrated, but is soluble or dispersible in the subsequent process step c).
- the treatment corresponding to process stage c) in turn results in a drop of liquid which is greatly thickened at the discharge point (s) compared to the other surface areas, but which is due to the considerably lower concentration of the polymer solution or dispersion after the final drying in accordance with process stage d) leads a layer which has substantially the same thickness as the layer of the other surface areas.
- solutions or dispersions used contain the usual polymers.
- Polyacrylates, polyurethanes, polyesters, polystyrene and epoxy, phenol, silicone, urea and / or melamine resins and copolymers thereof are particularly suitable.
- the polymer solution or dispersion should additionally contain a chromium VI and / or a chromium III compound, preferably in water-soluble form.
- Another preferred embodiment of the invention provides for the individual parts to be brought into contact with a solution or dispersion which additionally contains adhesion-promoting pigments, leveling agents and / or defoamers.
- the pH of the solution or dispersion used is expediently in the range from 1.5 to 10.
- the preferred pH range is 2 to 4, when alkaline polymer concentrates are used, 7.5 to 9.
- the way in which the individual parts are brought into contact with the solution or dispersion is largely arbitrary. Immersion or flood processes are particularly suitable. It is advisable to circulate the baths. The duration of the contact is to be dimensioned such that complete wetting is ensured. It is usually in the range of a few seconds to a minute. The temperature of the solution or dispersion used can be between 5 and 40 ° C.
- the drying step according to b) following process step a) can take place at room temperature. Then the drying time is 5 to 60 minutes depending on the thickness of the liquid film. According to a preferred embodiment of the invention, however, the drying is carried out at a temperature in the range from 40 to 60 ° C. Then a drying time of 1 to 3 minutes is usually sufficient. In any case, the above comments on the term drying used here should be observed.
- process stage a For the treatment of the individual parts in process stage c), the information given for process stage a) applies with regard to temperature, duration of treatment, etc.
- the final drying can take place at room temperature. Because of the increased drying speed, however, the use of elevated temperatures reaching up to 200 ° C. is of particular advantage. Depending on the intended temperature, the duration for the final drying is 5 seconds to 60 minutes.
- the prerequisite for the perfect coating of the individual parts is their purity. Unless it is given by an immediately preceding treatment, such as electrolytic or hot-dip galvanizing, thorough cleaning / water rinsing according to known methods is required.
- the cleaned individual parts can be treated with a wet surface or else dried using the method of the invention.
- the method according to the invention is intended in particular for the coating of individual parts made of steel, galvanized steel, aluminum, alloys thereof, as well as zinc and its alloys or of individual parts which have such surfaces. It can be used for sole treatment for permanent corrosion protection, as well as for pre-treatment before any painting. The process is particularly important for the pretreatment of individual parts for the subsequent powder coating.
- the layer thicknesses achieved with the method according to the invention are approximately 0.5 to 3 ⁇ m (based on the surface areas different from the runoff points).
- the present method has further significant advantages. It works wastewater-free. Because of the qualitatively essentially identical nature of the solution or dispersion used in process stage c), it can be added continuously or discontinuously to the solution or dispersion according to stage a) as a result of the concentration taking place by detaching the drops located at the outflow points, or for their preparation with the help the commercially available polymer concentrates, which usually contain 30 to 50% by weight of polymer, are used.
- the polymer dispersions were carried out for 2 minutes after the immersion treatment. Dried at 50 ° C, then was immersed in the polymer dispersion 4 according to the invention. Here, too, the immersion time was 10 seconds and the bath temperature was 20 ° C. The final drying was then carried out at 150 ° C. within 2 minutes.
- the layer thicknesses largely correspond both at the drainage points and at the surface areas different from the drainage points.
- the layer thicknesses at the drainage points are 25 to 52 times greater than at the other surface areas.
- the layer thickness at the surface areas different from the drain point is also insufficiently small.
- Comparative Example 5 makes it particularly clear that a two-stage immersion treatment with a polymer dispersion, the concentration of which is too low in the first stage, is insufficient with regard to the layer thickness at the surface areas different from the runoff points.
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Abstract
Description
Die Erfindung betrifft ein Verfahren zum Aufbringen von Kunststoff oder kunststoffhaltigen Schichten auf metallische Einzelteile sowie dessen Anwendung als Vorbehandlung der Einzelteile für die anschließende Pulverlackierung.The invention relates to a method for applying plastic or plastic-containing layers to metallic individual parts and its use as pretreatment of the individual parts for the subsequent powder coating.
Ein Verfahren der obengenannten Gattung ist in DE-A-196 42 970 offenbart.A method of the type mentioned above is disclosed in DE-A-196 42 970.
Im großtechnischen Bereich sind die unterschiedlichsten Verfahren zum Aufbringen von Kunststoff oder kunststoffhaltigen Schichten auf metallische Werkstücke im Einsatz. Je nach der Art der Werkstücke ist die Aufbringung ohne Schwierigkeiten durchführbar oder aber mit erheblichen Nachteilen verbunden. Beispielsweise ist die Behandlung von Band in einfacher Weise durch Anwendung des Walzenauftragsverfahrens (Roller Coating) möglich. Durch geeignete Einstellung der Konzentration der aufzubringenden Kunststofflösung oder - dispersion sowie der Auftragswalzen kann in einem Arbeitsgang eine Kunststoffschicht der jeweils erforderlichen Dicke erzeugt werden.A wide variety of processes are used in the industrial sector to apply plastic or plastic-containing layers to metallic workpieces. Depending on the type of workpieces, the application can be carried out without difficulty or is associated with considerable disadvantages. For example, the treatment of tape is possible in a simple manner by using the roller coating method. By suitably adjusting the concentration of the plastic solution or dispersion to be applied and the application rollers, a plastic layer of the required thickness can be produced in one operation.
Vergleichsweise einfach gestaltet sich auch die Behandlung relativ großflächiger, sphärischer Werkstücke, die meist im Elekfrotauchverfahren oder im Spritzverfahren geschieht.The treatment of relatively large, spherical workpieces is also comparatively simple, which is usually done using the electro-dip process or the spray process.
Schwierigkeiten bereitet hingegen die Beschichtung von Einzelteilen, insbesondere wenn sie eine räumliche Erstreckung aufweisen. Mit dem Begriff Einzelteile werden beispielsweise Heizkörper-Konvektionsflächen, Regalböden, Zaunelemente und Leitplanken bezeichnet. Walzenauffragsverfahren scheiden in diesem Fall aus. Spritzverfahren sind insbesondere wegen des hohe Anteils an over-spray unwirtschaftlich. Tauchverfahren sind mit dem Nachteil verbunden, daß an den Ablaufstellen Tropfen der Kunststofflösung oder - dispersion zurückbleiben, die nach der nachfolgenden Trocknung als Verdickung sichtbar sind. Diese Verdickung besitzt eine Schichtdicke, die etwa 30 bis 50 mal so hoch ist, wie die der anderen Oberflächenbereiche. Selbst nach einer nachfolgenden Lackierung sind diese Verdickungen deutlich erkennbar. Neben dem wenig attraktiven Aussehen sind die behandelten Teile - je nach Verwendungszweck - auch wegen mangelnder Paßgenauigkeit praktisch unbrauchbar.On the other hand, the coating of individual parts presents difficulties, particularly if they have a spatial extension. The term individual parts describes, for example, radiator convection surfaces, shelves, fence elements and guardrails. In this case, roll request processes are ruled out. Spray processes are particularly uneconomical because of the high proportion of over-spray. Dipping processes have the disadvantage that drops of the plastic solution or dispersion remain at the drainage points and are visible as a thickening after the subsequent drying. This thickening has a layer thickness that is approximately 30 to 50 times as high as that of the other surface areas. Even after subsequent painting, these thickenings are clearly recognizable. In addition to the unattractive appearance, the treated parts are - depending on the intended use - practically unusable due to the lack of accuracy of fit.
Aufgabe der Erfindung ist es, ein Verfahren zum Aufbringen von Kunststoff oder kunststoffhaltigen Schichten auf metallische Einzelteile bereitzustellen, daß die bekannten, insbesondere vorgenannten Nachteile vermeidet und auch an der Ablaufstelle Schichten mit einer Schichtdicke entstehen läßt, die mit der Schichtdicke der sonstigen mit Kunststoff beschichteten Oberflächenbereiche im wesentlichen übereinstimmt.The object of the invention is to provide a method for applying plastic or plastic-containing layers to metallic individual parts that avoids the known, in particular the aforementioned disadvantages and also creates layers at the drainage point with a layer thickness that matches the layer thickness of the other surface areas coated with plastic essentially matches.
Die Aufgabe wird gelöst, in dem das Verfahren der eingangs genannten Art entsprechend der Erfindung in der Weise ausgebildet wird, daß man
- a) die Einzelteile mit einer 5 bis 50 Gew. % organisches Polymer enthaltenden Lösung oder Dispersion in Kontakt bringt,
- b) die Lösung oder Dispersion antrocknet,
- c) die Einzelteile mit einer qualitativ im wesentlichen identischen Lösung oder Dispersion gemäß Stufe a), die jedoch nur 0,5 bis 5 Gew.% organisches Polymer enthält, in Kontakt bringt,
- d) und endtrocknet.
- a) bringing the individual parts into contact with a solution or dispersion containing 5 to 50% by weight of organic polymer,
- b) the solution or dispersion dries,
- c) the individual parts are brought into contact with a qualitatively essentially identical solution or dispersion according to stage a), but which contains only 0.5 to 5% by weight of organic polymer,
- d) and dries up.
Unter Antrocknen ist hierbei verstanden, daß der durch Behandlung gemäß Verfahrensstufe a) an den von den Ablaufstellen verschiedenen Oberflächenbereichen erzeugte Flüssigkeitsfilm völlig angetrocknet ist. Demgegenüber ist die an den Ablaufstellen vorhandene Polymerlösung oder - dispersion zwar geringfügig aufkonzentriert, aber in der nachfolgenden Verfahrensstufe c) lösbar oder dispergierbar.Drying on is understood here to mean that the liquid film produced by treatment according to process step a) has completely dried on the surface areas different from the drainage points. In contrast, the polymer solution or dispersion present at the outflow points is slightly concentrated, but is soluble or dispersible in the subsequent process step c).
Durch die Behandlung entsprechend der Verfahrensstufe c) entsteht zwar wiederum an der (den) Ablaufstelle (n) ein gegenüber den anderen Oberflächenbereichen stark verdickter Flüssigkeitstropfen, der jedoch in Folge der erheblich geringeren Konzentration der Polymerlösung oder - dispersion nach der Endtrocknung entsprechend Verfahrensstufe d) zu einer Schicht führt, die im wesentlichen die gleiche Dicke aufweist wie die Schicht der anderen Oberflächenbereiche.The treatment corresponding to process stage c) in turn results in a drop of liquid which is greatly thickened at the discharge point (s) compared to the other surface areas, but which is due to the considerably lower concentration of the polymer solution or dispersion after the final drying in accordance with process stage d) leads a layer which has substantially the same thickness as the layer of the other surface areas.
Die sich zunächst anbietende Wasserspülung zur Entfernung des verdickten Flüssigkeitsfilmes an der (den) Ablaufstelle (n) anstelle der Verfahrensstufe c) ist nicht praktikabel, da dann an diesen Stellen die blanke Metalloberfläche frei läge.The initially available water rinsing to remove the thickened liquid film at the discharge point (s) instead of process step c) is not practical, since the bare metal surface would then be exposed at these points.
Die zum Einsatz kommenden Lösungen oder Dispersionen enthalten die an sich üblichen Polymere. Besonders geeignet sind Polyacrylate, Polyurethane, Polyester, Polystyrol sowie Epoxid-, Phenol-, Silikon-, Harnstoff- und/oder Melaminharze sowie Mischpolymere hiervon.The solutions or dispersions used contain the usual polymers. Polyacrylates, polyurethanes, polyesters, polystyrene and epoxy, phenol, silicone, urea and / or melamine resins and copolymers thereof are particularly suitable.
Gemäß einer bevorzugten Ausgestaltung der Erfindung sollte die Polymerlösung oder - dispersion zusätzlich eine Chrom-VI- und/oder eine Chrom III- Verbindung, vorzugsweise in wasserlöslicher Form enthalten.According to a preferred embodiment of the invention, the polymer solution or dispersion should additionally contain a chromium VI and / or a chromium III compound, preferably in water-soluble form.
Eine weitere bevorzugte Ausführungsform der Erfindung sieht vor, die Einzelteile mit einer Lösung oder Dispersion in Kontakt zu bringen, die zusätzlich haftvermittelnde Pigmente, Verlaufsmittel und/oder Entschäumer enthalten. Der Gehalt der vorgenannten Additive sollte etwa 0,5 - bis 10 Gew.% des Polymergehaltes betragen (Trockensubstanz der Polymere = 100%). Es werden Additive verwendet, die in der Kunststoffbeschichtungs-Technik allgemein gebräuchlich sind.Another preferred embodiment of the invention provides for the individual parts to be brought into contact with a solution or dispersion which additionally contains adhesion-promoting pigments, leveling agents and / or defoamers. The content of the aforementioned additives should be about 0.5 to 10% by weight of the polymer content amount (dry substance of the polymers = 100%). Additives are used which are commonly used in plastic coating technology.
Der pH-Wert der zur Anwendung gelangenden Lösung oder Dispersion liegt zweckmäßigerweise im Bereich von 1,5 bis 10. Bei Einsatz von sauer eingestellten Polymerkonzentraten ist der bevorzugte pH-Bereich 2 bis 4, bei Einsatz von alkalisch eingestellten Polymerkonzentraten 7,5 bis 9.The pH of the solution or dispersion used is expediently in the range from 1.5 to 10. When using acidic polymer concentrates, the preferred pH range is 2 to 4, when alkaline polymer concentrates are used, 7.5 to 9.
Die Weise, in der die Einzelteile mit der Lösung oder Dispersion in Kontakt gebracht werden, ist weitgehend beliebig. Tauch- oder Flutverfahren sind besonders geeignet. Hierbei ist es zweckmäßig die Bäder umzuwälzen. Die Dauer des In-Kontakt-Bringens ist derart zu bemessen, daß eine vollständige Benetzung gewährleistet ist. Sie liegt in der Regel im Bereich von wenigen Sekunden bis zu einer Minute. Die Temperatur der zum Einsatz kommenden Lösung oder Dispersion kann zwischen 5 und 40 ° C liegen.The way in which the individual parts are brought into contact with the solution or dispersion is largely arbitrary. Immersion or flood processes are particularly suitable. It is advisable to circulate the baths. The duration of the contact is to be dimensioned such that complete wetting is ensured. It is usually in the range of a few seconds to a minute. The temperature of the solution or dispersion used can be between 5 and 40 ° C.
Die sich an die Verfahrensstufe a) anschließende Antrockenstufe gemäß b) kann bei Raumtemperatur erfolgen. Dann liegt die Trockendauer je nach Dicke des Flüssigkeitsfilmes bei 5 bis 60 Minuten. Entsprechend einer bevorzugten Ausgestaltung der Erfindung nimmt man jedoch das Antrocknen bei einer Temperatur im Bereich von 40 bis 60 ° C vor. Dann reicht üblicherweise eine Trockendauer von 1 bis 3 Minuten. Jedenfalls sind die oben genannten Anmerkungen zum hier verwendeten Begriff des Antrocknens zu beachten.The drying step according to b) following process step a) can take place at room temperature. Then the drying time is 5 to 60 minutes depending on the thickness of the liquid film. According to a preferred embodiment of the invention, however, the drying is carried out at a temperature in the range from 40 to 60 ° C. Then a drying time of 1 to 3 minutes is usually sufficient. In any case, the above comments on the term drying used here should be observed.
Für die Behandlung der Einzelteile in der Verfahrensstufe c) gelten hinsichtlich Temperatur, Dauer der Behandlung etc. die zur Verfahrensstufe a) gemachten Angaben.For the treatment of the individual parts in process stage c), the information given for process stage a) applies with regard to temperature, duration of treatment, etc.
Die Endtrocknung kann bei Raumtemperatur erfolgen. Wegen der erhöhten Trocknungsgeschwindigkeit ist jedoch die Anwendung erhöhter, bis zu 200 ° C reichender Temperaturen von besonderem Vorteil. Je nach vorgesehener Temperatur liegt die Dauer für die Endtrocknung bei 5 Sekunden bis 60 Minuten.The final drying can take place at room temperature. Because of the increased drying speed, however, the use of elevated temperatures reaching up to 200 ° C. is of particular advantage. Depending on the intended temperature, the duration for the final drying is 5 seconds to 60 minutes.
Voraussetzung für die einwandfreie Beschichtung der Einzelteile ist deren Reinheit. Sofern sie nicht durch eine unmittelbar vorausgegangene Behandlung, wie zum Beispiel eine elektrolytische oder eine Schmelztauch- Verzinkung, gegeben ist, ist eine gründliche Reinigung / Wasserspülung nach bekannten Methoden erforderlich. Die gereinigten Einzelteile können mit nasser Oberfläche oder aber getrocknet nach dem Verfahren der Erfindung behandelt werden.The prerequisite for the perfect coating of the individual parts is their purity. Unless it is given by an immediately preceding treatment, such as electrolytic or hot-dip galvanizing, thorough cleaning / water rinsing according to known methods is required. The cleaned individual parts can be treated with a wet surface or else dried using the method of the invention.
Das erfindungsgemäße Verfahren ist insbesondere für die Beschichtung von Einzelteilen aus Stahl, verzinktem Stahl, Aluminium, Legierungen hiervon, sowie Zink und dessen Legierungen bzw. von Einzelteilen, die derartige Oberflächen aufweisen, bestimmt. Es kann zur alleinigen Behandlung zum permanenten Korrosionsschutz, wie zur Vorbehandlung vor einer beliebigen Lackierung eingesetzt werden. Eine besonders herausragende Bedeutung hat das Verfahren für die Vorbehandlung von Einzelteilen für die anschließende Pulverlackierung.The method according to the invention is intended in particular for the coating of individual parts made of steel, galvanized steel, aluminum, alloys thereof, as well as zinc and its alloys or of individual parts which have such surfaces. It can be used for sole treatment for permanent corrosion protection, as well as for pre-treatment before any painting. The process is particularly important for the pretreatment of individual parts for the subsequent powder coating.
Die mit dem erfindungsgemäßen Verfahren erzielten Schichtdicken betragen je nach Konzentration der zum Einsatz kommenden Lösung oder Dispersion etwa 0,5 bis 3 µm (bezogen auf die von den Ablaufstellen verschiedenen Oberflächenbereiche).Depending on the concentration of the solution or dispersion used, the layer thicknesses achieved with the method according to the invention are approximately 0.5 to 3 μm (based on the surface areas different from the runoff points).
Neben der Lösung der mit der Erfindung gestellten Aufgabe hat das vorliegende Verfahren weitere erhebliche Vorteile. Es arbeitet abwasserfrei. Wegen der qualitativ im wesentlichen identischen Beschaffenheit der in der Verfahrensstufe c) eingesetzten Lösung oder Dispersion kann sie infolge der stattfindenden Aufkonzentrierung durch Ablösung der an den Ablaufstellen befindlichen Tropfen kontinuierlich oder diskontinuierlich der Lösung oder Dispersion gemäß Stufe a) zugeführt bzw. zu deren Ansatz mit Hilfe der handelsüblichen Polymerkonzentrate, die üblicherweise 30 bis 50 Gew. % Polymer enthalten, verwendet werden.In addition to solving the problem set by the invention, the present method has further significant advantages. It works wastewater-free. Because of the qualitatively essentially identical nature of the solution or dispersion used in process stage c), it can be added continuously or discontinuously to the solution or dispersion according to stage a) as a result of the concentration taking place by detaching the drops located at the outflow points, or for their preparation with the help the commercially available polymer concentrates, which usually contain 30 to 50% by weight of polymer, are used.
Die Erfindung wird anhand der nachfolgenden Beispiele beispielhaft und näher erläutert.The invention is illustrated by way of example and in more detail using the examples below.
Zur Behandlung wurden zuvor gereinigte und gespülte Regalböden aus verzinktem Stahl mit noch nasser Oberfläche eingesetzt.For treatment, previously cleaned and rinsed shelves made of galvanized steel with a still wet surface were used.
Die Erzeugung der kunststoffhaltigen Schichten erfolgte mit Dispersionen, die als Polymer ein Mischpolymerisat von Acrylsäure, Acrylsäureester, Styrol und ürethan enthielten. Die Konzentration des Polymers sowie die weiteren Gehalte an Ammoniumdichromat und üblichen Additiven sind in Tabelle 1 aufgeführt.
Die Behandlung der Regalböden geschah im Tauchen mit einer Tauchdauer von 10 sec bei einer Badtemperatur von 20 ° C.The shelves were treated in diving with a diving duration of 10 seconds at a bath temperature of 20 ° C.
Bei den Beispielen gemäß Erfindung (Beispiele 1 bis 3) wurden nach der Tauchbehandlung die Polymerdispersionen für die Dauer von 2 min. bei 50 ° C angetrocknet, danach wurde erfindungsgemäß in die Polymerdispersion 4 getaucht. Auch hier waren die Tauchdauer 10 sec und die Badtemperatur 20 ° C. Anschließend erfolgte die Endtrocknung bei 150°C innerhalb von 2 min.In the examples according to the invention (Examples 1 to 3), the polymer dispersions were carried out for 2 minutes after the immersion treatment. Dried at 50 ° C, then was immersed in the polymer dispersion 4 according to the invention. Here, too, the immersion time was 10 seconds and the bath temperature was 20 ° C. The final drying was then carried out at 150 ° C. within 2 minutes.
Bei den Vergleichsversuchen 1 bis 4 erfolgte jeweils nur eine Tauchbehandlung mit den Polymerdispersionen 1, 2, 3 und 4 und anschließend die Endtrocknung. Bei Vergleichsbeispiel 5 wurde die Polymerdispersion 4 bei zwei Tauchbehandlungen eingesetzt. Die Behandlungsbedingungen waren jeweils idenfisch mit denen der Beispiele 1 bis 3. Die erzielten Ergebnisse sind in Tabelle 2 zusammengestellt.
Hieraus ergibt sich, daß bei den erfindungsgemäßen Beispielen 1 bis 3 die Schichtdicken sowohl an den Ablaufstellen als auch an den von den Ablaufstellen verschiedenen Oberflächenbereichen weitgehend übereinstimmen. Bei den Vergleichsbeispielen 1 bis 4 hingegen sind die Schichtdicken an den Ablaufstellen um den Faktor 25 bis 52 größer als an den anderen Oberflächenbereichen. Bei Vergleichsbeispiel 4 ist außerdem die Schichtdicke an den von der Ablaufstelle verschiedenen Oberflächenbereichen ungenügend gering.It follows from this that in Examples 1 to 3 according to the invention, the layer thicknesses largely correspond both at the drainage points and at the surface areas different from the drainage points. In comparison examples 1 to 4, on the other hand, the layer thicknesses at the drainage points are 25 to 52 times greater than at the other surface areas. In Comparative Example 4, the layer thickness at the surface areas different from the drain point is also insufficiently small.
Das Vergleichsbeispiel 5 macht insbesondere deutlich, daß eine zweistufige Tauchbehandlung mit einer Polymerdispersion, deren Konzentration in der ersten Stufe zu gering ist, hinsichtlich der Schichtdicke an den von den Ablaufstellen verschiedenen Oberffächenbereichen unzureichend ist.Comparative Example 5 makes it particularly clear that a two-stage immersion treatment with a polymer dispersion, the concentration of which is too low in the first stage, is insufficient with regard to the layer thickness at the surface areas different from the runoff points.
Claims (7)
- A process for applying plastics or plastics-containing layers onto metal components, characterised in thata) the components are brought into contact with a solution or dispersion containing 5 to 50 wt.% of organic polymer,b) the solution or dispersion is surface-dried,c) the components are brought into contact with a solution or dispersion according to stage a) which is substantially qualitatively identical, but contains only 0.5 to 5 wt.% of organic polymer andd) there is final drying.
- A process according to claim 1, characterised in that the components are brought into contact with a solution or dispersion which additionally contains a chromium(IV) and/or chromium(III) compound, preferably in water-soluble form.
- A process according to claim 1 or 2, characterised in that the components are brought into contact with a solution or dispersion which additionally contains adhesion-promoting pigments, levelling agents and/or defoaming agents (additives).
- A process according to claim 1, 2 or 3, characterised in that the components are brought into contact with a solution or dispersion which has a temperature of 5 to 40°C.
- A process according to 1 or more of claims 1 to 4, characterised in that the surface-drying in stage b) is performed at a temperature in the range from 40 to 60°C.
- A process according to one or more of claims 1 to 5, characterised in that the final drying in stage d) is performed at an elevated temperature extending up to 200°C.
- Use of the process according to one or more of claims 1 to 6 as a pretreatment of the components for subsequent powder coating.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19725780A DE19725780A1 (en) | 1997-06-18 | 1997-06-18 | Applying plastic to metallic parts |
DE19725780 | 1997-06-18 | ||
PCT/EP1998/003617 WO1998057759A1 (en) | 1997-06-18 | 1998-06-16 | Application of plastic on individual metal parts |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0991483A1 EP0991483A1 (en) | 2000-04-12 |
EP0991483B1 true EP0991483B1 (en) | 2002-12-04 |
Family
ID=7832864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98936350A Expired - Lifetime EP0991483B1 (en) | 1997-06-18 | 1998-06-16 | Application of plastic on individual metal parts |
Country Status (6)
Country | Link |
---|---|
US (1) | US6299943B1 (en) |
EP (1) | EP0991483B1 (en) |
CN (1) | CN1134311C (en) |
DE (2) | DE19725780A1 (en) |
TW (1) | TW446581B (en) |
WO (1) | WO1998057759A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19947233A1 (en) * | 1999-09-30 | 2001-11-22 | Chemetall Gmbh | Process for producing a polymeric film on a metal surface, and concentrate and treatment liquid therefor |
DE19961411A1 (en) * | 1999-12-17 | 2001-06-21 | Chemetall Gmbh | Process for the production of coated metal surfaces and their use |
DE19962020A1 (en) * | 1999-12-22 | 2001-07-05 | Volkswagen Ag | Protectively coating a part particularly in the automobile industry comprises applying different layers of PVC powder and drying |
DE102014113000A1 (en) * | 2014-09-10 | 2016-03-10 | Rieter Ingolstadt Gmbh | Coating for a turntable |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2550232A (en) * | 1947-06-11 | 1951-04-24 | Ind Lining Engineers Inc | Method of coating metallic articles with vinyl resin dispersions |
JPS6321140A (en) * | 1986-07-14 | 1988-01-28 | 株式会社神戸製鋼所 | Aluminum alloy plate having excellent corrosion resistance |
US4948633A (en) * | 1989-08-23 | 1990-08-14 | Wu Mu Lin | Method for painting an article |
DE4032391A1 (en) | 1990-10-12 | 1992-04-16 | Hoechst Ag | Coat formation on substrate esp. for automobile(s) - using water thinnable base lacquer contg. metal-or coloured pigment, on which powdered pigment-free clear lacquer is formed etc. |
US5385655A (en) * | 1992-10-30 | 1995-01-31 | Man-Gill Chemical Company | Treatment of metal parts to provide rust-inhibiting coatings |
US5464650A (en) | 1993-04-26 | 1995-11-07 | Medtronic, Inc. | Intravascular stent and method |
DE4339773C2 (en) * | 1993-11-23 | 2001-12-13 | Nuetro Maschinen & Anlagen | Method and device for dip painting |
DE19643082C2 (en) | 1995-10-18 | 2003-10-30 | Volkswagen Ag | Process for the interior and exterior coating of a body with cavities |
-
1997
- 1997-06-18 DE DE19725780A patent/DE19725780A1/en not_active Withdrawn
-
1998
- 1998-04-28 TW TW087106548A patent/TW446581B/en not_active IP Right Cessation
- 1998-06-16 WO PCT/EP1998/003617 patent/WO1998057759A1/en active IP Right Grant
- 1998-06-16 EP EP98936350A patent/EP0991483B1/en not_active Expired - Lifetime
- 1998-06-16 CN CNB98806412XA patent/CN1134311C/en not_active Expired - Lifetime
- 1998-06-16 US US09/423,573 patent/US6299943B1/en not_active Expired - Lifetime
- 1998-06-16 DE DE59806549T patent/DE59806549D1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE59806549D1 (en) | 2003-01-16 |
CN1261296A (en) | 2000-07-26 |
US6299943B1 (en) | 2001-10-09 |
DE19725780A1 (en) | 1998-12-24 |
TW446581B (en) | 2001-07-21 |
WO1998057759A1 (en) | 1998-12-23 |
EP0991483A1 (en) | 2000-04-12 |
CN1134311C (en) | 2004-01-14 |
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