EP0973998A1 - Verfahren zur kühlung einer turbinenschaufel - Google Patents
Verfahren zur kühlung einer turbinenschaufelInfo
- Publication number
- EP0973998A1 EP0973998A1 EP98924039A EP98924039A EP0973998A1 EP 0973998 A1 EP0973998 A1 EP 0973998A1 EP 98924039 A EP98924039 A EP 98924039A EP 98924039 A EP98924039 A EP 98924039A EP 0973998 A1 EP0973998 A1 EP 0973998A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cooling
- turbine blade
- cooling fluid
- wall
- fluid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/14—Form or construction
- F01D5/18—Hollow blades, i.e. blades with cooling or heating channels or cavities; Heating, heat-insulating or cooling means on blades
- F01D5/187—Convection cooling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/14—Form or construction
- F01D5/18—Hollow blades, i.e. blades with cooling or heating channels or cavities; Heating, heat-insulating or cooling means on blades
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2260/00—Function
- F05D2260/20—Heat transfer, e.g. cooling
- F05D2260/201—Heat transfer, e.g. cooling by impingement of a fluid
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2260/00—Function
- F05D2260/20—Heat transfer, e.g. cooling
- F05D2260/202—Heat transfer, e.g. cooling by film cooling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2260/00—Function
- F05D2260/20—Heat transfer, e.g. cooling
- F05D2260/205—Cooling fluid recirculation, i.e. after cooling one or more components is the cooling fluid recovered and used elsewhere for other purposes
Definitions
- the invention relates to a turbine blade which has an inflow area, an outflow area and between them opposite one another, a pressure side and a suction side and also a wall structure around which an action fluid can flow.
- the wall structure includes an outer wall surrounding an interior for guiding cooling fluid.
- the invention further relates to the use of such a turbine blade and a method for cooling a turbine blade around which a hot action fluid flows.
- a guide vane of a gas turbine with a guide of cooling air for cooling it is described in US Pat. No. 5,419,039.
- the guide vane is designed as a casting or composed of two castings. In its interior, it has a supply of cooling air from the compressor of the associated gas turbine system.
- cast-in cooling pockets which are open on one side are provided in their wall structure exposed to the hot gas flow of the gas turbine and enclosing the cooling air supply.
- the cooling pockets are arranged on the outside of the wall structure both in the direction of flow of the hot gas and perpendicular to the direction of flow of the hot gas along the main direction of expansion of the guide vane. Cooling air flows into the cooling bag from the cooling air supply through a plurality of holes in the wall structure into each cooling bag. This is in the flow direction of the
- the cooling air exits into the flow of the hot gas in an opening area already formed by the casting of the guide vanes. In this way, film cooling is achieved to a certain extent on the outer surface of the wall structure.
- One or more unspecified bases can be placed in the cooler bag to improve the heat line should be provided.
- GB 21 12 869 describes a gas turbine blade which has a wall structure which determines the blade shape and has two cooling air supply chambers and one cooling air discharge chamber. Cooling channels are arranged on the outside of the wall structure in the direction of flow. The cooling channels are introduced as depressions in the form of elongated grooves in the wall structure. The cooling ducts are connected on the one hand in terms of flow technology to a cooling air supply chamber and on the other hand to the cooling air discharge chamber. In order to close off the cooling channels from the outside, a metal sheet completely surrounding the turbine blade is arranged.
- the object of the invention is to provide a turbine blade with a coolable wall structure. Further tasks consist in specifying the use of such a turbine blade and a method for cooling a turbine blade which is exposed to a hot action fluid.
- the object directed to a turbine blade is achieved by such a turbine blade according to the preamble of claim 1, in which at least one cooling chamber thermally coupled to the outer wall with an inlet and an outlet for cooling fluid and in the interior at least one cooling fluid supply and one cooling fluid discharge are provided .
- the cooling chamber is connected to the cooling fluid supply via the inlet and to the cooling fluid discharge via the outlet.
- several inlets and outlets per cooling chamber can also be provided.
- Such a turbine blade can thus be cooled by cooling fluid, which is guided entirely inside the turbine blade.
- a closed cooling circuit is therefore formed in the turbine blade. That through the turbine Cooling fluid that flows through and heats up can be fed to a further turbine blade or a component of the turbine system assigned to the turbine blade, for example a combustion chamber wall, for further cooling purposes.
- Such a closed cooling circuit allows a cooling fluid to be used, for example steam, which should not flow into the action fluid flowing around the turbine blade.
- the cooling fluid can first be used to cool a guide blade which is subjected to the greatest thermal stress and then a rotor blade axially downstream of the guide blade.
- a closed cooling circuit m of the turbine blade also prevents the hot action fluid flowing around the turbine blade from being influenced, as a result of which the aerodynamic efficiency is increased.
- the cooling chamber extends both in the direction of flow and perpendicularly thereto (i.e. essentially in the direction of a main axis of the turbine blade), in particular the extent perpendicular to the direction of flow can be approximately as large or larger than in the direction of flow. Due to this two-dimensional expansion of the cooling chamber, a uniform cooling performance is achieved. In particular, a uniform temperature distribution can be achieved, which leads to an extension of the lifespan of the turbine blade by avoiding high temperature gradients, as can occur in individual cooling channels, due to the wide webs of solid material that are inevitably present between the cooling channels. Furthermore, by way of the type, location, size and number of inlets and outlets, cooling fluid can be adapted to the cooling requirements and flow into the cooling chamber. As a result, significantly less cooling fluid is required to achieve a specific cooling output than when using a plurality of individual cooling channels.
- the cooling chamber is preferably cast in the wall structure. This ensures that a closed cooling system is formed. By poured Kuhlhunt the risk of the cooling system is one Abred mitchanenden sheath in ⁇ follow high mechanical and thermal loads reliably avoided. In addition, the cooling chamber can be produced simply and with high accuracy in one work step with the turbine blade by casting.
- the turbine blade extends along a main axis, the outlet and the inlet being arranged such that the cooling chamber can preferably be formed with a flow of cooling fluid substantially perpendicular to the main axis.
- a plurality of cooling chambers are preferably provided on the pressure side and / or the suction side of the turbine blade, so that effective cooling of the outer wall is ensured even in the case of complicatedly shaped turbine blades.
- a guide vane of a stationary gas turbine can have three times three cooling chambers both on the suction side and on the pressure side and, depending on the heat transfer to be achieved, also more or fewer cooling chambers.
- the cooling chambers are preferably fed with cooling fluid from at least two cooling fluid feeds, which cooling fluid can also be removed from the turbine blade again by means of at least two cooling fluid discharges.
- the cooling fluid supplies and cooling fluid discharges are preferably parallel to one another in terms of flow technology.
- the cooling fluid inlets and outlets are arranged alternately one behind the other in a direction perpendicular to the main axis, so that cooling chambers arranged one behind the other can be supplied with cooling fluid with little design effort.
- Particularly effective cooling is achieved if the outer wall to be cooled is made as thin as possible.
- the outer wall preferably has, at least in some areas, an average wall thickness which is less than 2.5 mm, in particular approximately 1 mm.
- the conceptual division of the wall structure allows an outer wall and an inner wall to decouple the functional properties of the wall structure, with less demands being placed on the mechanical stability on the outer wall than on the inner wall.
- the inner wall can therefore, since it is not directly exposed to a flow of a hot action fluid, in particular a hot gas, be made with a greater wall thickness than the outer wall. It can essentially take over the mechanical supporting function for the turbine blade.
- the outer wall on the other hand, can be designed with a smaller wall thickness, as a result of which it can be cooled particularly effectively via heat transfer elements.
- heat transfer elements which can flow around the cooling fluid and which are thermally connected to the outer wall are preferably arranged one behind the other in a main flow direction of the cooling fluid. This ensures effective heating of the cooling fluid in the cooling chamber over a long distance.
- the warm-technical connection of the heat transfer elements with the outer wall ensures effective heat transfer from the outer wall to the cooling fluid.
- the cross-section of the cooling area between the inner wall and the outer wall is preferably made small to form a high speed of the cooling fluid and is in particular in the region of the wall thickness of the outer wall. Due to a smaller cross-section of the cooling chamber and a high speed of the cooling fluid, high heat transfer rates can be achieved.
- the main direction of flow m of the cooling chamber preferably corresponds to that Direction of flow of an action fluid flowing around the turbine blade, or is the opposite.
- the heat transfer elements are preferably column-like or platform-like and extend from the outer wall to the inner wall. They can also be firmly connected to the inner wall.
- the cross section of the heat transfer elements can be adapted to the heat transfer and flow technology requirements, for example circular, polygonal or in the form of a flow profile.
- the turbine blade with a wall structure comprising at least one cooling chamber, which is arranged between an outer wall and an inner wall, can be produced as a whole by casting in one work step.
- the turbine blade can also contain two or more cast parts, which are firmly connected to one another after casting by suitable methods (joining method).
- the outlet and the inlet are made by casting.
- the turbine blade preferably has a large number of cooling chambers both along its main axis and in a plane perpendicular to the main axis.
- the inlet is preferably made approximately perpendicular to the outer wall, so that incoming cooling fluid impinges on the outer wall, whereby additional impingement cooling of the outer wall can be achieved at least in the area of the inlet.
- An additional cooling fluid supply is preferably provided in the upstream area and / or in the downstream area, which feeds through at least one outlet on the outer surface of the outer wall.
- the additional cooling fluid supply as well as the cooling fluid supply and the cooling fluid discharge are directed essentially parallel to the main axis of the turbine blade.
- ⁇ m sondere the Anstrom Siemens the turbine blade to a plurality of outlets, which may be implemented for example as bores.
- the cooling fluid that reaches the outer surface of the turbine blade through the outlets enables light the formation of a cooling fluid film on the outer surface.
- the thermally highly stressed inflow area can therefore also be cooled from the outside according to the so-called film cooling principle.
- the inflow area and the outflow area can be cooled with a different cooling fluid than the outer wall in the area of the suction and pressure side due to the separate cooling fluid supply system. It is particularly suitable for cooling the outflow area and the inflow area in a turbine blade for a gas turbine, cooling air which can be supplied in particular by a compressor assigned to the gas turbine. In addition to a cooling gas, in particular cooling air from a compressor in a gas turbine system, water vapor, which has a higher heat transfer ratio than air, is also suitable for cooling the cooling chambers.
- a turbine blade is preferably suitable for use in a gas turbine, hot gas flowing around the turbine blade. At a temperature of the hot gas which is above the melting temperature of the base material of the turbine blade, cooling of the turbine blade prevents failure.
- the temperature on the outer wall can be reduced to an uncritical temperature level by cooling by means of the closed cooling circuit. Cooling fluid from the interior leads to a convective transition and to heat conduction through the outer wall, as a result of which the surface of the outer wall can be cooled sufficiently.
- the turbine blade can be both a rotor blade and a guide blade, each of which is connected to the housing of the turbine or the rotor of the turbine via a suitable fastening device, for example a blade root.
- the turbine blade according to the invention is therefore particularly suitable for use as a moving blade or guide blade in a gas turbine system, in particular in a gas turbine system.
- bine m the temperatures of well over 1000 ° C of the hot gas flowing around the turbine blade occur.
- the object directed to a method for cooling a turbine blade is achieved in that, in the case of a turbine blade which has a wall structure which is surrounded by a hot action fluid, the wall structure comprising an outer wall which surrounds an interior space, through a first cooling fluid a cooling fluid supply is introduced into the interior h - from there m a thermally to the
- the cooling chamber coupled to the outer wall flows and the interior flows out of the turbine blade again through a cooling fluid discharge.
- Such cooling prevents cooling fluid from reaching the flow of the hot action fluid and thus influencing the flow of the action fluid to reduce efficiency. An increase in efficiency can therefore be achieved.
- a cooling fluid different from the hot action fluid can also be used by a closed cooling process.
- steam can be used as the cooling fluid in a gas turbine in which the action fluid is a hot gas. In the case of a combined gas and steam turbine system, for example, this steam can be easily removed from a steam turbine connected downstream of the gas turbine.
- a further cooling fluid is preferably fed to the flow area and / or the flow area of the turbine blade and the action fluid is conveyed through the wall structure. In addition to cooling the inflow area and / or the outflow area, this also ensures film cooling on the outer surface of the turbine blade.
- Both the cooling fluid supplied to the additional cooling fluid feeds and the cooling fluid supplied to the upstream and / or downstream region preferably flow in the interior parallel to the main axis of the turbine blade, each partial flow into or through the cooling chambers Outlets in the upstream and downstream areas are fed to the hot action fluid.
- Figures 1 and 2 each show schematically below Dar ⁇ position of the structural and functional characteristics used for explanation of a turbine blade of a gas turbine in a cross section.
- FIG. 1 shows a turbine blade 1 of a gas turbine that extends along a main axis 19.
- the turbine blade 1 can be curved, twisted and twisted along the main axis 19, so that the cross section of the turbine blade 1 shown in the figure can change over the main axis 19.
- the turbine blade 1 has a blade root for attachment at one end, not shown.
- the turbine blade 1 has a wall structure 2 with an inflow region 8, an outflow region 9 and a pressure side 10 and a suction side 11, which are arranged opposite one another.
- the wall structure 2 also has an outer wall 3 which encloses an interior 21.
- cooling fluid feeds 22, 22a, cooling fluid discharges 23, 23a and additional cooling fluid feeds 25, 25a which are separated from one another in terms of flow technology, are provided, each of which is directed essentially parallel to the main axis 19.
- the cooling fluid feeds 22, 22a, 25, 25a and cooling fluid discharges 23, 23a mentioned extend from the blade root (not shown) to a second end (not shown) opposite the first end of the turbine blade 1, where they are closed.
- a hot gas 18 (action fluid) flows around the turbine blade 1, so that the hot gas 18 can act on an outer surface 14 of the outer wall 3.
- the hot gas 18 flows the turbine blade 1 at the inflow region 8 and flows along the turbine blade 1 to the outflow region 9.
- the wall structure 2 has a plurality of cooling chambers 20 arranged one behind the other. Further cooling chambers 20, not shown, are provided on the suction side 10 and on the pressure side 11 m in the direction of the main axis 19.
- the cooling chambers 20 are arranged between an inner wall 4 facing the interior 21 and the outer wall 3.
- Each cooling chamber 20 has a respective inlet 15 for cooling fluid 6, which is in each case connected to an associated cooling fluid supply 22, 22a.
- each cooling chamber 20 has an outlet 16, which establishes a flow-technical connection between the cooling chamber 20 and an associated cooling fluid drain 23, 23a.
- the cooling chambers 20 can each be flowed through by the cooling fluid 6 m in the direction or counter to the flow direction of the hot gas 18.
- a plurality of heat transfer elements 7 arranged downstream of one another are arranged in each cooling chamber 20. Further heat transfer elements 7 arranged in the cooling chambers along the axis 19 are not shown.
- the additional cooling fluid supply 25 m in the inflow region 8 has a plurality of outlets 16, through which cooling fluid 6 a reaches the outer surface 14 of the turbine blade 1. This results in additional film cooling of the turbine blade 1 the cooling fluid 6a ensured.
- the additional fluid supply 25a of the outflow region 9 likewise has an outlet 16a for the outflow of cooling fluid 6a, heat transfer elements 7 being arranged between the outer walls of the suction side 11 and the pressure side 10.
- Cooling fluid 6 is discharged into each partial flow into each cooling chamber 20 arranged axially one above the other. Each partial flow flows through the cooling chamber 20 and receives heat via a heat exchange with the outer wall 3 and the heat transfer elements 7, as a result of which the outer wall 3 is cooled. After flowing through the cooling chamber 20, each partial flow enters a cooling fluid discharge 23, 23a em. The cooling fluid flow combined again in the cooling fluid discharges 23, 23a comes out of the turbomachine blade 1 again through the first end (not shown). The cooling fluid 6 can thus be reused for cooling a further component of the gas turbine.
- externally cooled cooling air can flow through a first row of turbine guide vanes, which are exposed to the hot gas at the highest temperature, and the heated cooling air can be fed to the first turbine blade row immediately downstream of the first guide blade row.
- the same cooling fluid 6 or another cooling fluid 6a can be supplied to the inflow region 8 and / or the outflow region 9 via the additional cooling fluid supply 25, 25a.
- This cooling fluid 6a enters the flow of the hot gas 18 via the outlets 16a and thus enables film cooling of the inflow region 8 or the outflow region 9.
- FIG. 2 A turbine blade 1 with a closed cooling circuit for cooling fluid 6 is shown in FIG. 2 analogously to FIG.
- the turbine blade 1 according to FIG. 2 is similar to that Turbine blade 1 constructed according to Figure 1.
- the cooling chambers 20 extend both into the inflow region 8 and m into the outflow region 9, so that these regions 8, 9 can also be cooled in a closed cooling circuit via the cooling fluid 6 m.
- the explanations regarding the guidance of the cooling fluid, the cooling chambers 20, the cooling fluid discharge 23, 23a and the cooling fluid supply 22, 22a relating to FIG. 1 also apply accordingly to the turbine blade 1 according to FIG. 2.
- the meaning of the reference symbols in FIG. 2 corresponds to the meaning of the reference symbols Figure 1
- the invention is characterized in that the outer wall of a turbine blade on the suction side and the pressure side can be cooled by a closed cooling circuit.
- Cooling fluid supplies are supplied to cooling chambers with cooling fluid, in particular cooling air or water vapor.
- the cooling fluid flowing through the cooling chambers passes out of the cooling fluid discharge means provided in the turbine blade, without coming into the flow of a hot action fluid flowing around the turbine blade.
- the upstream and downstream areas of the turbine blade can be cooled with an open cooling system, wherein a cooling fluid other than that used in the closed cooling circuit can be used.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19714285 | 1997-04-07 | ||
DE19714285 | 1997-04-07 | ||
PCT/DE1998/000874 WO1998045577A1 (de) | 1997-04-07 | 1998-03-24 | Verfahren zur kühlung einer turbinenschaufel |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0973998A1 true EP0973998A1 (de) | 2000-01-26 |
EP0973998B1 EP0973998B1 (de) | 2001-09-19 |
Family
ID=7825674
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98924039A Expired - Lifetime EP0973998B1 (de) | 1997-04-07 | 1998-03-24 | Verfahren zur kühlung einer turbinenschaufel |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0973998B1 (de) |
JP (1) | JP4170400B2 (de) |
KR (1) | KR20010006106A (de) |
DE (1) | DE59801529D1 (de) |
WO (1) | WO1998045577A1 (de) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5931638A (en) * | 1997-08-07 | 1999-08-03 | United Technologies Corporation | Turbomachinery airfoil with optimized heat transfer |
DE19738065A1 (de) * | 1997-09-01 | 1999-03-04 | Asea Brown Boveri | Turbinenschaufel einer Gasturbine |
US6506013B1 (en) * | 2000-04-28 | 2003-01-14 | General Electric Company | Film cooling for a closed loop cooled airfoil |
US6435814B1 (en) * | 2000-05-16 | 2002-08-20 | General Electric Company | Film cooling air pocket in a closed loop cooled airfoil |
GB0114503D0 (en) * | 2001-06-14 | 2001-08-08 | Rolls Royce Plc | Air cooled aerofoil |
FR2829174B1 (fr) | 2001-08-28 | 2006-01-20 | Snecma Moteurs | Perfectionnement apportes aux circuits de refroidissement pour aube de turbine a gaz |
FR2858352B1 (fr) * | 2003-08-01 | 2006-01-20 | Snecma Moteurs | Circuit de refroidissement pour aube de turbine |
US9115590B2 (en) * | 2012-09-26 | 2015-08-25 | United Technologies Corporation | Gas turbine engine airfoil cooling circuit |
EP3158169A1 (de) * | 2014-06-17 | 2017-04-26 | Siemens Energy, Inc. | Turbinenschaufelkühlsystem mit anströmkantenprallkühlungssystem und wandnahem prallsystem |
US10247012B2 (en) | 2014-12-18 | 2019-04-02 | Rolls-Royce Plc | Aerofoil blade or vane |
US10801344B2 (en) * | 2017-12-18 | 2020-10-13 | Raytheon Technologies Corporation | Double wall turbine gas turbine engine vane with discrete opposing skin core cooling configuration |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3191908A (en) * | 1961-05-02 | 1965-06-29 | Rolls Royce | Blades for fluid flow machines |
DE1601613A1 (de) * | 1967-08-03 | 1970-12-17 | Motoren Turbinen Union | Turbinenschaufel,insbesondere Turbinenleitschaufel fuer Gasturbinentriebwerke |
IT1153370B (it) * | 1981-12-09 | 1987-01-14 | Westinghouse Electric Corp | Elemento a profilo aerodinamico per palette di turbina a combustione, raffreddato tra il longherone e l'involucro, utilizzante cavita' multiple del longherone |
JPS58197402A (ja) * | 1982-05-14 | 1983-11-17 | Hitachi Ltd | ガスタ−ビン翼 |
US5405242A (en) | 1990-07-09 | 1995-04-11 | United Technologies Corporation | Cooled vane |
US5295530A (en) * | 1992-02-18 | 1994-03-22 | General Motors Corporation | Single-cast, high-temperature, thin wall structures and methods of making the same |
-
1998
- 1998-03-24 EP EP98924039A patent/EP0973998B1/de not_active Expired - Lifetime
- 1998-03-24 JP JP54222798A patent/JP4170400B2/ja not_active Expired - Fee Related
- 1998-03-24 DE DE59801529T patent/DE59801529D1/de not_active Expired - Lifetime
- 1998-03-24 KR KR1019997009184A patent/KR20010006106A/ko not_active Application Discontinuation
- 1998-03-24 WO PCT/DE1998/000874 patent/WO1998045577A1/de not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO9845577A1 * |
Also Published As
Publication number | Publication date |
---|---|
JP4170400B2 (ja) | 2008-10-22 |
EP0973998B1 (de) | 2001-09-19 |
WO1998045577A1 (de) | 1998-10-15 |
KR20010006106A (ko) | 2001-01-26 |
DE59801529D1 (de) | 2001-10-25 |
JP2001521599A (ja) | 2001-11-06 |
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