EP0876522B1 - Procédé de production de fibres de cellulose - Google Patents
Procédé de production de fibres de cellulose Download PDFInfo
- Publication number
- EP0876522B1 EP0876522B1 EP96945731A EP96945731A EP0876522B1 EP 0876522 B1 EP0876522 B1 EP 0876522B1 EP 96945731 A EP96945731 A EP 96945731A EP 96945731 A EP96945731 A EP 96945731A EP 0876522 B1 EP0876522 B1 EP 0876522B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fibers
- post
- bath
- pct
- orientation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/02—Chemical after-treatment of artificial filaments or the like during manufacture of cellulose, cellulose derivatives, or proteins
Definitions
- the invention relates to a method for manufacturing of cellulose fibers with reduced orientation and reduced module.
- NMMNO N-methyl-morpholine-N-oxide
- the fibers produced by the NMMNO process are high strength compared to viscose fibers and characteristic of moduli. This is the tensile strength generally in an approximate range of approx. 20 to 50 cN / tex and the initial moduli in one Range over approx. 1500 cN / tex. That means that Strengths pleasantly high, often even higher than required are.
- the high Module usually through a high orientation of the Causes fibers, and the high orientation is decisive responsible for a strong inclination of the Fibrillating fibers. This high tendency to fibrillate however affects many applications of the fibers in the textile area unfavorable.
- the task related to the manufacturing process The fiber is characterized by its distinctive features of claim 1 solved.
- the sub-claims show advantageous Further training.
- the method according to the invention is carried out in such a way that that in and of itself from the state of the art Technology known from spinning solutions the cellulose in amine oxides, preferably in N-methyl-morpholine-N-oxide (NMMNO) is assumed.
- NMMNO N-methyl-morpholine-N-oxide
- the special properties of the after the amine oxide process fibers are made by structural Characteristics marked, one opposite textile viscose fibers more compact precipitation structure with increased crystallinity and chain orientation as well as changed crystallite form can be determined. In particular, it shows that with increasing orientation the module and the tendency to fibrillation increase. It is also known to have springs in the water all types of fibers made from regenerated cellulose (modal fibers, Viscose fibers, polynosic fibers) to reduce Strength, crystallinity and orientation leads. This effect increases - with the exception of Effect on orientation - when swelling in dilute Caustic soda. This also applies to from NMMNO solution spun fibers. The structural parameters mentioned however, always remain at a higher level than with the other fibers (J.
- an aftertreatment bath used the water and contains water-mixed alkanols, diols, triols. It is preferred if this is the first Post-treatment bath alkali is added. As special a mixture of alkanols, proven preferably from ethanol and sodium hydroxide solution.
- the aftertreatment bath preferably consists of Ethanol and 1 to 30%, preferably 8 to 20% sodium hydroxide solution.
- a subsequent wash bath is necessary to Components of the first post-treatment bath, the cannot be removed by drying the threads (e.g. sodium hydroxide solution).
- the composition of this Wash bath affects the properties of the threads.
- the wash bath preferably contains water, an alcohol, a diol or a triol or a mixture from that. It is particularly preferred if that Wash bath contains ethanol. That is the orientation the amorphous areas and the module of the threads clearly lower if after treatment in an ethanol / sodium hydroxide bath as a washing bath instead of ethanol of water is used during orientation the crystalline areas after both types of treatment is practically the same.
- the tensile load can be between 0 and 60%, preferably between 0 and 40%.
- a solution consisting of 9% cellulose, 79% NMMNO and 12% water is spun by means of an extruder through a 40-hole nozzle with a hole diameter of 0.1 mm into an aqueous precipitation bath.
- the undried threads are then partially subjected to post-treatment in a special bath, then washed and dried without tensile stress.
- f a and f c are the orientation factors for the amorphous or crystalline fraction according to "Hermans” (in “Physics and Chemistry of Cellulose Fibers", Elsevier Publishing Company, New York, 1949). They are 1 for ideal orientation and 0 for ideal anisotropy.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Claims (8)
- Procédé de production de fibres de cellulose flexibles par filage des solutions de cellulose à travers des filières par l'intermédiaire d'une couche d'air dans un bain de régénération aqueux et/ou alcoolique contenant un oxyde d'amine et séchage subséquent,
caractérisé en ce que
les fils humides après filage sont conduits avant le séchage, à travers au moins un bain de retraitement contenant de l'eau et des alkanols, des diols, des triols, miscibles à l'eau ou leurs mélanges et au moins un bain de lavage contenant de l'eau, un alkanol, un diol ou un triol. - Procédé selon la revendication 1,
caractérisé en ce que
le bain de retraitement est alcalin. - Procédé selon la revendication 1 ou 2,
caractérisé en ce que
le bain de retraitement consiste en un mélange d'alkanols et de lessive de soude. - Procédé selon la revendication 3,
caractérisé en ce que
le bain de retraitement consiste en de l'éthanol et de 1 à 30 % de lessive de soude. - Procédé selon au moins l'une quelconque des revendications 1 à 4,
caractérisé en ce que
le bain de lavage contient un alkanol. - Procédé selon la revendication 5,
caractérisé en ce que
le bain de lavage contient de l'éthanol. - Procédé selon au moins l'une quelconque des revendications 1 à 6,
caractérisé en ce que
les fibres lors du séchage sont soumises à une charge de traction. - Procédé selon la revendication 7,
caractérisé en ce que
la charge de traction se situe entre 0 et 60 % de la résistance à l'état humide.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19600572 | 1996-01-09 | ||
DE19600572A DE19600572B4 (de) | 1996-01-09 | 1996-01-09 | Verfahren zur Herstellung von Cellulosefasern und die mit diesem Verfahren hergestellten Fasern |
PCT/DE1996/002190 WO1997025462A1 (fr) | 1996-01-09 | 1996-11-13 | Procede de production de fibres de cellulose et fibres obtenues a l'aide dudit procede |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0876522A1 EP0876522A1 (fr) | 1998-11-11 |
EP0876522B1 true EP0876522B1 (fr) | 2001-03-21 |
Family
ID=7782391
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96945731A Expired - Lifetime EP0876522B1 (fr) | 1996-01-09 | 1996-11-13 | Procédé de production de fibres de cellulose |
Country Status (5)
Country | Link |
---|---|
US (1) | US6103162A (fr) |
EP (1) | EP0876522B1 (fr) |
AT (1) | ATE199943T1 (fr) |
DE (2) | DE19600572B4 (fr) |
WO (1) | WO1997025462A1 (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0853146A3 (fr) * | 1997-01-09 | 1999-03-24 | Akzo Nobel N.V. | Procédé de production de fibres cellulosiques et fibres cellulosiques |
AT406588B (de) * | 1998-09-29 | 2000-06-26 | Chemiefaser Lenzing Ag | Verfahren zur herstellung cellulosischer fasern |
DE10043297B4 (de) * | 2000-09-02 | 2005-12-08 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Verfahren zur Herstellung von Cellulosefasern und Cellulosefilamentgarnen |
AT413285B (de) * | 2003-11-06 | 2006-01-15 | Chemiefaser Lenzing Ag | Verfahren zum waschen eines saugfähigen materials |
AT413286B (de) * | 2003-11-06 | 2006-01-15 | Chemiefaser Lenzing Ag | Verfahren zum waschen eines saugfähigen materials |
AT413287B (de) * | 2003-11-25 | 2006-01-15 | Chemiefaser Lenzing Ag | Verfahren zur herstellung cellulosischer fasern |
TWI667378B (zh) * | 2014-01-03 | 2019-08-01 | 奧地利商蘭精股份有限公司 | 纖維素纖維 |
EP3536853A1 (fr) | 2018-03-06 | 2019-09-11 | Lenzing Aktiengesellschaft | Fibre lyocell à formation de bouloche réduite |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9103297D0 (en) * | 1991-02-15 | 1991-04-03 | Courtaulds Plc | Fibre production method |
DE4420304C1 (de) * | 1994-06-10 | 1995-09-21 | Fraunhofer Ges Forschung | Flexible Cellulosefasern mit reduziertem Modul und vermindertem NMR-Ordnungsgrad und deren Herstellung |
-
1996
- 1996-01-09 DE DE19600572A patent/DE19600572B4/de not_active Expired - Fee Related
- 1996-11-13 US US09/091,679 patent/US6103162A/en not_active Expired - Fee Related
- 1996-11-13 WO PCT/DE1996/002190 patent/WO1997025462A1/fr active IP Right Grant
- 1996-11-13 EP EP96945731A patent/EP0876522B1/fr not_active Expired - Lifetime
- 1996-11-13 DE DE59606647T patent/DE59606647D1/de not_active Expired - Lifetime
- 1996-11-13 AT AT96945731T patent/ATE199943T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ATE199943T1 (de) | 2001-04-15 |
DE59606647D1 (de) | 2001-04-26 |
DE19600572A1 (de) | 1997-07-10 |
EP0876522A1 (fr) | 1998-11-11 |
DE19600572B4 (de) | 2005-03-10 |
US6103162A (en) | 2000-08-15 |
WO1997025462A1 (fr) | 1997-07-17 |
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