EP0826766A2 - Waschmittelzusammensetzung - Google Patents

Waschmittelzusammensetzung Download PDF

Info

Publication number
EP0826766A2
EP0826766A2 EP97306644A EP97306644A EP0826766A2 EP 0826766 A2 EP0826766 A2 EP 0826766A2 EP 97306644 A EP97306644 A EP 97306644A EP 97306644 A EP97306644 A EP 97306644A EP 0826766 A2 EP0826766 A2 EP 0826766A2
Authority
EP
European Patent Office
Prior art keywords
chain
long
acyl
salt
amino acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP97306644A
Other languages
English (en)
French (fr)
Other versions
EP0826766B1 (de
EP0826766A3 (de
EP0826766B2 (de
Inventor
Eiko C. Res. Lab. Ajinomoto Co. Inc. Oshimura
Hideki C. Res. Lab. Ajinomoto Co. Inc. Yoshihara
Kazutami C. Res. Lab. Ajinomoto Co. Inc. Sakamoto
Tatsuya Tokai Plant Ajinomoto Co. Inc. Hattori
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Original Assignee
Ajinomoto Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=16911924&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0826766(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ajinomoto Co Inc filed Critical Ajinomoto Co Inc
Priority to DE69723375T priority Critical patent/DE69723375T3/de
Publication of EP0826766A2 publication Critical patent/EP0826766A2/de
Publication of EP0826766A3 publication Critical patent/EP0826766A3/de
Publication of EP0826766B1 publication Critical patent/EP0826766B1/de
Application granted granted Critical
Publication of EP0826766B2 publication Critical patent/EP0826766B2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/10Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/37Mixtures of compounds all of which are anionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143Sulfonic acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines

Definitions

  • the wash composition of the present invention may contain another surface active agent to adjust washability and a lathering properties unless this impairs the effect of the present invention.
  • surface active agents include anionic surface active agents such as higher fatty acid salts, alkyl sulfonates, alkylbenzene sulfonates, ⁇ -olefin sulfonates, polyoxyethylenealkyl ether sulfonates, N-acyl aminocarboxylates, polyoxyethylenealkyl ether carboxylates, alkyl ether phosphates and sulfosuccinic acids; ampholytic surface active agents such as alkylbetaine surface active agents, amidobetaine surface active agents, alkylsulfobetaine surface active agents, amidosulfobetaine surface active agents and imidazoline surface active agents; nonionic surface active agents such as sugar ether surface active agents, sugar amide surface active agents, sugar ester surface active agents, alkyl saccharide surface active agents, polyoxyethyleneal

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)
EP97306644A 1996-08-30 1997-08-29 Waschmittelzusammensetzung Expired - Lifetime EP0826766B2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE69723375T DE69723375T3 (de) 1996-08-30 1997-08-29 Waschmittelzusammensetzung

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP230698/96 1996-08-30
JP23069896 1996-08-30
JP23069896 1996-08-30

Publications (4)

Publication Number Publication Date
EP0826766A2 true EP0826766A2 (de) 1998-03-04
EP0826766A3 EP0826766A3 (de) 1999-02-03
EP0826766B1 EP0826766B1 (de) 2003-07-09
EP0826766B2 EP0826766B2 (de) 2011-07-20

Family

ID=16911924

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97306644A Expired - Lifetime EP0826766B2 (de) 1996-08-30 1997-08-29 Waschmittelzusammensetzung

Country Status (4)

Country Link
US (1) US5854199A (de)
EP (1) EP0826766B2 (de)
DE (1) DE69723375T3 (de)
ES (1) ES2202554T5 (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1669055A1 (de) * 2003-10-02 2006-06-14 Asahi Kasei Chemicals Corporation Waschmittel
EP1672055A1 (de) * 2003-10-03 2006-06-21 Ajinomoto Co., Inc. Waschmittel und deren herstellung
EP2246036A1 (de) * 2009-04-27 2010-11-03 KPSS-Kao Professional Salon Services GmbH Wässrige Reinigungszusammensetzung

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11181477A (ja) * 1997-12-18 1999-07-06 Kao Corp 洗浄剤組成物
JP3888576B2 (ja) * 2001-06-06 2007-03-07 味の素株式会社 新規化粧料組成物
US10836712B2 (en) * 2012-03-30 2020-11-17 Givaudan S.A. Organic compounds
WO2014070689A1 (en) 2012-10-29 2014-05-08 The Procter & Gamble Company Personal care compositions having a tan delta of 0.30 or more at 10°c
WO2015064678A1 (ja) 2013-10-31 2015-05-07 味の素株式会社 N-長鎖アシル酸性アミノ酸および/またはその塩を含む水溶液、並びにその製造方法
US20170119841A1 (en) * 2015-11-04 2017-05-04 Thetis Pharmaceuticals Llc Amino acid salts of unsaturated fatty acids
CA3056156A1 (en) * 2016-03-24 2018-09-28 Cysal Gmbh Aspartyl-dipeptides for skin care and cosmetic use
EP4375270A1 (de) * 2021-07-23 2024-05-29 Suzhou Oulit Biopharm Co., Ltd. Supramolekulare aminosäure oder salz davon sowie herstellungsverfahren dafür und anwendung davon

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4835058B1 (de) 1970-03-23 1973-10-25
US4116768A (en) * 1975-04-29 1978-09-26 (Zaidanhojin) Sagami Chemical Research Center Process for producing a peptide
JPS632962A (ja) 1986-01-24 1988-01-07 Kawaken Fine Chem Co Ltd N−長鎖アシルアミノ酸型界面活性剤の製造方法および該活性剤を含有する液体洗浄剤組成物
JPH01272697A (ja) * 1988-04-26 1989-10-31 Ajinomoto Co Inc 液体洗浄剤組成物
JP2731865B2 (ja) 1989-09-27 1998-03-25 川研ファインケミカル株式会社 ゲル状洗浄剤
US5120463A (en) * 1989-10-19 1992-06-09 Genencor International, Inc. Degradation resistant detergent compositions based on cellulase enzymes
US5688290A (en) * 1989-10-19 1997-11-18 Genencor International, Inc. Degradation resistant detergent compositions based on cellulase enzymes
JPH06507172A (ja) * 1991-04-19 1994-08-11 アフィニティー バイオテック,インコーポレイテッド 転換可能なミクロエマルジョン処方剤
GB2259703B (en) * 1991-08-26 1995-01-04 Kao Corp N-(N'-long chain acyl-ß-alanyl)-ß-alanine or its salt and detergent composition containing the same
US5427711A (en) * 1991-12-29 1995-06-27 Kao Corporation Synthesized inorganic ion exchange material and detergent composition containing the same
FR2705673B1 (fr) * 1993-05-25 1995-07-28 Givaudan Lavirotte Compositions comportant des dérivés d'acides aminés, leurs procédés de préparation et leurs utilisations.
US5393468A (en) * 1993-07-14 1995-02-28 Colgate Palmolive Company Hard surface cleaner
JPH1081656A (ja) 1996-09-06 1998-03-31 Ajinomoto Co Inc N−長鎖アシル酸性アミノ酸またはその塩の製造法
JP3522494B2 (ja) 1997-05-07 2004-04-26 カネボウ株式会社 パール光沢を有する洗浄料組成物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1669055A1 (de) * 2003-10-02 2006-06-14 Asahi Kasei Chemicals Corporation Waschmittel
KR100789686B1 (ko) * 2003-10-02 2008-01-03 아사히 가세이 케미칼즈 가부시키가이샤 세정제 조성물
EP1669055A4 (de) * 2003-10-02 2008-07-30 Asahi Kasei Chemicals Corp Waschmittel
US8425889B2 (en) 2003-10-02 2013-04-23 Asahi Kasei Chemicals Corporation Cleansing composition
EP1672055A1 (de) * 2003-10-03 2006-06-21 Ajinomoto Co., Inc. Waschmittel und deren herstellung
EP1672055A4 (de) * 2003-10-03 2006-12-13 Ajinomoto Kk Waschmittel und deren herstellung
EP2246036A1 (de) * 2009-04-27 2010-11-03 KPSS-Kao Professional Salon Services GmbH Wässrige Reinigungszusammensetzung
WO2010124818A2 (en) * 2009-04-27 2010-11-04 Kpss-Kao Professional Salon Services Gmbh Aqueous cleansing composition
US20120034181A1 (en) * 2009-04-27 2012-02-09 Kpss-Kao Professional Salon Services Gmbh Aqueous cleansing composition
WO2010124818A3 (en) * 2009-04-27 2012-03-15 Kpss-Kao Professional Salon Services Gmbh Aqueous cleansing composition

Also Published As

Publication number Publication date
EP0826766B1 (de) 2003-07-09
DE69723375T2 (de) 2004-04-15
DE69723375D1 (de) 2003-08-14
EP0826766A3 (de) 1999-02-03
DE69723375T3 (de) 2012-12-20
ES2202554T5 (es) 2011-11-28
US5854199A (en) 1998-12-29
EP0826766B2 (de) 2011-07-20
ES2202554T3 (es) 2004-04-01

Similar Documents

Publication Publication Date Title
EP0648833B1 (de) Waschmittelzusammensetzung
TW319797B (de)
WO2006030881A1 (ja) 洗浄剤組成物
JP3622441B2 (ja) 洗浄剤組成物
WO2004098558A1 (ja) 洗浄剤組成物
EP0826766B1 (de) Waschmittelzusammensetzung
JPH0812993A (ja) 洗浄剤組成物
JP3774735B2 (ja) 洗浄剤組成物
JP2003183152A (ja) クリーム状皮膚洗浄料
JP2509896B2 (ja) 洗浄剤組成物
JPH0759714B2 (ja) 低刺激性洗浄剤組成物
WO1996005281A1 (fr) Composition detergente
WO1998004239A2 (en) Shampoo compositions
JP2876173B2 (ja) 洗浄剤組成物
JP3178085B2 (ja) 洗浄剤組成物
JPH06264091A (ja) 洗浄剤組成物
JP3200226B2 (ja) 洗浄剤組成物
JP2511776B2 (ja) 洗浄剤組成物
JPH07330553A (ja) 毛髪化粧料
JPH1072331A (ja) 化粧料および洗浄剤組成物
JP3492745B2 (ja) シャンプー組成物
JP3130373B2 (ja) 洗浄剤組成物
JPH03115498A (ja) 洗浄剤組成物
JPH059495A (ja) 洗浄剤組成物
JP3300740B2 (ja) 洗浄剤組成物

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): DE ES FR GB IT

AX Request for extension of the european patent

Free format text: AL;LT;LV;RO;SI

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

AX Request for extension of the european patent

Free format text: AL;LT;LV;RO;SI

AKX Designation fees paid

Free format text: DE ES FR GB IT

17P Request for examination filed

Effective date: 19990727

17Q First examination report despatched

Effective date: 20010216

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Designated state(s): DE ES FR GB IT

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 69723375

Country of ref document: DE

Date of ref document: 20030814

Kind code of ref document: P

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2202554

Country of ref document: ES

Kind code of ref document: T3

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

ET Fr: translation filed
26 Opposition filed

Opponent name: COGNIS DEUTSCHLAND GMBH & CO. KG

Effective date: 20040407

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

PLAY Examination report in opposition despatched + time limit

Free format text: ORIGINAL CODE: EPIDOSNORE2

PLBC Reply to examination report in opposition received

Free format text: ORIGINAL CODE: EPIDOSNORE3

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

APBQ Date of receipt of statement of grounds of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA3O

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: COGNIS GMBH

Effective date: 20040407

APBU Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9O

PLAY Examination report in opposition despatched + time limit

Free format text: ORIGINAL CODE: EPIDOSNORE2

PLBC Reply to examination report in opposition received

Free format text: ORIGINAL CODE: EPIDOSNORE3

PLAY Examination report in opposition despatched + time limit

Free format text: ORIGINAL CODE: EPIDOSNORE2

PUAH Patent maintained in amended form

Free format text: ORIGINAL CODE: 0009272

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT MAINTAINED AS AMENDED

27A Patent maintained in amended form

Effective date: 20110720

AK Designated contracting states

Kind code of ref document: B2

Designated state(s): DE ES FR GB IT

REG Reference to a national code

Ref country code: DE

Ref legal event code: R102

Ref document number: 69723375

Country of ref document: DE

REG Reference to a national code

Ref country code: ES

Ref legal event code: DC2A

Ref document number: 2202554

Country of ref document: ES

Kind code of ref document: T5

Effective date: 20111128

REG Reference to a national code

Ref country code: DE

Ref legal event code: R102

Ref document number: 69723375

Country of ref document: DE

Effective date: 20110720

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20140827

Year of fee payment: 18

Ref country code: ES

Payment date: 20140711

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20140819

Year of fee payment: 18

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20150829

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150829

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 20

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150829

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20160927

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20160823

Year of fee payment: 20

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150830

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20160712

Year of fee payment: 20

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 69723375

Country of ref document: DE