EP0789095B1 - System zum Behandeln von Edelstahlbändern - Google Patents
System zum Behandeln von Edelstahlbändern Download PDFInfo
- Publication number
- EP0789095B1 EP0789095B1 EP97250011A EP97250011A EP0789095B1 EP 0789095 B1 EP0789095 B1 EP 0789095B1 EP 97250011 A EP97250011 A EP 97250011A EP 97250011 A EP97250011 A EP 97250011A EP 0789095 B1 EP0789095 B1 EP 0789095B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- strip
- descaling
- electrolytic
- steel strips
- treatment plant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001220 stainless steel Inorganic materials 0.000 title description 7
- 239000010935 stainless steel Substances 0.000 title description 7
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 9
- 239000010959 steel Substances 0.000 claims abstract description 9
- 238000002604 ultrasonography Methods 0.000 claims description 18
- 238000000034 method Methods 0.000 abstract description 12
- 238000005554 pickling Methods 0.000 abstract description 5
- 230000009977 dual effect Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000004506 ultrasonic cleaning Methods 0.000 abstract description 3
- 238000009434 installation Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
- B08B3/12—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
- B08B3/123—Cleaning travelling work, e.g. webs, articles on a conveyor
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F1/00—Electrolytic cleaning, degreasing, pickling or descaling
- C25F1/02—Pickling; Descaling
- C25F1/04—Pickling; Descaling in solution
- C25F1/06—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F7/00—Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
Definitions
- the invention relates to a system for descaling the surface of Stainless steel strips in an electrolytic strip treatment plant for production of pickled hot strip and cold strip, with several immediately one after the other arranged alternately anodically connected with cathodic band polarization and connected with a corresponding anodic band polarization Electrodes
- Tinder layers of the type described have usually been used in the past Blasting devices removed abrasively or with chemical pickling treatment processes. The combination of the two devices with one another has also been proposed.
- the dual descaling system uses e.g. B. sodium sulfate, ammonium sulfate, Sulfuric acid or similar media as electrolytes and connects the electrolytic process with a known ultrasonic cleaning.
- the effect of the electrolytic pickling part on descaling is based on one Volume enlargement of the scale through oxidation and a chipping effect the resulting gas bubbles.
- these processes do not make it to produce flawless metallic pure material surface, because a large part of the Tinder remains due to adhesive energy on the base material of the belt.
- annealed Cold strip is the most effective cleaning effect of an electrolytic pickle at 80 % to 100%, depending on the material quality. With hot strip, however, this effect drops to 20 % to 50%, because the higher roughness of the belt surface increases the adhesion of the Tinder causes.
- electrolytic pickling is combined with a Ultrasonic cleaning, such as, for example, US-A-5 409 594, WO-A-95/03439 or propose and use JP-A-50 075 530 for treating wire Ultrasound generating devices, such as, for example, in GB-A-998 575 are described, so can be invented with the invented system Solve task and total descaling of the surface of the stainless steel strips of any kind of tinder.
- a Ultrasonic cleaning such as, for example, US-A-5 409 594, WO-A-95/03439 or propose and use JP-A-50 075 530 for treating wire Ultrasound generating devices, such as, for example, in GB-A-998 575 are described, so can be invented with the invented system Solve task and total descaling of the surface of the stainless steel strips of any kind of tinder.
- the power is to be changed of the electrodes and / or the ultrasound generating device depending on the To change the belt throughput speed.
- the ultrasound generating device By arranging the ultrasound generating device above and below the Band, a further optimization of the proposed method is achieved. It has proven to be favorable if the ultrasound generating device Ultrasound waves at an angle adapted to the speed of the tape point against the tape running direction. In this way, the chipping effect of the adhering scale particles reinforced by the belt surface. A good effect leaves can also be achieved if, according to a further feature of the invention Ultrasonic waves can be introduced axially to the tape.
- An additional area of application of the technology according to the invention is the removal of scale from hot-rolled normal steel. So far, the tinder has been and will be treated with acids such as B. H 2 SO 4 or HCl removed. Despite the use of regeneration processes to recover the acids, these processes also result in environmental pollution, namely immissions in air and water.
- FIG 1 is roughly schematically a plant for performing the invention Procedure illustrated.
- 5 is the treatment tank of the belt treatment plant referred to, which the band 4 to be treated passes in the horizontal direction.
- the tape 4 is guided and supported by the rollers 3.
- the so-called working electrodes Above and below the band are generally designated 1, they are in Belt running direction (arrow) alternately connected cathodically or anodically.
- Ultrasound generating devices 2 are located between the working electrodes 1. and arranged below the band, which are symbolized by triangles. This Ultrasonic generation devices serve to support the detachment process of the surface scale.
- the effect of the ultrasound on the belt surface is on the cavitation generated in the liquid is attributed to the scale, which is practical mechanically removed from the surface of the belt.
- FIG. 2 shows two containers 5 and 6 arranged one behind the other.
- the Band 4 first passes through the container 6 with the working electrodes 1 in the direction of the arrow, which are alternately connected cathodically or anodically. Subsequently the belt 4 passes through the container 5, in which several are grouped together Ultrasonic generating devices 2 are arranged above and below the Generate the band's ultrasound waves and loosen the scale by cavitation. At In this version, both descaling mechanisms can be used without mutual interference being controlled. While in the first container 6 the scale layer loosened by gas bubbles and oxidized in the anodic area can in subsequent second container 5 of this "loose" scale recognized with the help of ultrasound become.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Description
- Figur 1
- einen grob schematischen Querschnitt durch eine elektrolytische Bandbehandlungsanlage mit dem erfindungsgemäßen System und
- Figur 2
- eine eben solche Anlage mit Modularanordnung von Elektroden und Ultraschallerzeugungseinrichtung.
Claims (6)
- System zur Entzunderung der Oberfläche von Edelstahlbändern in einer elektrolytischen Bandbehandlungsanlage zur Herstellung von gebeiztem Warmband und Kaltband, mit mehreren unmittelbar hintereinander angeordneten abwechselnd bei kathodischer Bandpolarisation anodisch geschalteten und bei entsprechender anodischen Bandpolarisation kathodisch geschalteten Elektroden,
dadurch gekennzeichnet,
daß mindestens zwischen einzelnen benachbarten Anoden-(+) und/oder Kathodenbänken (-) Ultraschallerzeugungseinrichtungen (2) angeordnet sind. - System zur Entzunderung der Oberfläche von Edelstahlbändern in einer elektrolytischen Bandbehandlungsanlage mit mehreren unmittelbar hintereinander angeordneten abwechselnd bei kathodischer Bandpolarisation anodisch geschalteten und bei entsprechender anodischen Bandpolarisation kathodisch geschalteten Elektroden,
dadurch gekennzeichnet,
daß in einer Modularanordnung einer die Elektroden (1) aufnehmenden elektrolytischen Zelle (6) eine die Ultraschallerzeugungseinrichtung (2) aufnehmende Zelle (5) folgt. - System zur Entzunderung der Oberfläche von Edelstahlbändern in einer elektrolytischen Bandbehandlungsanlage nach Anspruch 1 und 2,
dadurch gekennzeichnet,
daß die Leistung der Elektroden (1) und/oder der Ultraschallerzeugungseinrichtung (2) in Abhängigkeit von der Banddurchlaufgeschwindigkeit veränderbar ist. - System zur Entzunderung der Oberfläche von Edelstahlbändern in einer elektrolytischen Bandbehandlungsanlage nach Anspruch 1 bis 3,
dadurch gekennzeichnet,
daß die Ultraschallerzeugungseinrichtungen (2) oberhalb und unterhalb des Bandes (4) angeordnet sind. - System zur Entzunderung der Oberfläche von Edelstahlbändern in einer elektrolytischen Bandbehandlungsanlage nach Anspruch 2 bis 4,
dadurch gekennzeichnet,
daß die Ultraschallerzeugungseinrichtungen (2) die Ultraschallwellen in einem der Banddurchlaufgeschwindigkeit angepaßten Winkel gegen die Laufrichtung des Band (4) richteten. - System zur Entzunderung der Oberfläche von Edelstahlbändern in einer elektrolytischen Bandbehandlungsanlage nach Anspruch 2 bis 4,
dadurch gekennzeichnet,
daß die Ultraschallwellen axial zum Band (4) einleitbar sind.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19604971 | 1996-02-02 | ||
DE19604971A DE19604971A1 (de) | 1996-02-02 | 1996-02-02 | Verfahren und System zum Behandeln von Edelstahlbändern |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0789095A1 EP0789095A1 (de) | 1997-08-13 |
EP0789095B1 true EP0789095B1 (de) | 1999-11-03 |
Family
ID=7785103
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97250011A Expired - Lifetime EP0789095B1 (de) | 1996-02-02 | 1997-01-24 | System zum Behandeln von Edelstahlbändern |
Country Status (6)
Country | Link |
---|---|
US (1) | US5897764A (de) |
EP (1) | EP0789095B1 (de) |
JP (1) | JPH101800A (de) |
AT (1) | ATE186338T1 (de) |
DE (2) | DE19604971A1 (de) |
ES (1) | ES2137756T3 (de) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1093450C (zh) * | 1999-01-28 | 2002-10-30 | 北京工业大学 | 时效马氏体钢钨极氩弧焊金属粉芯焊丝及其制造方法 |
WO2001066829A1 (fr) | 2000-03-08 | 2001-09-13 | Nippon Steel Corporation | Procede de decapage par ultrasons, et dispositif correspondant |
EP1545329B1 (de) * | 2002-10-04 | 2012-07-11 | Tyco Healthcare Group LP | Spitze nadel |
WO2006007639A1 (en) * | 2004-07-16 | 2006-01-26 | Soniclean Pty Ltd | An improved apparatus and method for cleaning using a combination of electrolysis and ultrasonics |
TWI487816B (zh) | 2012-10-24 | 2015-06-11 | Zen Material Technologies Inc | Alkaline electrolysis derusting method |
CN103898525A (zh) * | 2012-12-28 | 2014-07-02 | 周宜锦 | 去除钢材的锈皮的方法 |
WO2020095090A1 (en) * | 2018-11-06 | 2020-05-14 | Arcelormittal | Cleaning method by ultrasound |
WO2020095091A1 (en) * | 2018-11-06 | 2020-05-14 | Arcelormittal | Equipment improving the ultrasound cleaning |
DE102020106353A1 (de) | 2020-03-09 | 2021-09-09 | Thyssenkrupp Steel Europe Ag | Verfahren zum Entzundern eines Stahlbands und Anlage zum Entzundern eines Stahlbands |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB998575A (en) * | 1962-01-17 | 1965-07-14 | Noburo Sasaki | Process for cleaning metal surfaces and apparatus therefor |
JPS5075530A (de) * | 1973-11-09 | 1975-06-20 | ||
US4046592A (en) * | 1976-01-12 | 1977-09-06 | Westinghouse Electric Corporation | Wire cleaning system |
AT399167B (de) * | 1991-06-10 | 1995-03-27 | Andritz Patentverwaltung | Verfahren und vorrichtung zum elektrolytischen beizen von kontinuierlich durchlaufendem elektrisch leitendem gut |
US5407544A (en) * | 1993-07-21 | 1995-04-18 | Dynamotive Corporation | Method for removal of certain oxide films from metal surfaces |
IL110297A0 (en) * | 1993-07-21 | 1994-10-21 | Dynamotive Corp | A method for removal of certain oxide films from metal surfaces |
TW296988B (de) * | 1993-09-17 | 1997-02-01 | Hitachi Ltd | |
US5409594A (en) * | 1993-11-23 | 1995-04-25 | Dynamotive Corporation | Ultrasonic agitator |
US5795460A (en) * | 1996-04-10 | 1998-08-18 | Dynamotive Corporation | Method for removal of films from metal surfaces using electrolysis and cavitation action |
US5653860A (en) * | 1996-05-02 | 1997-08-05 | Mitsubishi Semiconductor America, Inc. | System for ultrasonic removal of air bubbles from the surface of an electroplated article |
-
1996
- 1996-02-02 DE DE19604971A patent/DE19604971A1/de not_active Withdrawn
-
1997
- 1997-01-24 EP EP97250011A patent/EP0789095B1/de not_active Expired - Lifetime
- 1997-01-24 ES ES97250011T patent/ES2137756T3/es not_active Expired - Lifetime
- 1997-01-24 DE DE59700638T patent/DE59700638D1/de not_active Expired - Fee Related
- 1997-01-24 AT AT97250011T patent/ATE186338T1/de not_active IP Right Cessation
- 1997-01-27 JP JP9027159A patent/JPH101800A/ja active Pending
- 1997-01-30 US US08/791,819 patent/US5897764A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US5897764A (en) | 1999-04-27 |
ATE186338T1 (de) | 1999-11-15 |
EP0789095A1 (de) | 1997-08-13 |
DE59700638D1 (de) | 1999-12-09 |
JPH101800A (ja) | 1998-01-06 |
DE19604971A1 (de) | 1997-08-07 |
ES2137756T3 (es) | 1999-12-16 |
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