EP0756461B1 - Tabakerzeugnisse oder tabakerzeugnissen ähnliche waren mit antioxidativ wirkenden naturstoffen und verfahren zur herstellung derselben - Google Patents
Tabakerzeugnisse oder tabakerzeugnissen ähnliche waren mit antioxidativ wirkenden naturstoffen und verfahren zur herstellung derselben Download PDFInfo
- Publication number
- EP0756461B1 EP0756461B1 EP95917934A EP95917934A EP0756461B1 EP 0756461 B1 EP0756461 B1 EP 0756461B1 EP 95917934 A EP95917934 A EP 95917934A EP 95917934 A EP95917934 A EP 95917934A EP 0756461 B1 EP0756461 B1 EP 0756461B1
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- EP
- European Patent Office
- Prior art keywords
- tobacco
- smokable
- natural substances
- filter
- product according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/301—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by aromatic compounds
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
Definitions
- the present invention relates to tobacco products or tobacco products Similar goods with known antioxidants acting natural products and / or nature-identical synthetic products provided and intended for smoking, and methods of making these products.
- the human organism is a natural basic burden exposed to toxic substances and is therefore with a variety of mutagenic and carcinogenic substances, some of them on your own metabolism be formed by himself.
- the body's defense system is particularly important, which are also influenced individually by the way of life can.
- the food intake in the body a number of chemical reactions, whereby mutagen and antimutagen acting substances are closely interrelated.
- tobacco products are both cigarettes, cigarillos and tobacco cartridges (so-called plug-in cigarettes) with or without a filter as well Fine cut and pipe tobacco made entirely or in part of tobacco and / or another smokable material, as well as tobacco products Similar tobacco products such as “Kretek” cigarettes with the addition of up to 50% by weight of smokable spices, or to understand pure, tobacco-free plant cigarettes.
- WPI KIKKOMAN CORP describes the use of a tobacco filter, on which ellagic acid is applied in an amount of 1 - 20mg. This is said to stimulate tobacco smoke reduced and mildness added to the tobacco smoke without the Change the taste and smell of the smoke.
- ellagic acid namely a strong blood coagulation activity and an antioxidant Effect; but it is very expensive, which is known to the expert is so that under no circumstances will he think of this in to use such a high concentration in smoking articles.
- WPI NAKAJIMA discloses that a cigarette has a substance add to remove the harmful substances from the smoke can.
- the substance mentioned there is a mixture of different Individual components, to which ascorbic acid and Vanillin belong without knowing more about these individual components Statements would have been made.
- the object of the present invention is therefore in Creation of another tobacco product containing additives which further reduces the potential risks of smoking be, as well as in the provision of a method for manufacturing such tobacco products.
- they are antioxidative acting natural products and / or nature-identical synthesis products the same in the tobacco product in combination of one or more antioxidant vitamins and one or more contain other natural products of plant origin, where their relative amounts based on the total weight in Dependency of the intended target component or components of a smokable tobacco product may vary.
- the natural substances can be found in the smoking tobacco including the common additives as well as in individual the main stream smoke accessible components of tobacco products such as filters, Wrapping papers, substrates, seam glue etc. in a known manner Be incorporated or upgraded in a way that is beneficial to both Manufacturer of the tobacco product as well as proportionately with it Suppliers can happen.
- the pure natural substances When the pure natural substances are added to tobacco, lies their preferred relative amount in the range of 0.1 per thousand to 25 wt .-%, with a content between 1 and 5 wt .-% particularly is preferred.
- the preferred amounts are 0.1 to 50 wt .-%, with amounts of 1 to 20 wt .-% particularly preferred are.
- the filter used can be a chamber filter, a Cellulose acetate filter or a cellulose tangled fiber filter or a multiple filter, preferably a double filter (each with or without filter ventilation), the double filter a higher strand-side draw resistance and a lower one mouth-side draw resistance and an overall filter efficiency of 80 - 99%. Filters from other sources can also be used known filter materials in combination with the antioxidative acting natural substances are used.
- the natural substances according to the invention are contained from the outset in non-tobacco-containing, predominantly plant-based, smokable materials that are added to the tobacco, or alternatively the smokable mixture consists exclusively of optionally different, coordinated, non-tobacco-containing, plant-based materials with or without plant-specific, natural substances according to the invention, then also apply the preferred amounts of 0.1 per mille to 25% by weight, based on the pure natural substances, as well as the particularly preferred amounts of use of 1.0 to 5% by weight, the intended use amount in all cases by adding the pure natural substances or the pure substances according to the invention can be added to the smokable mixture.
- the substances of the invention Production of a smokable mixture in a manner known per se be added to the leaf cut and / or the rib cut, optionally using known adhesives and binders.
- the substances can be used in film or Tape tobacco are incorporated, which is particularly the case with offers the use of solid, ground natural products.
- a new type of plant foil that does not contain tobacco be at least partially the natural substances according to the invention in the form of herbal ingredients from parts of the contains vegetable film material.
- smokable base material a mixture of lamina tobacco or a mixture of lamina tobacco and foil tobacco or a tobacco-free Mixture of plant material, which comes from coltsfoot, Peppermint, nettle, white plantain, spearmint, Lavender, thyme, sweet or sour cherry leaves, knotweed leaves, Derived from rose petals, allspice leaves or cinnamon bark.
- the smokable material is a Combination of tobacco blend and tobacco-free blend is.
- the substances according to the invention can be in liquid form the casing and / or flavorings are added, whereby can even replace them.
- the usual filter systems essentially consist of either a filter fiber tow made from cellulose acetate fibers or from each other matted cellulose fibers, which are a cellulose tangled fiber fleece surrender.
- the filter fiber tow is usually during the manufacture of the cigarette filter with one of the permissible Sprayed harder to cross-link the fibers and thus the filter to harden.
- These hardeners mostly consist of triacetin or Triethylene glycol diacetate (TEGDA) and can according to the invention for Part or all of the natural substances according to the invention in liquid form, if they dissolve in the hardener or even act as a hardener, such as eugenol.
- Natural substances like eugenol, or in common hardeners like TEGDA can in turn be other natural substances such as cinnamaldehyde, ethyl vanillin, but also ⁇ -tocopherol, tocopherol acetate, Tocopherol succinate, retinol and retinol palmitate be solved so that bi- or ternary or multiple Mixtures of solutions result, which advantageously both as hardeners for cellulose acetate fibers as well as casing materials for smokable mixtures can be used.
- Suspensions of solid natural substances can also be used in the hardener, but also scattering of ground natural substances in filter fiber tow from cellulose acetate fibers.
- Flavoring Eugenol The different solubilities and miscibilities of some Flavorings and vitamins preferred according to the invention in or with the usual hardener substances triacetin and TEGDA as well as the natural usable according to the invention even as a hardening substance Flavoring Eugenol are shown in Table 2. From the Data in Table 2 are in particular the excellent solubilizers Properties of the hardener according to the invention or hardener component of usable eugenols. The However, substance eugenol can also be in the form of a mixture with others in Tables 2 and 3 as hardeners or solvents listed substances are used, the concrete Mixtures and their respective proportions taking into account their properties and their market prices as well as depending of the component or components to be treated of the invention Product can be easily selected.
- Particularly preferred is a mixture of 80 parts triacetin, 15 parts eugenol and 5 parts of ⁇ -tocopherol acetate.
- the in this ratio mixed substances result in a clear solution from which after abandonment on cellulose acetate fibers preferred triacetin and Diffuse eugenol into the interior of the fibers, creating the ⁇ -tocopherol acetate enriched on the surface of the filter fibers , and therefore particularly easy from here as an emitter acting "filter" can be transferred into the main stream smoke can.
- the filter to be used in the process for producing a tobacco product does not consist of cellulose acetate fibers, it and / or the other components of the later product, such as the smokable tobacco-containing or tobacco-free vegetable material, the cigarette paper and the suture to be used, are mixed according to the invention with a solution of the inventive ones Flavorings and vitamins (or provitamins) are treated, whereby individual representatives of these groups of substances can in turn be used as solvents.
- the respective solubilities and miscibilities of the entire substances in or with some of the natural substances which can also be used as solvents according to the invention are shown in Table 3.
- the inventive Substances already on the part of the filter material manufacturer be worked into the fleece.
- the solid substances according to the invention can, for example, in granular shape with a grain diameter of about 0.8 mm on the part of the filter rod manufacturer introduced into the chambers of chamber filters liquid substances according to the invention, taken up, for example, from wood flour or lignin granules, lignin which is particularly suitable or has a lot of antioxidant activity containing wood particles in fiber-dust or granulate form also solitary as chamber embedding materials or as self-supporting, porous or smoke-permeable press hinge in the desired Filter format can be used. Furthermore, also that which comes into contact with the main stream smoke when smoking Inside of the filter wrapping paper with the inventive Natural substances can be coated.
- the cigarette paper can with the natural substances according to the invention in encapsulated or unencapsulated form in a manner known per se Be provided in this way, both single and two-layer Cigarette papers are suitable.
- the inner tobacco rod wrapper which also mesh-like or highly porous (10 - 20,000 CORESTA) can be provided with the substances according to the invention.
- This net-like inner tobacco rod wrapping can predominantly or for Entirely made of a suitable antioxidant containing lignin Wood pulp are made, at least partially the fiber content of otherwise customary cigarette papers made from suitable unbleached lignin wood pulp.
- the test principle essentially consists in the fact that histidine auxotrophic (his - ) indicator bacteria of the species Salmonella typhimurium mutate back into their prototrophic form (his + ) under the influence of mutagenic substances. Carrying out the Ames test, with or without “S 9 activation", allows a statement to be made as to whether a test substance is mutagenic in its original form or only after metabolism.
- the tobacco product proposed according to the invention points the traditional products have a greatly reduced risk potential on, because the natural substances used their antioxidations Properties on a variety of undesirable substances exercise and exert their effects at the place of metabolism.
- the Ames test was used to determine the mutagenic effect (loc. cit.) in the version "plate incorporation" as below described.
- test batches in petri dishes were evenly distributed on an agar which only allowed the growth of the his + back mutants.
- the petri dishes were subsequently incubated at 37 ° C in the dark for 48 hours. After the incubation period, the colonies formed from individual his + back-mutated bacteria were counted.
- the mutation frequency is the measure of the mutagenic activity.
- FIGS Some of the substances according to the invention with antimutagenic activity shown on smoke condensate.
- Scopoletin (7-hydroxy-6-methoxycoumarin) with a melting point of 205 ° C, without boiling point, is a natural plant ingredient in Virginia tobacco in a concentration of about Contain 300 ppm.
- scopoletin to detect the mainstream smoke, three versions of Trial cigarettes based on the same lot of cigarettes as prepared in Example 1.
- the concentration to scopoletin of tobacco by spraying on an ethanolic Solution of Scopoletin on the original cigarette tobacco Increased 330 ppm to 630 ppm and 5.330 ppm.
- the manufactured Cigarettes were smoked as described in Example 1, whereby the collected smoke condensate is dissolved in methanol has been.
- the filter sleeve design data corresponded to that of the example 1, the strand weight decreased to 930 ⁇ 20 mg, the amount of tobacco smoked was 785 mg.
- Cut tobacco with additions of cloves, cinnamon sticks and eugenol mixture Composition of the cut tobacco mixture Tobacco (% tr.) Cloves (% Tr.) Cinnamon sticks (% Tr.) added pure eugenol (% Tr.) 1 70 30th --- --- 2nd 70 --- 30th --- 3rd 70 15 15 --- 4th 94.9 --- --- 5.1 5 100 --- --- --- --- ---
- the experimental cigarettes were smoked under standard conditions (see example 1).
- the resulting smoke condensate solutions were examined with the Ames test according to Example 2, and in the embodiment "with S9 activation".
- the test results are shown graphically in FIG.
- the mutagenicity of the smoke condensate of mixture 1 was increased 55.5% of the effect of the comparison diminished, which corresponds to the explain the amount of eugenol contained in the cloves.
- the used Carnations had an eugenic content of 17.0%. In contrast this can be accompanied by the surprising reduction in mutagenicity of the smoke condensate of mixture 2 to 65.3% not alone with the amounts of cinnamaldehyde and eugenol contained.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Manufacture Of Tobacco Products (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Compounds Of Unknown Constitution (AREA)
Description
Inhaltsstoff | MG | Kp (°C) | Fp (°C) |
Ethylvanillin | 166.2 | 74-77 | |
Zimtaldehyd | 132.2 | 253 | -7.5 |
Anisaldehyd | 136.2 | 248 | 2.5 |
Eugenol | 164.2 | 253-255 | -9 |
Limonen | 136,2 | 176 | -97 |
Löslichkeit von antioxidativ wirksamen Aromastoffen und den Vitaminen A und E in Filterhärtern | |||||||||
Härter | Aromastoffe | Vitamine | |||||||
Zimtaldehyd | Jasminaldehyd | Ethylvanillin | 6-Methylcumarin | A | A Palmitat | E | E Acetat | E Succinat | |
Triacetin | |||||||||
Eugenol | 10 |
Ausgezählte TA 98-Kolonien in Abhängigkeit zur
eingesetzten Kondensatmenge (Mittelwerte aus Dreifachbestimmungen) | |||
Menge Rauchkondensat (µ.g pro Platte) | S9-Aktivierung | ausgezählte Kolonien | Induzierte Kolonien |
0 | ohne | 41 | - |
120 | ohne | 43 | 2 |
240 | ohne | 40 | -1 |
360 | ohne | 35 | -6 |
0 | mit | 50 | - |
120 | mit | 216 | 166 |
240 | mit | 441 | 391 |
360 | mit | 581 | 531 |
Säule: | Li Chro CART superspher RP 8, 250-4 (Fa. Merck) |
Fließmittel: | Wasser/Methanol/Essigsäure -85/13/2 |
Fließgeschwindigkeit: | 1,2 ml/min |
Betrieb isokratisch bei 45°C Detektor bei 340 nm Einspritzvolumen: | 10 µl Probe |
Übergang von Scopoletin in den Hauptatromrauch | ||||
Cigarettenversion | Scopoletin | |||
Konzentration im Tabak (ppm) | Menge im abgerauchten Tabak (µg) | im Hauptstromrauch gefundene Menge (µg) | Anteil von der Menge des abgerauchten Tabaks (%) | |
Vergleich | 330 | 259,1 | 28,2 | 10,9 |
Versuchsmischung 1 | 630 | 494,6 | 47,6 | 9,6 |
Versuchsmischung 2 | 5.330 | 4.184,1 | 331,1 | 6,2 |
Abgerauchte Tabakmenge: 785 mg pro Cigarette |
Schnittabak mit Zusätzen von Nelken, Zimtstangen und Eugenol | ||||
Mischung | Zusammensetzung der Schnittabakmischung | |||
Tabak (% Tr.) | Nelken (% Tr.) | Zimtstangen (% Tr.) | zugesetztes reines Eugenol (% Tr.) | |
1 | 70 | 30 | --- | --- |
2 | 70 | --- | 30 | --- |
3 | 70 | 15 | 15 | --- |
4 | 94,9 | --- | --- | 5,1 |
5 | 100 | --- | --- | --- |
Claims (19)
- Rauchbares Erzeugnis aus Tabak und/oder einem anderen rauchbaren Material, wobei der Tabak und/oder das rauchbare Material einen Zusatz von antioxidativ wirkenden Naturstoffen und/oder naturidentischen Syntheseprodukten derselben enthält, dadurch gekennzeichnet, daß der Zusatz eine Kombination ist aus(a) antioxidativ wirkenden Vitaminen, ausgewählt aus der Gruppe bestehend aus Retinol, α-Tocopherol, ihren Vorstufen und/oder Derivaten, und(b) weiteren Naturstoffen pflanzlichen Ursprungs mit antimutagenen und aromatisierenden Eigenschaften, ausgewählt aus der Gruppe bestehend aus Ethylvanillin, Zimtaldehyd, Anisaldehyd, Eugenol, Limonen, Zimt und Zimtextrakt.
- Rauchbares Erzeugnis nach Anspruch 1, dadurch gekennzeichnet, daß es bis 25 Gew.-% der antioxidativ wirkenden Naturstoffe und/oder naturidentischen Syntheseprodukte enthält.
- Rauchbares Erzeugnis nach Anspruch 2, dadurch gekennzeichnet, daß es 1 bis 5 Gew.-% der antioxidativ wirkenden Naturstoffe und/oder naturidentischen Syntheseprodukte enthält.
- Rauchbares Erzeugnis nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß es eine Cigarette mit oder ohne Filter ist.
- Rauchbares Erzeugnis nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß es ein Cigarillo mit oder ohne Filter ist.
- Rauchbares Erzeugnis nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß es eine Tabakpatrone mit oder ohne Filter ist.
- Rauchbares Erzeugnis nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß es Rauchtabak in Form von Feinschnitt oder Pfeifentabak ist.
- Rauchbares Erzeugnis nach einem der Ansprüche 4 bis 6, dadurch gekennzeichnet, daß der Filter bis 50 Gew.-% der antioxidativ wirkenden Naturstoffe und/oder naturidentischen Syntheseprodukte nach Anspruch 1 enthält.
- Rauchbares Erzeugnis nach Anspruch 8, dadurch gekennzeichnet, daß der Filter 1 bis 20 Gew.-% der antioxidativ wirkenden Naturstoffe und/oder naturidentischen Syntheseprodukte nach Anspruch 1 enthält.
- Rauchbares Erzeugnis nach Anspruch 4, dadurch gekennzeichnet, daß das Cigarettenpapier bis 50 Gew.-% der antioxidativ wirkenden Naturstoffe und/oder naturidentischen Syntheseprodukte nach Anspruch 1 enthält.
- Rauchbares Erzeugnis nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß das rauchbare Basis-Material Mischungen aus Lamina-Tabaken oder Lamina-Tabak und Folientabak sind.
- Rauchbares Erzeugnis nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß das rauchbare Material bis 25 Gew.-% der antioxidativ wirkenden Naturstoffen und/oder naturidentischen Syntheseprodukte nach Anspruch 1 enthält.
- Rauchbares Erzeugnis nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß das rauchbare Material eine tabakfreie Mischung aus Pflanzenmaterial ist, welches sich von Huflattich, Pfefferminze, Brennessel, Breitwegerich, Krauseminze, Lavendel, Thymian, Süß- oder Sauerkirschblättern, Knöterichblättern, Rosenblättern, Pimentblättern oder Zimtrinde ableitet.
- Rauchbares Erzeugnis nach Anspruch 13, dadurch gekennzeichnet, daß sich das rauchbare Material von Zimtrinde ableitet.
- Rauchbares Erzeugnis nach den Ansprüchen 11 bis 14, dadurch gekennzeichnet, daß das rauchbare Material eine Kombination aus Tabakmischung und tabakfreier Mischung ist.
- Verfahren zur Herstellung eines rauchbaren Erzeugnisses nach den Ansprüchen 1 bis 15 in an sich bekannter Weise, bei dem man die antioxidativ wirkenden Naturstoffe und/oder deren naturidentische Syntheseprodukte in an sich bekannter Weise in den Tabak und/oder ein anderes rauchbares Material einarbeitet oder aviviert.
- Verfahren nach Anspruch 16, dadurch gekennzeichnet, daß das rauchbare Material eine tabakfreie Mischung aus Pflanzenmaterial, Hüllpapiere, Trägerstoffe, Nahtleim und dergleichen umfaßt.
- Verfahren nach den Ansprüchen 16 und 17, dadurch gekennzeichnet, daß das rauchbare Erzeugnis eine Cigarette, ein Cigarillo oder eine Tabakpatrone mit Filter ist, in deren Filter man bis 50 Gew.-% der antioxidativ wirkenden Naturstoffe und/oder naturidentischen Syntheseprodukte nach Anspruch 1 einarbeitet oder aviviert.
- Verfahren nach Anspruch 18, dadurch gekennzeichnet, daß man die üblicherweise als Härter für die den späteren Filter bildenden Celluloseacetatfasern verwendeten Substanzen zum Teil oder vollständig durch die antioxidativ wirkenden Naturstoffe nach Anspruch 1 und/oder deren naturidentische Syntheseprodukte ersetzt.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SI9530458T SI0756461T1 (en) | 1994-04-19 | 1995-04-18 | Tobacco products, or substances similar to such products, containing natural substances with anti-oxidant properties, and process for producing the same |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4416101 | 1994-04-19 | ||
DE4416101A DE4416101C2 (de) | 1994-04-19 | 1994-04-19 | Tabakerzeugnisse oder Tabakerzeugnissen ähnliche Waren mit antioxidativ wirkenden Naturstoffen und Verfahren zur Herstellung derselben |
PCT/EP1995/001452 WO1995028098A1 (de) | 1994-04-19 | 1995-04-18 | Tabakerzeugnisse oder tabakerzeugnissen ähnliche waren mit antioxidativ wirkenden naturstoffen und verfahren zur herstellung derselben |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0756461A1 EP0756461A1 (de) | 1997-02-05 |
EP0756461B1 true EP0756461B1 (de) | 2000-11-02 |
Family
ID=6517522
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95917934A Expired - Lifetime EP0756461B1 (de) | 1994-04-19 | 1995-04-18 | Tabakerzeugnisse oder tabakerzeugnissen ähnliche waren mit antioxidativ wirkenden naturstoffen und verfahren zur herstellung derselben |
Country Status (27)
Country | Link |
---|---|
US (1) | US5944026A (de) |
EP (1) | EP0756461B1 (de) |
JP (1) | JPH10503082A (de) |
KR (1) | KR100357665B1 (de) |
CN (1) | CN1148324A (de) |
AT (1) | ATE197226T1 (de) |
BG (1) | BG63420B1 (de) |
CA (1) | CA2184592A1 (de) |
CZ (1) | CZ294496A3 (de) |
DE (2) | DE4416101C2 (de) |
DK (1) | DK0756461T3 (de) |
EE (1) | EE9600149A (de) |
ES (1) | ES2151598T3 (de) |
GR (1) | GR3035240T3 (de) |
HK (1) | HK1012873A1 (de) |
HU (1) | HUT76247A (de) |
LV (1) | LV11721B (de) |
MD (1) | MD1976B2 (de) |
PL (1) | PL177413B1 (de) |
PT (1) | PT756461E (de) |
RO (1) | RO117888B1 (de) |
RU (1) | RU2142729C1 (de) |
SI (1) | SI0756461T1 (de) |
SK (1) | SK120496A3 (de) |
TW (1) | TW272117B (de) |
UA (1) | UA45336C2 (de) |
WO (1) | WO1995028098A1 (de) |
Families Citing this family (87)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4416101C2 (de) * | 1994-04-19 | 1997-06-12 | Reemtsma H F & Ph | Tabakerzeugnisse oder Tabakerzeugnissen ähnliche Waren mit antioxidativ wirkenden Naturstoffen und Verfahren zur Herstellung derselben |
DE19541873A1 (de) * | 1995-11-09 | 1997-05-15 | Rhodia Ag Rhone Poulenc | Filterzigarette |
JPH1192410A (ja) * | 1997-09-25 | 1999-04-06 | Naohiko Sato | 抗酸化活性物質 |
BR9907793B1 (pt) | 1998-02-09 | 2011-05-31 | produtos de tabaco com vitamina e. | |
US6082370A (en) * | 1998-02-09 | 2000-07-04 | Rousseau Research, Inc. | Cigarette with dry powered Vitamin E |
US6615842B1 (en) | 1998-02-13 | 2003-09-09 | Cerami Consulting Corp. | Methods for removing nucleophilic toxins from tobacco smoke |
WO2000049901A2 (de) * | 1999-02-26 | 2000-08-31 | H.F. & Ph.F.Reemtsma Gmbh | Rauchbares erzeugnis |
ATE362718T1 (de) * | 2000-06-26 | 2007-06-15 | Cerami Consulting Corp | Verfahren und vorrichtung zum entfernen von nukleophilen toxinen aus tabak und tabakrauch |
US20050138910A1 (en) * | 2000-10-16 | 2005-06-30 | Peter Rohdewald | Air filter with scavenging effect on free radicals in gaseous phase and its method of preparation |
WO2002080708A2 (en) * | 2001-04-09 | 2002-10-17 | George Frederick Enslin | A smoker's requisite |
KR20030004562A (ko) * | 2001-07-05 | 2003-01-15 | 정진남 | 담배 |
US6953040B2 (en) * | 2001-09-28 | 2005-10-11 | U.S. Smokeless Tobacco Company | Tobacco mint plant material product |
HUP0201257A2 (hu) * | 2002-04-17 | 2004-05-28 | Péter Rozim | Szűrőbetét füstszűrős cigarettához |
US20040255965A1 (en) * | 2003-06-17 | 2004-12-23 | R. J. Reynolds Tobacco Company | Reconstituted tobaccos containing additive materials |
JP4824571B2 (ja) * | 2003-11-03 | 2011-11-30 | ユーエス スモークレス タバコ カンパニー リミテッド ライアビリティ カンパニー | 香味付け無煙たばこおよび製造方法 |
CA2599317C (en) | 2005-03-02 | 2010-02-09 | Japan Tobacco Inc. | Cigarette making apparatus |
RU2444917C2 (ru) * | 2005-07-08 | 2012-03-20 | Иото Интернасионал Индустрия Э Комерсио Де Продутус Ароматикус Лтда | Способ и машина для восстановления порошков растительного происхождения |
US7323476B2 (en) * | 2006-03-03 | 2008-01-29 | Savipu Pharmaceuticals | Myriceric acid derivatives for the treatment of cancer, cardiovascular and inflammatory diseases |
US20070207989A1 (en) * | 2006-03-03 | 2007-09-06 | Savipu Pharmaceuticals | Diterpene derivatives for the treatment of cardiovascular, cancer and inflammatory diseases |
US7795306B2 (en) * | 2006-03-03 | 2010-09-14 | Inderjit Kumar Dev | Triterpene derivatives for the treatment of cancer and inflammatory disease by inhibition of NF-κB |
US20070243273A1 (en) * | 2006-04-12 | 2007-10-18 | Savipu Pharmaceuticals | Reduction of the Deleterious Effects of Tobacco Smoking |
US20080017207A1 (en) * | 2006-07-18 | 2008-01-24 | Savipu Pharmaceuticals | Reduction of the Deleterious Effects of Tobacco Smoking by the Induction of Phase 2 Enzymes by Nerf2 |
US20080187608A1 (en) * | 2007-02-05 | 2008-08-07 | Savipu Pharmaceuticals | Enriched fractions from clary sage for the treatment of cancer, cardiovascular and inflammatory diseases |
US20090022821A1 (en) * | 2007-07-17 | 2009-01-22 | Inderjit Kumar Dev | Compositions from wax myrtle for the treatment of cancer, cardiovascular and inflammatory diseases |
KR100903951B1 (ko) | 2007-07-19 | 2009-06-25 | 주식회사 케이티앤지 | 주류연 중 자유 라디칼 제거용 아스코르빈산 유도체 함유궐련 필터 |
US8360072B2 (en) | 2009-10-09 | 2013-01-29 | Philip Morris Usa Inc. | Combination treatment of tobacco extract using antioxidants and antioxidant scavengers |
CN102495162B (zh) * | 2011-11-16 | 2013-11-20 | 中国烟草总公司郑州烟草研究院 | 一种配方烟丝中丁子香酚含量的测定方法 |
CN102499437A (zh) * | 2011-11-20 | 2012-06-20 | 红云红河烟草(集团)有限责任公司 | 一种掺配薰衣草的烟草烘烤调香方法 |
KR101475611B1 (ko) * | 2013-07-01 | 2014-12-22 | 이규서 | 방향요법을 이용한 항 스트레스 담배의 제조방법 |
CN103601710B (zh) * | 2013-11-04 | 2015-12-02 | 广东中烟工业有限责任公司 | 香豆素衍生物及其制备方法和应用 |
WO2015194007A1 (ja) * | 2014-06-19 | 2015-12-23 | 株式会社ダイセル | たばこフィルター用トウバンド |
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US20190192449A1 (en) * | 2016-08-31 | 2019-06-27 | Richard Baybutt | Composition and use thereof |
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SG10201903923SA (en) * | 2018-12-31 | 2020-03-30 | Ysq Int Pte Ltd | Apparatus and method for producing a filter element |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3339558A (en) * | 1966-10-28 | 1967-09-05 | Haskett Barry F | Smoking article and filter therefor containing vitamin a |
US3861401A (en) * | 1973-03-08 | 1975-01-21 | Theodore S Briskin | Smokable tobacco substitute material and method |
US3943943A (en) * | 1974-07-09 | 1976-03-16 | Liggett & Myers Incorporated | Cinnamic derivatives as tobacco additives |
US3940499A (en) * | 1974-09-19 | 1976-02-24 | International Flavors & Fragrances Inc. | Food or flavor containing 2,6,6-trimethyl-1-cyclohexen-1-ylacetaldehyde |
US4170236A (en) * | 1977-06-16 | 1979-10-09 | International Flavors & Fragrances Inc. | Isobutyl substituted heterocyclic compounds and uses for augmenting or enhancing the organoleptic properties of smoking compositions |
DE3200305C2 (de) * | 1982-01-08 | 1983-11-17 | B.A.T. Cigaretten-Fabriken Gmbh, 2000 Hamburg | Verfahren zur Verbesserung der Füllfähigkeit von Tabak, insbesondere Tabakblattschnitt |
US4516590A (en) * | 1982-11-26 | 1985-05-14 | Philip Morris Incorporated | Air-cured bright tobacco filler, blends and smoking articles |
CH662042A5 (en) * | 1983-07-14 | 1987-09-15 | Baumgartner Papiers Sa | Cigarette endpiece |
HU192213B (en) * | 1985-04-29 | 1987-05-28 | Pecsi Dohanygyar | Method for producing smoke filter neutralizing the materials injurious the health being in tobacco smoke particularly aldehydes |
JPS6214772A (ja) * | 1985-07-10 | 1987-01-23 | 中島 三夫 | 無害巻きたばこ |
US4727058A (en) * | 1985-09-26 | 1988-02-23 | International Flavors & Fragrances Inc. | Process for preparing natural benzaldehyde and acetaldehyde, natural benzaldehyde and acetaldehyde compositions, products produced thereby and organoleptic utilities therefor |
IT8717404A0 (it) * | 1987-05-07 | 1987-05-07 | Barbaro Daniele | Sistema di erogazione locale,per fumatori,della vitamina a (o di altri retinoidi) avente come eluente (solvente e veicolo) il fumo di sigaretta o di sigaro. |
WO1989001301A1 (en) * | 1987-08-13 | 1989-02-23 | C.A. Blockers, Inc. | Tobacco smoking article |
US5000198A (en) * | 1989-06-13 | 1991-03-19 | Mituo Nakajima | Agent for removing noxious tobacco components |
JPH03219860A (ja) * | 1990-01-25 | 1991-09-27 | Daicel Chem Ind Ltd | たばこ煙用フィルター |
JPH0523159A (ja) * | 1991-07-19 | 1993-02-02 | Kikkoman Corp | タバコフイルター |
US5308874A (en) * | 1992-06-26 | 1994-05-03 | Vyrex Corporation | Airborne protectants against oxidative tissue damage |
JPH0662824A (ja) * | 1992-08-12 | 1994-03-08 | Kyodo Nyugyo Kk | タバコ煙からのフリ−ラジカルの除去法 |
DE4244467C2 (de) * | 1992-12-24 | 1996-11-14 | Reemtsma H F & Ph | Cigarette |
DE4416101C2 (de) * | 1994-04-19 | 1997-06-12 | Reemtsma H F & Ph | Tabakerzeugnisse oder Tabakerzeugnissen ähnliche Waren mit antioxidativ wirkenden Naturstoffen und Verfahren zur Herstellung derselben |
-
1994
- 1994-04-19 DE DE4416101A patent/DE4416101C2/de not_active Revoked
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1995
- 1995-04-18 US US08/727,411 patent/US5944026A/en not_active Expired - Fee Related
- 1995-04-18 CZ CZ962944A patent/CZ294496A3/cs unknown
- 1995-04-18 DE DE59508825T patent/DE59508825D1/de not_active Expired - Fee Related
- 1995-04-18 SI SI9530458T patent/SI0756461T1/xx unknown
- 1995-04-18 RU RU96121906A patent/RU2142729C1/ru active
- 1995-04-18 KR KR1019960705290A patent/KR100357665B1/ko not_active IP Right Cessation
- 1995-04-18 CN CN95192648A patent/CN1148324A/zh active Pending
- 1995-04-18 EE EE9600149A patent/EE9600149A/xx unknown
- 1995-04-18 WO PCT/EP1995/001452 patent/WO1995028098A1/de not_active Application Discontinuation
- 1995-04-18 JP JP7526734A patent/JPH10503082A/ja active Pending
- 1995-04-18 RO RO96-01987A patent/RO117888B1/ro unknown
- 1995-04-18 PL PL95316760A patent/PL177413B1/pl unknown
- 1995-04-18 AT AT95917934T patent/ATE197226T1/de not_active IP Right Cessation
- 1995-04-18 MD MD96-0320A patent/MD1976B2/ro unknown
- 1995-04-18 HU HU9602896A patent/HUT76247A/hu unknown
- 1995-04-18 EP EP95917934A patent/EP0756461B1/de not_active Expired - Lifetime
- 1995-04-18 CA CA002184592A patent/CA2184592A1/en not_active Abandoned
- 1995-04-18 DK DK95917934T patent/DK0756461T3/da active
- 1995-04-18 TW TW084103810A patent/TW272117B/zh active
- 1995-04-18 UA UA96103945A patent/UA45336C2/uk unknown
- 1995-04-18 ES ES95917934T patent/ES2151598T3/es not_active Expired - Lifetime
- 1995-04-18 PT PT95917934T patent/PT756461E/pt unknown
- 1995-04-18 SK SK1204-96A patent/SK120496A3/sk unknown
-
1996
- 1996-09-04 LV LVP-96-357A patent/LV11721B/lv unknown
- 1996-10-18 BG BG100927A patent/BG63420B1/bg unknown
-
1998
- 1998-12-21 HK HK98114162A patent/HK1012873A1/xx not_active IP Right Cessation
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2001
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Also Published As
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---|---|
EP0756461A1 (de) | 1997-02-05 |
PT756461E (pt) | 2001-04-30 |
SI0756461T1 (en) | 2001-04-30 |
JPH10503082A (ja) | 1998-03-24 |
HU9602896D0 (en) | 1996-12-30 |
WO1995028098A1 (de) | 1995-10-26 |
PL316760A1 (en) | 1997-02-03 |
HK1012873A1 (en) | 1999-09-17 |
TW272117B (de) | 1996-03-11 |
PL177413B1 (pl) | 1999-11-30 |
ES2151598T3 (es) | 2001-01-01 |
KR970701507A (ko) | 1997-04-12 |
RU2142729C1 (ru) | 1999-12-20 |
MD1976B2 (ro) | 2002-08-31 |
US5944026A (en) | 1999-08-31 |
KR100357665B1 (ko) | 2003-02-05 |
DK0756461T3 (da) | 2000-12-18 |
HUT76247A (en) | 1997-07-28 |
CZ294496A3 (en) | 1997-04-16 |
CN1148324A (zh) | 1997-04-23 |
UA45336C2 (uk) | 2002-04-15 |
RO117888B1 (ro) | 2002-09-30 |
DE59508825D1 (de) | 2000-12-07 |
BG100927A (en) | 1997-07-31 |
ATE197226T1 (de) | 2000-11-15 |
EE9600149A (et) | 1997-04-15 |
DE4416101C2 (de) | 1997-06-12 |
SK120496A3 (en) | 1997-03-05 |
GR3035240T3 (en) | 2001-04-30 |
LV11721B (en) | 1997-12-20 |
LV11721A (lv) | 1997-04-20 |
DE4416101A1 (de) | 1995-10-26 |
CA2184592A1 (en) | 1995-10-26 |
BG63420B1 (bg) | 2002-01-31 |
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