EP0736217A1 - Sinterkontaktwerkstoff, verfahren zu dessen herstellung sowie diesbezügliche kontaktauflagen - Google Patents
Sinterkontaktwerkstoff, verfahren zu dessen herstellung sowie diesbezügliche kontaktauflagenInfo
- Publication number
- EP0736217A1 EP0736217A1 EP95903252A EP95903252A EP0736217A1 EP 0736217 A1 EP0736217 A1 EP 0736217A1 EP 95903252 A EP95903252 A EP 95903252A EP 95903252 A EP95903252 A EP 95903252A EP 0736217 A1 EP0736217 A1 EP 0736217A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- nickel
- silver
- contact
- sintered
- particle size
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
- H01H1/023—Composite material having a noble metal as the basic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
Definitions
- the invention relates to a sintered contact material made of silver and nickel, to a method for the production thereof and to contact pads made therefrom.
- contact materials made of silver (Ag) and nickel (Ni) have proven useful for switching currents in switching devices in energy technology.
- the manufacture of such contact materials as well as the manufacture and testing of related contact pieces is described in Int. J. Powder Metallurgy and Powder Technology, Vol. 12 (1976), p. 219-228, described in detail.
- silver and nickel powder are usually mixed wet in a mixer, dried, compression-molded and sintered under a reducing atmosphere to produce a contact material made of silver and nickel.
- the fineness of the structure essentially depends on the size of the starting powder used. Such relationships are described in detail in the monograph by H. Schreiner "Powder Metallurgy of Electrical Contacts", Springer-Verlag (1976), pages 105 to 140. In particular, an AgNi material with average grain sizes of 1 ⁇ m produced using precipitation powder is specified.
- JP-OS 66/33090 already discloses a method for producing materials for silver-based electrical contacts is known in which such a metal is selected as a further component, which has no or only low solubility in silver.
- This metal is in particular nickel, iron, tungsten or another metal which does not form a mixed crystal with silver or in which, for thermodynamic reasons, there is a tendency towards segregation in accordance with the state diagram.
- JP-OS 6633090 a mixed crystal-like constitution of the material is sought.
- electrolyte / silver powder and carbonyl-nickel powder are mixed in a ball mill with steel balls under so-called styrene gas over longer periods, for example up to 300 h, in order to obtain a mechanically alloyed powder.
- the powder obtained in this way should have grain sizes of less than 0.01 ⁇ m.
- the disappearance of nickel reflections and thus the presence of an amorphous alloy was confirmed in an X-ray diffraction analysis.
- secondary precipitations should be possible, but the grain size of the nickel particles should be limited to 1 ⁇ m.
- the object of the invention is to provide a remedy here.
- a contact material made of silver and nickel is to be created which has improved contact properties compared to conventional silver-nickel materials.
- the associated manufacturing process and corresponding contact requirements are specified.
- the object is achieved according to the invention in a sintered contact material made of silver and nickel in that the mass fraction of nickel is between 5 and 50% and that the nickel in the silver structure with average particle sizes 1 ⁇ m ⁇ d ⁇ 10 ⁇ in a largely homogeneous distribution is present.
- the mean particle size of nickel is preferably d ⁇ 5 ⁇ m, in particular d ⁇ 3 ⁇ m. With the specified particle size distributions, the average distance D between the nickel particles should be between 5 and 10 ⁇ m.
- the process for producing the specified sintered contact material from silver and nickel is characterized according to the invention in that, prior to sintering, the nickel is introduced into the silver structure in the manner of mechanical alloying, this process taking place in an air atmosphere.
- the nickel is introduced into the silver structure in the manner of mechanical alloying, this process taking place in an air atmosphere.
- Nickel powder or granules of silver and nickel are used. Particle size distributions of less than 500 ⁇ m, preferably less than 100 ⁇ m, in particular less than 50 ⁇ m, are preferred.
- Mixing in the manner of mechanical alloying takes place in a ball mill until a lamellar structure has formed with Ni lamella widths very much smaller than the particle diameter of the starting powder. With such a degree of refinement of the structure, one is already in the range of the detection limit of a light microscope.
- contact layers can be produced from the silver-nickel powder produced in the manner of mechanical alloying by compression molding, such as extrusion or molding technology, and sintering under a reducing atmosphere.
- the contact pads are preferably designed as strips or profiles or as contact pieces and are used in a switching device in power engineering.
- mechanical alloying is not carried out under protective gas in the invention. Instead, normal atmospheric air is used. Mixing does not take place as long as possible, in particular in JP-OS 6633090, in order to obtain an alloy powder which is as fine as possible. Rather, it is consciously used to carry out the mechanical alloying process in air.
- oxide skins are formed on the particles, which have the same effect as additives that reduce perspiration.
- the oxides on the surface of the particles contribute to the embrittlement of the composite particles and thereby to faster structure refinement.
- the mechanical alloying process is considerably shortened compared to mechanical alloying under inert gas.
- Figure 1 shows the micrograph of a material AgNilO and Figure 2 shows the micrograph of a material AgNi40.
- Silver powders with a particle size distribution ⁇ 300 ⁇ m and nickel powder with a particle size distribution ⁇ 150 ⁇ m are used as starting materials for the production of the materials AgNilO and AgNi40. After appropriate weighing, the powders are placed in a ball mill (attritor) and mechanically alloyed there until the nickel that forms is ⁇ 3 ⁇ m in size and is homogeneously present in the silver.
- the ball mill works in an air atmosphere and without waxes as further additives.
- the structure refinement resulting from mechanical alloying is accompanied by a change in the powder particle shape and size. Processing in an air atmosphere consciously accepts that oxide skins form on the particles.
- contact layers are produced in a known manner by compression molding and sintering in a reducing atmosphere.
- extrusion molding for the production of strips or profiles or the so-called molding technique for the production of individual contact pieces can be considered as a method of pressure forming. It is also advantageous to produce two-layer contact pads or contact pieces with a first layer made of silver-nickel and a second layer made of pure silver, in order to ensure a secure connection technique with the contact piece carrier.
- the micrographs according to FIG. 1 and FIG. 2 show the material AgNilO on the one hand and AgNi40 on the other.
- the table shows measured values for welding force Fs, burn-up A and the contact resistances Rk when switching on and off.
- the switching properties of contacts No. 2 and No. 4 produced according to the invention are shown using the example of the material compositions AgNilO and AgNi40, which are compared with the properties of conventionally produced contacts No. 1 and No. 3 of the same composition are.
- the contact resistance test was carried out under 10 A.
- the burnup was determined by weighing both contact pieces and averaging. The volume erosion was derived from this, taking into account the theoretical density.
- the nickel-rich melt resulting from the silver-nickel material according to the invention compared to a previously known AgNi material with the same nickel concentration has a higher viscosity.
- less material is sprayed during melting, which means that contact burn-off is less with mechanically alloyed material.
- the gas dissolved in the melt is only added released to a lesser extent, so that when the material solidifies, pores are formed in the switching structure which reduce the mechanical strength and thus the welding force.
- Example grain size welding force composition [mOhm] [mOhm] [mm 3 ]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Powder Metallurgy (AREA)
- Contacts (AREA)
- Manufacture Of Switches (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4344322A DE4344322A1 (de) | 1993-12-23 | 1993-12-23 | Sinterkontaktwerkstoff |
DE4344322 | 1993-12-23 | ||
PCT/DE1994/001527 WO1995017759A1 (de) | 1993-12-23 | 1994-12-22 | Sinterkontaktwerkstoff, verfahren zu dessen herstellung sowie diesbezügliche kontaktauflagen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0736217A1 true EP0736217A1 (de) | 1996-10-09 |
EP0736217B1 EP0736217B1 (de) | 1997-11-05 |
Family
ID=6506101
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95903252A Expired - Lifetime EP0736217B1 (de) | 1993-12-23 | 1994-12-22 | Sinterkontaktwerkstoff, verfahren zu dessen herstellung sowie diesbezügliche kontaktauflagen |
Country Status (7)
Country | Link |
---|---|
US (1) | US5763105A (de) |
EP (1) | EP0736217B1 (de) |
JP (1) | JPH09506931A (de) |
BR (1) | BR9408402A (de) |
DE (2) | DE4344322A1 (de) |
ES (1) | ES2109804T3 (de) |
WO (1) | WO1995017759A1 (de) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5679471A (en) * | 1995-10-16 | 1997-10-21 | General Motors Corporation | Silver-nickel nano-composite coating for terminals of separable electrical connectors |
JP4257755B2 (ja) * | 1998-10-31 | 2009-04-22 | キヤノンファインテック株式会社 | 画像読取装置及び画像形成装置 |
TW487742B (en) * | 1999-05-10 | 2002-05-21 | Matsushita Electric Ind Co Ltd | Electrode for PTC thermistor, manufacture thereof, and PTC thermistor |
EP2913413B1 (de) * | 2012-08-20 | 2017-05-17 | Wenzhou Hongfeng Electrical Alloy Co., Ltd. | Herstellungsverfahren für elektrische kontaktmaterialien |
CN102808097B (zh) * | 2012-08-20 | 2014-04-16 | 温州宏丰电工合金股份有限公司 | 一种银/镍/金属氧化物电接触材料的制备方法 |
US20140326605A1 (en) * | 2013-05-03 | 2014-11-06 | Tyco Electronics Corporation | Electroplating contacts with silver-alloys in a basic bath |
CN103996426B (zh) * | 2014-05-28 | 2016-05-11 | 东北大学 | 一种镍网状分布的银镍复合电触头材料及其制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2511041B1 (fr) * | 1981-08-07 | 1986-12-05 | Louyot Comptoir Lyon Alemand | Materiaux a base d'argent et d'oxyde de nickel, utilisables pour la realisation de contacts electriques, et procedes pour leur fabrication |
DE3146972A1 (de) * | 1981-11-26 | 1983-06-01 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zum herstellen von formteilen aus cadmiumfreien silber-metalloxid-verbundwerkstoffen fuer elektrische kontaktstuecke |
JPS6026632A (ja) * | 1983-07-22 | 1985-02-09 | Omron Tateisi Electronics Co | 電気接点材料 |
JPH0791608B2 (ja) * | 1990-06-21 | 1995-10-04 | 松下電工株式会社 | 接点材料およびその製造方法 |
DE4117312A1 (de) * | 1991-05-27 | 1992-12-03 | Siemens Ag | Kontaktwerkstoff auf silberbasis zur verwendung in schaltgeraeten der energietechnik sowie verfahren zur herstellung von kontaktstuecken aus diesem werkstoff |
-
1993
- 1993-12-23 DE DE4344322A patent/DE4344322A1/de not_active Withdrawn
-
1994
- 1994-12-22 US US08/666,445 patent/US5763105A/en not_active Expired - Fee Related
- 1994-12-22 JP JP7517091A patent/JPH09506931A/ja active Pending
- 1994-12-22 ES ES95903252T patent/ES2109804T3/es not_active Expired - Lifetime
- 1994-12-22 BR BR9408402A patent/BR9408402A/pt not_active Application Discontinuation
- 1994-12-22 EP EP95903252A patent/EP0736217B1/de not_active Expired - Lifetime
- 1994-12-22 WO PCT/DE1994/001527 patent/WO1995017759A1/de active IP Right Grant
- 1994-12-22 DE DE59404552T patent/DE59404552D1/de not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO9517759A1 * |
Also Published As
Publication number | Publication date |
---|---|
US5763105A (en) | 1998-06-09 |
DE59404552D1 (de) | 1997-12-11 |
BR9408402A (pt) | 1997-08-05 |
ES2109804T3 (es) | 1998-01-16 |
WO1995017759A1 (de) | 1995-06-29 |
JPH09506931A (ja) | 1997-07-08 |
DE4344322A1 (de) | 1995-06-29 |
EP0736217B1 (de) | 1997-11-05 |
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