EP0598143A1 - Reinigungs- , Netz- und Lösungsmittel - Google Patents

Reinigungs- , Netz- und Lösungsmittel Download PDF

Info

Publication number
EP0598143A1
EP0598143A1 EP92121273A EP92121273A EP0598143A1 EP 0598143 A1 EP0598143 A1 EP 0598143A1 EP 92121273 A EP92121273 A EP 92121273A EP 92121273 A EP92121273 A EP 92121273A EP 0598143 A1 EP0598143 A1 EP 0598143A1
Authority
EP
European Patent Office
Prior art keywords
total weight
cleaning
agent
diethanolamine
nonyl phenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP92121273A
Other languages
English (en)
French (fr)
Inventor
Edward E. Friloux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Delta Omega Technologies Ltd
Original Assignee
Delta Omega Technologies Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from BR9204963A external-priority patent/BR9204963A/pt
Application filed by Delta Omega Technologies Ltd filed Critical Delta Omega Technologies Ltd
Publication of EP0598143A1 publication Critical patent/EP0598143A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43Solvents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86Mixtures of anionic, cationic, and non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

Definitions

  • the present invention relates to cleaning agents, and more particularly to a chemical composition for use as a cleaning, wetting agent and solvent and in other suitable applications.
  • solvents are used in textile industry and act as wetting agents in a process designed to remove sizing from cloth before the fabric is dyed or printed.
  • Electronic circuit printboards have to be regularly cleaned to prevent disfunction of the electronic device due to accumulation of dust or other foreign material on the surface.
  • the present invention contemplates provision of a cleaning, wetting solvent agent which is non-toxic, non-flammable and economical, which does not deplete the ozone layer.
  • Still a further object of the invention is to provide a dispersant which maintains a buoyancy effect on dispersed hydrocarbons, making collection and disposal of contaminants easier and more cost-effective.
  • composition of matter which comprises dodecylbenzenesulfonic acid, ethoxylated nonyl phenol, lauric acid diethanolamide, diethanolamine and propylene glycol mixed in a water base.
  • the composition of matter provides for a mixture in water of between about 0.17% and 1.36% by total weight of ethoxylated nonyl phenol, mixed with dodecylbenzenesulfonic acid in an amount between about 2 and 2.5 times the concentration of ethoxylated nonyl phenol, lauric acid diethanolamide in amount between about 1.5 and 2 times the concentration of the dodecylbenzenesulfonic acid, and diethanolamine and propylene glycol in equal amounts of between about 2 and 2.5 times the concentration of lauric acid diethanolamide.
  • composition of matter provides for the use of 3% by total weight of dodecylbenzenesulfonic acid, 0.3% by total weight of ethoxylated nonyl phenol, 5.66% by total weight of lauric acid diethanolamide and equal amounts of 2.46% by total weight of diethanolamine and propylene glycol all mixed in a water base.
  • the composition of matter in accordance with the present invention comprises between about 0.17 - 2.36% by weight of ethoxylated nonyl phenol, between about 2.83 - 22.6% by weight of lauric acid diethanolamide, between about 1.23 - 9.84% by weight of diethanolamine and between 1.23 - 9.84% by weight of propylene glycol in aqueous solution.
  • the cleaning, solvent agent of the present invention is a synthetic detergent compound which uses dodecylbenzene as a detergent agent and diethanolamide as an emulsifier.
  • the composition concentrate of the present invention exhibits all of the positive qualities of the petroleum-based solvents and chlorofluorocarbon-containing cleaning agent, while eliminating the negative attributes of these compositions.
  • composition of matter of the instant application are affective as solvents and cleaning agents, although effectiveness is not lost in less concentrated solutions.
  • the present composition was found to be especially effective in applications, wherein safe solvents and no-residue cleaning agents are required.
  • composition of the present invention is non-toxic, non-corrosive, non-flammable, non-hazardous, biodegradable and, since it uses no halons, causes no ozone layer depletion.
  • the composition of the present invention exhibits the following physical properties: Properties Data Color Clear colorless liquid Odor Mild surfactant odor Weight 8.34 pounds per gallon ph 9.0 Specific gravity About 1.00 Boiling point 220 degrees Fahrenheit
  • EXAMPLE 1 25.07% by weight of water was placed in a vat.
  • EXAMPLE 2 25.07% by weight of water was deposited in a vat. In a separate vat 3% by weight of dodecylbenzenesulfonic acid was mixed with 0.34% of ethoxylated nonyl phenol. The resultant composition was thoroughly blended and then deposited in the first vat containing water.
  • EXAMPLE 3 25.07% of water was deposited in a vat. In a separate vat 12% by weight of dodecylbenzenesulfonic acid was premixed with 1.36% by weight of ethoxylated nonyl phenol. The mixture was thoroughly blended and then deposited into the first vat containing water. While continuously stirring the following ingredients were added to the first vat: 22.64% of lauric acid diethanolamide, 9.84% by weight of diethanolamine and 9.84% by weight of propylene glycol. Finally, 19.25% by weight of water was added to the mixture which was stirred for an additional 15 minutes.
  • the resultant composition has specific gravity of about 0.97 - 1.09, depending on the amount of active ingredients in the aqueous solution and exhibits other physical properties aforementioned.
  • the resultant composition successfully replaces petroleum-based solvents, and can be used as a wetting agent to aid in emulsification of the various sizing materials adapted for use, for example, in textile industry.
  • the composition after it served its purposes, can be safely disposed of by discharging into a plant's sediment pond prior to discharge into a municipal waste treatment system.
  • composition of the present invention can be used for a number of cleaning jobs, especially those which require that no film or residue is left on the surface.
  • it can be used for hard metal cleaning in aqueous solutions having a dilution ratio of from about 0.1 to 1.0.
  • the composition can be used in cleaning of oxygen breathing equipment in aqueous solutions having a dilution ratio of from about 0.1 to 1.0 without causing any danger of explosion or fire.
  • the composition can be utilized in preparing rubber or vinyl surfaces for repair in aqueous solutions having a dilution ratio of from about 0.1 to 1.0.
  • the composition of the instant invention can be used for cleaning circuit printboards of electronic devices.
  • Another exemplary use can be found in the field of cleaning delicate precision optical devices, or even ocular glass or plastic lenses.
  • the ratio of dilutions would be approximately the same.
  • the composition is effective as a wetting agent for use in textile industry and other applications, where the reduction of the surface tension of water is a requirement.
  • composition of the present invention is non-toxic, non-flammable, non-explosive, does not release ozone depleting substances, can be discharged into municipal waste systems along with the water which is used for rinsing off of the solution.
  • the discharge diluted as described above meets with the current requirements of environmental safety agencies.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Detergent Compositions (AREA)
  • Eyeglasses (AREA)
  • Coloring (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Manufacturing Of Printed Wiring (AREA)
EP92121273A 1992-10-30 1992-12-14 Reinigungs- , Netz- und Lösungsmittel Withdrawn EP0598143A1 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CA002081803A CA2081803A1 (en) 1992-10-30 1992-10-30 Cleaning, wetting agent and solvent
DE4238424 1992-11-13
DE4238424A DE4238424A1 (de) 1992-10-30 1992-11-13 Reinigendes Benetzungs- und Lösungsmittel
BR9204963A BR9204963A (pt) 1991-09-05 1992-12-09 Composiçao agente de limpeza, agente umectante e agente solvente e processo de limpeza de superficies.
JP5017001A JPH06234999A (ja) 1992-10-30 1993-01-07 洗浄、湿潤剤及び溶媒

Publications (1)

Publication Number Publication Date
EP0598143A1 true EP0598143A1 (de) 1994-05-25

Family

ID=27425217

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92121273A Withdrawn EP0598143A1 (de) 1992-10-30 1992-12-14 Reinigungs- , Netz- und Lösungsmittel

Country Status (4)

Country Link
EP (1) EP0598143A1 (de)
JP (1) JPH06234999A (de)
CA (1) CA2081803A1 (de)
DE (1) DE4238424A1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997043012A1 (en) * 1996-05-14 1997-11-20 Eckhard Biller Fire suppressant foam dispersant and detergent eckhard iii-formula
WO2015120562A1 (de) * 2014-02-11 2015-08-20 Wetrok Ag Mittel zum entschichten von oberflächen

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10204492A (ja) * 1997-01-20 1998-08-04 Toyota Motor Corp 水溶性洗浄剤
EP1963083A2 (de) 2005-12-20 2008-09-03 Johnson & Johnson Vision Care, Inc. Verfahren zum entfernen von nicht umgesetzten komponenten aus ophthalmischen hydrogellinsen

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4184974A (en) * 1974-05-16 1980-01-22 Leuven James W Van Liquid biocidal compositions comprising a mixture of silver ions and sodium pectate
EP0109022A2 (de) * 1982-11-09 1984-05-23 MIRA LANZA S.p.a. Konzentrierte flüssige Detergenszusammensetzung,geeignet für die Herstellung von flüssigen Wäschefeinwaschmitteln oder Geschirrwaschmitteln.
GB2165855A (en) * 1984-09-28 1986-04-23 Colgate Palmolive Co High foaming nonionic surfactant based liquid detergent
WO1991000138A1 (en) * 1989-06-23 1991-01-10 Delta-Omega Technologies, Ltd. Cleaning composition, oil dispersant and use thereof
US5061383A (en) * 1990-05-21 1991-10-29 Friloux Edward E Emulsifying film foam

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4184974A (en) * 1974-05-16 1980-01-22 Leuven James W Van Liquid biocidal compositions comprising a mixture of silver ions and sodium pectate
EP0109022A2 (de) * 1982-11-09 1984-05-23 MIRA LANZA S.p.a. Konzentrierte flüssige Detergenszusammensetzung,geeignet für die Herstellung von flüssigen Wäschefeinwaschmitteln oder Geschirrwaschmitteln.
GB2165855A (en) * 1984-09-28 1986-04-23 Colgate Palmolive Co High foaming nonionic surfactant based liquid detergent
WO1991000138A1 (en) * 1989-06-23 1991-01-10 Delta-Omega Technologies, Ltd. Cleaning composition, oil dispersant and use thereof
US5061383A (en) * 1990-05-21 1991-10-29 Friloux Edward E Emulsifying film foam

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997043012A1 (en) * 1996-05-14 1997-11-20 Eckhard Biller Fire suppressant foam dispersant and detergent eckhard iii-formula
WO2015120562A1 (de) * 2014-02-11 2015-08-20 Wetrok Ag Mittel zum entschichten von oberflächen
WO2015120560A1 (de) * 2014-02-11 2015-08-20 Wetrok Ag Mittel zum entschichten von oberflächen

Also Published As

Publication number Publication date
DE4238424A1 (de) 1994-05-19
JPH06234999A (ja) 1994-08-23
CA2081803A1 (en) 1994-05-01

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