EP0316859B2 - Method and apparatus for washing moving sheet-like materials - Google Patents
Method and apparatus for washing moving sheet-like materials Download PDFInfo
- Publication number
- EP0316859B2 EP0316859B2 EP88119007A EP88119007A EP0316859B2 EP 0316859 B2 EP0316859 B2 EP 0316859B2 EP 88119007 A EP88119007 A EP 88119007A EP 88119007 A EP88119007 A EP 88119007A EP 0316859 B2 EP0316859 B2 EP 0316859B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- treatment
- washing liquor
- washing
- fabric web
- liquor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/20—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics with means to improve the circulation of the treating material on the surface of the fabric
Definitions
- the invention relates to a method for water-saving washing of moving webs in accordance with the introductory part of claim 1 and a device suitable for carrying out the method according to the introductory part of claim 5.
- DE 33 24 650 A1 discloses a method for the wet treatment of broadly running webs of goods, in which the treatment liquor supplied in the treatment sections is collected after the treatment process, fed to the same treatment process again and only then discharged from the treatment section or passed on to the next treatment section becomes.
- two spray tubes are arranged on both sides of the first ramping material web section and two further spray tubes above the last two top rollers.
- spray tubes are arranged in the vicinity of the three lower deflection rollers.
- the present invention has for its object to achieve a considerable saving of fresh wash water by better utilization of the wash liquor and thus reduce operating costs. Another object is to provide a device suitable for carrying out the method.
- the first object is achieved by the feature specified in the characterizing part of claim 1. Further advantageous features of the method according to the invention can be found in claims 2 to 4.
- the second object is achieved by the feature specified in the characterizing part of claim 5. Further advantageous features of the device according to the invention can be found in claims 6 to 15.
- distributor pipes 25, 26, 27 and flat jet nozzles 28, 29, 30, 38 are indicated in the housing 11, which is passed through by the web during the treatment. through which the treatment fleet is fed to the web.
- the fleet running off the web is discharged separately for each compartment at the bottom of each compartment 12, 13, 14 and collected in collecting containers 15, 16, 17, 18.
- the treatment liquor is conveyed back from these containers to the same compartment in the circuit by pumps 19, 20, 21, 22 and is returned to the material web via the distributor pipes and flat jet nozzles.
- the delivered amounts of liquor can be adjusted by regulating valves in the feed lines, as the figure shows.
- the circulation of the treatment liquor is superimposed on the guidance of the liquor in countercurrent to the direction of travel of the fabric through the treatment, which is achieved in that the receptacles 15, 16, 17, 18 are cascaded with overflows in such a way that the liquor is removed from the receptacles the areas of more advanced treatment are returned to the collecting containers of the collecting containers which are further ahead in the treatment, that is to say contrary to the direction of travel of the fabric.
- the fleet is renewed by overflowing the amount of water fed in as fresh water from the collecting tank to the collecting tank.
- a sieve belt 23 is guided around the collecting container, through which the liquor running off the web is immediately freed of filterable impurities.
- the sieve belt is cleaned after the passage of the last, lowest arranged collecting container by spraying with a partial flow of the waste water by means of nozzles 24 from the inside. So no fresh water is used for cleaning.
- the belt is cleaned shortly after the point at which the greatest amount of filterable substance is expected.
- the sieve belt 23 runs continuously slowly in the direction of the liquor run through the collecting container.
- Fig. 1 the heating of the cold fresh water 34 is indicated by a waste water heat recovery device with a heat exchanger 35, a reheater 37 connected to heating steam 36, and the associated valves and control devices.
- a waste water heat recovery device with a heat exchanger 35, a reheater 37 connected to heating steam 36, and the associated valves and control devices.
- a reheater 37 connected to heating steam 36, and the associated valves and control devices.
- interruption 40, bypass 39, discharge line 42, etc. which enable optimum washing performance with the lowest fresh water consumption for different operating requirements.
- FIG. 2 The embodiment of an inventive device of FIG. 2 reveals the precise running of the web 10 through the successive washing compartments 12, 13, 14, and the fleet guides.
- the individual designations are the same as in FIG. 1.
- the material web 10 is inserted into the compartment 12 in the vapor-tight housing 11 via a water lock 31.
- the web of material is first sprayed with the dirtiest liquor on both sides by flat jets 38. This rinses off surface impurities and already significantly reduces the concentration of the substances to be washed out in the goods.
- the fleet is then fed to the web in the individual compartments 12, 13, 14 in the manner which has already been described in FIG. 1. Likewise, the circulation and countercurrent management of the treatment liquor.
- the web 10 leaves the housing 11 again via a water lock 33 and can then be fed to an end squeezer 41, which then completes the washing treatment.
Abstract
Description
Die Erfindung betrifft ein Verfahren zum wassersparenden Waschen von laufenden Warenbahnen gemaß dem einleitenden Teil des Anspruchs 1 und eine zum Durchführen des Verfahrens geeignete Vorrichtung gemäß dem einleitenden Teil des Anspruchs 5.The invention relates to a method for water-saving washing of moving webs in accordance with the introductory part of
Gemäß EP 0 197 429 A1, auf der die Erfindung aufbaut, wird umgewälzte Waschflotte - abgesehen von einer am Wareneinlauf vorgesehenen Düsenanordnung zum Abspritzen von Flusen - den einzelnen Behandlungsabteilen ausschließlich durch Flachstrahldüsen zugeführt, die jeweils am Ausgang des Behandlungsabteils angeordnet sind. Dabei wird die in einem Behandlungsabteil gesammelte Waschflotte insbesondere einem anderen Behandlungsabteil zugeführt, in dem die Behandlung der Ware weiter fortgeschritten ist.According to EP 0 197 429 A1, on which the invention is based, circulated washing liquor - apart from a nozzle arrangement for spraying lint off at the goods inlet - is fed to the individual treatment compartments exclusively through flat jet nozzles, which are each arranged at the exit of the treatment compartment. The washing liquor collected in one treatment compartment is in particular fed to another treatment compartment in which the treatment of the goods has progressed further.
Durch die DE 33 24 650 A1 ist ein Verfahren zur Naßbehandlung von breit geführten laufenden Warenbahnen bekannt, bei dem in den Behandlungsabschnitten zugeführte Behandlungsflotte nach dem Behandlungsvorgang aufgefangen, dem gleichen Behandlungsvorgang erneut zugeführt und erst danach aus dem Behandlungsabschnitt abgeführt bzw. in den nächsten Behandlungsabschnitt weitergeleitet wird. Bei Behandlungsabschnitten mit vertikaler Führung der Warenbahn sind zwei Spritzrohre beiderseits des ersten hochlaufenden Warenbahnabschnitts und zwei weitere Spritzrohre oberhalb der letzten beiden Oberwalzen angeordnet.DE 33 24 650 A1 discloses a method for the wet treatment of broadly running webs of goods, in which the treatment liquor supplied in the treatment sections is collected after the treatment process, fed to the same treatment process again and only then discharged from the treatment section or passed on to the next treatment section becomes. In the case of treatment sections with vertical guidance of the material web, two spray tubes are arranged on both sides of the first ramping material web section and two further spray tubes above the last two top rollers.
Bei einem Behandlungsabschnitt mit horizontaler Warenbahnführung sind Spritzrohre in der Nähe der drei unteren Umlenkwalzen angeordnet.In a treatment section with a horizontal web guide, spray tubes are arranged in the vicinity of the three lower deflection rollers.
Der vorliegenden Erfindung liegt die Aufgabe zugrunde, durch bessere Ausnutzung der Waschflotte eine erhebliche Einsparung an frischem Waschwasser zu erzielen und somit die Betriebskosten zu senken. Eine weitere Aufgabe besteht darin, eine zur Durchführung des Verfahrens geeignete Vorrichtung zu schaffen.The present invention has for its object to achieve a considerable saving of fresh wash water by better utilization of the wash liquor and thus reduce operating costs. Another object is to provide a device suitable for carrying out the method.
Die erste Aufgabe wird durch das im kennzeichnenden Teil des Anspruchs 1 angegebene Merkmal gelöst. Weitere vorteilhafte Merkmale des erfindungsgemäßen Verfahrens sind den Ansprüchen 2 bis 4 zu entnehmen.The first object is achieved by the feature specified in the characterizing part of
Die zweite Aufgabe wird durch das im kennzeichnenden Teil des Anspruchs 5 angegebene Merkmal gelöst. Weitere vorteilhafte Merkmale der erfindungsgemäßen Vorrichtung sind den Ansprüchen 6 bis 15 zu entnehmen.The second object is achieved by the feature specified in the characterizing part of claim 5. Further advantageous features of the device according to the invention can be found in
Anhand der beiliegenden Zeichnungen soll die Erfindung nachfolgend noch weiter erläutert werden. Auf den Zeichnungen zeigen
- Fig. 1
- das Behandlungsflottenführungsschema gemäß der Erfindung und
- Fig. 2
- ein Ausführungsbeispiel für eine erfindungsgemäße Vorrichtung in stark schematisierter Darstellung.
- Fig. 1
- the treatment fleet management scheme according to the invention and
- Fig. 2
- an embodiment of a device according to the invention in a highly schematic representation.
Bei dem Flottenführungsschema der Fig. 1 ist die Warenbahn 10 nur angedeutet, um die Darstellung nicht zu verwirren. Der vollständige Lauf der Warenbahn durch die Behandlung ist in Fig. 2 dargestellt. In beiden Figuren sind gleiche Teile mit gleichen Bezugszeichen versehen.In the fleet management scheme of FIG. 1, the
Wie Fig. 1 erkennen läßt, sind in dem Gehäuse 11, welches von der Warenbahn bei der Behandlung durchlaufen wird, Verteilerrohre 25, 26, 27 und Flachstrahldüsen 28, 29,30,38 angedeutet. durch die der Warenbahn die Behandlungsflotte zugeführt wird. Die von der Warenbahn ablaufende Flotte wird am Boden jedes Abteils 12, 13, 14 für jedes Abteil getrennt abgeführt und in Auffangbehältern 15, 16, 17, 18 gesammelt. Aus diesen Behältern wird die Behandlungsflotte über Pumpen 19,20,21,22 jeweils in das gleiche Abteil im Kreislauf zurückgefördert und über die Verteilerohre und Flachstrahldüsen wieder der Warenbahn zugeführt. Die geförderten Flottenmengen können durch Regelventile in den Zuleitungen eingestellt werden, wie die Figur erkennen läßt.As can be seen in FIG. 1,
Der Umwälzung der Behandlungsflotte ist eine Führung der Flotte im Gegenstrom zur Laufrichtung der Warenbahn durch die Behandlung überlagert, die dadurch erreicht wird, daß die Auffangbehälter 15, 16, 17, 18 kaskadenförmig mit Überläufen in der Weise angeordnet sind, daß die Flotte von den Auffangbehältern der Bereiche weiter fortgeschrittener Behandlung zu den Auffangbehältern der in der Behandlung weiter voran liegenden Auffangbehälter, also entgegen der Laufrichtung der Warenbahn durch die Behandlung zurückgeführt wird. Die Flottenerneuerung erfolgt durch Überlauf der als Frischwasser eingespeisten Wassermenge von Auffangbehälter zu Auffangbehälter.The circulation of the treatment liquor is superimposed on the guidance of the liquor in countercurrent to the direction of travel of the fabric through the treatment, which is achieved in that the
Um die Auffangbehälter herum ist ein Siebband 23 geführt, durch das die von der Warenbahn ablaufende Flotte sofort von abfiltrierbaren Verunreinigungen befreit wird. Die Reinigung des Siebbandes geschieht nach der Passage des letzten am niedrigsten angeordneten Auffangbehälters durch Abspritzen mit einem Teilstrom des Abwassers mittels Düsen 24 von innen her. Es wird also kein Frischwasser zur Reinigung verbraucht. Das Band wird kurz nach der Stelle gereinigt, an der die größte Menge an abfiltrierbarer Substanz zu erwarten ist. Das Siebband 23 läuft ständig langsam in Richtung des Flottenlaufes durch die Auffangbehälter um.A
In Fig. 1 ist noch die Aufheizung des kalten Frischwassers 34 über eine Abwasser-Wärmerückgewinnungseinrichtung mit Wärmetauscher 35, einem mit Heizdampf 36 in Verbindung stehenden Nacherhitzer 37, sowie den dazugehörigen Ventilen und Regeleinrichtungen angedeutet. Außerdem lassen sich verschiedene Möglichkeiten für besondere Flottenführungen hinter den Auffangbehältern, wie Unterbrechung 40, Umführung 39, Ableitung 42 usw. erkennen, durch die eine optimale Waschleistung mit geringstem Frischwasserverbrauch für unterschiedliche Betriebserfordernisse ermöglicht wird.In Fig. 1, the heating of the cold
Das Ausführungsbeispiel einer erfindungsmäßigen Vorrichtung der Fig. 2 läßt den genauen Lauf der Warenbahn 10 durch die aufeinanderfolgenden Waschabteile 12, 13, 14 erkennen, sowie die Flottenführungen. Die einzelen Bezeichnungen sind die gleichen wie in Fig. 1.The embodiment of an inventive device of FIG. 2 reveals the precise running of the
Die Warenbahn 10 wird über ein Wasserschloß 31 in das Abteil 12 im dampfdichten Gehäuse 11 eingeführt. Im Einlaufbereich wird die Warenbahn zunächst mit der schmutzigsten Flotte beidseitig durch Flachstrahlen 38 abgespritzt. Damit werden oberflächliche Verunreinigungen abgespü-lt und die Konzentration der auszuwaschenden Substanzen in der Ware bereits deutlich herabgesetzt.The
Die Zuführung der Flotte zur Warenbahn in den einzelnen Abteilen 12, 13, 14 erfolgt dann in der Weise, die bei Fig. 1 bereits beschrieben ist. Ebenso die Kreislaufführung und die Gegenstromführung der Behandlungsflotte.The fleet is then fed to the web in the
Am Ende der Behandlung verläßt die Warenbahn 10 das Gehäuse 11 wieder über ein Wasserschloß 33 und kann dann einem Endquetschwerk 41 zugeführt werden, womit dann die Waschbehandlung abgeschlossen ist.At the end of the treatment, the
Claims (12)
- A method for washing moving fabric webs in a water-saving manner, in particular in washing processes for washing with a solution or the like,wherein the fabric web, which is guided in substantially vertical loops over upper and lower guide rollers, passes through various treatment sections in succession,wherein washing liquor is applied to the fabric web in each treatment section by spraying with fan jets before it leaves the treatment section, the washing liquor which runs off is collected and a first partial flow of the collected washing liquor is guided back for spraying with fan jets into the same treatment section by circulating it in the circuit,wherein a second partial flow of the collected washing liquor is introduced into the collected washing liquor of the treatment section adjacent in countercurrent to the moving direction of the fabric web,characterized in that part of the first partial flow is introduced into the angle between the fabric web and the lower guide rollers.
- A method according to Claim 1, characterized in that, before being applied to the fabric web again, the washing liquor circulated in the circuit is subjected to a filtering process.
- A method according to Claim 1 or 2, characterized in that the total quantity of washing liquor circulated and the quantity of washing liquor supplied to the fan jets can be regulated separately.
- A device for carrying out the method according to Claim 1,with a housing (11), which has an inlet and an outlet opening for the fabric web (10) and is otherwise closed and vapour-tight,with a plurality of treatment compartments (12, 13, 14), which are arranged consecutively in the housing (11) in the moving direction of the fabric, are separate from one another and in which there are accommodated upper and lower rows of guide rollers for guiding the fabric web (10) through in vertical loops,with fan nozzles (28, 29, 30), arranged at the outlet of each treatment compartment (12, 13, 14) and acted upon by the circulating washing liquor, for supplying liquor in short, approximately horizontal fabric-web guides,with collecting vessels (15, 16, 17) which are arranged beneath the treatment compartments (12, 13, 14), are suitable for collecting the washing liquor flowing off the fabric web, and are connected in a cascade-like manner via weirs for guiding the collected washing liquor from the individual treatment compartments (12, 13, 14) in a countercurrent to the moving direction of the fabric web (10)and with pumps (19, 20, 21), which are connected to the collecting vessels (15, 16, 17), for supplying the washing liquor in the circuit by way of pipes to the fan nozzles (28, 29, 30),characterized in that, in order to supply the washing liquor from the collecting vessels (15, 16, 17) to the fabric web (10), the lower guide rollers are provided with distributing pipes (25, 26, 27), which branch off from the ducts of the fan nozzles (28, 29, 30), for directly introducing the circulated washing liquor into the angle between the fabric web (10) and the guide rollers.
- A device according to Claim 4, characterized in that an additional washing liquor circuit is provided in the inlet treatment compartment (12), this additional washing liquor circuit having fan nozzles (38) arranged on both sides of the fabric web (10) for removing surface dirt and for intensifying the treatment, an associated collecting vessel (18) and a circulating pump (22).
- A device according to Claim 4 or 5, characterized in that a rotating screen belt (23) is placed around the collecting vessels (15, 16, 17, 18), and its strand above the collecting vessels (15, 16, 17, 18) rotates in the same direction as the countercurrent flow of the washing liquor.
- A device according to Claim 6, characterized in that spraying pipes (24) are mounted at the end of the discharging strand of the rotating screen belt (23), these spraying pipes (24) acting upon the screen belt from the inside outwards.
- A device according to any one of Claims 4 to 7, characterized in that components for regulating the quantity of washing liquor circulated are provided in the pipes feeding the distributor pipes (25, 26, 27) and the jet nozzles (28, 29, 30, 38).
- A device according to any one of Claims 4 to 8, characterized in that feed rollers are mounted on the upper guide rollers for the fabric web (10), these feed rollers serving to increase the treatment effect.
- A device according to any one of Claims 4 to 9, characterized in that surge tanks (31, 33) are provided at the inlet of the fabric web (10) into the housing (11) and at the outlet out of the housing (11).
- A device according to any one of Claims 4 to 10, characterized in that surge tanks (32) with partitions are mounted between the individual treatment compartments.
- A device according to any one of Claims 4 to 11, characterized in that, where chemical treatments are included in the overall treatment in one or more of the treatment compartments, the washing liquor is guided in a countercurrent flow around these treatment compartments with a lowering of the level in the associated collecting vessels and with the insertion of upright chemical baths, and in that intermediate squeezing mechanisms are arranged at the outlet of these compartments.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT88119007T ATE87985T1 (en) | 1987-11-20 | 1988-11-15 | METHOD AND DEVICE FOR WATER-SAVING WASHING OF RUNNING WEBS. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3739346 | 1987-11-20 | ||
DE19873739346 DE3739346A1 (en) | 1987-11-20 | 1987-11-20 | METHOD AND DEVICE FOR WATER-SAVING WASHING OF RUNNING PRODUCTS |
Publications (4)
Publication Number | Publication Date |
---|---|
EP0316859A2 EP0316859A2 (en) | 1989-05-24 |
EP0316859A3 EP0316859A3 (en) | 1989-08-30 |
EP0316859B1 EP0316859B1 (en) | 1993-04-07 |
EP0316859B2 true EP0316859B2 (en) | 1996-04-10 |
Family
ID=6340881
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88119007A Expired - Lifetime EP0316859B2 (en) | 1987-11-20 | 1988-11-15 | Method and apparatus for washing moving sheet-like materials |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0316859B2 (en) |
AT (1) | ATE87985T1 (en) |
DE (2) | DE3739346A1 (en) |
ES (1) | ES2040819T3 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2063088T3 (en) * | 1988-09-15 | 1995-01-01 | Babcock Textilmasch | DEVICE FOR WASHING WITH SAVING OF WATER OF MOVING BANDS. |
US5321864A (en) * | 1990-02-26 | 1994-06-21 | Eduard Kusters Maschinenfabrik Gmbh & Co. Kg | Continuous method and installation for bleaching a textile fabric web |
DE4005979A1 (en) * | 1990-02-26 | 1991-08-29 | Kuesters Eduard Maschf | CONTINUE METHOD AND SYSTEM FOR BLEACHING A TEXTILE TRACK |
DE4021479A1 (en) * | 1990-07-05 | 1992-01-16 | Babcock Textilmasch | METHOD AND DEVICE FOR IMPREGNATING RUNNING TEXTILE RAILS OR THE LIKE |
DE4104920A1 (en) * | 1991-02-18 | 1992-08-20 | Jasper Gmbh & Co Josef | Textile scouring bleaching dyeing - utilises a series of vats, with connections and pumps to circulate fluid |
DE29708256U1 (en) * | 1997-05-07 | 1997-07-24 | Babcock Textilmasch | Washing compartment |
DE10339020A1 (en) | 2003-08-25 | 2005-03-24 | Fehring, Hannes, Dipl.-Ing. | Method and device for cleaning sails |
DE102008029359A1 (en) * | 2008-06-18 | 2009-12-24 | Mageba Textilmaschinen Gmbh & Co. Ohg | Band merchandise-treatment steamer |
IT202000017230A1 (en) * | 2020-07-15 | 2022-01-15 | Master Srl | TANK FOR ECOLOGICAL WASHING OF YARNS AND FABRICS |
CN113529320B (en) * | 2021-09-17 | 2021-12-03 | 佛山市南海德耀翔胜纺织有限公司 | A rinsing machine for cloth back is whole |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH1572567D (en) * | 1966-11-12 | |||
FR2087329A5 (en) * | 1970-05-14 | 1971-12-31 | Ruthner Ind Planungs Ag | Continuous cleaning of metal wire |
DE3012612A1 (en) * | 1980-04-01 | 1981-10-08 | Konrad Hornschuch Ag, 7119 Weissbach | Permeable material washing - has sprayed water on one side and suction on the other |
DE3033945A1 (en) * | 1980-09-10 | 1982-04-15 | Vepa AG, 4125 Riehen, Basel | Pile carpeting washing process - having two identical spray suction units to remove unfixed dyestuff |
US4479370A (en) * | 1981-12-10 | 1984-10-30 | Burlington Industries, Inc. | Full counterflow mini-bath open-width fabric washer |
DE3324650A1 (en) * | 1983-07-08 | 1985-01-17 | Babcock Textilmaschinen GmbH, 2105 Seevetal | METHOD AND DEVICE FOR THE WET TREATMENT OF WIDTH-BASED RUNNING PRODUCTS |
DE3439403C2 (en) * | 1984-10-27 | 1996-10-17 | Babcock Textilmasch | Device for washing the solution of continuous webs |
DE3511949A1 (en) * | 1985-04-02 | 1986-10-09 | Babcock Textilmaschinen GmbH, 2105 Seevetal | METHOD AND DEVICE FOR SAVING WATER IN WASHING MACHINES |
DE8704817U1 (en) * | 1987-04-01 | 1987-07-30 | Babcock Textilmaschinen Gmbh, 2105 Seevetal, De | |
DE8715388U1 (en) * | 1987-11-20 | 1988-01-14 | Babcock Textilmaschinen Gmbh, 2105 Seevetal, De |
-
1987
- 1987-11-20 DE DE19873739346 patent/DE3739346A1/en not_active Withdrawn
-
1988
- 1988-11-15 ES ES198888119007T patent/ES2040819T3/en not_active Expired - Lifetime
- 1988-11-15 DE DE8888119007T patent/DE3880091D1/en not_active Expired - Fee Related
- 1988-11-15 AT AT88119007T patent/ATE87985T1/en active
- 1988-11-15 EP EP88119007A patent/EP0316859B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2040819T3 (en) | 1993-11-01 |
EP0316859A3 (en) | 1989-08-30 |
EP0316859A2 (en) | 1989-05-24 |
DE3739346A1 (en) | 1989-06-01 |
DE3880091D1 (en) | 1993-05-13 |
ATE87985T1 (en) | 1993-04-15 |
EP0316859B1 (en) | 1993-04-07 |
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