EP0280150B1 - Space heating element consisting of a ceramic body provided with an electrically resistant layer, especially in the form of a ceramic plate - Google Patents

Space heating element consisting of a ceramic body provided with an electrically resistant layer, especially in the form of a ceramic plate Download PDF

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Publication number
EP0280150B1
EP0280150B1 EP88102207A EP88102207A EP0280150B1 EP 0280150 B1 EP0280150 B1 EP 0280150B1 EP 88102207 A EP88102207 A EP 88102207A EP 88102207 A EP88102207 A EP 88102207A EP 0280150 B1 EP0280150 B1 EP 0280150B1
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EP
European Patent Office
Prior art keywords
glaze
heating element
layer
ceramic
space heating
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Expired - Lifetime
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EP88102207A
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German (de)
French (fr)
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EP0280150A1 (en
Inventor
Martin Bard
Gottfried Dr. Cremer
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Buchtal GmbH
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Buchtal GmbH
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Priority to AT88102207T priority Critical patent/ATE68655T1/en
Publication of EP0280150A1 publication Critical patent/EP0280150A1/en
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/20Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
    • H05B3/22Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
    • H05B3/26Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor mounted on insulating base
    • H05B3/265Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor mounted on insulating base the insulating base being an inorganic material, e.g. ceramic

Definitions

  • the invention relates to a space heating element consisting of a ceramic molded body provided with an electrical resistance coating, in particular in the form of a ceramic plate.
  • a space heating element consisting of a ceramic molded body is known, which is provided on the side facing away from its visible side with a flat heating conductor in the form of an electrical resistance coating made of an electrically conductive ceramic glaze, in which the electrical resistance coating is formed as a resistance layer from a material in which non-metallic, large specific surface area, electrically conductive particles which do not change their electrical conductivity significantly when the temperature rises are embedded in an electrically non-conductive or poorly conductive carrier substance and this material is applied in such a way that the resistance coating has a uniform electrical and thermal conductivity.
  • a special form of such a space heating element is e.g. B. a large wall, floor or ceiling panel.
  • contact is made with the electrical resistance coating, in particular through contact elements arranged symmetrically on the electrical resistance layer.
  • contact elements arranged symmetrically on the electrical resistance layer.
  • the invention has set itself the task of designing the electrically conductive resistance coating of the clothing body so that this detachment either no longer occurs directly from the fastening base or from an insulating layer placed over it and furthermore brings about an improvement in the heating properties of the space heating element.
  • the resistance layer in the form of an electrically conductive resistance glaze is covered by a layer of non-conductive or poorly conductive ceramic glaze with a carrier substance of the same ceramic composition as that of the resistance glaze but with built-in kaolin particles and the structure made of ceramic Molded body, electrically conductive ceramic glaze and ceramic cover layer heated to below the quartz transformation point ( ⁇ 750 ° C) and so the resistance layer and cover layer are burned onto the ceramic clothing body.
  • any organic insulating coating adheres to such a coated body of clothing without any problems.
  • an electrical current passage which is uniform over the surface is achieved in that the contacting of the electrical heating layer is carried out in such a way that the contact elements or the contact layer is applied directly to the ceramic shaped body, this layer being ramp-like to the outer edge of the ceramic molded body grows and the ramp height is measured according to the thickness of the heating layer and the ramp width is more than fifty times this thickness.
  • the heating layer thickness was 120 u and the width of the contact layer was 15 mm. Furthermore, this measure reduces the tendency for the contact elements or contact layer to detach.
  • contact layer is applied directly to the back of the ceramic molded body as the first process step, which is followed by the application of the electrical heating layer as the second step.
  • cover layer is applied and the entire structure is then subjected to a firing or heating process in a fourth step.
  • the electrical resistance coating 2 is composed of a carrier substance 5 and conductive particles 4 embedded in this carrier substance.
  • the cover layer 3 is composed of the same carrier substance 5 and kaolin particles 6 embedded therein.
  • FIG. 2 shows a space heating element as described in EP-A-0 158 091, which is constructed from a ceramic molded body 1, an electrical resistance coating 2 and a contact element 7.
  • FIG. 3 shows an embodiment of the space heating element according to the invention comprising an electrical resistance coating 2, a cover layer 3 and a contact element 8.
  • This contact element 8 grows in a ramp shape at 9 towards the outer edge of the ceramic molded body.
  • the contact element which can be formed by a contact layer, is formed in the exemplary embodiment shown with a substantially triangular cross section.
  • the maximum ramp height 10 corresponds to the layer thickness 11 of the electrical resistance coating 2.
  • the width 12 of the contact element is more than fifty times the thickness or thickness 11 of the electrical resistance coating 2. From FIG. 4 it follows that the contact element, on the two opposite Long sides of the space heating element is formed.
  • the space heating element is expediently designed as a large-area wall-floor or ceiling cladding panel, which in particular as a square panel has side dimensions of 60 ⁇ 60 cm.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Resistance Heating (AREA)
  • Surface Heating Bodies (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Saccharide Compounds (AREA)
  • Steroid Compounds (AREA)
  • Central Heating Systems (AREA)

Abstract

A space heating element having a ceramic body, an electrically conductive ceramic glaze provided on the side of the ceramic shaped body opposite the visible side, and a nonconductive ceramic glaze provided over the electrically conductive glaze. The electrically resistive glaze has nonmetallic electrically conductive particles embedded in a carrier substance. The nonconductive glaze has the same carrier substance as the electrically conductive glaze but has kaolin particles embedded therein in place of the nonmetallic electrically conductive particles. The ceramic body, electrically resistive glaze and nonconductive ceramic glaze are heated to a temperature below the quartz transition temperature.

Description

Die Erfindung bezicht sich auf ein Raumheizelement, bestehend aus einem mit einer elektrischen Widerstandsbeschichtung versehenen keramischen Formkörper, insbesondere in form einer keramischen Platte.The invention relates to a space heating element consisting of a ceramic molded body provided with an electrical resistance coating, in particular in the form of a ceramic plate.

Aus der EP-A- 0 158 091 ist ein Raumheizelement bestehend aus einem keramischen Formkörper, der auf der seiner Sichtseite abgewendeten Seite mit einem flächenhaften Heizleiter in Form einer elektrischen Widerstandsbeschichtung aus einer elektrisch leitenden keramischen Glasur versehen ist, bekannt, bei dem die elektrische Widerstandsbeschichtung als Widerstandsschicht aus einem Material ausgebildet ist, bei dem nichtmetallische, große spezifische Oberfläche aufweisende, elektrisch leitende, bei Temperaturerhöhung ihre elektrische Leitfähigkeit nicht wesentlich ändernde Partikel in einer elektrisch nicht oder nur schlecht leitenden Trägersubstanz eingebettet sind und dieses Material so aufgetragen ist, daß die Widerstandsbeschichtung eine gleichmäßige elektrische und thermische Leitfähigkeit aufweist. Eine Spezialform eines solchen Raumheizelementes ist z. B. eine großflächige Wand-, Boden- oder Deckenbekleidungsplatte.From EP-A-0 158 091 a space heating element consisting of a ceramic molded body is known, which is provided on the side facing away from its visible side with a flat heating conductor in the form of an electrical resistance coating made of an electrically conductive ceramic glaze, in which the electrical resistance coating is formed as a resistance layer from a material in which non-metallic, large specific surface area, electrically conductive particles which do not change their electrical conductivity significantly when the temperature rises are embedded in an electrically non-conductive or poorly conductive carrier substance and this material is applied in such a way that the resistance coating has a uniform electrical and thermal conductivity. A special form of such a space heating element is e.g. B. a large wall, floor or ceiling panel.

Unter ungünstigen Bedingungen kann es bei Ausbildung der elektrischen Widerstandsbeschichtung aus einer elektrisch leitenden keramischen Widerstandsglasur vorkommen, daß sich solche Platten von ihrem sie tragenden Untergrund plötzlich ablösen. Damit wird ihre Anbringung an Decken, aber auch an Wänden durch Verkleben problematisch, vielmehr sind zusätzliche Befestigungsmittel, wie Klammern oder Haken erforderlich, was vielfach unmöglich oder wenigstens manchmal nicht erwünscht ist.Under unfavorable conditions, when the electrical resistance coating is formed from an electrically conductive ceramic resistance glaze, it can happen that such plates suddenly detach from their supporting surface. This makes their attachment to ceilings, but also to walls, by gluing problematic, rather additional fasteners, such as clips or hooks are required, which is often impossible or at least sometimes not desirable.

Nach der EU-A- 0 158 091 erfolgt eine Kontaktierung der elektrischen Widerstandsbeschichtung insbesondere durch symmetrisch auf der elektrischen Widerstandsschicht angeordnete Kontaktierungselemente. Es hat sich aber gezeigt, daß solche auf der Heizschicht angebrachte Elemente zum Ablösen neigen, aber auch den über eine Fläche gleichmäßigen elektrischen Stromdurchgang nur unzureichend gewährleisten.According to EU-A-0 158 091, contact is made with the electrical resistance coating, in particular through contact elements arranged symmetrically on the electrical resistance layer. However, it has been shown that such elements attached to the heating layer tend to detach, but also only insufficiently ensure the uniform electrical current passage over a surface.

Das Problem einer unzureichenden Haftung tritt überraschenderweise auch zwischen leitender Widerstandsschicht und einer Isolierschicht auf, über die der Bekleidungskörper am Befestigungsuntergrund befestigt ist.The problem of insufficient adhesion also surprisingly arises between a conductive resistance layer and an insulating layer, by means of which the clothing body is fastened to the fastening base.

Es gibt offenbar bis jetzt noch kein isolierendes Material, insbesondere organisches Isoliermaterial, das mit der leitenden Widerstandsschicht eine dauerhafte und sichere Verbindung eingeht.So far, there is apparently no insulating material, in particular organic insulating material, that forms a permanent and secure connection with the conductive resistance layer.

Die Erfindung hat sich die Aufgabe gestellt, die elektrisch leitende Widerstandsbeschichtung des Bekleidungskörpers so auszugestalten, daß dieses Ablösen entweder unmittelbar vom Befestigungsgrund oder von einer darübergelegten Isolierschicht nicht mehr auftritt und ferner eine Verbesserung der Heizeigenschaften des Raumheizelementes bewirkt wird.The invention has set itself the task of designing the electrically conductive resistance coating of the clothing body so that this detachment either no longer occurs directly from the fastening base or from an insulating layer placed over it and furthermore brings about an improvement in the heating properties of the space heating element.

Diese Aufgabe wird erfindungsgemäß dadurch gelöst, daß die in Form einer elektrisch leitenden Widerstandsglasur vorliegende Widerstandsschicht durch eine Schicht aus nicht leitender oder nur schlecht leitender keramischer Glasur mit einer Trägersubstanz gleicher keramischer Zusammensetzung wie die der Widerstandsglasur aber mit eingebauten Kaolinteilchen abgedeckt ist und das Gebilde aus keramischen Formkörper, elektrisch leitender keramischer Glasur und keramischer Abdeckschicht bis unterhalb des Quarzumwandlungspunktes (<750°C) erhitzt und so Widerstandsschicht und Abdeckschicht auf dem keramischen Bekleidungskörper eingebrannt sind.This object is achieved in that the resistance layer in the form of an electrically conductive resistance glaze is covered by a layer of non-conductive or poorly conductive ceramic glaze with a carrier substance of the same ceramic composition as that of the resistance glaze but with built-in kaolin particles and the structure made of ceramic Molded body, electrically conductive ceramic glaze and ceramic cover layer heated to below the quartz transformation point (<750 ° C) and so the resistance layer and cover layer are burned onto the ceramic clothing body.

Überraschenderweise haftet auf einem solchermaßen beschichteten Bekleidungskörper auch jede organische Isolierbeschichtung ohne Probleme.Surprisingly, any organic insulating coating adheres to such a coated body of clothing without any problems.

Überraschenderweise hat sich ferner herausgestellt, daß sich bei Anwendung der vorgeschlagenen Lösung eine erhebliche Reduzierung des elektrischen Widerstandes der abgedeckten Widerstandsbeschichtung, also der Heizschicht ergibt. Dies erklärt sich daraus, daß bei einem sinnvoll gewählten Überschuß an Kaolinteilchen im Verhältnis zu den Glasanteilen der Trägersubstanz diese beim Brennen des gesamten Gebildes Glasanteile aus der Widerstandsglasur (Heizschicht) lösen und in die Abdeckschicht einbinden. Dadurch wird die isolierende Glassubstanz in der Widerstandsglasur verringert, welche die elektrische Leitung der Widerstandsglasur negativ beeinflußt, wodurch sich der elektrische Widerstand der Widerstandsglasur, d. h. der Heizschicht, verringert. Es ergibt sich mithin eine Verbesserung der Heizeigenschaften des Raumheizelementes infolge der Einbettung von Kaolinteilchen in die Abdeckschicht.Surprisingly, it has also been found that using the proposed solution results in a considerable reduction in the electrical resistance of the covered resistance coating, that is to say the heating layer. This can be explained by the fact that if the excess of kaolin particles is chosen in relation to the glass portions of the carrier substance, they release glass portions from the resistance glaze (heating layer) when the entire structure is fired and bind them into the cover layer. This reduces the insulating glass substance in the resistance glaze, which negatively influences the electrical conduction of the resistance glaze, as a result of which the electrical resistance of the resistance glaze, i. H. the heating layer. There is thus an improvement in the heating properties of the space heating element as a result of the embedding of kaolin particles in the covering layer.

So wurde z. B. bei 30 % Gewichtsanteil Kaolin eine Widerstandserniedrigung von 50 % gegenüber dem des gleichen Gebildes ohne Zufügung einer Abdeckschicht festgestellt.So z. B. at 30% by weight kaolin, a resistance reduction of 50% compared to that of the same structure without adding a cover layer.

Diese Erscheinung hat man sich erfindungsgemäß in der Weise zunutze gemacht, daß man die Menge an Kaolinteilchen der Deckschicht so wählt, daß damit eine bestimmte Leitfähigkeitsänderung erzielt wird, die es wiederum erlaubt, die Menge an elektrisch leitenden Partikeln in der Heizschicht spürbar zu reduzieren, ohne den ursprünglich angestrebten elektrischen Widerstand der Heizschicht, also ohne Abdeckung, zu verändern.This phenomenon has been exploited according to the invention in such a way that the amount of kaolin particles in the cover layer is selected in such a way that a certain change in conductivity is achieved, which in turn allows the amount of electrically conductive particles in the heating layer to be reduced appreciably without to change the originally desired electrical resistance of the heating layer, i.e. without a cover.

Hinsichtlich den auf der Heizschicht angebrachten elektrischen Kontaktierungselementen wird ein über die Fläche gleichmäßiger elektrischer Stromdurchgang dadurch erreicht, daß die Kontaktierung der elektrischen Heizschicht so vorgenommen wird, daß die Kontaktelemente bzw. die Kontaktschicht direkt auf den keramischen Formkörper aufgebracht wird, wobei diese Schicht rampenförmig zur Außenkante des keramischen Formkörpers hin anwächst und sich die Rampenhöhe nach der Stärke der Heizschicht und die Rampenbreite sich mit mehr als dem Fünfzigfachen dieser Stärke bemißt. Bei einem Ausführungsbeispiel betrug die Heizschichtdicke 120 u und die Breite der Kontaktschicht 15 mm. Ferner wird durch diese Maßnahme die Neigung zum Ablösen der Kontaktelemente bzw. Kontaktschicht verringert.With regard to the electrical contacting elements attached to the heating layer, an electrical current passage which is uniform over the surface is achieved in that the contacting of the electrical heating layer is carried out in such a way that the contact elements or the contact layer is applied directly to the ceramic shaped body, this layer being ramp-like to the outer edge of the ceramic molded body grows and the ramp height is measured according to the thickness of the heating layer and the ramp width is more than fifty times this thickness. In one embodiment, the heating layer thickness was 120 u and the width of the contact layer was 15 mm. Furthermore, this measure reduces the tendency for the contact elements or contact layer to detach.

Ein weiterer Vorteil dieser vorgeschlagenen Lösung beruht darin, daß die Anbringung der Kontaktschicht unmittelbar auf die Rückseite des keramischen Formkörpers als erster Verfahrensschritt erfolgt, dem als zweiter Schritt die Aufbringung der elektrischen Heizschicht folgt. Als dritter Schritt wird die Abdeckschicht appliziert und das gesamte Gebilde in einem vierten Schritt dann einem Brenn- oder Erhitzungsprozeß unterworfen.Another advantage of this proposed solution is that the contact layer is applied directly to the back of the ceramic molded body as the first process step, which is followed by the application of the electrical heating layer as the second step. As a third step, the cover layer is applied and the entire structure is then subjected to a firing or heating process in a fourth step.

Nachfolgend werden Ausführungsbeispiele der Erfindung schematisch anhand der Zeichnung beschrieben. Darin zeigen.

Fig. 1
einen schematischen Teilschnitt durch ein Raumheizelement,
Fig. 2
einen Teilschnitt durch ein Raumheizelement nach der EU-A- 0 158 091,
Fig. 3
einen Teilschnitt durch eine weitere Ausführungsform der Erfindung sowie
Fig. 4
eine Draufsicht auf ein Raumheizlement nach Fig. 3.
Exemplary embodiments of the invention are described schematically below with reference to the drawing. Show in it.
Fig. 1
a schematic partial section through a space heating element,
Fig. 2
a partial section through a space heating element according to EU-A- 0 158 091,
Fig. 3
a partial section through a further embodiment the invention as well
Fig. 4
3 shows a plan view of a room heating element according to FIG. 3.

Das in Fig. 1 dargestellte Raumheizelement umfaßt einen keramischen Formkörper 1, der auf seiner der Sichtseite abgewendeten Seite mit einer elektrischen Widerstandsbeschichtung 2, welche die Heizschicht bildet, sowie ferner mit einer Abdeckschicht 3 versehen ist. Die elektrische Widerstandsbeschichtung 2 setzt sich aus einer Trägersubstanz 5 und in dieser Trägersubstanz eingebetteten leitfähigen Partikeln 4 zusammen. Die Abdeckschicht 3 setzt sich aus derselben Trägersubstanz 5 und darin eingebetteten Kaolinteilchen 6 zusammen.1 comprises a ceramic molded body 1, which is provided on its side facing away from the visible side with an electrical resistance coating 2, which forms the heating layer, and also with a cover layer 3. The electrical resistance coating 2 is composed of a carrier substance 5 and conductive particles 4 embedded in this carrier substance. The cover layer 3 is composed of the same carrier substance 5 and kaolin particles 6 embedded therein.

Fig. 2 zeigt ein Raumheizelement, wie es in der EP-A- 0 158 091 beschrieben ist, welches aus einem keramischen Formkörper 1, einer elektrischen Widerstandsbeschichtung 2 und einem Kontaktelement 7 aufgebaut ist.FIG. 2 shows a space heating element as described in EP-A-0 158 091, which is constructed from a ceramic molded body 1, an electrical resistance coating 2 and a contact element 7.

Fig. 3 zeigt eine Ausführungsform des erfindungsgemäßen Raumheizelementes aus einer elektrischen Widerstandsbeschichtung 2, einer Abdeckschicht 3 und einem Kontaktelement 8. Dieses Kontaktelement 8 wächst rampenförmig bei 9 zur Außenkante des keramischen Formkörpers an. Das Kontaktelement, welches durch eine Kontaktschicht gebildet sein kann, ist im dargestellten Ausführungsbeispiel mit im wesentlichen dreieckförmigem Querschnitt ausgebildet. Die maximale Rampenhöhe 10 entspricht der Schichtdicke 11 der elektrischen Widerstandsbeschichtung 2. Die Breite 12 des Kontaktelementes beträgt mehr als das Fünfzigfache der Dicke bzw. der Stärke 11 der elektrischen Widerstandsbeschichtung 2. Aus Fig. 4 ergibt sich, daß das Kontaktelement,an den beiden gegenüberliegenden Längsseiten des Raumheizelementes ausgebildet ist. Das Raumheizelement ist in zweckmäßiger Weise als großflächige Wand-Boden- oder Deckenbekleidungsplatte ausgebildet, welches insbesondere als quadratische Platte Seitenabmessungen von 60 × 60 cm aufweist.3 shows an embodiment of the space heating element according to the invention comprising an electrical resistance coating 2, a cover layer 3 and a contact element 8. This contact element 8 grows in a ramp shape at 9 towards the outer edge of the ceramic molded body. The contact element, which can be formed by a contact layer, is formed in the exemplary embodiment shown with a substantially triangular cross section. The maximum ramp height 10 corresponds to the layer thickness 11 of the electrical resistance coating 2. The width 12 of the contact element is more than fifty times the thickness or thickness 11 of the electrical resistance coating 2. From FIG. 4 it follows that the contact element, on the two opposite Long sides of the space heating element is formed. The space heating element is expediently designed as a large-area wall-floor or ceiling cladding panel, which in particular as a square panel has side dimensions of 60 × 60 cm.

Claims (7)

  1. Space heating element, in particular plate, consisting of a shaped ceramic body, on the face opposing its visual side being provided with an area-adhesive heating conductor in form of an electrical resistance coating from an electrically conducting ceramic glaze, wherein the electrical resistance coating is embodied as resistance layer from a material in which non-metallic, electrically conducting particles having a large specific surface and not essentially changing their electrical conductivity in case of an increase in temperature are embedded into a base material having no or only poor electrical conductivity and said material is applied in such manner that the resistance coating shows uniform electrical and thermal conductivity,
    characterized in that
    said shaped ceramic body being provided with said electrical resistance coating from an electrically conducting ceramic glaze is covered by a layer of non-conductive or only poorly conducting glaze with a base material of ceramic composition identical to that of the resistance glaze but containing incorporated kaolin particles and the structure of shaped ceramic body, electrically conducting ceramic glaze and ceramic covering layer was heated up to below the transformation point of quartz.
  2. Space heating element as defined in claim 1,
    characterized in that
    the amount of incorporated kaolin particles is chosen such that a sensible reduction of the electrical resistance of the resistance glaze will occur.
  3. Space heating element as defined in claim 1,
    characterized in that
    the amount of incorporated kaolin particles is chosen such that because of the reduction caused thereby, of the original electrical resistance of the heating layer the amount of non-metallic electrically conducting particles of the resistance coating can be substantially reduced for obtaining the originally desired electrical resistance.
  4. Space heating element with at least one electrical contact member, for the heating layer,
    characterized in that
    the contact member is directly applied to the ceramic body and that the thickness of said contact member has a ramp-like shape increasing indirection to the outer edge of the shaped ceramic body.
  5. Space heating element as defined in claim 4,
    characterized in that
    the maximum ramp height depends on the thickness of the heating layer and that the width of the ramp amounts to more than 50 times of said thickness.
  6. Space heating element as defined in claim 4 or 5,
    characterized in that
    the contact member has an essentially triangular cross-section.
  7. Space heating element as defined in one of claims 4 to 6,
    characterized in that
    the contact member is formed by a contact layer.
EP88102207A 1987-02-17 1988-02-15 Space heating element consisting of a ceramic body provided with an electrically resistant layer, especially in the form of a ceramic plate Expired - Lifetime EP0280150B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88102207T ATE68655T1 (en) 1987-02-17 1988-02-15 SPACE HEATING ELEMENT, CONSISTING OF A CERAMIC MOLDING WITH AN ELECTRICAL RESISTANCE COATING, PARTICULARLY IN THE FORM OF A CERAMIC PLATE.

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE3705028 1987-02-17
DE3705028 1987-02-17
DE19873710626 DE3710626A1 (en) 1987-02-17 1987-03-31 ROOM HEATING ELEMENT CONSISTING OF A CERAMIC MOLDED BODY WITH AN ELECTRIC RESISTANT COATING, IN PARTICULAR IN THE FORM OF A CERAMIC PLATE
DE3710626 1987-03-31

Publications (2)

Publication Number Publication Date
EP0280150A1 EP0280150A1 (en) 1988-08-31
EP0280150B1 true EP0280150B1 (en) 1991-10-16

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EP88102207A Expired - Lifetime EP0280150B1 (en) 1987-02-17 1988-02-15 Space heating element consisting of a ceramic body provided with an electrically resistant layer, especially in the form of a ceramic plate

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US (1) US4868899A (en)
EP (1) EP0280150B1 (en)
JP (1) JPS63314790A (en)
AT (1) ATE68655T1 (en)
CA (1) CA1298602C (en)
DE (2) DE3710626A1 (en)
DK (1) DK80388A (en)
FI (1) FI880603A (en)
NO (1) NO880679L (en)

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DE3107290A1 (en) * 1980-03-03 1982-01-07 Canon K.K., Tokyo HEATING DEVICE
US4469936A (en) * 1983-04-22 1984-09-04 Johnson Matthey, Inc. Heating element suitable for electric space heaters
DE3433667A1 (en) * 1984-02-29 1985-09-05 Buchtal Gmbh, 8472 Schwarzenfeld Ceramic moulding with electrical resistance coating bonded to back - with uniform electrical and thermal conductivity, useful for heating room, swimming pool etc.
DE3545118A1 (en) * 1985-12-19 1987-06-25 Buchtal Gmbh Flat ceramic body I
DE3545117A1 (en) * 1985-12-19 1987-06-25 Buchtal Gmbh Flat ceramic body II

Also Published As

Publication number Publication date
EP0280150A1 (en) 1988-08-31
ATE68655T1 (en) 1991-11-15
DK80388A (en) 1988-08-18
DE3865454D1 (en) 1991-11-21
JPS63314790A (en) 1988-12-22
FI880603A (en) 1988-08-18
FI880603A0 (en) 1988-02-10
DE3710626A1 (en) 1988-08-25
CA1298602C (en) 1992-04-07
NO880679D0 (en) 1988-02-16
NO880679L (en) 1988-08-18
US4868899A (en) 1989-09-19
DK80388D0 (en) 1988-02-16

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