EP0132034A1 - Container sterilization - Google Patents

Container sterilization Download PDF

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Publication number
EP0132034A1
EP0132034A1 EP84303744A EP84303744A EP0132034A1 EP 0132034 A1 EP0132034 A1 EP 0132034A1 EP 84303744 A EP84303744 A EP 84303744A EP 84303744 A EP84303744 A EP 84303744A EP 0132034 A1 EP0132034 A1 EP 0132034A1
Authority
EP
European Patent Office
Prior art keywords
blank
conveyor means
tubular blank
magazine
sterilant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84303744A
Other languages
German (de)
French (fr)
Other versions
EP0132034B1 (en
Inventor
Frank A. Rodocker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ex-Cell-O Corp
Original Assignee
Ex-Cell-O Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ex-Cell-O Corp filed Critical Ex-Cell-O Corp
Publication of EP0132034A1 publication Critical patent/EP0132034A1/en
Application granted granted Critical
Publication of EP0132034B1 publication Critical patent/EP0132034B1/en
Expired legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B43/00Forming, feeding, opening or setting-up containers or receptacles in association with packaging
    • B65B43/42Feeding or positioning bags, boxes, or cartons in the distended, opened, or set-up state; Feeding preformed rigid containers, e.g. tins, capsules, glass tubes, glasses, to the packaging position; Locating containers or receptacles at the filling position; Supporting containers or receptacles during the filling operation
    • B65B43/50Feeding or positioning bags, boxes, or cartons in the distended, opened, or set-up state; Feeding preformed rigid containers, e.g. tins, capsules, glass tubes, glasses, to the packaging position; Locating containers or receptacles at the filling position; Supporting containers or receptacles during the filling operation using rotary tables or turrets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B55/00Preserving, protecting or purifying packages or package contents in association with packaging
    • B65B55/02Sterilising, e.g. of complete packages
    • B65B55/04Sterilising wrappers or receptacles prior to, or during, packaging
    • B65B55/10Sterilising wrappers or receptacles prior to, or during, packaging by liquids or gases

Definitions

  • This invention relates generally to sterilization techniques and, more specifically, to an improved apparatus and method for sterilizing thermoplastic coated, liquid carrying paperboard containers prior to their being filled with a liquid and sealed.
  • thermoplastic coated, liquid carrying paperboard containers has typically been accomplished on the forming, filling and sealing machine at a location between the station where the bottom formed container is stripped from an indexing mandrel and a station downstream thereof where the container is filled with a liquid, such as milk or juice.
  • a liquid such as milk or juice.
  • One object of the invention is to enable efficient sterilization of paperboard containers, by means and compatible with existing forming, filling and sealing machine, aid further, in conjunction with the indexing sprocket and mandrel assembly currently included on many models of forming, filling and sealing machines.
  • an atomising or nebulizing nozzle on a forming, filling and sealing machine so as to dispense a suitable sterilant in a fog state into and through a tubular,open ended carton blank, just after the blank has been removed in a folded-over flattened state from a magazine and opened in the usual manner, and just prior to and during the time that the tubular blank is being slidably mounted on a mandrel of a forming, filling and sealing machine.
  • Figures 1 - 3 illustrate a sterilization arrangement 10, including a nebulizing nozzle 12 mounted on the frame 14 of a conventional forming, filling and sealing machine, represented as 16.
  • the latter includes a magazine 18, a blank feeder assembly 20, a blank loader assembly 22, and an indexing mandrel assembly or bottom closing mechanism 24 mounted on a drive shaft 26.
  • the assembly 24 includes six equally spaced mandresl 28 extending radially from a hub 30 mounted on the drive shaft 26.
  • Connected to the nebulizing nozzle 12 is a line 32 which leads from a suitable generator 34 connected via lines 36 to a source (not shown) of a suitable sterilizing fluid under pressure.
  • the feeder and loader assemblies 20 and 22 are adapted generally to withdraw blanks successively from the magazine 18, erect them into an open-ended tubular form, and then load them onto respective mandrels 28 of the bottom closing mechanism 24.
  • these mechanisms are driven in synchronism with each other from the main drive of the machine 16.
  • thermoplastic coated paperboard container blank 40 ( Figure 4A) is removed by vacuum pick-up or suction cups 42 (Figure 2) from the magazine 18 ( Figure 1), causing the blank 40 to open into a four-sided tube 44 ( Figure 4B), and deposited upon a small conveyor 46 ( Figure 1).
  • the conveyor 46 moves the tube 44 toward and onto one of the mandrels 28 at a load station A located in the 4:00 o'clock position, as viewed in Figure 1.
  • the nebulizing nozzle 12 is located adjacent the rear end of the tube 44, aligned with the longitudinal axis thereof.
  • the blank feeder assembly 20 ( Figure 2) comprises a pivotally mounted gate member 48 adapted to swing through an angle of about 90 degrees between the two positions shown in Figure 2.
  • a plurality of the vacuum pick-up cups 42 are mounted on the gate member 48, adapted to engage a side panel of the lowermost blank 40 in the magazine 18.
  • Outward movement of the gate member 48 after engagement with a blank causes such blank to commence opening, as shown in Figure 2, and snap past the stop abutments 50.
  • the left-hand lateral edge of the blank is cammed against a fixed arcuate guide 52, opening the blank still further until it reaches its fully opened position at the end of the arcuate travel of the gate member 48, whereupon it is deposited on the small conveyor 46.
  • the blank loader assembly 22 typically comprises an endless chain 54 having an outwardly projecting finger 56 formed thereon.
  • the chain is arranged to move the finger through a stroke generally parallel to the side walls of the squared blank 44. In the course of such movement, the finger engages the rear outer edge of a bottom closure panel.
  • the vacuum cups 42 on the gate member 48 release the blank and the latter is urged along fixed guides (not shown) until it telescopes over an aligned mandrel 28 of the indexing mandrel assembly 24.
  • the mandrel assembly 24 indexes from the load station A to a bottom panel pre-breaker station B in the 2:00 o'clock position, prior to indexing to a bottom panel heat station C in the 12:00 o'clock position.
  • the next index is to the bottom panel tuck and pressure station D at.10:00 o'clock, followed by transfer to a station E which may be used as a second pressure station at 8:00 o'clock, and finally indexing to a discharge or stripper station F at 6:00 o'clock as a bottom-sealed container 58 ( Figure 2C).
  • the stripping of the bottom-sealed container 58 from each successive mandrel 28 is effected by a reciprocally actuated mechanical stripper 60 having a rubber vacuum cup 62 mounted on the end thereof for engagement with the closed and sealed bottom of the container 58.
  • the container 58 is pulled downwardly by the mechanical stripper 60 from the mandrel 28 at station F and deposited on a suitable conveyor, represented at 64 in Figure 1.
  • the open-topped container 58 is thereafter acted upon at a top pre-breaker station G, such pre-breaking serving to facilitate the subsequent folding and sealing of the top closure.
  • the container 58 is next conveyed to a filling station H where a measured volume of a product, such as juice, is dispensed into the open end of the container.
  • the container 58 is then caused to encounter a top partial folding or tucking station I, prior to indexing to a heating station J which heats the thermoplastic top closure panels just prior to transfer of the container to a sealing station K where the top closure panels are brought together with a combined pressure and cooling action to become tightly sealed into a completed gable top container 66, prior to delivery to a discharge station L.
  • the axially aligned nebulizing nozzle 12 serves to dispense a sterilant fog into the tube, substantially along the entire inside surfaces of the four sides thereof.
  • the fog strikes the bottom of the mandrel 28 and bounces or swirls back into the tube 44 to further settle onto the four interior wall surfaces.
  • the heat therefrom is believed to enhance the action of a sterilant, such as chlorine dioxide, within the tube 44.
  • the above-described sterilisation apparatus provides an improved means for initiating the sterilization of carton blanks once formed into a tube, prior to being formed into bottom-sealed containers, rather than after the bottom forming operation at a remote station along a forming, filling and sealing machine, thereby substantially increasing the sterilizing time allotted to each carton.
  • Such sterilization apparatus serves to intermittently distribute the chlorine dioxide or hydrogen peroxide fog throughout any machine enclosure (not shown) in which the indexing mandrel assembly 24 is mounted while the tubular blank 44 is being mounted on a mandrel 28. This feature thus serves to continuously sterilize the complete mandrel assembly 24 all the while that it is operational.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Making Paper Articles (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Supplying Of Containers To The Packaging Station (AREA)
  • Closing Of Containers (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)

Abstract

Apparatus and method for sterilizing the interiors of paperboard containers 58, wherein such apparatus and method are operative prior to the container being mounted on a mandrel assembly 24 on which the container bottom closures are formed, closed and sealed. This is accomplished by providing nebulizing means 12 for communicating a suitable sterilant fog through and onto the inside surfaces of the carbon blank 40 immediately after it has been removed from a magazine 18 and opened into a four-sided tubular 44 shape, thereby greatly increasing the total interior sterilizing time available prior to the container being filled, as compared to conventional sterilization processes which are operative after the bottom panels of the carton have been closed and sealed.

Description

  • This invention relates generally to sterilization techniques and, more specifically, to an improved apparatus and method for sterilizing thermoplastic coated, liquid carrying paperboard containers prior to their being filled with a liquid and sealed.
  • It is desirable from a marketing standpoint to increase the storage or shelf life of various comestible products. This is accomplished by employing a sterilization process in conjunction with the forming, filling and sealing operations. Heretofore, sterilization of thermoplastic coated, liquid carrying paperboard containers has typically been accomplished on the forming, filling and sealing machine at a location between the station where the bottom formed container is stripped from an indexing mandrel and a station downstream thereof where the container is filled with a liquid, such as milk or juice. Such an arrangement is shown and described in U.S. Patent specification No. 3,566,575.
  • It is also known to use a sterilization apparatus and process wherein a channel is formed through the length of each mandrel of a typical indexing sprocket and mandrel assembly, with the channel communicating with openings and compartments formed in the hub of the indexing sprocket and mandrel assembly, such that as each mandrel reaches the 6:00 position, there is communication with a line leading from a generator which is capable of continuously producing a chlorine dioxide or hydrogen peroxide fog, thereby conveying such fog through the compartment and respective channels to the interior of each container as the latter is being mechanically stripped from the mandrel upon which it is slidably mounted. Such an arrangement is shown and described in U.S. Patent application No. 369,940.
  • One object of the invention is to enable efficient sterilization of paperboard containers, by means and compatible with existing forming, filling and sealing machine, aid further, in conjunction with the indexing sprocket and mandrel assembly currently included on many models of forming, filling and sealing machines.
  • In accordance with the present invention we propose providing an atomising or nebulizing nozzle on a forming, filling and sealing machine so as to dispense a suitable sterilant in a fog state into and through a tubular,open ended carton blank, just after the blank has been removed in a folded-over flattened state from a magazine and opened in the usual manner, and just prior to and during the time that the tubular blank is being slidably mounted on a mandrel of a forming, filling and sealing machine.
  • An embodiment of the present invention will now be described by way of example with reference to the accompanying drawings.
    • Figure 1 is a fragmentary side elevational view of a forming, filling and sealing machine embodying the invention;
    • Figure 2 is an enlarged, fragmentary cross-sectional view taken along line 2- 2 in Figure 1;
    • Figure 3 is a perspective schematic view illustrating typical operations performed on a container as it travels through a forming, filling and sealing machine;
    • Figure 4A shows a typical folded-over, flattened and side seamed container blank suitable for being loaded into the magazine of a forming, filling and sealing machine;
    • Figure 4B is a perspective view of the container blank shown in Figure 4a in open-ended, tubular form as it appears prior to and while being mounted on a mandrel at Station A in Figure 3;
    • Figure 4c is a perspective view of the container after the bottom closure panels have been sealed at station D in Figure 3; and
    • Figure 4D is a perspective view of a filled and sealed container after passing through to the discharge station of the machine, represented as L in Figure 3.
  • Referring now to the drawings in greater detail, Figures 1 - 3 illustrate a sterilization arrangement 10, including a nebulizing nozzle 12 mounted on the frame 14 of a conventional forming, filling and sealing machine, represented as 16. The latter includes a magazine 18, a blank feeder assembly 20, a blank loader assembly 22, and an indexing mandrel assembly or bottom closing mechanism 24 mounted on a drive shaft 26. The assembly 24 includes six equally spaced mandresl 28 extending radially from a hub 30 mounted on the drive shaft 26. Connected to the nebulizing nozzle 12 is a line 32 which leads from a suitable generator 34 connected via lines 36 to a source (not shown) of a suitable sterilizing fluid under pressure.
  • The feeder and loader assemblies 20 and 22 are adapted generally to withdraw blanks successively from the magazine 18, erect them into an open-ended tubular form, and then load them onto respective mandrels 28 of the bottom closing mechanism 24. For such purpose, these mechanisms are driven in synchronism with each other from the main drive of the machine 16.
  • Conventionally, a thermoplastic coated paperboard container blank 40 (Figure 4A) is removed by vacuum pick-up or suction cups 42 (Figure 2) from the magazine 18 (Figure 1), causing the blank 40 to open into a four-sided tube 44 (Figure 4B), and deposited upon a small conveyor 46 (Figure 1). The conveyor 46 moves the tube 44 toward and onto one of the mandrels 28 at a load station A located in the 4:00 o'clock position, as viewed in Figure 1. The nebulizing nozzle 12 is located adjacent the rear end of the tube 44, aligned with the longitudinal axis thereof.
  • Typically, the blank feeder assembly 20 (Figure 2) comprises a pivotally mounted gate member 48 adapted to swing through an angle of about 90 degrees between the two positions shown in Figure 2. A plurality of the vacuum pick-up cups 42 are mounted on the gate member 48, adapted to engage a side panel of the lowermost blank 40 in the magazine 18. Outward movement of the gate member 48 after engagement with a blank causes such blank to commence opening, as shown in Figure 2, and snap past the stop abutments 50. With further outward movement of the gate, the left-hand lateral edge of the blank is cammed against a fixed arcuate guide 52, opening the blank still further until it reaches its fully opened position at the end of the arcuate travel of the gate member 48, whereupon it is deposited on the small conveyor 46.
  • The blank loader assembly 22 typically comprises an endless chain 54 having an outwardly projecting finger 56 formed thereon. The chain is arranged to move the finger through a stroke generally parallel to the side walls of the squared blank 44. In the course of such movement, the finger engages the rear outer edge of a bottom closure panel. When this occurs, the vacuum cups 42 on the gate member 48 release the blank and the latter is urged along fixed guides (not shown) until it telescopes over an aligned mandrel 28 of the indexing mandrel assembly 24.
  • Once loaded, the mandrel assembly 24 indexes from the load station A to a bottom panel pre-breaker station B in the 2:00 o'clock position, prior to indexing to a bottom panel heat station C in the 12:00 o'clock position. The next index is to the bottom panel tuck and pressure station D at.10:00 o'clock, followed by transfer to a station E which may be used as a second pressure station at 8:00 o'clock, and finally indexing to a discharge or stripper station F at 6:00 o'clock as a bottom-sealed container 58 (Figure 2C). The stripping of the bottom-sealed container 58 from each successive mandrel 28 is effected by a reciprocally actuated mechanical stripper 60 having a rubber vacuum cup 62 mounted on the end thereof for engagement with the closed and sealed bottom of the container 58.
  • In general, once the sealing of the bottom closure is completed, the container 58 is pulled downwardly by the mechanical stripper 60 from the mandrel 28 at station F and deposited on a suitable conveyor, represented at 64 in Figure 1. The open-topped container 58 is thereafter acted upon at a top pre-breaker station G, such pre-breaking serving to facilitate the subsequent folding and sealing of the top closure. The container 58 is next conveyed to a filling station H where a measured volume of a product, such as juice, is dispensed into the open end of the container. The container 58 is then caused to encounter a top partial folding or tucking station I, prior to indexing to a heating station J which heats the thermoplastic top closure panels just prior to transfer of the container to a sealing station K where the top closure panels are brought together with a combined pressure and cooling action to become tightly sealed into a completed gable top container 66, prior to delivery to a discharge station L.
  • After each blank 40 is removed from the magazine 18 and opened into the tubular blank 44 form, as it is being conveyed by the small conveyor 64 toward the mandrel 28, the axially aligned nebulizing nozzle 12 serves to dispense a sterilant fog into the tube, substantially along the entire inside surfaces of the four sides thereof. Secondarily, the fog strikes the bottom of the mandrel 28 and bounces or swirls back into the tube 44 to further settle onto the four interior wall surfaces. At the bottom panel heat station C, the heat therefrom is believed to enhance the action of a sterilant, such as chlorine dioxide, within the tube 44.
  • In the event that hydrogen peroxide is used as the sterilizing agent, it may be necessary to include a drying or heating unit (not shown) between stations G and H, which would serve to remove the hydrogen peroxide residue from inside the container prior to the filling of the container with the desired product at station H.
  • The above-described sterilisation
    apparatus provides an improved means for initiating the sterilization of carton blanks once formed into a tube, prior to being formed into bottom-sealed containers, rather than after the bottom forming operation at a remote station along a forming, filling and sealing machine, thereby substantially increasing the sterilizing time allotted to each carton.
  • Such sterilization apparatus serves to intermittently distribute the chlorine dioxide or hydrogen peroxide fog throughout any machine enclosure (not shown) in which the indexing mandrel assembly 24 is mounted while the tubular blank 44 is being mounted on a mandrel 28. This feature thus serves to continuously sterilize the complete mandrel assembly 24 all the while that it is operational.

Claims (3)

1. Sterilization apparatus for four-sided paperboard container blanks stored in a magazine of a forming. filling and sealing machine in a folded-over, flattened state with their free edges sealed together, the machine including an indexing mandrel assembly; suction means for removing the folded-over, flattened blanks one-at- a-time from the magazine; opening each of the blanks into a four-sided, open-ended tubular blank; and placing such tubular blank on conveyor means; the apparatus comprising a source of sterilant under pressure; a generator for receiving and dispensing the sterilant in a fog state; and a fixed nebulizing nozzle operatively connected to the generator and mounted on the machine so as to be axially aligned with each respective tubular blank on the conveyor means for dispensing the sterilant fog into the tubular blank through the adjacent open end thereof just prior to and concurrent with the tubular blank being mounted on an axially aligned mandrel of the indexing mandrel assembly by the conveyor means.
2. A method for producing a sterilized paperboard container to be filled with a liquid, in which a folded-over, flattened four-sided blank with its free edges sealed together is pulled by suction means from the bottom of a stack of blanks in a magazine on a forming, filling and sealing machine; opened into an open-ended tubular blank; and placed on conveyor means for being conveyed toward and onto a mandrel of an indexing sprocket assembly, characterized by drawing a sterilant from a source under pressure into a nebulizing nozzle, and dispensing the sterilant in a fog state via the nozzle into the rear open end of the tubular blank while the blank is being conveyed by the conveyor means towards and onto the mandrel.
3. On a forming, filling and sealing machine including a magazine for holding flattened, four-sided paperboard container blanks having their free cut edges sealed together, an indexing mandrel assembly including a plurality of radially extending, equally spaced mandrels, means for closing and sealing one end of each tubular blank mounted on respective mandrels, conveyor means operative intermediate the magazine and the respective mandrels, and suction and opening means for pulling each flattened blank from the magazine, opening such flattened blank into a tubular blank, and placing each tubular blank on the conveyor means; a method for sterilizing each tubular blank while being conveyed by the conveyor means towards and onto the respective mandrels, the method comprising the following steps:
a) mounting a nebulizing nozzle on the machine below the magazine and behind the conveyor means, with the axis of the nozzle aligned with the axis of each tubular blank while the latter is being conveyed by the conveyor means;
b) connecting the nozzle to a source of sterilant under pressure and cooperating generating means for dispensing the sterilant in a fog state; and
c) dispensing the sterilant in a fog state by the nozzle into each of the tubular blanks and onto the interior surfaces thereof all the while each such blank is being conveyed by the conveyor means towards and onto each respective mandrel.
EP84303744A 1983-07-15 1984-06-04 Container sterilization Expired EP0132034B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US51437383A 1983-07-15 1983-07-15
US514373 1983-07-15

Publications (2)

Publication Number Publication Date
EP0132034A1 true EP0132034A1 (en) 1985-01-23
EP0132034B1 EP0132034B1 (en) 1987-01-07

Family

ID=24046870

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84303744A Expired EP0132034B1 (en) 1983-07-15 1984-06-04 Container sterilization

Country Status (14)

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EP (1) EP0132034B1 (en)
JP (1) JPS6036056A (en)
AU (1) AU564499B2 (en)
BR (1) BR8403508A (en)
CA (1) CA1232188A (en)
CH (1) CH665398A5 (en)
DE (1) DE3461908D1 (en)
DK (1) DK157482C (en)
ES (1) ES534283A0 (en)
FI (1) FI75316C (en)
IN (1) IN159815B (en)
NO (1) NO159648C (en)
PT (1) PT78893B (en)
ZA (1) ZA844351B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0232998A1 (en) * 1986-02-13 1987-08-19 Ex-Cell-O Corporation Container sterilization apparatus and method
WO2018149562A1 (en) * 2017-02-14 2018-08-23 Sig Technology Ag Packaging machine and method for operating a packaging machine

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4039040C2 (en) * 1990-12-07 2000-03-23 Merz Verpackungsmaschinen Gmbh Method and device for disinfecting the inside of film tubes
DE102007033197B4 (en) * 2007-07-17 2015-11-05 Jürgen Löhrke GmbH disinfection procedures

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3723060A (en) * 1968-02-26 1973-03-27 Ex Cell O Corp Aseptic packaging machine

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3723060A (en) * 1968-02-26 1973-03-27 Ex Cell O Corp Aseptic packaging machine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0232998A1 (en) * 1986-02-13 1987-08-19 Ex-Cell-O Corporation Container sterilization apparatus and method
WO2018149562A1 (en) * 2017-02-14 2018-08-23 Sig Technology Ag Packaging machine and method for operating a packaging machine

Also Published As

Publication number Publication date
ES8506528A1 (en) 1985-08-01
FI75316B (en) 1988-02-29
FI75316C (en) 1988-06-09
PT78893B (en) 1986-06-05
AU2905484A (en) 1985-01-17
PT78893A (en) 1984-08-01
ZA844351B (en) 1985-02-27
NO159648C (en) 1989-01-25
CH665398A5 (en) 1988-05-13
DK332984D0 (en) 1984-07-06
EP0132034B1 (en) 1987-01-07
DK157482B (en) 1990-01-15
AU564499B2 (en) 1987-08-13
DE3461908D1 (en) 1987-02-12
ES534283A0 (en) 1985-08-01
FI842763A (en) 1985-01-16
NO159648B (en) 1988-10-17
FI842763A0 (en) 1984-07-10
DK157482C (en) 1990-06-11
NO842872L (en) 1985-01-16
IN159815B (en) 1987-06-06
BR8403508A (en) 1985-06-25
DK332984A (en) 1985-01-16
JPS6036056A (en) 1985-02-25
CA1232188A (en) 1988-02-02

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