EP0101388B1 - Continuous process for the manufacture of decorated plastic floor or wall coverings and device for carrying out the process - Google Patents

Continuous process for the manufacture of decorated plastic floor or wall coverings and device for carrying out the process Download PDF

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Publication number
EP0101388B1
EP0101388B1 EP83420102A EP83420102A EP0101388B1 EP 0101388 B1 EP0101388 B1 EP 0101388B1 EP 83420102 A EP83420102 A EP 83420102A EP 83420102 A EP83420102 A EP 83420102A EP 0101388 B1 EP0101388 B1 EP 0101388B1
Authority
EP
European Patent Office
Prior art keywords
plastisol
support
process according
transfer
decorated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP83420102A
Other languages
German (de)
French (fr)
Other versions
EP0101388A2 (en
EP0101388A3 (en
Inventor
Daniel Berenger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gerland SA
Original Assignee
Gerland SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gerland SA filed Critical Gerland SA
Priority to AT83420102T priority Critical patent/ATE19270T1/en
Publication of EP0101388A2 publication Critical patent/EP0101388A2/en
Publication of EP0101388A3 publication Critical patent/EP0101388A3/en
Application granted granted Critical
Publication of EP0101388B1 publication Critical patent/EP0101388B1/en
Expired legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0002—Wallpaper or wall covering on textile basis
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/08—Inorganic fibres
    • D06N2201/082—Glass fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/042—Polyolefin (co)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/065—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/066—Silicon polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/02—Dispersion
    • D06N2205/026—Plastisol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles

Definitions

  • the present invention relates to a continuous process for obtaining decorated plastic coverings for floors or walls and the installation provided for the implementation of this process.
  • polyvinyl chloride sheets possibly comprising a frame such as a glass fiber mast, a grid, etc. intended to receive an impression are commonly manufactured by coating, that is to say by application, using a conventional material (doctor blade, reverse-roll coater, curtain machine, etc.) of a vinyl composition polyvinyl chloride liquid supplemented with plasticizers and various additives.
  • This coating must then be solidified hot, generally between 150 and 180 ° C, so as to ensure its gelation.
  • This gelling operation can be carried out in an oven; it is also advantageously in contact with a perfectly polished cylinder heated to the necessary temperatures, which makes it possible to achieve, at the same time as the gelation, a perfect surface condition of the plastic layer obtained.
  • These gelification cylinders or drums are commonly used in the industry of plastic floor or wall coverings, and vinyl coating in general.
  • PVC polyvinyl chloride
  • Direct printing on a non-gelled plastic support can indeed pose a certain number of problems due, in particular, to the dimensional instability of said support resulting in deformations of the design.
  • the paper used for this purpose is treated, before printing, using compositions specially developed so that the inks normally used for printing polyvinyl chloride (generally based on copolymers of acetate and polyvinyl chloride ) adhere to it only weakly and can be completely transferred hot on the plastic support to be decorated.
  • polyvinyl chloride generally based on copolymers of acetate and polyvinyl chloride
  • the actual transfer operation is usually done at a temperature between 100 ° and 180 ° C and under low pressure, the printed side of the paper and the side to be decorated with the plastic support are kept in contact for a very short time, but however sufficient to transfer the printing from paper to plastic support.
  • This operation is carried out on any equipment ensuring intimate contact at the necessary temperatures between the printed paper and the plastic support, for example on glazing machines, doublers, or doubling machines used in the plastics and rubber industry. , such as those designated commercially under the brands of: Auma, Rotodorn, Rotocure, etc.
  • the speed at which the transfer takes place is relatively high and is between 20 and 50 m / min. After moderate cooling (up to 50-80 ° C for example) the paper is separated from the plastic support onto which the printed design has been transferred.
  • the object of the present invention is to propose a continuous process for obtaining decorated plastic coatings which is applicable, under economic conditions, to low films and does not require significant investment.
  • the paper used to carry out the transfer printing is advantageously provided, before its own printing, with a film-forming layer based on products capable of facilitating the subsequent transfer of said printing.
  • zein carboxymethylcelluloses
  • silicones and synthetic resins such as polyethylene, polypropylene and polyamide.
  • the support serving as a reinforcement for the decorated floor or wall covering consists of a veil of fibers such as glass fibers, previously impregnated with a layer of plastisol and then gelled. There is thus a perfectly flat surface making it possible to obtain, once the simultaneous gelling and transfer printing operation of this support coated with a new layer of liquid plastisol has been carried out, a coating having no appearance irregularity. .
  • the installation used for implementing the method according to the invention essentially comprises a first plastisol storage station, means for feeding a veil of glass fibers to a first means of applying plastisol to said veil, means for gelling the veil coated with plastisol, a second plastisol storage station, means for supplying the coated and gelled veil constituting the support for a second means for applying plastisol, a storage and unrolling station for a sheet of transfer paper previously impregnated, means making it possible to bring the coated face of the support and the new layer of plastisol into contact with the printed face of the transfer paper, means making it possible to simultaneously ensure the transfer of the dye from the paper to the support coated with liquid plastisol and the gelling of this plastisol, means for separating the gelled support decorated with the sheet of transfer paper, a storage and winding station for the fe uille of transfer paper devoid of its printing and of the means allowing the storage of the gelled and decorated support, possibly preceded by additional finishing means of
  • (1) represents the support to be printed, (2) the plastisol, (3) the printed transfer paper and (4) the finished product, printed and gelled.
  • the viscosity of the plastisol is adjusted to 2500 mPa - 2,500 centipoise) by the addition of 1 to 2% of dodecylbenzene.
  • This coating can be applied to the doctor blade, as shown in the drawing, or using the so-called “reverse roll” device .
  • the support (1) coated with this liquid plastisol (2) is then brought into contact with the cylinder gelling agent (11) at the same time as the printed transfer paper (3) coming from the roll (10), the printed side of the paper (3) being against the coated side of the support (1).
  • the viscosity was adjusted with methyl ethyl ketone to obtain, when in use, an ink of 30 mPa - s (15 seconds (FORD cut number 4).
  • Certain inks contain an expansion inhibitor making it possible to obtain relief drawings, such as trimellitic anhydride or benzotriazole at a dose ranging from 2.5 to 10%, depending on the relief of the drawing.
  • the gel cylinder (11) is brought to a temperature which can be between 130 and 190 ° C and which, in the case of a line running at 20 m / minute, is around 170 ° C.
  • the printed transfer paper (3) and the impregnated glass veil (1) and coated with the inflatable plastisol (2) are pressed together against the hot cylinder (1) and remain in intimate contact over a large part of the circumference of the latter.
  • the complex is cooled (2-3), then the paper which is no longer printed is separated and is taken up on the roller (12). You can optionally reprint it again for a subsequent operation.
  • the impression applied to the paper is then transferred to the layer of inflatable plastisol (2) applied to the support (1) and a coated and printed coating (4) is obtained.
  • the support (4) thus coated then passes into an oven at 200-210 ° C. At this temperature the blowing agent decomposes to give a chemical foam, except where the printing ink contained the inhibitor.
  • the surface is gelled.
  • This plastisol is mechanically foamed by incorporating dry air into a mechanical beater of the MONDOMIX type (registered trademark). 300 g / m 2 of mechanical foam with a fresh density of 500 g per liter are applied using a doctor blade. It is gelled in an oven at 175 ° C. The gelled and decorated coating (4) is rolled up at (13).
  • the viscosity of the plastisol is adjusted with white spirit to 5,000 mPa - s (5,000 centipoise). 400 g / m 2 are applied using a doctor blade .
  • micronized amorphous silica of the type sold by the company GRACE under the brand Siloid is added to this composition. This will give a matt surface varnish.
  • an expansion inhibitor such as trimellitic anhydride at a dose of 5% for a medium relief and 10% for a more marked relief.
  • the printing and the surface varnish are simultaneously transferred and the inflatable plastisol is pre-gelated by passing the support (1) coated with plastisol (2) and paper (3) over the gel cylinder (11) .
  • the transfer paper is then removed and the inflatable plastisol (2) is expanded in an oven brought to 200-220 ° C (not shown).
  • the support (1) thus coated with plastisol (2) is pressed at the same time as the printed transfer paper (3) against the cylinder (11) brought to 180 ° C.
  • This plastisol is deaerated under vacuum, it is applied with a reverse-roll, it is gelled in an oven at 210 ° C. and a mechanical embossing is optionally carried out, allowing a certain relief to be imparted to the surface of the coating before being stored on the roller ( 12).

Landscapes

  • Textile Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Printing Methods (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Finishing Walls (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
  • Panels For Use In Building Construction (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Paints Or Removers (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
  • Seasonings (AREA)
  • Revetment (AREA)

Abstract

Floor and wall coverings having a pattern are made by coating a plastisol onto a sheet support, and simultaneously with a thermal activation of the plastisol to gelify it, bringing a transferable pattern on a paper layer into contact with the plastisol.

Description

La présente invention concerne un procédé continu d'obtention de revêtements plastiques décorés pour sols ou murs et l'installation prévue pour la mise en oeuvre de ce procédé.The present invention relates to a continuous process for obtaining decorated plastic coverings for floors or walls and the installation provided for the implementation of this process.

On sait que les feuilles de polychlorure de vinyle, comportant éventuellement une armature telle qu'un mât de fibres de verre, une grille, etc. destinées à recevoir une impression sont couramment fabriquées par enduction, c'est-à-dire par application, à l'aide d'un matériel classique (racle, reverse-roll coater, machine à rideau, etc.) d'une composition vinylique liquide à base de polychlorure de vinyle additionné de plastifiants et de divers additifs. Cette enduction doit ensuite être solidifiée à chaud, généralement entre 150 et 180 °C, de façon à assurer sa gélification. Cette opération de gélification peut être effectuée dans un four ; elle l'est aussi avantageusement au contact d'un cylindre parfaitement poli chauffé aux températures nécessaires, ce qui permet de réaliser, en même temps que la gélification, un parfait état de surface de la couche plastique obtenue. Ces cylindres ou tambours de gélification sont couramment utilisés dans l'industrie des revêtements de sol ou de mur plastiques, et de l'enduction vinylique en général.It is known that polyvinyl chloride sheets, possibly comprising a frame such as a glass fiber mast, a grid, etc. intended to receive an impression are commonly manufactured by coating, that is to say by application, using a conventional material (doctor blade, reverse-roll coater, curtain machine, etc.) of a vinyl composition polyvinyl chloride liquid supplemented with plasticizers and various additives. This coating must then be solidified hot, generally between 150 and 180 ° C, so as to ensure its gelation. This gelling operation can be carried out in an oven; it is also advantageously in contact with a perfectly polished cylinder heated to the necessary temperatures, which makes it possible to achieve, at the same time as the gelation, a perfect surface condition of the plastic layer obtained. These gelification cylinders or drums are commonly used in the industry of plastic floor or wall coverings, and vinyl coating in general.

Un grand nombre de ces produits plastiques à base de polychlorure de vinyle (PVC) enduits ou calandrés, tels que nappes, stores, rideaux, bâches, revêtements de sols, revêtements de mur, etc. comportent un décor apporté par une impression en plusieurs couleurs. Cette impression peut être réalisée par différentes techniques : héliographie, offset, sérigraphie (à plat ou au cadre rotatif), flexographie, etc. et elle est en général appliquée après gélification du support plastique à décorer.A large number of these coated or calendered polyvinyl chloride (PVC) plastic products, such as tablecloths, blinds, curtains, tarpaulins, floor coverings, wall coverings, etc. have a decor provided by printing in several colors. This printing can be done by different techniques: heliography, offset, screen printing (flat or rotary frame), flexography, etc. and it is generally applied after gelation of the plastic support to be decorated.

L'impression directe sur un support plastique non gélifié peut en effet poser un certain nombre de problèmes en raison, notamment, de l'instabilité dimensionnelle dudit support entraînant des déformations du dessin.Direct printing on a non-gelled plastic support can indeed pose a certain number of problems due, in particular, to the dimensional instability of said support resulting in deformations of the design.

Il est bien entendu possible d'intégrer, à la-suite du dispositif de gélification du support plastique, une unité d'impression, afin de fabriquer de façon continue les revêtements décorés. Toutefois, et en raison non seulement de l'investissement élevé que présente une machine à imprimer mais aussi du coût important de gravure ou préparation des cadres ou matrices nécessaires à l'obtention de chaque couleur du dessin à réaliser, cette intégration ne se justifie économiquement que pour l'obtention de métrages importants pour un même dessin.It is of course possible to integrate, following the gelling device of the plastic support, a printing unit, in order to continuously manufacture the decorated coatings. However, and due not only to the high investment presented by a printing machine but also to the significant cost of engraving or preparing the frames or dies necessary to obtain each color of the design to be produced, this integration is not justified economically. than for obtaining important footage for the same drawing.

Il faut enfin noter que l'utilisation d'unités d'impression classiques pour l'échantillonnage des dessins, que ces unités soient ou non intégrées dans une ligne continue de fabrication, aggrave le prix de revient de l'impression, en raison notamment du coût élevé de certains supports plastiques.Finally, it should be noted that the use of conventional printing units for sampling designs, whether or not these units are integrated into a continuous production line, increases the cost of printing, in particular because of the high cost of certain plastic supports.

On s'est vite rendu compte de tout l'intérêt présenté par le procédé d'impression par transfert selon lequel le dessin à réaliser est tout d'abord imprimé sur un papier de faible coût avant d'être transféré, comme par décalcomanie, sur le support plastique.We quickly realized all the interest presented by the transfer printing process according to which the drawing to be produced is firstly printed on a low cost paper before being transferred, as by decal, on the plastic support.

Le papier utilisé dans ce but est traité, avant impression, à l'aide de compositions spécialement mises au point pour que les encres normalement utilisées pour l'impression du chlorure de polyvinyle (généralement à base de copolymères d'acétate et de chlorure de polyvinyle) n'y adhèrent que faiblement et puissent être totalement transférées à chaud sur le support plastique à décorer.The paper used for this purpose is treated, before printing, using compositions specially developed so that the inks normally used for printing polyvinyl chloride (generally based on copolymers of acetate and polyvinyl chloride ) adhere to it only weakly and can be completely transferred hot on the plastic support to be decorated.

L'opération même de transfert se fait habituellement à une température comprise entre 100° et 180 °C et sous une faible pression, la face imprimée du papier et la face à décorer du support plastique sont maintenues en contact pendant un temps très court mais toutefois suffisant pour réaliser le transfert de l'impression du papier au support plastique.The actual transfer operation is usually done at a temperature between 100 ° and 180 ° C and under low pressure, the printed side of the paper and the side to be decorated with the plastic support are kept in contact for a very short time, but however sufficient to transfer the printing from paper to plastic support.

Cette opération se fait sur tout équipement permettant d'assurer un contact intime aux températures nécessaires entre le papier imprimé et le support plastique, par exemple sur des glaceuses, des doubleuses, ou des machines de doublage utilisées dans l'industrie des plastiques et du caoutchouc, telles que celles désignées commercialement sous les marques de : Auma, Rotodorn, Rotocure, etc. La vitesse à laquelle s'effectue le transfert est relativement élevée et se situe entre 20 et 50 m/min. Après un refroidissement modéré (jusqu'à 50-80 °C par exempte) te papier est séparé du support plastique sur lequel a été transféré le dessin imprimé.This operation is carried out on any equipment ensuring intimate contact at the necessary temperatures between the printed paper and the plastic support, for example on glazing machines, doublers, or doubling machines used in the plastics and rubber industry. , such as those designated commercially under the brands of: Auma, Rotodorn, Rotocure, etc. The speed at which the transfer takes place is relatively high and is between 20 and 50 m / min. After moderate cooling (up to 50-80 ° C for example) the paper is separated from the plastic support onto which the printed design has been transferred.

La présente invention s'est donné pour but de proposer un procédé continu d'obtention de revêtements plastiques décorés qui soit applicable, dans des conditions économiques, à de faibles métrages et ne nécessite pas d'investissements importants.The object of the present invention is to propose a continuous process for obtaining decorated plastic coatings which is applicable, under economic conditions, to low films and does not require significant investment.

C'est ainsi qu'elle a pour objet un procédé continu d'obtention de revêtements plastiques décorés, notamment pour sols et murs, et dont l'originalité consiste en ce que l'étape d'enduction, à l'aide de plastisol liquide, du support servant d'armature aux dits revêtements est immédiatement suivie d'une étape d'impression par transfert au cours de laquelle la face imprimée du papier transfert est mise au contact de la couche de plastisol liquide et en ce que l'ensemble ainsi constitué est soumis à l'action simultanée de la chaleur et de la pression afin d'assurer en une seule opération le transfert du dessin et la prégélification du plastisol.Thus it has for its object a continuous process for obtaining decorated plastic coatings, in particular for floors and walls, and whose originality consists in that the coating step, using liquid plastisol , the support serving as a framework for said coatings is immediately followed by a transfer printing step during which the printed face of the transfer paper is brought into contact with the layer of liquid plastisol and in that the assembly thus constituted is subjected to the simultaneous action of heat and pressure in order to ensure in a single operation the transfer of the design and the pre-gelation of the plastisol.

Le papier servant à réaliser l'impression transfert est avantageusement muni, avant sa propre impression, d'une couche filmogène à base de produits aptes à faciliter le transfert ultérieur de ladite impression.The paper used to carry out the transfer printing is advantageously provided, before its own printing, with a film-forming layer based on products capable of facilitating the subsequent transfer of said printing.

Parmi les produits convenant à cet usage, on peut citer la zéine, les carboxyméthylcelluloses, les silicones et les résines synthétiques telles que les polyéthylène, le polypropylène et le polyamide.Among the products suitable for this use, mention may be made of zein, carboxymethylcelluloses, silicones and synthetic resins such as polyethylene, polypropylene and polyamide.

Selon un mode de réalisation préféré de l'invention, le support servant d'armature au revêtement de sol ou de mur décoré est constitué par un voile de fibres telles que des fibres de verre, préalablement imprégné d'une couche de plastisol puis gélifié. On dispose ainsi d'une surface parfaitement plane permettant d'obtenir, une fois réalisée l'opération simultanée de gélification et d'impression transfert de ce support enduit d'une nouvelle couche de plastisol liquide, un revêtement ne présentant aucune irrégularité d'aspect.According to a preferred embodiment of the invention, the support serving as a reinforcement for the decorated floor or wall covering consists of a veil of fibers such as glass fibers, previously impregnated with a layer of plastisol and then gelled. There is thus a perfectly flat surface making it possible to obtain, once the simultaneous gelling and transfer printing operation of this support coated with a new layer of liquid plastisol has been carried out, a coating having no appearance irregularity. .

L'installation utilisée pour la mise en oeuvre du procédé selon l'invention comporte essentiellement un premier poste de stockage de plastisol, des moyens d'amenée d'un voile de fibres de verre à un premier moyen d'application de plastisol audit voile, des moyens de gélification du voile enduit de plastisol, un second poste de stockage de plastisol, des moyens d'amenée du voile enduit et gélifié constituant le support à un second moyen d'application de plastisol, un poste de stockage et de déroulage d'une feuille de papier transfert préalablement imprégné, des moyens permettant d'amener la face enduite du support et de la nouvelle couche de plastisol au contact de la face imprimée du papier transfert, des moyens permettant d'assurer simultanément le transfert du colorant du papier au support enduit de plastisol liquide et la gélification de ce plastisol, des moyens de séparation du support gélifié et décoré de la feuille de papier transfert, un poste de stockage et d'enroulage de la feuille de papier transfert dépourvue de son impression et des moyens permettant le stockage du support gélifié et décoré, éventuellement précédés de moyens de finissage supplémentaires du support gélifié et décoré.The installation used for implementing the method according to the invention essentially comprises a first plastisol storage station, means for feeding a veil of glass fibers to a first means of applying plastisol to said veil, means for gelling the veil coated with plastisol, a second plastisol storage station, means for supplying the coated and gelled veil constituting the support for a second means for applying plastisol, a storage and unrolling station for a sheet of transfer paper previously impregnated, means making it possible to bring the coated face of the support and the new layer of plastisol into contact with the printed face of the transfer paper, means making it possible to simultaneously ensure the transfer of the dye from the paper to the support coated with liquid plastisol and the gelling of this plastisol, means for separating the gelled support decorated with the sheet of transfer paper, a storage and winding station for the fe uille of transfer paper devoid of its printing and of the means allowing the storage of the gelled and decorated support, possibly preceded by additional finishing means of the gelled and decorated support.

La présente invention sera mieux comprise d'ailleurs et ses avantages ressortiront bien des exemples qui suivent de différents modes de réalisation du procédé selon l'invention, en référence au dessin schématique annexé dont la figure unique représente une installation permettant la mise en oeuvre dudit procédé.The present invention will be better understood moreover and its advantages will emerge clearly from the examples which follow of different embodiments of the method according to the invention, with reference to the appended schematic drawing whose single figure represents an installation allowing the implementation of said method. .

Sur le dessin (1) représente le support à imprimer, (2) le plastisol, (3) le papier transfert imprimé et (4) le produit fini, imprimé et gélifié.In the drawing (1) represents the support to be printed, (2) the plastisol, (3) the printed transfer paper and (4) the finished product, printed and gelled.

Exemple 1 - Obtention d'un revêtement de sol expansé à reliefEXAMPLE 1 Obtaining an Expanded Relief Flooring Préparation du support (1).Preparation of the support (1).

On enduit tout d'abord, à l'aide du moyen de raclage (14), un voile de verre (6) de 50 g/m2 (provenant d'une installation non représentée au dessin et qui peut constituer la tête de ligne de l'installation selon l'invention) avec 400 g/m2 du plastisol (5) stocké dans le réservoir (7) et présentant la composition suivante :

  • - Polychlorure de vinyle microsuspension, valeur K-80, type PB 1702, commercialisé par la Société ORGAVYL (France) 100 g
  • - Di-Iso-octyl phtalate 60 g
  • - Stabilisant liquide (Ba-Zn) 2 g
  • - Carbonate de calcium (diamètre moyen 14 u,m) 45 g
  • - Oxyde de titane 5 g
  • - Additif de mouillage 2 g
First of all, using a scraper means (14), a glass veil (6) of 50 g / m 2 is coated (coming from an installation not shown in the drawing and which can constitute the head of line of the installation according to the invention) with 400 g / m 2 of plastisol (5) stored in the tank (7) and having the following composition:
  • - Polyvinyl chloride microsuspension, value K-80, type PB 1702, sold by the company ORGAVYL (France) 100 g
  • - Di-Iso-octyl phthalate 60 g
  • - Liquid stabilizer (Ba-Zn) 2 g
  • - Calcium carbonate (average diameter 14 u, m) 45 g
  • - Titanium oxide 5 g
  • - Wetting additive 2 g

La viscosité du plastisol est ajustée à 2500 mPa - s 2 500 centipoises) par addition de 1 à 2 % de dodécylbenzène.The viscosity of the plastisol is adjusted to 2500 mPa - 2,500 centipoise) by the addition of 1 to 2% of dodecylbenzene.

Une fois enduit, le voile (6) est gélifié sur le cylindre (8) dont la température est portée à 150-155 °C. Après refroidissement, on applique en (15) sur ce voile enduit, qui constitue le support (1), une enduction (300 g/m2) de plastisol gonflable (2) stocké dans le réservoir (9) ayant la composition suivante :

  • - Polychlorure de vinyle microsuspension, valeur K-68, type PB 1152 C, commercialisé par la Société ORGAVYL (France) 40 g
  • - Polychlorure de vinyle, émulsion, valeur K-68, type P 68 E, commercialisé par la Société WACKER (Allemagne) 40 g
  • - Polychlorure de vinyle, suspension, (« Blending resin ») type PB 8015, commercialisé par la Société ORGAVYL (France) 20 g
  • - Butyl benzylphtalate 20 g
  • - Di-octyl phtalate 35 g
  • - Carbonate de calcium 10 g
  • - Agent gonflant (azodicarbonamide) 2,40 g
  • - Stabilisant catalyseur (oxyde de zinc) 1,20 g
  • - Oxyde de titane 3,60 g
Once coated, the veil (6) is gelled on the cylinder (8), the temperature of which is raised to 150-155 ° C. After cooling, in (15) is applied to this coated web, which constitutes the support (1), a coating (300 g / m 2 ) of inflatable plastisol (2) stored in the tank (9) having the following composition:
  • - Polyvinyl chloride microsuspension, value K-68, type PB 1152 C, sold by the company ORGAVYL (France) 40 g
  • - Polyvinyl chloride, emulsion, value K-68, type P 68 E, sold by the company WACKER (Germany) 40 g
  • - Polyvinyl chloride, suspension, (“Blending resin”) type PB 8015, sold by the company ORGAVYL (France) 20 g
  • - Butyl benzylphthalate 20 g
  • - Di-octyl phthalate 35 g
  • - Calcium carbonate 10 g
  • - Blowing agent (azodicarbonamide) 2.40 g
  • - Catalyst stabilizer (zinc oxide) 1.20 g
  • - Titanium oxide 3.60 g

La viscosité de ce plastisol est ajustée à 4000 mPa - s (4000 centipoises), au dodécylbenzène.The viscosity of this plastisol is adjusted to 4000 mPa - s (4000 centipoise), with dodecylbenzene.

Cette enduction peut être indifféremment appliquée à la racle, comme représenté au dessin, ou à l'aide du dispositif dit « reverse roll ".This coating can be applied to the doctor blade, as shown in the drawing, or using the so-called "reverse roll " device .

Le support (1) enduit avec ce plastisol liquide (2) est ensuite amené au contact du cylindre gélificateur (11) en même temps que le papier transfert imprimé (3) provenant du rouleau (10), la face imprimée du papier (3) étant contre la face enduite du support (1).The support (1) coated with this liquid plastisol (2) is then brought into contact with the cylinder gelling agent (11) at the same time as the printed transfer paper (3) coming from the roll (10), the printed side of the paper (3) being against the coated side of the support (1).

Ce papier transfert (3) est un papier couché de 50 g, préalablement enduit d'une couche dite « release de 20 g/m2 d'une résine telle que le polypropylène ; il a été imprimé en hélio avec une encre présentant la composition suivante :

  • - Copolymère acétate et chlorure de polyvinyle type VYNS, marque déposée, commercialisé par UNION CARBIDE 17 g
  • - Méthyléthyl-cétone 80 g
  • - Méthyl-isobutyl-cétone 20 g
  • - Pigments type Microlith K (marque déposée), commercialisés par CIBA GEIGY, selon le coloris 0,1 à 10 g
This transfer paper (3) is a coated paper of 50 g, previously coated with a layer called “release of 20 g / m 2 of a resin such as polypropylene; it was printed in rotogravure with an ink having the following composition:
  • - Polyvinyl acetate and chloride copolymer, VYNS type, registered trademark, marketed by UNION CARBIDE 17 g
  • - Methyl ethyl ketone 80 g
  • - Methyl isobutyl ketone 20 g
  • - Microlith K type pigments (registered trademark), marketed by CIBA GEIGY, depending on the color 0.1 to 10 g

La viscosité était ajustée à la méthyl-éthyl-cétone pour obtenir, à l'utilisation, une encre de 30 mPa - s (15 secondes (coupe FORD numéro 4).The viscosity was adjusted with methyl ethyl ketone to obtain, when in use, an ink of 30 mPa - s (15 seconds (FORD cut number 4).

Certaines encres contiennent un inhibiteur d'expansion permettant l'obtention de dessins en relief, tel que l'anhydride trimellitique ou le benzotriazole à une dose allant de 2,5 à 10 %, selon le relief du dessin.Certain inks contain an expansion inhibitor making it possible to obtain relief drawings, such as trimellitic anhydride or benzotriazole at a dose ranging from 2.5 to 10%, depending on the relief of the drawing.

Le cylindre gélificateur (11) est porté à une température qui peut se situer entre 130 et 190 °C et qui, dans le cas d'une ligne marchant à 20 m/minute, se situe aux environs de 170 °C. Le papier transfert imprimé (3) et le voile de verre imprégné (1) et enduit le plastisol gonflable (2) sont pressés ensemble contre le cylindre chaud (1) et restent en contact intime sur une grande partie de la circonférence de ce dernier. A la sortie du cylindre (11) on refroidit le complexe (2-3), puis on sépare le papier qui ne porte plus d'impression et est repris sur le rouleau (12). On peut éventuellement le réimprimer à nouveau pour une opération suivante. L'impression appliquée sur le papier s'est alors transférée sur la couche de plastisol gonflable (2) appliquée au support (1) et l'on obtient un revêtement enduit et imprimé (4).The gel cylinder (11) is brought to a temperature which can be between 130 and 190 ° C and which, in the case of a line running at 20 m / minute, is around 170 ° C. The printed transfer paper (3) and the impregnated glass veil (1) and coated with the inflatable plastisol (2) are pressed together against the hot cylinder (1) and remain in intimate contact over a large part of the circumference of the latter. At the outlet of the cylinder (11) the complex is cooled (2-3), then the paper which is no longer printed is separated and is taken up on the roller (12). You can optionally reprint it again for a subsequent operation. The impression applied to the paper is then transferred to the layer of inflatable plastisol (2) applied to the support (1) and a coated and printed coating (4) is obtained.

On peut ensuite, et spécialement dans le cas où l'encre d'impression contenait un inhibiteur d'expansion, enduire le revêtement imprimé (4), par exemple au moyen d'une installation dite « reverse-roll (non représentée au dessin mais située avant le rouleau de stockage (13)) de 320 g/m2 d'une couche de surface transparente désaérée présentant la composition suivante :

  • - Polychlorure de vinyle, microsuspension, valeur K-80, type PB 1702, commercialisé par la société ORGAVYL (France) 40 g
  • - Polychlorure de vinyle, émulsion, valeur K-80, type P 80, commercialisé par la société WACKER (Allemagne) 40 g
  • - Polychlorure de vinyle, suspension, valeur K-65, type C 65 V, commercialisé par la société WACKER (Allemagne) 20 g
  • - Butylbenzylphtalate 26 g
  • - Dioctyl phtalate 7 g
  • - Isobutyrate de texanol 7 g
  • - Huile de soja époxydée 4 g
  • - Stabilisant liquide Ba-Zn 3 g
  • - Absorbeur ultra-violet 0,2 g
  • - Additif de désaération 0,2 g
  • - Dodécyl benzène 5 g
It is then possible, and especially in the case where the printing ink contained an expansion inhibitor, to coat the printed coating (4), for example by means of a so-called “reverse-roll installation (not shown in the drawing but located before the storage roller (13)) of 320 g / m 2 of a deaerated transparent surface layer having the following composition:
  • - Polyvinyl chloride, microsuspension, value K-80, type PB 1702, sold by the company ORGAVYL (France) 40 g
  • - Polyvinyl chloride, emulsion, value K-80, type P 80, sold by the company WACKER (Germany) 40 g
  • - Polyvinyl chloride, suspension, value K-65, type C 65 V, sold by the company WACKER (Germany) 20 g
  • - Butylbenzylphthalate 26 g
  • - Dioctyl phthalate 7 g
  • - Texanol isobutyrate 7 g
  • - Epoxidized soybean oil 4 g
  • - Ba-Zn liquid stabilizer 3 g
  • - 0.2 g ultra-violet absorber
  • - 0.2 g deaeration additive
  • - Dodecyl benzene 5 g

Le support (4) ainsi enduit passe alors dans un four à 200-210 °C. A cette température l'agent gonflant se décompose pour donner une mousse chimique, sauf aux endroits où l'encre d'impression contenait de l'inhibiteur.The support (4) thus coated then passes into an oven at 200-210 ° C. At this temperature the blowing agent decomposes to give a chemical foam, except where the printing ink contained the inhibitor.

La surface est gélifiée.The surface is gelled.

Le revêtement de sol obtenu imprimé et en relief peut, dans certains cas, recevoir à l'envers une enduction supplémentaire de mousse mécanique présentant la composition suivante :

  • - Polychlorure de vinyle, émulsion, valeur K-70, type EF 701, commercialisé par PLASTIMER (France) 100 g
  • - Butyl benzyl phtalate 25 g
  • - Di-octyl phtalate 25 g
  • - Stabilisant liquide (Ba-Zn) 2 g
  • - Carbonate de calcium 20 g
  • - Surfactif silicone 3 g
The floor covering obtained printed and in relief can, in certain cases, receive an additional coating of mechanical foam upside down having the following composition:
  • - Polyvinyl chloride, emulsion, value K-70, type EF 701, sold by PLASTIMER (France) 100 g
  • - Butyl benzyl phthalate 25 g
  • - Di-octyl phthalate 25 g
  • - Liquid stabilizer (Ba-Zn) 2 g
  • - Calcium carbonate 20 g
  • - 3 g silicone surfactant

Ce plastisol est moussé mécaniquement par incorporation d'air sec dans un batteur mécanique du type MONDOMIX (marque déposée). On dépose à la racle 300 g/m2 de mousse mécanique de densité fraîche 500 g au litre. On gélifie dans un four à 175 °C. Le revêtement gélifié et décoré (4) est enroulé en (13).This plastisol is mechanically foamed by incorporating dry air into a mechanical beater of the MONDOMIX type (registered trademark). 300 g / m 2 of mechanical foam with a fresh density of 500 g per liter are applied using a doctor blade. It is gelled in an oven at 175 ° C. The gelled and decorated coating (4) is rolled up at (13).

Exemple 2 - Revêtement mural expansé à reliefExample 2 - Expanded relief wallcovering

Un voile de verre (1) de 50 g/m2 est enduit directement en (15) avec la composition (2) suivante :

  • - Polychlorure de vinyle microsuspension, valeur K-68 50 g
  • - Polychlorure de vinyle, émulsion, valeur K-68 50 g
  • - Butyl benzyl phtalate 25 g
  • - Di-octyl phtalate 35 g
  • - Carbonate de calcium 40 g
  • - Agent gonflant (azodicarbonamide) 2,40 g
  • - Catalyseur (oxyde de zinc) 1,20 g
  • - Oxyde de titane et pigments 7 g
  • - Huile de soja époxydée 5 g
  • - Stabilisant liquide (Ba-Zn) 2 g
A glass veil (1) of 50 g / m 2 is directly coated in (15) with the following composition (2):
  • - Polyvinyl chloride microsuspension, value K-68 50 g
  • - Polyvinyl chloride, emulsion, K-68 value 50 g
  • - Butyl benzyl phthalate 25 g
  • - Di-octyl phthalate 35 g
  • - Calcium carbonate 40 g
  • - Blowing agent (azodicarbonamide) 2.40 g
  • - Catalyst (zinc oxide) 1.20 g
  • - Titanium oxide and pigments 7 g
  • - Epoxidized soybean oil 5 g
  • - Liquid stabilizer (Ba-Zn) 2 g

La viscosité du plastisol est ajustée au white spirit à 5 000 mPa - s (5 000 centipoises). On dépose à la racle 400 g/m2. The viscosity of the plastisol is adjusted with white spirit to 5,000 mPa - s (5,000 centipoise). 400 g / m 2 are applied using a doctor blade .

Le papier transfert (3) (papier couché de 50 g/m2 revêtu d'un film de polyamide de. 20 g/m2) est préparé pour apporter en même temps l'impression et le vernis de surface. Pour cela, on imprime tout d'abord sur le papier un vernis acrylique de composition :

  • - Résine acrylique : ELVACITE 2041, marque déposée, commercialisé par la société DUPONT de NEMOURS (USA) 20 g
  • - Méthyléthylcétone 100 g
The transfer paper (3) (coated paper of 50 g / m 2 coated with a polyamide film of 20 g / m 2 ) is prepared to provide the impression and the surface varnish at the same time. For this, we first print on paper an acrylic varnish of composition:
  • - Acrylic resin: ELVACITE 2041, registered trademark, marketed by the company DUPONT de NEMOURS (USA) 20 g
  • - Methyl ethyl ketone 100 g

On ajoute éventuellement à cette composition 10 % de silice amorphe micronisée du type commercialisée par la firme GRACE sous la marque Siloïd. On obtiendra ainsi un vernis de surface mat.Optionally, 10% of micronized amorphous silica of the type sold by the company GRACE under the brand Siloid is added to this composition. This will give a matt surface varnish.

On imprime ensuite le papier avec une encre présentant la composition suivante :

  • - Résine acrylique (ELVACITE 2041) commercialisée par DUPONT de NEMOURS 17 g
  • - Méthyléthylcétone 80 g
  • - Méthylisobutylcétone 20 g
  • - Pigments enrobés acrylique, type ROWALID. PP. AC, marque déposée, commercialisés par ROWA (R.F.A.) 0,1 à 10 g
The paper is then printed with an ink having the following composition:
  • - Acrylic resin (ELVACITE 2041) sold by DUPONT de NEMOURS 17 g
  • - Methyl ethyl ketone 80 g
  • - Methyl isobutyl ketone 20 g
  • - Acrylic coated pigments, ROWALID type. PP. AC, registered trademark, marketed by ROWA (RFA) 0.1 to 10 g

On peut aussi adjoindre à cette encre un inhibiteur d'expansion tel que l'anhydride trimellitique à une dose de 5 % pour un relief moyen et de 10 % pour un relief plus marqué.One can also add to this ink an expansion inhibitor such as trimellitic anhydride at a dose of 5% for a medium relief and 10% for a more marked relief.

On transfère simultanément l'impression et le vernis de surface et l'on effectue en même temps la prégélification du plastisol gonflable par passage du support (1) enduit du plastisol (2) et du papier (3) sur le cylindre gélificateur (11).The printing and the surface varnish are simultaneously transferred and the inflatable plastisol is pre-gelated by passing the support (1) coated with plastisol (2) and paper (3) over the gel cylinder (11) .

On enlève ensuite le papier transfert et l'on effectue l'expansion du plastisol gonflable (2) dans un four porté à 200-220 °C (non représenté).The transfer paper is then removed and the inflatable plastisol (2) is expanded in an oven brought to 200-220 ° C (not shown).

On obtient ainsi directement un revêtement mural en relief imprimé avec un vernis de surface qui est stocké en (13).One thus obtains directly a relief wall covering printed with a surface varnish which is stored in (13).

Exemple 3 - Revêtement de sol (ou de mur) non expansé. Préparation du support (1)Example 3 - Unexpanded floor (or wall) covering. Substrate preparation (1)

Sur un voile de verre (6) de 50 g/m2, on enduit à la racle en (14) 300 g/m2 du plastisol (5) suivant :

  • - Polychlorure de vinyle, émulsion, valeur K 80, du type E 80 CA, commercialisé par la société WACKER 100 g
  • - Di-octyl phtalate 60 g
  • - Paraffine chlorée 25 g
  • - Stabilisant liquide (Ba-Cd-Zn) . 2 g
  • - Carbonate de calcium 150 g
  • - Oxyde de titane et pigments 3,5 g
  • - Additif de mouillage 1,5 g
  • - Réducteur de viscosité 2 à 4 g
On a glass veil (6) of 50 g / m 2 , the following plastisol (5) is coated with a doctor blade (14) 300 g / m 2 :
  • - Polyvinyl chloride, emulsion, value K 80, of type E 80 CA, sold by the company WACKER 100 g
  • - Di-octyl phthalate 60 g
  • - Chlorinated paraffin 25 g
  • - Liquid stabilizer (Ba-Cd-Zn). 2 g
  • - Calcium carbonate 150 g
  • - Titanium oxide and pigments 3.5 g
  • - Wetting additive 1.5 g
  • - Viscosity reducer 2 to 4 g

On ajuste la viscosité à 3500 mPa - s (3 500 centipoises). Après gélification de ce plastisol sur le tambour chauffant (8) (140-145 °C), on applique à l'aide de la racle (15) sur le support (1) ainsi obtenu 350 g d'un plastisol (2) ayant la composition suivante :

  • - Polychlorure de vinyle, émulsion, valeur K-70 40 g
  • - Polychlorure de vinyle, émulsion, valeur K-80 40 g
  • - Polychlorure de vinyle, suspension, valeur K-57 20 g
  • - Carbonate de calcium 40 g
  • - Di-octyl phtalate 40 g
  • - Stabilisant liquide Ba-Zn 2 g
  • - Oxyde de titane et pigments 5 g
The viscosity is adjusted to 3500 mPa - s (3500 centipoise). After gelling of this plastisol on the heating drum (8) (140-145 ° C), 350 g of a plastisol (2) having been applied using the doctor blade (15) on the support (1) thus obtained. the following composition:
  • - Polyvinyl chloride, emulsion, K-70 value 40 g
  • - Polyvinyl chloride, emulsion, K-80 value 40 g
  • - Polyvinyl chloride, suspension, K-57 value 20 g
  • - Calcium carbonate 40 g
  • - Di-octyl phthalate 40 g
  • - Ba-Zn liquid stabilizer 2 g
  • - Titanium oxide and pigments 5 g

Le support (1) ainsi enduit du plastisol (2) est pressé en même temps que le papier transfert imprimé (3) contre le cylindre (11) porté à 180 °C.The support (1) thus coated with plastisol (2) is pressed at the same time as the printed transfer paper (3) against the cylinder (11) brought to 180 ° C.

Le papier est ensuite enlevé et stocké en (12) et on applique (sur une partie non représentée de l'installation) sur le produit imprimé (4) une enduction de plastisol de surface transparente (100 g/m2 pour un revêtement mural, 250 g/M 2 pour un revêtement de sol), ayant la composition suivante :

  • - Polychlorure de vinyle, microsuspension, valeur K-70, type PB 1302, commercialisé par ORGAVYL (France) 50 g
  • - Polychlorure de vinyle, émulsion, valeur K-70, type P 70, commercialisé par la société WACKER (R.F.A.) 50 g
  • - Santicizer 213, commercialisé par la société MONSANTO (Belgique) 40 g
  • - Stabilisant liquide Ba-Zn 3 g
  • - Epoxystéarate d'Octyl 4 g
  • - Absorbeur ultra-violet 0,2 g
  • - Additif de désaération 0,2 g
  • - Dodécylbenzène 2 g
The paper is then removed and stored in (12) and a coating of plastisol with a transparent surface (100 g / m 2 for a wall covering) is applied (to a part not shown of the installation) on the printed product (4). 250 g / M 2 for a floor covering), having the following composition:
  • - Polyvinyl chloride, microsuspension, value K-70, type PB 1302, sold by ORGAVYL (France) 50 g
  • - Polyvinyl chloride, emulsion, value K-70, type P 70, sold by the company WACKER (RFA) 50 g
  • - Santicizer 213, marketed by MONSANTO (Belgium) 40 g
  • - Ba-Zn liquid stabilizer 3 g
  • - Octyl epoxystearate 4 g
  • - 0.2 g ultra-violet absorber
  • - 0.2 g deaeration additive
  • - Dodecylbenzene 2 g

On désaère ce plastisol sous vide, on l'applique au reverse-roll, on gélifie dans un four à 210 °C et on effectue éventuellement un gaufrage mécanique permettant de communiquer à la surface du revêtement un certain relief avant son stockage sur le rouleau (12).This plastisol is deaerated under vacuum, it is applied with a reverse-roll, it is gelled in an oven at 210 ° C. and a mechanical embossing is optionally carried out, allowing a certain relief to be imparted to the surface of the coating before being stored on the roller ( 12).

Claims (9)

1. A continuous process to obtain decorated plastics coverings, notably for floors and walls, characterized in that the coating stage, by means of a liquid plastisol, of the support serving as a backing for the said coverings is immediately followed by a transfer printing stage in the course of which the printed surface of the transfer paper is placed in contact with the layer of liquid plastisol, and in that the body so formed is submitted to the simultaneous action of heat and pressure in order to ensure in a single operation the transfer of the design and the pre-gelling of the plastisol.
2. A process according to Claim 1, characterized in that the liquid plastisol on to which the printed face of the transfer paper is applied is an expandable plastisol.
3. A process according to Claim 1, characterized in that the paper that is used to produce the transfer printing is supplied, before it is printed, with a layer of film-forming products suitable to facilitate the latter transfer of the said printing.
4. A process according to Claim 3, characterized in that the film-forming product is selected, from amongst the synthetic resins such as the polyethylenes, the polypropylenes and the polyamides.
5. A process according to Claim 3, characterized in that the film-forming product is chosen from amonst the silicones.
6. A process according to Claim 3, characterized in that the film-forming product is chosen from the group comprising zein and carboxymethylcelluloses.
7. A process according to any of Claims 1 to 6, characterized in that the support serving as a backing for the decorated floor or wall covering is formed by a network of fibres firstly impregnated with a layer of plastisol and then gelled.
8. A process according to Claim 7, characterized in that the support serving as a backing is a network of glass fibres.
9. An installation to carry out the process according to any_of Claims 1 to 8, characterized in that it essentially comprises a first storage point (7) for plastisol (5), means of transport for a network of fibres (6) to a first means of application (14) of plastisol to the said network, means of gelling (8) of the network coated with plastisol, a second storage point (9) for plastisol (2), means of transport for the coated, gelled network forming the support (1) to a second means of application of plastisol (15), means enabling the face of the support coated by the new layer of plastisol (2) to be brought into contact with the printed face of the transfer paper (3), means (11) enabling simultaneous transfer of the colouring matter in the paper to the support coated with liquid plastisol and gelling of the plastisol, means of separating the gelled, decorated support (4)_from the sheet of transfer paper, a storage and winding-up point (12) for the sheet of transfer paper after removal of its printing, and means (13) allowing storage of the gelled, decorated support, possibly preceded by supplementary means of finishing the gelled, decorated support.
EP83420102A 1982-06-18 1983-06-16 Continuous process for the manufacture of decorated plastic floor or wall coverings and device for carrying out the process Expired EP0101388B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83420102T ATE19270T1 (en) 1982-06-18 1983-06-16 CONTINUOUS PROCESS FOR PRODUCTION OF DECORATED PLASTIC WALL AND FLOOR COVERINGS AND MEANS FOR CARRYING OUT THE PROCESS.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8211122 1982-06-18
FR8211122A FR2528896A1 (en) 1982-06-18 1982-06-18 CONTINUOUS PROCESS FOR OBTAINING DECORATED PLASTIC COATINGS FOR FLOORS OR WALLS AND INSTALLATION PROVIDED FOR THE IMPLEMENTATION OF THIS PROCESS AND COATINGS OBTAINED

Publications (3)

Publication Number Publication Date
EP0101388A2 EP0101388A2 (en) 1984-02-22
EP0101388A3 EP0101388A3 (en) 1984-03-28
EP0101388B1 true EP0101388B1 (en) 1986-04-16

Family

ID=9275383

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83420102A Expired EP0101388B1 (en) 1982-06-18 1983-06-16 Continuous process for the manufacture of decorated plastic floor or wall coverings and device for carrying out the process

Country Status (14)

Country Link
US (1) US4495012A (en)
EP (1) EP0101388B1 (en)
JP (1) JPS599286A (en)
AT (1) ATE19270T1 (en)
AU (1) AU553392B2 (en)
BR (1) BR8303219A (en)
CA (1) CA1206303A (en)
DE (1) DE3363048D1 (en)
EG (1) EG16052A (en)
ES (1) ES8407544A1 (en)
FR (1) FR2528896A1 (en)
NZ (1) NZ204623A (en)
OA (1) OA07466A (en)
ZA (1) ZA834328B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2607055B1 (en) * 1986-11-20 1989-04-21 Pennel Flipo NEW COATED FABRIC WITH MARKED DECOR AND METHOD FOR MANUFACTURING THE SAME
FR2668422B1 (en) * 1990-10-24 1995-03-10 Hexcel Genin Sa PROCESS FOR THE PRINTING OF COLORFUL PATTERNS ON A SUBSTRATE BASED ON FIBERGLASS AND NEW PRODUCT OBTAINED.
GB2285935B (en) * 1994-02-01 1998-06-24 Scapa Group Plc Industrial fabric
GB2307447A (en) * 1995-11-27 1997-05-28 Tung Tai Yuen Manufacturing Co Wallpaper and its production method
DE29718222U1 (en) * 1997-10-14 1999-02-18 Sauer, Wigbert H., 71229 Leonberg Textile glass fabric sheet
US6159582A (en) * 1999-07-16 2000-12-12 Cheng Feng Blinds Ind. Co., Ltd Decorative patterns for use on venetian blind and wall paper
US6291011B1 (en) 1999-11-16 2001-09-18 Johns Manville International, Inc. Design effect fiberglass wallcoverings
DE60130283T2 (en) * 2000-04-07 2008-05-29 Johns Manville Europe Gmbh Peelable fiberglass wall hanging
US6759116B2 (en) * 2002-05-01 2004-07-06 Per Edlund Volumetric effect glass fiber wallcoverings
DE102010061866A1 (en) * 2010-11-24 2012-05-24 Evonik Oxeno Gmbh Use of di (2-ethylhexyl) terephthalate (DEHT) in foamable PVC formulations

Family Cites Families (11)

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Publication number Priority date Publication date Assignee Title
NL95532C (en) * 1900-01-01
FR1061259A (en) * 1952-08-05 1954-04-12 Blanchiment Et Apprets De Tara Process and device for the manufacture of polyvinyl chloride floor and floor coverings and resulting product
NL272890A (en) * 1966-04-19 1900-01-01
GB1343927A (en) * 1971-05-22 1974-01-16 Harrico Oadby Ltd Apparatus for heat treating fabric
US3901990A (en) * 1972-06-09 1975-08-26 Arieh Solomon Method for applying pattern to candles
US4405393A (en) * 1977-03-30 1983-09-20 Tillotson John G Method for forming a layer of blown cellular urethane on a carpet backing
US4225374A (en) * 1978-04-20 1980-09-30 Armstrong Cork Company Decorative flooring
US4335495A (en) * 1978-12-04 1982-06-22 Buchanan Beverly J Fishing lure fabrication, including pattern application
DE2906134C2 (en) * 1979-02-17 1984-01-19 Schering AG, 1000 Berlin und 4709 Bergkamen Polyvinyl chloride plastisols with improved properties and process for their production
SE435356B (en) * 1979-03-12 1984-09-24 Forbo Forshaga Ab PROCEDURE FOR MANUFACTURING A PREPARATION AND RELIEF-MASTERED PLASTIC MATERIAL
US4401720A (en) * 1981-06-24 1983-08-30 Eastman Kodak Company Poly(vinyl chloride) plastisol compositions

Also Published As

Publication number Publication date
AU553392B2 (en) 1986-07-10
FR2528896A1 (en) 1983-12-23
AU1592183A (en) 1983-12-22
US4495012A (en) 1985-01-22
BR8303219A (en) 1984-01-31
OA07466A (en) 1984-12-31
ZA834328B (en) 1984-03-28
JPS599286A (en) 1984-01-18
DE3363048D1 (en) 1986-05-22
ES523369A0 (en) 1984-10-01
EG16052A (en) 1987-07-30
FR2528896B1 (en) 1984-12-28
EP0101388A2 (en) 1984-02-22
ATE19270T1 (en) 1986-05-15
NZ204623A (en) 1985-10-11
CA1206303A (en) 1986-06-24
ES8407544A1 (en) 1984-10-01
EP0101388A3 (en) 1984-03-28

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