EP0035601B1 - Procédé de fabrication d'un alliage-mémoire - Google Patents
Procédé de fabrication d'un alliage-mémoire Download PDFInfo
- Publication number
- EP0035601B1 EP0035601B1 EP80200184A EP80200184A EP0035601B1 EP 0035601 B1 EP0035601 B1 EP 0035601B1 EP 80200184 A EP80200184 A EP 80200184A EP 80200184 A EP80200184 A EP 80200184A EP 0035601 B1 EP0035601 B1 EP 0035601B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- powder
- temperature
- process according
- soft
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/006—Resulting in heat recoverable alloys with a memory effect
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/0425—Copper-based alloys
Definitions
- the invention is based on a method for producing a memory alloy according to the preamble of claim 1.
- Memory alloys of the Cu / Al type or of the Cu / Al type plus at least one of the elements Ni, Fe, Mn and Co are known and have been described in various publications (for example US Pat. No. 3,783,037). Such memory alloys, which belong to the general type with the ⁇ high-temperature phase, are generally produced by melt metallurgy.
- the invention is based on the object of specifying a production method for memory alloys of the Cu / AI type or of the Cu / AI type plus at least one of the elements Ni, Fe, Mn and Co which results in dense, compact bodies with good mechanical properties and at the same time too precisely reproducible values of the transition temperature and other quantities related to the memory effect.
- the essence of the new process is not to start from elementary powders or from a starting powder corresponding to the final alloy, but to use a mixture of pre-alloyed powders and specially composed powder mixtures. This allows the required ductility to be optimally adapted to the processing process with extensive freedom in terms of composition.
- the grain size of the crystallites of the finished body can largely be predetermined. Grain growth is not to be feared. Coherent oxide skins that prevent homogenization and impair mechanical properties are avoided. If a certain small percentage is present, the metal oxides are present in finely divided form as dispersoids and have a beneficial effect on the mechanical properties of the end product, preventing grain growth.
- a round rod was made from a memory alloy with the following final composition:
- thermomechanical processing consisted of round hammering at 950 ° C, the diameter of the rod being reduced to 18 mm in the first round hammering stitch and by 2 mm for each further stitch.
- the procedure was such that homogenization annealing followed after 2 thermomechanical operations.
- the rod hammered down to 8 mm in diameter was finally subjected to a final annealing in a stream of argon for 15 minutes at a temperature of 950 ° C. and immediately quenched in water.
- the test showed a density of 99.5-99.8% of the theoretical value for the workpiece.
- thermomechanical machining / homogenization can be continued for as long as required until the final shape of the workpiece is reached. When the theoretical density is reached, further homogenization is generally no longer necessary.
- a round rod was made from a memory alloy with the following final composition:
- Example I The powders given in Example I were weighed out as follows and mixed in a tumble mixer for 15 minutes:
- a tape was made from a memory alloy of the following final composition:
- Example I The powders given in Example I were weighed out as follows and mixed in a tumble mixer for 12 minutes:
- this powder mixture were filled into a soft-annealed tombac tube with an inner diameter of 20 mm and a wall thickness of 1.6 mm and completely encapsulated by covering the ends and soldering under an argon atmosphere.
- the tube and powder were then isostatically pressed at a pressure of 12,000 bar and the compact was reduced and presintered in a stream of hydrogen at a temperature of 850 ° C. for 11 ⁇ 2 hours and then sintered in a stream of argon at a temperature of 820 ° C. for 22 hours.
- the workpiece was then reduced in 2 round hammer passes at a temperature of 900 ° C to 18 or 16 mm in diameter and homogenized in a stream of argon at 920 ° C for 1 h. This was followed by two round hammer passes at 900 ° C, so that the rod finally had a diameter of 13 mm.
- the rod was rolled down in several successive hot rolling operations, each with a 20-25% reduction in cross section, to form a strip 1.5 mm thick and 20 mm wide.
- a square bar was made from a memory alloy of the following final composition:
- the powders given under the example were weighed out as follows and mixed in a tumble mixer for 10 min.
- the reduction ratio (decrease in cross-section) was 11: 1.
- the rod was then homogenized at a temperature of 920 ° C. for 30 minutes and then pulled down in 2 passes on a warming bench at a temperature of 750 ° C. to an edge length of 6 mm. After the final annealing at 900 ° C. for 15 minutes in a stream of argon, the rod was quenched in water. The density of the finished rod was 99.8% of the theoretical value.
- a round plate was made from a memory alloy of the following final composition:
- Example I The powders given in Example I were weighed out as follows and mixed in a tumble mixer for 15 minutes:
- 1000 g of this powder mixture were filled into a plastic tube with an inner diameter of 66 mm and pressed isostatically at a pressure of 12,000 bar to a cylinder with a diameter of 60 mm and a height of 80 mm.
- the green body was reduced in a hydrogen / nitrogen stream at a temperature of 880 ° C. for 1 h and presintered and then sintered in a stream of argon at a temperature of 930 ° C. for 25 h.
- the raw sintered body was turned to a diameter of 58 mm, introduced into a soft-annealed box made of soft iron with an outside diameter of 64 mm and completely encapsulated by putting the lid on and soldering in an argon atmosphere.
- the workpiece produced in this way was subjected to thermomechanical processing under a hot press, interrupted by homogenization annealing.
- the height of the cylinder was successively reduced to approx. 32 mm, whereby the material condensed to approx. 95% of the theoretical density and now had a diameter of 70 mm corresponding to the die.
- the preformed circular plate with parallel flat end faces was inserted in a forging die with a different diameter and in several operations, which were interrupted by intermediate annealing, at temperatures between 1000 ° C and 750 ° C the finished form forged.
- the 20 mm thick plate had a radial bead of 5 x 5 mm on the upper side and a central recess of 20 mm diameter and 5 mm axial depth on the lower side. After a final annealing at 980 ° C for 15 minutes, the plate was quenched in water. The density was 99.299.5% of the theoretical value.
- the powder mixtures are within the following limits:
- Isostatic pressing requires pressures of at least 8000 bar.
- the compact is advantageously reduced and presintered in the temperature range from 700 to 1000 ° C. for at least 30 minutes in a stream of hydrogen or hydrogen / nitrogen.
- the sintering of the compact must be above the temperature of the eutectoid transformation, i.e. H. at least 700 ° C for 10 h in a stream of argon to achieve the most homogeneous structure possible.
- thermomechanical processing which can consist of hot pressing, hot extrusion, hot forging, hot rolling, hot drawing and / or hot round hammering, should be carried out at temperatures between 700 and 1000 ° C, as well as the intermediate homogenization in the inert gas stream (intermediate annealing) at at least 700 ° C for at least 30 min.
- the final annealing in a stream of argon is carried out at temperatures between 700 and 1050 ° C. ( ⁇ -mixed crystal region) for 10 to 15 minutes and the workpiece is then immediately quenched in water.
- thermomechanical processing it is expedient to encapsulate the material beforehand in a ductile metallic shell that does not react chemically with it, which is removed mechanically or chemically at the end of the shaping as a surface layer in most applications.
- Soft-annealed metals and alloys such as copper, copper alloys and soft iron are particularly suitable as materials for the casing. Encapsulation can take place immediately before the thermomechanical processing, in that the sintered body undergoes a mechanical surface treatment beforehand by turning, milling, planing, etc., or the powder can be filled directly into a suitable tube, a can, etc., instead of into a rubber or plastic tube will.
- the powder metallurgical method according to the invention enables the production of workpieces from a memory alloy of the Cu / Al and Cu / Al / Ni type, which compared to conventional, i.e. H. bodies produced by melt metallurgy have a fine-grained structure and optionally contain dispersoids in the form of finely divided oxide particles.
- the mechanical properties, in particular the elongation, notch toughness and the working capacity of such workpieces are significantly better than those of cast and / or hot-kneaded bodies. This opens up a further area of application for this type of alloy.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Powder Metallurgy (AREA)
- Heat Treatment Of Nonferrous Metals Or Alloys (AREA)
Claims (8)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE8080200184T DE3065931D1 (en) | 1980-03-03 | 1980-03-03 | Process for making a memory alloy |
EP80200184A EP0035601B1 (fr) | 1980-03-03 | 1980-03-03 | Procédé de fabrication d'un alliage-mémoire |
US06/239,626 US4365996A (en) | 1980-03-03 | 1981-03-02 | Method of producing a memory alloy |
JP2850481A JPS56136942A (en) | 1980-03-03 | 1981-03-02 | Production of copper - aluminum - nickel memory alloy |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP80200184A EP0035601B1 (fr) | 1980-03-03 | 1980-03-03 | Procédé de fabrication d'un alliage-mémoire |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0035601A1 EP0035601A1 (fr) | 1981-09-16 |
EP0035601B1 true EP0035601B1 (fr) | 1983-12-21 |
Family
ID=8186966
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP80200184A Expired EP0035601B1 (fr) | 1980-03-03 | 1980-03-03 | Procédé de fabrication d'un alliage-mémoire |
Country Status (4)
Country | Link |
---|---|
US (1) | US4365996A (fr) |
EP (1) | EP0035601B1 (fr) |
JP (1) | JPS56136942A (fr) |
DE (1) | DE3065931D1 (fr) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0035070B1 (fr) * | 1980-03-03 | 1985-05-15 | BBC Aktiengesellschaft Brown, Boveri & Cie. | Alliage-mémoire à base d'une solution solide riche en cuivre ou en nickel |
EP0045985B1 (fr) * | 1980-08-07 | 1984-02-08 | BBC Aktiengesellschaft Brown, Boveri & Cie. | Procédé de fabrication d'un alliage à mémoire à base de cuivre |
CH659482A5 (de) * | 1982-02-05 | 1987-01-30 | Bbc Brown Boveri & Cie | Verfahren zur erzeugung eines reversiblen zweiweg-gedaechtniseffekts in einem bauteil aus einer einen einwegeffekt zeigenden legierung. |
JPS6029406A (ja) * | 1983-07-27 | 1985-02-14 | Tohoku Metal Ind Ltd | 焼結体の製造方法 |
US4464205A (en) * | 1983-11-25 | 1984-08-07 | Cabot Corporation | Wrought P/M processing for master alloy powder |
US4759293A (en) * | 1986-06-30 | 1988-07-26 | Davis Jr Thomas O | Article using shape-memory alloy to improve and/or control the speed of recovery |
US4839479A (en) * | 1986-06-30 | 1989-06-13 | Davis Jr Thomas O | Article using shape-memory alloy to improve and/or control the speed of recovery |
US4836979A (en) * | 1988-06-14 | 1989-06-06 | Inco Limited | Manufacture of composite structures |
US5443615A (en) * | 1991-02-08 | 1995-08-22 | Honda Giken Kogyo Kabushiki Kaisha | Molded ceramic articles |
JPH083133B2 (ja) * | 1990-07-12 | 1996-01-17 | 日立粉末冶金株式会社 | 船外機用バルブシート材およびその製造方法 |
US5344605A (en) * | 1991-11-22 | 1994-09-06 | Sumitomo Electric Industries, Ltd. | Method of degassing and solidifying an aluminum alloy powder |
US6132486A (en) * | 1998-11-09 | 2000-10-17 | Symmco, Inc. | Powdered metal admixture and process |
JP4424810B2 (ja) * | 2000-03-27 | 2010-03-03 | 株式会社小松製作所 | 焼結材料 |
US6548013B2 (en) * | 2001-01-24 | 2003-04-15 | Scimed Life Systems, Inc. | Processing of particulate Ni-Ti alloy to achieve desired shape and properties |
JP4282284B2 (ja) * | 2001-08-22 | 2009-06-17 | 株式会社小松製作所 | 履帯 |
DE102005032544B4 (de) * | 2004-07-14 | 2011-01-20 | Hitachi Powdered Metals Co., Ltd., Matsudo | Abriebsresistente gesinterte Aluminiumlegierung mit hoher Festigkeit und Herstellugsverfahren hierfür |
US10245639B2 (en) * | 2012-07-31 | 2019-04-02 | United Technologies Corporation | Powder metallurgy method for making components |
JP7216842B2 (ja) * | 2019-12-11 | 2023-02-01 | 株式会社ダイヤメット | Cu-Ni-Al系焼結合金の製造方法 |
CN113684389B (zh) * | 2021-08-16 | 2022-07-29 | 大连大学 | 一种控制γ相分布提高Co-Ni-Al磁记忆合金超弹性的方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2210671A (en) * | 1940-03-16 | 1940-08-06 | Westinghouse Electric & Mfg Co | Copper base alloy |
US2430419A (en) * | 1945-02-02 | 1947-11-04 | Walter W Edens | Welding rod |
FR1068305A (fr) * | 1952-12-13 | 1954-06-24 | Pechiney | Appareillage pour la fabrication de l'urée |
US3117002A (en) * | 1960-02-16 | 1964-01-07 | Ampco Metal Inc | Aluminum bronze alloy having improved wear resistance by the addition of cobalt, chromium, and manganese |
US3091527A (en) * | 1961-01-27 | 1963-05-28 | Leeds & Northrup Co | Copper base alloys particularly suited for precision resistance |
US3333950A (en) * | 1964-10-06 | 1967-08-01 | Engelhard Ind Inc | Metal composition for powder metallurgy moldings and method for production |
SE333437B (fr) * | 1969-03-03 | 1971-03-15 | Asea Ab | |
BE758862A (fr) * | 1969-11-12 | 1971-04-16 | Fulmer Res Inst Ltd | Perfectionnements relatifs au traitement d'alliages |
US3653980A (en) * | 1970-06-11 | 1972-04-04 | Olin Corp | Method of obtaining exceptional formability in aluminum bronze alloys |
US3824097A (en) * | 1972-12-19 | 1974-07-16 | Federal Mogul Corp | Process for compacting metal powder |
US4113475A (en) * | 1976-04-09 | 1978-09-12 | Kennecott Copper Corporation | Tarnish resistant copper alloy |
US4158719A (en) * | 1977-06-09 | 1979-06-19 | Carpenter Technology Corporation | Low expansion low resistivity composite powder metallurgy member and method of making the same |
NL7714494A (nl) * | 1977-12-28 | 1979-07-02 | Leuven Res & Dev Vzw | Werkwijze voor het maken van vaste lichamen uit koper-zinkaluminiumlegeringen. |
JPS54104301A (en) * | 1978-02-02 | 1979-08-16 | Nippon Dia Clevite Co | Porous sound absorber of aluminum or aluminum alloy |
US4310354A (en) * | 1980-01-10 | 1982-01-12 | Special Metals Corporation | Process for producing a shape memory effect alloy having a desired transition temperature |
-
1980
- 1980-03-03 DE DE8080200184T patent/DE3065931D1/de not_active Expired
- 1980-03-03 EP EP80200184A patent/EP0035601B1/fr not_active Expired
-
1981
- 1981-03-02 US US06/239,626 patent/US4365996A/en not_active Expired - Fee Related
- 1981-03-02 JP JP2850481A patent/JPS56136942A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JPS56136942A (en) | 1981-10-26 |
US4365996A (en) | 1982-12-28 |
EP0035601A1 (fr) | 1981-09-16 |
DE3065931D1 (en) | 1984-01-26 |
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