ECSP088525A - Proceso para la preparación de aminas - Google Patents

Proceso para la preparación de aminas

Info

Publication number
ECSP088525A
ECSP088525A EC2008008525A ECSP088525A ECSP088525A EC SP088525 A ECSP088525 A EC SP088525A EC 2008008525 A EC2008008525 A EC 2008008525A EC SP088525 A ECSP088525 A EC SP088525A EC SP088525 A ECSP088525 A EC SP088525A
Authority
EC
Ecuador
Prior art keywords
compound
formula
iii
compounds
preparation
Prior art date
Application number
EC2008008525A
Other languages
English (en)
Inventor
Josef Ehrenfreund
Hans Tobler
Harald Walter
Camilla Corsi
Fanny Giordano
Martin Zeller
Original Assignee
Syngenta Participations Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Participations Ag filed Critical Syngenta Participations Ag
Publication of ECSP088525A publication Critical patent/ECSP088525A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/24—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds
    • C07C209/28—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds by reduction with other reducing agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/23—Preparation of halogenated hydrocarbons by dehalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/30—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by a Diels-Alder synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C07C17/354—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/06—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
    • C07C209/10—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/24—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds
    • C07C209/26—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds by reduction with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/57—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings being part of condensed ring systems of the carbon skeleton
    • C07C211/60—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings being part of condensed ring systems of the carbon skeleton containing a ring other than a six-membered aromatic ring forming part of at least one of the condensed ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/57—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings being part of condensed ring systems of the carbon skeleton
    • C07C211/61—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings being part of condensed ring systems of the carbon skeleton with at least one of the condensed ring systems formed by three or more rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/18—Polycyclic aromatic halogenated hydrocarbons
    • C07C25/22—Polycyclic aromatic halogenated hydrocarbons with condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/24—Halogenated aromatic hydrocarbons with unsaturated side chains
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/60—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
    • C07C2603/66—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings

Abstract

La presente invención se refiere a un nuevo proceso para la preparación del compuesto de la fórmula general (I): en donde R1 y R2 son independientemente H o alquilo C1-6, el cual comprende tratar con un agente de reducción o bien un compuesto de la fórmula general (II): en donde R1 y R2 poseen los significados proporcionados para el compuesto de la fórmula (I), R3 es H o alquilo C1-4 y Ph es fenilo, oun compuesto de la fórmula general (III): en donde R1, R2, R3 y Ph poseen los significados proporcionados para el compuesto de la fórmula (II),siendo el agente de reducción efectivo para escindir el resto bencilo Ph-CH(R3)- del resto bencilamino PhCH(R3)NH- en el compuesto de la fórmula (II) o en el compuesto de la fórmula (III) para dejar un grupo amino y, además, en el caso del compuesto de la fórmula (III), para reducir tanto el enlace 2,3-doble como el enlace doble que une el resto R1R2C- a la posición 9 del anillo benzonorborneno a enlaces simples. Ésta también se refiere a procesos para la preparación de los compuestos (II) y (III) y sus precursores y a los compuestos (II) y (III) en sí mismos y a ciertos de sus precursores, los cuales son nuevos compuestos. Los compuestos (I) son útiles para la preparación de varias benzonorbornen-5-il-amidas de ácido heterociclil-carboxílico fungicidas.
EC2008008525A 2005-12-12 2008-06-10 Proceso para la preparación de aminas ECSP088525A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP05027072 2005-12-12
EP06008248 2006-04-21

Publications (1)

Publication Number Publication Date
ECSP088525A true ECSP088525A (es) 2008-07-30

Family

ID=37946810

Family Applications (1)

Application Number Title Priority Date Filing Date
EC2008008525A ECSP088525A (es) 2005-12-12 2008-06-10 Proceso para la preparación de aminas

Country Status (21)

Country Link
US (1) US7781615B2 (es)
EP (5) EP2316813B1 (es)
JP (1) JP5144533B2 (es)
KR (1) KR101364220B1 (es)
CN (3) CN102516086B (es)
AR (1) AR058302A1 (es)
AU (1) AU2006326289B2 (es)
BR (1) BRPI0619629B1 (es)
CA (1) CA2631973C (es)
CL (2) CL2010000015A1 (es)
CR (1) CR10052A (es)
DK (1) DK1963251T3 (es)
EA (1) EA014275B1 (es)
EC (1) ECSP088525A (es)
EG (1) EG25547A (es)
ES (1) ES2391904T3 (es)
IL (3) IL191760A (es)
IN (1) IN2015DN00818A (es)
PL (1) PL1963251T3 (es)
TW (1) TWI396676B (es)
WO (1) WO2007068417A2 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2316813B1 (en) * 2005-12-12 2013-04-03 Syngenta Participations AG Process for the preparation of amines
EP2319319A1 (en) 2007-09-20 2011-05-11 Basf Se Combinations comprising a fungicidal strain and at least one additional fungicide
EA020599B1 (ru) 2008-07-04 2014-12-30 Басф Се Фунгицидные смеси, содержащие замещенные 1-метилпиразол-4-илкарбоксанилиды и абамектин
KR101596814B1 (ko) 2008-10-27 2016-02-23 신젠타 파티서페이션즈 아게 벤조노르보르넨의 제조 방법
US20110257410A1 (en) 2008-12-24 2011-10-20 Syngenta Crop Protection, Llc Methods for the preparation of fungicides
WO2011131544A1 (en) 2010-04-20 2011-10-27 Syngenta Participations Ag Process for the preparation of pyrazole carboxylic acid amides
CN107266368A (zh) 2010-11-15 2017-10-20 拜耳知识产权有限责任公司 5‑卤代吡唑甲酰胺
RU2493145C1 (ru) * 2012-10-02 2013-09-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Волгоградский государственный технический университет" (ВолгГТУ) Способ получения 2-(аминоалкил)-3-(аминофенил)бицикло[2.2.1]гептанов
CN105208860B (zh) 2013-03-14 2018-05-01 美国陶氏益农公司 使用6-芳基吡啶羧酸、2-芳基嘧啶羧酸或其盐或酯防治阔叶作物
US11560384B2 (en) 2017-05-04 2023-01-24 University Of Utah Research Foundation Benzonorbornadiene derivatives and reactions thereof

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1086978A (en) * 1965-09-21 1967-10-11 Shionogi & Co Improvements in or relating to the preparation of 7-oxobenzonorbornene derivatives
JPH075487B2 (ja) 1985-11-14 1995-01-25 住友化学工業株式会社 １―ブロモ―２―クロロ―４―フルオロベンゼンの製造法
US7223879B2 (en) 1998-07-10 2007-05-29 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
CN1896048A (zh) * 2001-03-16 2007-01-17 出光兴产株式会社 芳香氨基化合物的生产方法
JP4219622B2 (ja) * 2002-06-11 2009-02-04 独立行政法人科学技術振興機構 ベンザイン化合物の新規製造法
US7531559B2 (en) 2002-08-22 2009-05-12 Syngenta Crop Protection, Inc. Fungicidal 1,2,3 triazole derivatives
GB0224316D0 (en) * 2002-10-18 2002-11-27 Syngenta Participations Ag Chemical compounds
EP2316813B1 (en) * 2005-12-12 2013-04-03 Syngenta Participations AG Process for the preparation of amines

Also Published As

Publication number Publication date
WO2007068417A3 (en) 2007-10-04
IL218351A (en) 2014-05-28
IL218351A0 (en) 2012-04-30
CL2012000114A1 (es) 2012-08-31
CN102516086B (zh) 2014-10-22
PL1963251T3 (pl) 2013-01-31
EP1963251B1 (en) 2012-08-15
KR101364220B1 (ko) 2014-02-21
CN104151132A (zh) 2014-11-19
EP2316813B1 (en) 2013-04-03
IL218350A0 (en) 2012-04-30
EP1963251A2 (en) 2008-09-03
EP2316814A1 (en) 2011-05-04
EA200870038A1 (ru) 2008-10-30
EP2316815A1 (en) 2011-05-04
CN101360703B (zh) 2012-07-18
US7781615B2 (en) 2010-08-24
TW200800854A (en) 2008-01-01
IN2015DN00818A (es) 2015-07-10
BRPI0619629A2 (pt) 2011-10-04
EG25547A (en) 2012-02-15
TWI396676B (zh) 2013-05-21
CN102516086A (zh) 2012-06-27
AU2006326289A1 (en) 2007-06-21
JP5144533B2 (ja) 2013-02-13
ES2391904T3 (es) 2012-11-30
EP2316809A1 (en) 2011-05-04
DK1963251T3 (da) 2012-11-26
IL191760A (en) 2014-05-28
AU2006326289B2 (en) 2011-12-22
CL2010000015A1 (es) 2010-07-02
KR20080077011A (ko) 2008-08-20
JP2009518346A (ja) 2009-05-07
AR058302A1 (es) 2008-01-30
EP2316813A1 (en) 2011-05-04
EA014275B1 (ru) 2010-10-29
EP2316809B1 (en) 2014-06-18
US20090221856A1 (en) 2009-09-03
CA2631973C (en) 2015-02-03
BRPI0619629B1 (pt) 2016-03-01
CN101360703A (zh) 2009-02-04
CN104151132B (zh) 2016-07-06
CR10052A (es) 2008-09-17
CA2631973A1 (en) 2007-06-21
IL191760A0 (en) 2008-12-29
WO2007068417A2 (en) 2007-06-21

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