EA201890652A1 - Способ получения уксусной кислоты карбонилированием метанола - Google Patents

Способ получения уксусной кислоты карбонилированием метанола

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Publication number
EA201890652A1
EA201890652A1 EA201890652A EA201890652A EA201890652A1 EA 201890652 A1 EA201890652 A1 EA 201890652A1 EA 201890652 A EA201890652 A EA 201890652A EA 201890652 A EA201890652 A EA 201890652A EA 201890652 A1 EA201890652 A1 EA 201890652A1
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EA
Eurasian Patent Office
Prior art keywords
acetic acid
methanol
present
carbonylation
catalyst
Prior art date
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EA201890652A
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English (en)
Other versions
EA035965B1 (ru
Inventor
Юмин Ни
Вэньлян Чжу
Лей Ши
Хончао Лю
Юн Лю
Чжунминь Лю
Original Assignee
Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс
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Publication of EA201890652A1 publication Critical patent/EA201890652A1/ru
Publication of EA035965B1 publication Critical patent/EA035965B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B01J29/24—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/66—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing iron group metals, noble metals or copper
    • B01J29/67—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0254—Nitrogen containing compounds on mineral substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Настоящее изобретение предлагает способ получения уксусной кислоты карбонилированием метанола, предусматривающий пропускание исходного материала, содержащего метанол, моноксид углерода и воду, через реакционную область, загруженную катализатором, содержащим кислотное молекулярное сито с адсорбированным органическим амином, и осуществление реакции в следующих условиях для получения уксусной кислоты. Способ согласно настоящему изобретению обеспечивает высокую селективность по отношению к уксусной кислоте и хорошую устойчивость катализатора. Катализатор согласно настоящему изобретению не содержит благородных металлов, таких как родий или иридий, и не нуждается в дополнительном агенте, содержащем йод, и, таким образом, не образуется йодистоводородная кислота, вызывающая сильную коррозию, и т.п.
EA201890652A 2015-09-11 2015-12-08 Способ получения уксусной кислоты карбонилированием метанола EA035965B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201510578383.5A CN106518657B (zh) 2015-09-11 2015-09-11 一种通过甲醇羰基化制备乙酸的方法
PCT/CN2015/096649 WO2017041373A1 (zh) 2015-09-11 2015-12-08 一种通过甲醇羰基化制备乙酸的方法

Publications (2)

Publication Number Publication Date
EA201890652A1 true EA201890652A1 (ru) 2018-10-31
EA035965B1 EA035965B1 (ru) 2020-09-07

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EA201890652A EA035965B1 (ru) 2015-09-11 2015-12-08 Способ получения уксусной кислоты карбонилированием метанола

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Country Link
US (1) US10370318B2 (ru)
EP (1) EP3330248B1 (ru)
JP (1) JP6615324B2 (ru)
CN (1) CN106518657B (ru)
BR (1) BR112018004736B1 (ru)
EA (1) EA035965B1 (ru)
WO (1) WO2017041373A1 (ru)
ZA (1) ZA201801832B (ru)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107552085B (zh) * 2017-08-24 2020-07-10 中国烟草总公司郑州烟草研究院 一种碳改性分子筛催化剂及其制备方法和应用
WO2020008506A1 (ja) * 2018-07-02 2020-01-09 株式会社ダイセル 酢酸の製造方法
CN109908947B (zh) * 2019-03-14 2021-03-30 厦门大学 一种合成气高选择性转化制乙酸的催化剂及其应用
CN111822041B (zh) * 2019-04-15 2021-11-09 中国科学院大连化学物理研究所 一种复合催化剂、其制备方法及其应用
CN115536040B (zh) * 2022-09-27 2023-08-15 厦门大学 一种纳米荷叶状富铝型丝光沸石分子筛及合成方法和应用

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4123446A (en) * 1977-04-11 1978-10-31 Allied Chemical Corporation Synthesis of metal alkyl carbonates
US4300011A (en) * 1980-04-28 1981-11-10 Mobil Oil Corporation Selective production of aromatics
GB9223170D0 (en) * 1992-11-05 1992-12-16 British Petroleum Co Plc Process for preparing carboxylic acids
JP4410481B2 (ja) * 2003-04-18 2010-02-03 三菱重工業株式会社 酢酸の製造方法、及び酢酸の製造装置
US6846951B1 (en) * 2003-10-09 2005-01-25 Acetex (Cyprus) Limited Integrated process for acetic acid and methanol
US7767848B2 (en) * 2005-02-08 2010-08-03 Celanese International Corporation Method of controlling acetic acid process
GB0607395D0 (en) * 2006-04-12 2006-05-24 Bp Chem Int Ltd Process
GB0607394D0 (en) * 2006-04-12 2006-05-24 Bp Chem Int Ltd Process
EP2072491A1 (en) * 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of alcohol(s) into alcohol(s) with increased carbon-chain
EP2072492A1 (en) * 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
EP2085375A1 (en) * 2007-12-20 2009-08-05 BP Chemicals Limited Process for the production of acetic acid and/or methyl acetate in the presence of a zeolite of structure type MOR
CN101613274B (zh) * 2008-06-25 2012-12-05 中国科学院大连化学物理研究所 一种二甲醚羰基化制备乙酸甲酯的方法
EP2174713A1 (en) * 2008-10-13 2010-04-14 BP Chemicals Limited Dealumination process
EP2189215A1 (en) * 2008-11-19 2010-05-26 BP Chemicals Limited Carbonylation process catalysed by mordenite supported on inorganic oxides
EP2198963A1 (en) * 2008-12-10 2010-06-23 BP Chemicals Limited Bound mordenite zeolite carbonylation catalyst
EP2251314A1 (en) * 2009-05-14 2010-11-17 BP Chemicals Limited Carbonylation process
EP2251083A1 (en) * 2009-05-14 2010-11-17 BP Chemicals Limited Carbonylation catalyst and process
EP2251082A1 (en) * 2009-05-14 2010-11-17 BP Chemicals Limited Carbonylation catalyst and process
TW201235099A (en) * 2011-01-27 2012-09-01 Bp Chem Int Ltd Process
CN102847550B (zh) * 2012-09-17 2014-11-05 浙江大学 一种甲醇羰基化制乙酸和乙酸甲酯的催化剂及其制备方法
EP2940000B1 (en) * 2012-12-25 2017-10-18 Dalian Institute Of Chemical Physics, Chinese Academy of Sciences Process for preparing methyl acetate
CN103896769B (zh) * 2012-12-25 2016-01-06 中国科学院大连化学物理研究所 一种二甲醚羰基化制备乙酸甲酯的方法
CN103896768B (zh) * 2012-12-25 2016-03-09 中国科学院大连化学物理研究所 一种制备乙酸甲酯的方法
CN103896766B (zh) * 2012-12-25 2015-12-09 中国科学院大连化学物理研究所 一种生产乙酸甲酯的方法
US9387469B2 (en) * 2013-12-30 2016-07-12 Eastman Chemical Company Carbonylation catalyst and process using same

Also Published As

Publication number Publication date
EP3330248A1 (en) 2018-06-06
JP2018526406A (ja) 2018-09-13
CN106518657B (zh) 2019-03-29
US10370318B2 (en) 2019-08-06
EP3330248A4 (en) 2018-08-08
EP3330248B1 (en) 2019-08-28
EA035965B1 (ru) 2020-09-07
JP6615324B2 (ja) 2019-12-04
CN106518657A (zh) 2017-03-22
BR112018004736B1 (pt) 2022-04-19
US20180244599A1 (en) 2018-08-30
ZA201801832B (en) 2019-07-31
WO2017041373A1 (zh) 2017-03-16
BR112018004736A2 (pt) 2019-11-12

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