EA201890652A1 - Способ получения уксусной кислоты карбонилированием метанола - Google Patents
Способ получения уксусной кислоты карбонилированием метанолаInfo
- Publication number
- EA201890652A1 EA201890652A1 EA201890652A EA201890652A EA201890652A1 EA 201890652 A1 EA201890652 A1 EA 201890652A1 EA 201890652 A EA201890652 A EA 201890652A EA 201890652 A EA201890652 A EA 201890652A EA 201890652 A1 EA201890652 A1 EA 201890652A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- acetic acid
- methanol
- present
- carbonylation
- catalyst
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
- B01J29/24—Iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
- B01J29/66—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing iron group metals, noble metals or copper
- B01J29/67—Noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0254—Nitrogen containing compounds on mineral substrates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/30—Ion-exchange
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Dispersion Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Настоящее изобретение предлагает способ получения уксусной кислоты карбонилированием метанола, предусматривающий пропускание исходного материала, содержащего метанол, моноксид углерода и воду, через реакционную область, загруженную катализатором, содержащим кислотное молекулярное сито с адсорбированным органическим амином, и осуществление реакции в следующих условиях для получения уксусной кислоты. Способ согласно настоящему изобретению обеспечивает высокую селективность по отношению к уксусной кислоте и хорошую устойчивость катализатора. Катализатор согласно настоящему изобретению не содержит благородных металлов, таких как родий или иридий, и не нуждается в дополнительном агенте, содержащем йод, и, таким образом, не образуется йодистоводородная кислота, вызывающая сильную коррозию, и т.п.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510578383.5A CN106518657B (zh) | 2015-09-11 | 2015-09-11 | 一种通过甲醇羰基化制备乙酸的方法 |
PCT/CN2015/096649 WO2017041373A1 (zh) | 2015-09-11 | 2015-12-08 | 一种通过甲醇羰基化制备乙酸的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
EA201890652A1 true EA201890652A1 (ru) | 2018-10-31 |
EA035965B1 EA035965B1 (ru) | 2020-09-07 |
Family
ID=58240529
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201890652A EA035965B1 (ru) | 2015-09-11 | 2015-12-08 | Способ получения уксусной кислоты карбонилированием метанола |
Country Status (8)
Country | Link |
---|---|
US (1) | US10370318B2 (ru) |
EP (1) | EP3330248B1 (ru) |
JP (1) | JP6615324B2 (ru) |
CN (1) | CN106518657B (ru) |
BR (1) | BR112018004736B1 (ru) |
EA (1) | EA035965B1 (ru) |
WO (1) | WO2017041373A1 (ru) |
ZA (1) | ZA201801832B (ru) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107552085B (zh) * | 2017-08-24 | 2020-07-10 | 中国烟草总公司郑州烟草研究院 | 一种碳改性分子筛催化剂及其制备方法和应用 |
WO2020008506A1 (ja) * | 2018-07-02 | 2020-01-09 | 株式会社ダイセル | 酢酸の製造方法 |
CN109908947B (zh) * | 2019-03-14 | 2021-03-30 | 厦门大学 | 一种合成气高选择性转化制乙酸的催化剂及其应用 |
CN111822041B (zh) * | 2019-04-15 | 2021-11-09 | 中国科学院大连化学物理研究所 | 一种复合催化剂、其制备方法及其应用 |
CN115536040B (zh) * | 2022-09-27 | 2023-08-15 | 厦门大学 | 一种纳米荷叶状富铝型丝光沸石分子筛及合成方法和应用 |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4123446A (en) * | 1977-04-11 | 1978-10-31 | Allied Chemical Corporation | Synthesis of metal alkyl carbonates |
US4300011A (en) * | 1980-04-28 | 1981-11-10 | Mobil Oil Corporation | Selective production of aromatics |
GB9223170D0 (en) * | 1992-11-05 | 1992-12-16 | British Petroleum Co Plc | Process for preparing carboxylic acids |
JP4410481B2 (ja) * | 2003-04-18 | 2010-02-03 | 三菱重工業株式会社 | 酢酸の製造方法、及び酢酸の製造装置 |
US6846951B1 (en) * | 2003-10-09 | 2005-01-25 | Acetex (Cyprus) Limited | Integrated process for acetic acid and methanol |
US7767848B2 (en) * | 2005-02-08 | 2010-08-03 | Celanese International Corporation | Method of controlling acetic acid process |
GB0607395D0 (en) * | 2006-04-12 | 2006-05-24 | Bp Chem Int Ltd | Process |
GB0607394D0 (en) * | 2006-04-12 | 2006-05-24 | Bp Chem Int Ltd | Process |
EP2072491A1 (en) * | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of alcohol(s) into alcohol(s) with increased carbon-chain |
EP2072492A1 (en) * | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of hydrocarbons to ethanol |
EP2085375A1 (en) * | 2007-12-20 | 2009-08-05 | BP Chemicals Limited | Process for the production of acetic acid and/or methyl acetate in the presence of a zeolite of structure type MOR |
CN101613274B (zh) * | 2008-06-25 | 2012-12-05 | 中国科学院大连化学物理研究所 | 一种二甲醚羰基化制备乙酸甲酯的方法 |
EP2174713A1 (en) * | 2008-10-13 | 2010-04-14 | BP Chemicals Limited | Dealumination process |
EP2189215A1 (en) * | 2008-11-19 | 2010-05-26 | BP Chemicals Limited | Carbonylation process catalysed by mordenite supported on inorganic oxides |
EP2198963A1 (en) * | 2008-12-10 | 2010-06-23 | BP Chemicals Limited | Bound mordenite zeolite carbonylation catalyst |
EP2251314A1 (en) * | 2009-05-14 | 2010-11-17 | BP Chemicals Limited | Carbonylation process |
EP2251083A1 (en) * | 2009-05-14 | 2010-11-17 | BP Chemicals Limited | Carbonylation catalyst and process |
EP2251082A1 (en) * | 2009-05-14 | 2010-11-17 | BP Chemicals Limited | Carbonylation catalyst and process |
TW201235099A (en) * | 2011-01-27 | 2012-09-01 | Bp Chem Int Ltd | Process |
CN102847550B (zh) * | 2012-09-17 | 2014-11-05 | 浙江大学 | 一种甲醇羰基化制乙酸和乙酸甲酯的催化剂及其制备方法 |
EP2940000B1 (en) * | 2012-12-25 | 2017-10-18 | Dalian Institute Of Chemical Physics, Chinese Academy of Sciences | Process for preparing methyl acetate |
CN103896769B (zh) * | 2012-12-25 | 2016-01-06 | 中国科学院大连化学物理研究所 | 一种二甲醚羰基化制备乙酸甲酯的方法 |
CN103896768B (zh) * | 2012-12-25 | 2016-03-09 | 中国科学院大连化学物理研究所 | 一种制备乙酸甲酯的方法 |
CN103896766B (zh) * | 2012-12-25 | 2015-12-09 | 中国科学院大连化学物理研究所 | 一种生产乙酸甲酯的方法 |
US9387469B2 (en) * | 2013-12-30 | 2016-07-12 | Eastman Chemical Company | Carbonylation catalyst and process using same |
-
2015
- 2015-09-11 CN CN201510578383.5A patent/CN106518657B/zh active Active
- 2015-12-08 JP JP2018512544A patent/JP6615324B2/ja not_active Expired - Fee Related
- 2015-12-08 US US15/758,572 patent/US10370318B2/en not_active Expired - Fee Related
- 2015-12-08 EA EA201890652A patent/EA035965B1/ru not_active IP Right Cessation
- 2015-12-08 WO PCT/CN2015/096649 patent/WO2017041373A1/zh active Application Filing
- 2015-12-08 EP EP15903476.8A patent/EP3330248B1/en not_active Not-in-force
- 2015-12-08 BR BR112018004736-8A patent/BR112018004736B1/pt not_active IP Right Cessation
-
2018
- 2018-03-19 ZA ZA2018/01832A patent/ZA201801832B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP3330248A1 (en) | 2018-06-06 |
JP2018526406A (ja) | 2018-09-13 |
CN106518657B (zh) | 2019-03-29 |
US10370318B2 (en) | 2019-08-06 |
EP3330248A4 (en) | 2018-08-08 |
EP3330248B1 (en) | 2019-08-28 |
EA035965B1 (ru) | 2020-09-07 |
JP6615324B2 (ja) | 2019-12-04 |
CN106518657A (zh) | 2017-03-22 |
BR112018004736B1 (pt) | 2022-04-19 |
US20180244599A1 (en) | 2018-08-30 |
ZA201801832B (en) | 2019-07-31 |
WO2017041373A1 (zh) | 2017-03-16 |
BR112018004736A2 (pt) | 2019-11-12 |
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MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
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