EA201391305A1 - Активированный катализатор реакции синтеза фишера-тропша и способ производства углеводородов - Google Patents

Активированный катализатор реакции синтеза фишера-тропша и способ производства углеводородов

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Publication number
EA201391305A1
EA201391305A1 EA201391305A EA201391305A EA201391305A1 EA 201391305 A1 EA201391305 A1 EA 201391305A1 EA 201391305 A EA201391305 A EA 201391305A EA 201391305 A EA201391305 A EA 201391305A EA 201391305 A1 EA201391305 A1 EA 201391305A1
Authority
EA
Eurasian Patent Office
Prior art keywords
catalyst
synthesis reaction
tripsha
fisher
hydrocarbon production
Prior art date
Application number
EA201391305A
Other languages
English (en)
Other versions
EA027378B1 (ru
Inventor
Йосиюки Нагаясу
Хидеки Оно
Казуаки Хаясака
Маюми Йокои
Original Assignee
Джэпэн Ойл, Гэз Энд Металз Нэшнл Корпорейшн
Инпекс Корпорейшн
ДжейЭкс НИППОН ОЙЛ ЭНД ЭНЕРДЖИ КОРПОРЕЙШН
Джапан Петролеум Эксплорейшн Ко., Лтд.
Космо Ойл Ко., Лтд.
Ниппон Стил Энд Сумикин Инджиниринг Ко., Лтд.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Джэпэн Ойл, Гэз Энд Металз Нэшнл Корпорейшн, Инпекс Корпорейшн, ДжейЭкс НИППОН ОЙЛ ЭНД ЭНЕРДЖИ КОРПОРЕЙШН, Джапан Петролеум Эксплорейшн Ко., Лтд., Космо Ойл Ко., Лтд., Ниппон Стил Энд Сумикин Инджиниринг Ко., Лтд. filed Critical Джэпэн Ойл, Гэз Энд Металз Нэшнл Корпорейшн
Publication of EA201391305A1 publication Critical patent/EA201391305A1/ru
Publication of EA027378B1 publication Critical patent/EA027378B1/ru

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Катализатор реакции синтеза Фишера-Тропша включает носитель катализатора, содержащий кремнезем, и оксид циркония в количестве от 0,5 до 14 мас.% в расчете на массу носителя катализатора, и металлический кобальт и оксид кобальта, нанесенные на носитель катализатора в количестве, эквивалентном от 10 до 40 мас.% тетроксида трикобальта в расчете на массу катализатора, в котором степень восстановления атомов кобальта находится в интервале от 75 до 93% и количество адсорбируемого газообразного водорода на единицу массы катализатора при 100°С находится в интервале от 0,40 до 1,0 мл/г.
EA201391305A 2011-03-31 2012-03-14 Активированный катализатор реакции синтеза фишера-тропша и способ производства углеводородов EA027378B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011079049A JP5795483B2 (ja) 2011-03-31 2011-03-31 活性化されたフィッシャー・トロプシュ合成反応用触媒および炭化水素の製造方法
PCT/JP2012/056567 WO2012132905A1 (ja) 2011-03-31 2012-03-14 活性化されたフィッシャー・トロプシュ合成反応用触媒および炭化水素の製造方法

Publications (2)

Publication Number Publication Date
EA201391305A1 true EA201391305A1 (ru) 2014-02-28
EA027378B1 EA027378B1 (ru) 2017-07-31

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EA201391305A EA027378B1 (ru) 2011-03-31 2012-03-14 Активированный катализатор реакции синтеза фишера-тропша и способ производства углеводородов

Country Status (12)

Country Link
US (1) US9458387B2 (ru)
EP (1) EP2692431A4 (ru)
JP (1) JP5795483B2 (ru)
CN (2) CN107252687A (ru)
AP (1) AP2013007154A0 (ru)
AU (1) AU2012234817B2 (ru)
BR (1) BR112013024792A2 (ru)
CA (1) CA2830973C (ru)
EA (1) EA027378B1 (ru)
MY (1) MY165498A (ru)
WO (1) WO2012132905A1 (ru)
ZA (1) ZA201307421B (ru)

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Publication number Priority date Publication date Assignee Title
JP6007167B2 (ja) * 2013-11-18 2016-10-12 Ｊｘエネルギー株式会社 フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法
CN104162429B (zh) * 2014-08-19 2016-04-20 中国科学院山西煤炭化学研究所 一种费托合成钴基催化剂及其应用
FR3028770B1 (fr) * 2014-11-26 2016-12-02 Ifp Energies Now Procede de preparation d'un catalyseur fischer-tropsch avec traitement a la vapeur
US10066169B2 (en) * 2015-07-14 2018-09-04 Research & Business Foundation Sungkyunkwan University Mesoporous cobalt-metal oxide catalyst for Fischer-Tropsch synthesis reactions and a preparing method thereof
WO2017131231A1 (ja) * 2016-01-29 2017-08-03 Ｊｘエネルギー株式会社 フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法
JP6741694B2 (ja) * 2016-01-29 2020-08-19 Ｅｎｅｏｓ株式会社 フィッシャー・トロプシュ合成用触媒、フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法

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DE3365337D1 (en) 1982-11-22 1986-09-18 Shell Int Research Process for the preparation of a fischer-tropsch catalyst, a catalyst so prepared and use of this catalyst in the preparation of hydrocarbons
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JP4808688B2 (ja) * 2006-08-25 2011-11-02 新日本製鐵株式会社 合成ガスから炭化水素を製造する触媒、触媒の製造方法、触媒の再生方法、及び合成ガスから炭化水素を製造する方法
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CN101269329A (zh) * 2008-05-19 2008-09-24 中国科学院山西煤炭化学研究所 费托合成钴基催化剂及制备方法和应用
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Also Published As

Publication number Publication date
JP5795483B2 (ja) 2015-10-14
WO2012132905A1 (ja) 2012-10-04
ZA201307421B (en) 2015-01-28
EA027378B1 (ru) 2017-07-31
AU2012234817A8 (en) 2013-11-21
JP2012213678A (ja) 2012-11-08
EP2692431A1 (en) 2014-02-05
AU2012234817B2 (en) 2015-06-11
AU2012234817A1 (en) 2013-10-31
CA2830973C (en) 2016-04-05
CN107252687A (zh) 2017-10-17
MY165498A (en) 2018-03-27
BR112013024792A2 (pt) 2016-12-20
US20140018454A1 (en) 2014-01-16
CN103459018A (zh) 2013-12-18
CA2830973A1 (en) 2012-10-04
AP2013007154A0 (en) 2013-09-30
US9458387B2 (en) 2016-10-04
EP2692431A4 (en) 2015-01-14

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Designated state(s): AM AZ BY KG MD TJ