EA201070659A1 - Способ извлечения неблагородных металлов из использованного катализатора процессов гидрогенизации - Google Patents

Способ извлечения неблагородных металлов из использованного катализатора процессов гидрогенизации

Info

Publication number
EA201070659A1
EA201070659A1 EA201070659A EA201070659A EA201070659A1 EA 201070659 A1 EA201070659 A1 EA 201070659A1 EA 201070659 A EA201070659 A EA 201070659A EA 201070659 A EA201070659 A EA 201070659A EA 201070659 A1 EA201070659 A1 EA 201070659A1
Authority
EA
Eurasian Patent Office
Prior art keywords
metal
group
group viii
metals
coke
Prior art date
Application number
EA201070659A
Other languages
English (en)
Other versions
EA017665B1 (ru
Inventor
Рахул С. Бхадури
Кристофер А. Пауэрс
Дональд Х. Мохр
Брюс Э. Рейнолдс
Хосе Гитиан Лопес
Original Assignee
ШЕВРОН Ю. Эс. Эй. ИНК.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/946,736 external-priority patent/US7658895B2/en
Priority claimed from US12/003,218 external-priority patent/US7737068B2/en
Priority claimed from US12/004,032 external-priority patent/US7790646B2/en
Application filed by ШЕВРОН Ю. Эс. Эй. ИНК. filed Critical ШЕВРОН Ю. Эс. Эй. ИНК.
Publication of EA201070659A1 publication Critical patent/EA201070659A1/ru
Publication of EA017665B1 publication Critical patent/EA017665B1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/68—Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00—Obtaining refractory metals
    • C22B34/20—Obtaining niobium, tantalum or vanadium
    • C22B34/22—Obtaining vanadium
    • C22B34/225—Obtaining vanadium from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00—Obtaining refractory metals
    • C22B34/30—Obtaining chromium, molybdenum or tungsten
    • C22B34/34—Obtaining molybdenum
    • C22B34/345—Obtaining molybdenum from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Раскрывается способ извлечения металлов из отработанного диспергированного катализатора, происходящего из сульфида металла группы VIB, содержащего, по меньшей мере, металл группы VB и группы VIII, предназначенного для гидрогенизации нефтяного масла. В одном из вариантов осуществления этот способ включает следующие стадии: пиролиз потока, содержащего отработанный диспергированный катализатор, суспендированный в тяжелой нефти, для получения одного или более легкого углеводородного продукта и коксообразного материала; приведение потока, содержащего отработанный диспергированный катализатор, в контакт с выщелачивающим раствором, содержащим аммиак и воздух, для растворения металла группы VIB и металла группы VIII в выщелачивающем растворе при достаточной температуре и давлении; получение выщелачиванием под давлением суспензии, содержащей, по меньшей мере, растворимое комплексное соединение металла группы VIB, по меньшей мере, растворимое комплексное соединение металла группы VIII, сульфат аммония и твердый остаток, содержащий, по меньшей мере, комплексное соединение металла группы VB и кокс; отделение и удаление твердого остатка, содержащего метаванадат аммония и кокс, из раствора, полученного выщелачиванием под давлением (PLS); осаждение из PLS по меньшей мере части металла группы VIB и по меньшей мере части металла группы VIII путем регулирования рН в соответствии с предварительно выбранным значением рН с целью селективного осаждения в виде комплексных соединений металлов группы VIB и группы VIII.
EA201070659A 2007-11-28 2008-11-27 Способ извлечения неблагородных металлов из использованного катализатора процессов гидрогенизации EA017665B1 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US11/946,736 US7658895B2 (en) 2007-11-28 2007-11-28 Process for recovering base metals from spent hydroprocessing catalyst
US12/003,218 US7737068B2 (en) 2007-12-20 2007-12-20 Conversion of fine catalyst into coke-like material
US12/004,032 US7790646B2 (en) 2007-12-20 2007-12-20 Conversion of fine catalyst into coke-like material
PCT/US2008/085055 WO2009070778A2 (en) 2007-11-28 2008-11-27 Process for recovering base metals from used hydroprocessing catalyst

Publications (2)

Publication Number Publication Date
EA201070659A1 true EA201070659A1 (ru) 2010-12-30
EA017665B1 EA017665B1 (ru) 2013-02-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EA201070659A EA017665B1 (ru) 2007-11-28 2008-11-27 Способ извлечения неблагородных металлов из использованного катализатора процессов гидрогенизации

Country Status (10)

Country Link
EP (1) EP2334428B1 (ru)
JP (1) JP2011509165A (ru)
KR (1) KR101548029B1 (ru)
CN (1) CN101918132A (ru)
AU (1) AU2008329625B2 (ru)
BR (1) BRPI0819638A2 (ru)
CA (1) CA2706957C (ru)
EA (1) EA017665B1 (ru)
MX (1) MX2010005883A (ru)
WO (1) WO2009070778A2 (ru)

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JP5547922B2 (ja) * 2009-07-31 2014-07-16 住友化学株式会社 モリブデン及びコバルトを含有する複合酸化物の製造方法
FR2958656B1 (fr) * 2010-04-13 2012-05-11 Inst Francais Du Petrole Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape d'extraction.
WO2011042617A2 (fr) * 2009-10-08 2011-04-14 IFP Energies Nouvelles Procede d'hydroconversion de charges lourdes carbonees integrant une technologie a lit bouillonnant et une technologie en slurry
FR2958658B1 (fr) * 2010-04-13 2012-03-30 Inst Francais Du Petrole Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape de lixiviation.
FR2958657B1 (fr) * 2010-04-13 2012-05-11 Inst Francais Du Petrole Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape de cokefaction.
US8636967B2 (en) * 2010-01-21 2014-01-28 Intevep, S.A. Metal recovery from hydroconverted heavy effluent
GB2478332A (en) 2010-03-04 2011-09-07 Grimley Smith Associates Method of metals recovery from refinery residues
WO2012147097A2 (en) * 2011-04-15 2012-11-01 Aditya Birla Science & Technology Co. Ltd. A process for separation and purification of sodium sulfide
CN102795653B (zh) * 2011-05-25 2014-09-24 中国科学院过程工程研究所 一种有机硅废触体回收氧化铜和氧化锌的方法
CN102794179B (zh) * 2011-05-27 2015-04-01 中国科学院过程工程研究所 一种利用co2制甲酸酯的催化剂及制备方法
AU2012271758B2 (en) * 2011-06-14 2015-07-23 Shell Internationale Research Maatschappij B.V. Aqueous catalyst sulfiding process
DE102011109454A1 (de) * 2011-08-04 2013-02-07 Hte Aktiengesellschaft Verfahren zur Behandlung von Produktfluidströmen
US8912111B2 (en) * 2012-08-07 2014-12-16 Uop Llc Process for catalyst recovery and optional recycle in a slurry hydrocracking process
CN103740387A (zh) * 2014-01-10 2014-04-23 风卓机械科技(上海)有限公司 一种全自动生物质颗粒碳化生产线
ITUB20159304A1 (it) * 2015-12-22 2017-06-22 Eni Spa Procedimento per il trattamento di correnti di spurgo da raffineria.
ES2925285T3 (es) 2018-09-25 2022-10-14 Eni Spa Procedimiento para la hidroconversión de productos petroleros pesados con reciclaje
US20210313176A1 (en) * 2018-11-08 2021-10-07 Hewlett-Packard Development Company, L.P. Semiconductor formations
WO2020121220A1 (en) * 2018-12-11 2020-06-18 Eni S.P.A. Process for the selective recovery of transition metals from organic residues
IT201800020818A1 (it) 2018-12-21 2020-06-21 Eni Spa Procedimento di idroconversione di miscele di polimeri
TW202117027A (zh) * 2019-07-08 2021-05-01 美商雪維隆美國有限公司 自廢催化劑回收金屬
CN110614104A (zh) * 2019-07-29 2019-12-27 西安工程大学 一种高效处理污水的光催化剂的制备方法
CN110735041B (zh) * 2019-08-28 2021-03-23 广西银亿高新技术研发有限公司 一种循环催化氧化酸浸难溶金属废料的工艺方法
WO2021150552A1 (en) * 2020-01-20 2021-07-29 Chevron U.S.A. Inc. Metals recovery from spent catalyst
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Also Published As

Publication number Publication date
EP2334428A2 (en) 2011-06-22
CN101918132A (zh) 2010-12-15
EP2334428B1 (en) 2018-04-04
AU2008329625A1 (en) 2009-06-04
CA2706957C (en) 2016-07-19
WO2009070778A3 (en) 2009-09-17
WO2009070778A2 (en) 2009-06-04
JP2011509165A (ja) 2011-03-24
BRPI0819638A2 (pt) 2015-05-05
EA017665B1 (ru) 2013-02-28
KR20100101615A (ko) 2010-09-17
AU2008329625B2 (en) 2013-05-09
CA2706957A1 (en) 2009-06-04
MX2010005883A (es) 2010-06-09
KR101548029B1 (ko) 2015-08-27
EP2334428A4 (en) 2014-03-19

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