EA201070659A1 - Способ извлечения неблагородных металлов из использованного катализатора процессов гидрогенизации - Google Patents
Способ извлечения неблагородных металлов из использованного катализатора процессов гидрогенизацииInfo
- Publication number
- EA201070659A1 EA201070659A1 EA201070659A EA201070659A EA201070659A1 EA 201070659 A1 EA201070659 A1 EA 201070659A1 EA 201070659 A EA201070659 A EA 201070659A EA 201070659 A EA201070659 A EA 201070659A EA 201070659 A1 EA201070659 A1 EA 201070659A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- metal
- group
- group viii
- metals
- coke
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/68—Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/22—Obtaining vanadium
- C22B34/225—Obtaining vanadium from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/30—Obtaining chromium, molybdenum or tungsten
- C22B34/34—Obtaining molybdenum
- C22B34/345—Obtaining molybdenum from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8877—Vanadium, tantalum, niobium or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Catalysts (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Раскрывается способ извлечения металлов из отработанного диспергированного катализатора, происходящего из сульфида металла группы VIB, содержащего, по меньшей мере, металл группы VB и группы VIII, предназначенного для гидрогенизации нефтяного масла. В одном из вариантов осуществления этот способ включает следующие стадии: пиролиз потока, содержащего отработанный диспергированный катализатор, суспендированный в тяжелой нефти, для получения одного или более легкого углеводородного продукта и коксообразного материала; приведение потока, содержащего отработанный диспергированный катализатор, в контакт с выщелачивающим раствором, содержащим аммиак и воздух, для растворения металла группы VIB и металла группы VIII в выщелачивающем растворе при достаточной температуре и давлении; получение выщелачиванием под давлением суспензии, содержащей, по меньшей мере, растворимое комплексное соединение металла группы VIB, по меньшей мере, растворимое комплексное соединение металла группы VIII, сульфат аммония и твердый остаток, содержащий, по меньшей мере, комплексное соединение металла группы VB и кокс; отделение и удаление твердого остатка, содержащего метаванадат аммония и кокс, из раствора, полученного выщелачиванием под давлением (PLS); осаждение из PLS по меньшей мере части металла группы VIB и по меньшей мере части металла группы VIII путем регулирования рН в соответствии с предварительно выбранным значением рН с целью селективного осаждения в виде комплексных соединений металлов группы VIB и группы VIII.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/946,736 US7658895B2 (en) | 2007-11-28 | 2007-11-28 | Process for recovering base metals from spent hydroprocessing catalyst |
US12/003,218 US7737068B2 (en) | 2007-12-20 | 2007-12-20 | Conversion of fine catalyst into coke-like material |
US12/004,032 US7790646B2 (en) | 2007-12-20 | 2007-12-20 | Conversion of fine catalyst into coke-like material |
PCT/US2008/085055 WO2009070778A2 (en) | 2007-11-28 | 2008-11-27 | Process for recovering base metals from used hydroprocessing catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
EA201070659A1 true EA201070659A1 (ru) | 2010-12-30 |
EA017665B1 EA017665B1 (ru) | 2013-02-28 |
Family
ID=40679229
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201070659A EA017665B1 (ru) | 2007-11-28 | 2008-11-27 | Способ извлечения неблагородных металлов из использованного катализатора процессов гидрогенизации |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2334428B1 (ru) |
JP (1) | JP2011509165A (ru) |
KR (1) | KR101548029B1 (ru) |
CN (1) | CN101918132A (ru) |
AU (1) | AU2008329625B2 (ru) |
BR (1) | BRPI0819638A2 (ru) |
CA (1) | CA2706957C (ru) |
EA (1) | EA017665B1 (ru) |
MX (1) | MX2010005883A (ru) |
WO (1) | WO2009070778A2 (ru) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5547922B2 (ja) * | 2009-07-31 | 2014-07-16 | 住友化学株式会社 | モリブデン及びコバルトを含有する複合酸化物の製造方法 |
FR2958656B1 (fr) * | 2010-04-13 | 2012-05-11 | Inst Francais Du Petrole | Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape d'extraction. |
WO2011042617A2 (fr) * | 2009-10-08 | 2011-04-14 | IFP Energies Nouvelles | Procede d'hydroconversion de charges lourdes carbonees integrant une technologie a lit bouillonnant et une technologie en slurry |
FR2958658B1 (fr) * | 2010-04-13 | 2012-03-30 | Inst Francais Du Petrole | Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape de lixiviation. |
FR2958657B1 (fr) * | 2010-04-13 | 2012-05-11 | Inst Francais Du Petrole | Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape de cokefaction. |
US8636967B2 (en) * | 2010-01-21 | 2014-01-28 | Intevep, S.A. | Metal recovery from hydroconverted heavy effluent |
GB2478332A (en) | 2010-03-04 | 2011-09-07 | Grimley Smith Associates | Method of metals recovery from refinery residues |
WO2012147097A2 (en) * | 2011-04-15 | 2012-11-01 | Aditya Birla Science & Technology Co. Ltd. | A process for separation and purification of sodium sulfide |
CN102795653B (zh) * | 2011-05-25 | 2014-09-24 | 中国科学院过程工程研究所 | 一种有机硅废触体回收氧化铜和氧化锌的方法 |
CN102794179B (zh) * | 2011-05-27 | 2015-04-01 | 中国科学院过程工程研究所 | 一种利用co2制甲酸酯的催化剂及制备方法 |
AU2012271758B2 (en) * | 2011-06-14 | 2015-07-23 | Shell Internationale Research Maatschappij B.V. | Aqueous catalyst sulfiding process |
DE102011109454A1 (de) * | 2011-08-04 | 2013-02-07 | Hte Aktiengesellschaft | Verfahren zur Behandlung von Produktfluidströmen |
US8912111B2 (en) * | 2012-08-07 | 2014-12-16 | Uop Llc | Process for catalyst recovery and optional recycle in a slurry hydrocracking process |
CN103740387A (zh) * | 2014-01-10 | 2014-04-23 | 风卓机械科技(上海)有限公司 | 一种全自动生物质颗粒碳化生产线 |
ITUB20159304A1 (it) * | 2015-12-22 | 2017-06-22 | Eni Spa | Procedimento per il trattamento di correnti di spurgo da raffineria. |
ES2925285T3 (es) | 2018-09-25 | 2022-10-14 | Eni Spa | Procedimiento para la hidroconversión de productos petroleros pesados con reciclaje |
US20210313176A1 (en) * | 2018-11-08 | 2021-10-07 | Hewlett-Packard Development Company, L.P. | Semiconductor formations |
WO2020121220A1 (en) * | 2018-12-11 | 2020-06-18 | Eni S.P.A. | Process for the selective recovery of transition metals from organic residues |
IT201800020818A1 (it) | 2018-12-21 | 2020-06-21 | Eni Spa | Procedimento di idroconversione di miscele di polimeri |
TW202117027A (zh) * | 2019-07-08 | 2021-05-01 | 美商雪維隆美國有限公司 | 自廢催化劑回收金屬 |
CN110614104A (zh) * | 2019-07-29 | 2019-12-27 | 西安工程大学 | 一种高效处理污水的光催化剂的制备方法 |
CN110735041B (zh) * | 2019-08-28 | 2021-03-23 | 广西银亿高新技术研发有限公司 | 一种循环催化氧化酸浸难溶金属废料的工艺方法 |
WO2021150552A1 (en) * | 2020-01-20 | 2021-07-29 | Chevron U.S.A. Inc. | Metals recovery from spent catalyst |
US11578278B2 (en) | 2020-08-01 | 2023-02-14 | Honeywell International Inc. | Renewable transportation fuel process with thermal oxidation system |
US12017984B2 (en) | 2020-08-04 | 2024-06-25 | Honeywell International Inc. | Propane/butane dehydrogenation complex with thermal oxidation system |
US11780795B2 (en) | 2020-08-04 | 2023-10-10 | Honeywell International Inc. | Cumene-phenol complex with thermal oxidation system |
US11578020B2 (en) | 2020-08-04 | 2023-02-14 | Honeywell International Inc. | Naphtha complex with thermal oxidation system |
US11492306B2 (en) | 2020-09-30 | 2022-11-08 | Honeywell International Inc. | Alkylation process with thermal oxidation system |
CN113430382B (zh) * | 2021-06-29 | 2022-09-06 | 中国科学院过程工程研究所 | 一种催化提取废旧催化剂中钒钼镍的方法 |
CN113430383B (zh) * | 2021-06-29 | 2022-09-16 | 中国科学院过程工程研究所 | 一种硫酸铵溶液浸出废旧催化剂提取钒、镍和钼的方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4500495A (en) * | 1982-09-24 | 1985-02-19 | Chevron Research Company | Recovering metals from spent hydroprocessing catalysts |
US5232577A (en) * | 1990-08-14 | 1993-08-03 | Chevron Research And Technology Company | Hydrocracking process with polycyclic aromatic dimer removal |
US7790652B2 (en) * | 2003-09-17 | 2010-09-07 | Shell Oil Company | Process and catalyst for the hydroconversion of a heavy hydrocarbon feedstock |
US20050109674A1 (en) * | 2003-11-20 | 2005-05-26 | Advanced Refining Technologies Llc | Hydroconversion catalysts and methods of making and using same |
US7485267B2 (en) * | 2005-07-29 | 2009-02-03 | Chevron U.S.A. Inc. | Process for metals recovery from spent catalyst |
-
2008
- 2008-11-27 JP JP2010536203A patent/JP2011509165A/ja active Pending
- 2008-11-27 CA CA2706957A patent/CA2706957C/en not_active Expired - Fee Related
- 2008-11-27 EA EA201070659A patent/EA017665B1/ru not_active IP Right Cessation
- 2008-11-27 AU AU2008329625A patent/AU2008329625B2/en not_active Ceased
- 2008-11-27 BR BRPI0819638 patent/BRPI0819638A2/pt not_active IP Right Cessation
- 2008-11-27 EP EP08853416.9A patent/EP2334428B1/en not_active Not-in-force
- 2008-11-27 MX MX2010005883A patent/MX2010005883A/es active IP Right Grant
- 2008-11-27 KR KR1020107014346A patent/KR101548029B1/ko active IP Right Grant
- 2008-11-27 CN CN2008801251527A patent/CN101918132A/zh active Pending
- 2008-11-27 WO PCT/US2008/085055 patent/WO2009070778A2/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
EP2334428A2 (en) | 2011-06-22 |
CN101918132A (zh) | 2010-12-15 |
EP2334428B1 (en) | 2018-04-04 |
AU2008329625A1 (en) | 2009-06-04 |
CA2706957C (en) | 2016-07-19 |
WO2009070778A3 (en) | 2009-09-17 |
WO2009070778A2 (en) | 2009-06-04 |
JP2011509165A (ja) | 2011-03-24 |
BRPI0819638A2 (pt) | 2015-05-05 |
EA017665B1 (ru) | 2013-02-28 |
KR20100101615A (ko) | 2010-09-17 |
AU2008329625B2 (en) | 2013-05-09 |
CA2706957A1 (en) | 2009-06-04 |
MX2010005883A (es) | 2010-06-09 |
KR101548029B1 (ko) | 2015-08-27 |
EP2334428A4 (en) | 2014-03-19 |
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MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
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MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
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MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
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