DK138655B - Fremgangsmåde til fremstilling af N-phosphonomethyl-glycin. - Google Patents

Fremgangsmåde til fremstilling af N-phosphonomethyl-glycin.

Info

Publication number
DK138655B
DK138655B DK188175AA DK188175A DK138655B DK 138655 B DK138655 B DK 138655B DK 188175A A DK188175A A DK 188175AA DK 188175 A DK188175 A DK 188175A DK 138655 B DK138655 B DK 138655B
Authority
DK
Denmark
Prior art keywords
phosphonomethyl
glycine
preparation
Prior art date
Application number
DK188175AA
Other languages
English (en)
Other versions
DK138655C (da
DK188175A (da
Inventor
Arnold Hershman
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of DK188175A publication Critical patent/DK188175A/da
Publication of DK138655B publication Critical patent/DK138655B/da
Application granted granted Critical
Publication of DK138655C publication Critical patent/DK138655C/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DK188175AA 1974-05-01 1975-04-30 Fremgangsmåde til fremstilling af N-phosphonomethyl-glycin. DK138655B (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/465,976 US3969398A (en) 1974-05-01 1974-05-01 Process for producing N-phosphonomethyl glycine
KR7500924A KR790000297B1 (en) 1974-05-01 1975-04-30 Process for producing n-phosphono methyl gylcine

Publications (3)

Publication Number Publication Date
DK188175A DK188175A (da) 1975-11-02
DK138655B true DK138655B (da) 1978-10-09
DK138655C DK138655C (da) 1979-02-26

Family

ID=26625851

Family Applications (1)

Application Number Title Priority Date Filing Date
DK188175AA DK138655B (da) 1974-05-01 1975-04-30 Fremgangsmåde til fremstilling af N-phosphonomethyl-glycin.

Country Status (27)

Country Link
US (1) US3969398A (da)
JP (1) JPS5330690B2 (da)
KR (1) KR790000297B1 (da)
AR (1) AR215840A1 (da)
AT (1) AT336637B (da)
BE (1) BE828599A (da)
BG (1) BG26398A3 (da)
BR (1) BR7502651A (da)
CA (1) CA1030157A (da)
CH (1) CH613210A5 (da)
CS (1) CS179938B2 (da)
DD (1) DD119241A5 (da)
DE (1) DE2519388C3 (da)
DK (1) DK138655B (da)
EG (1) EG11700A (da)
ES (1) ES437154A1 (da)
FR (1) FR2269533B1 (da)
GB (1) GB1467778A (da)
IE (1) IE41118B1 (da)
IT (1) IT1037766B (da)
MY (1) MY7800280A (da)
NL (1) NL161763C (da)
PH (1) PH12324A (da)
RO (1) RO70907A (da)
SE (1) SE427752B (da)
YU (1) YU40117B (da)
ZA (1) ZA752792B (da)

Families Citing this family (92)

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US4100275A (en) * 1975-01-27 1978-07-11 Hoffmann-La Roche Inc. Compositions having antibiotic properties
US4134972A (en) * 1976-07-21 1979-01-16 Hoffmann-La Roche Inc. Compositions having antibiotic properties
NL7713959A (nl) * 1976-12-20 1978-06-22 Monsanto Co Werkwijze voor het bereiden van n-fosfono- methylglycinezouten.
HU184168B (en) * 1979-05-11 1984-07-30 Mta Koezponti Kemiai Kutato In Process for producing n-bracket-phosphono-methyl-bracket closed-glycine
US4454043A (en) * 1980-11-17 1984-06-12 Monsanto Company Column switching procedure
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US4442041A (en) * 1982-06-30 1984-04-10 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
IL68716A (en) * 1983-05-17 1987-03-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine
US4654429A (en) * 1983-12-02 1987-03-31 Monsanto Company Process for the preparation of a glyphosate product
US4617415A (en) * 1983-12-02 1986-10-14 Monsanto Company α-Substituted N-phosphonomethyliminodiacetic acid
US4624937A (en) * 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US5874612A (en) * 1984-12-28 1999-02-23 Baysdon; Sherrol L. Process for the preparation of glyphosate and glyphosate derivatives
US5068404A (en) * 1984-12-28 1991-11-26 Monsanto Company Thermal dealkylation of N-alkyl N-phosphonomethylglycine
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4579689A (en) * 1985-02-11 1986-04-01 Monsanto Company Oxidation with coated catalyst
US4696772A (en) * 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
DE3532344A1 (de) * 1985-09-11 1987-03-19 Hoechst Ag Verfahren zur herstellung von n-phosphonomethylglycin
US4657705A (en) * 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
US4694082A (en) * 1985-09-23 1987-09-15 Monsanto Company Compound 1,4-diisopropyl-2,5-diketopiperazine
US4684483A (en) * 1985-09-23 1987-08-04 Monsanto Company Preparation of N-substituted amino acids
US4740608A (en) * 1985-10-09 1988-04-26 Monsanto Company (Phosphonomethyl)trifluoromethyl sulfonates
US4853159A (en) * 1987-10-26 1989-08-01 Monsanto Company Process for producing N-phosphonomethylglycine
US4898972A (en) * 1988-09-26 1990-02-06 Monsanto Company Process for producing N-phosphonomethylglycine
US4965403A (en) * 1988-11-07 1990-10-23 Monsanto Company Oxidation/dealkylation process
US4937376A (en) * 1989-05-25 1990-06-26 Monsanto Company Process for producing N-phosphonomethylglycine
US4952723A (en) * 1989-07-31 1990-08-28 Monsanto Company Process for producing N-phosphonomethylglycine
US5095140A (en) * 1990-06-25 1992-03-10 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5312973A (en) * 1993-03-25 1994-05-17 Finchimica S.P.A. Process for producing n-phosphono-methyl-imino-diacetic acid
GB9410524D0 (en) * 1993-06-21 1994-07-13 Zeneca Ltd Manufacture of n- phosphonomethylglycine and its salts
SI9400449A (en) * 1994-12-20 1996-06-30 Pinus D D Process for preparing N-phosphonomethyl glycin
DE19500121A1 (de) * 1995-01-04 1996-07-11 Bayer Ag Verfahren zur Herstellung von N-Phosphonomethylglycin
TW322481B (da) * 1995-03-07 1997-12-11 Sankyo Co
WO1996028391A1 (en) * 1995-03-14 1996-09-19 Monsanto Company Treatment of a formaldehyde-containing waste stream
US6365772B1 (en) * 1995-05-30 2002-04-02 Hampshire Chemical Corp. Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid
US6054608A (en) 1997-05-05 2000-04-25 Monsanto Company Method for preparing formylphosphonic acid
US6232494B1 (en) 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
AU719152B2 (en) * 1998-02-12 2000-05-04 Monsanto Technology Llc Process for making glyphosate by oxidizing N-substituted glyphosates
US6417133B1 (en) 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
ID27537A (id) 1998-03-09 2001-04-12 Monsanto Co Campuran tangki dan pra-campuran untuk program pengendalian gulma yang melibatkan pemakaian pasca-tumbuh glifosat ditambah gramisida dalam kacang kedelai yang toleran terhadap gligosat
US5942643A (en) * 1998-05-14 1999-08-24 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a low temperature catalytic carbon
US5962729A (en) * 1998-05-14 1999-10-05 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
WO2000009520A1 (en) * 1998-08-12 2000-02-24 Monsanto Company Continuous process for the preparation of n-(phosphonomethyl) iminodiacetic acid
US6118022A (en) * 1998-09-08 2000-09-12 Hampshire Chemical Corp. Synthesis of phosphonomethyliminodiacetic acid with reduced effluent
US6194604B1 (en) 1998-12-10 2001-02-27 Monsanto Company Process for producing phosphorous acid
WO2001007447A1 (de) 1999-07-23 2001-02-01 Basf Aktiengesellschaft Verfahren zur herstellung von glyphosate oder eines salzes davon
JP2003518132A (ja) * 1999-12-21 2003-06-03 モンサント テクノロジー エルエルシー 炭素支持貴金属含有触媒と組み合わせた促進助剤の液相酸化反応における使用
DE10007702A1 (de) * 2000-02-19 2001-08-23 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-(Phosphonomethyl)glycin
US6274760B1 (en) 2000-03-14 2001-08-14 Monsanto Co. Preparation of formylphosphonic acid from tertiary aminomethylphosphonic acid N-oxides
US6376708B1 (en) * 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
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US7015351B2 (en) * 2000-05-22 2006-03-21 Monsanto Technology Llc Reaction systems for making N-(phosphonomethyl) glycine compounds
US6927304B2 (en) 2000-05-22 2005-08-09 Monsanto Technology Llc De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions
CN101311183B (zh) * 2000-05-22 2011-08-31 孟山都技术有限责任公司 制备n-(膦酰基甲基)甘氨酸化合物的反应***
US6441223B1 (en) 2000-11-30 2002-08-27 Monsanto Technology Llc Method of making phosphorus-containing compounds and products thereof
WO2002095373A1 (en) 2001-05-22 2002-11-28 Monsanto Technology Llc Use of infrared spectroscopy for on-line process control and endpoint detection
DE10130136A1 (de) * 2001-06-22 2003-01-02 Basf Ag Verfahren zur Gewinnung von N-Phosphonomethylglycin
CN1729052A (zh) 2001-10-18 2006-02-01 孟山都技术公司 用于伯醇脱氢以制备羧酸盐的方法和催化剂
EP1474231B1 (en) * 2002-02-14 2015-10-21 Monsanto Technology LLC Process for oxidation of n-(phosphonomethyl)iminodiacetic acid
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
US6921834B2 (en) 2002-05-22 2005-07-26 Dow Agrosciences Llc Continuous process for preparing N-phosphonomethyl glycine
JP4202047B2 (ja) * 2002-05-24 2008-12-24 富士通株式会社 ヘッド位置制御方法及びデイスク記憶装置
AU2003247825B2 (en) * 2002-06-28 2008-04-10 Monsanto Technology Llc Use of tellurium in carbon-supported, noble metal-containing catalysts for liquid phase oxidation reactions
EP2460586A3 (en) 2003-08-14 2012-11-14 Monsanto Technology LLC Process for oxidation of N-(phosphonomethyl)iminodiacetic acid or salt thereof
DE602004011091T2 (de) * 2003-09-17 2009-01-02 Monsanto Technology Llc Verfahren zur rückgewinnung eines kristallinen produkts aus einer lösung
FR2865468B1 (fr) * 2004-01-22 2006-04-28 Ceca Sa Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.
EP3366138A1 (en) 2004-03-30 2018-08-29 Monsanto Technology LLC Methods for controlling plant pathogens using n-phosphonomethylglycine
CN100372857C (zh) * 2004-05-12 2008-03-05 江苏好收成韦恩农药化工有限公司 N-膦酰基甲基甘氨酸的生产方法
JP5129961B2 (ja) * 2004-09-06 2013-01-30 日本エンバイロケミカルズ株式会社 酸化反応触媒およびそれを用いた化合物の製法
WO2006031938A2 (en) * 2004-09-15 2006-03-23 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
AR054096A1 (es) * 2004-11-12 2007-06-06 Monsanto Technology Llc Recuperacion de metales nobles de corrientes de proceso acuosas y proceso de preparacion de n-(fosfonometil)-glicina
EP2366452A3 (en) 2005-02-17 2012-08-22 Monsanto Technology LLC Transition metal-containing catalysts and their use as oxidation catalysts
WO2006096617A2 (en) 2005-03-04 2006-09-14 Monsanto Technology Llc Mitigating necrosis in transgenic glyphosate-tolerant cotton plants treated with herbicidal glyphosate formulations
CN101427406A (zh) * 2006-02-17 2009-05-06 孟山都技术公司 含过渡金属的催化剂、其制备方法及其作为燃料电池催化剂的用途
CN100460408C (zh) * 2007-01-26 2009-02-11 捷马化工股份有限公司 资源再利用的催化氧化制备草甘膦方法
US7771494B2 (en) * 2007-01-31 2010-08-10 Monsanto Technology Llc Process for selective removal of water and impurities from N-(phosphonomethyl)glycine
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
CN101337978B (zh) * 2008-05-13 2011-06-29 浙江新安化工集团股份有限公司 一种利用富氧气体催化氧化双甘膦制取草甘膦的方法
CN101481387B (zh) * 2008-11-27 2012-02-01 浙江新安化工集团股份有限公司 一种催化氧化合成草甘膦的制备方法
CN101508701B (zh) * 2008-12-10 2012-09-05 上海泰禾(集团)有限公司 一种活性碳作催化剂氧气氧化双甘膦制备草甘膦的方法
CN104058495B (zh) 2009-05-18 2016-04-20 孟山都技术公司 含水废物流中磷有用成分和盐杂质的回收
CN101781332B (zh) * 2010-03-02 2012-10-24 广西壮族自治区化工研究院 活性炭催化空气氧化双甘膦制备草甘膦的方法
CN102241703B (zh) * 2011-05-07 2014-05-07 安徽国星生物化学有限公司 一种改进的双甘膦制备草甘膦的方法
RU2674021C9 (ru) 2012-07-17 2019-01-24 МОНСАНТО ТЕКНОЛОДЖИ ЭлЭлСи Способ синтеза n-(фосфонометил)глицина
RU2015103314A (ru) 2012-07-17 2016-09-10 Страйтмарк Холдинг Аг Способ синтеза N-фосфонометилиминодиуксусной кислоты
EP2875036A1 (en) 2012-07-17 2015-05-27 Straitmark Holding AG Method for the synthesis of aminoalkylenephosphonic acid
WO2014012990A1 (en) 2012-07-17 2014-01-23 Straitmark Holding Ag Method for the synthesis of alpha-aminoalkylenephosphonic acid
PL2875034T3 (pl) 2012-07-17 2017-12-29 Straitmark Holding Ag Sposób syntezy N-(fosfonometylo)glicyny
EP3645458A4 (en) 2017-06-26 2021-03-10 Monsanto Technology LLC PHOSPHORUS CONTROL FOR WASTE FLOWS FROM GLYPHOSATE MANUFACTURING PROCESSES

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DE1217950B (de) * 1965-02-25 1966-06-02 Henkel & Cie Gmbh Verfahren zur Herstellung neuer Perhydrate von Aminoalkylphosphonsaeuren
DE2013371B1 (de) * 1970-03-20 1971-11-04 Joh A , Benckiser GmbH, Chemische Fabrik, 6700 Ludwigshafen Verfahren zur Herstellung von Amino methylenphosphonsauren
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Also Published As

Publication number Publication date
NL7505071A (nl) 1975-11-04
JPS50160222A (da) 1975-12-25
FR2269533A1 (da) 1975-11-28
NL161763C (nl) 1980-03-17
DE2519388A1 (de) 1975-11-13
JPS5330690B2 (da) 1978-08-29
BE828599A (fr) 1975-10-30
BG26398A3 (da) 1979-03-15
ES437154A1 (es) 1977-01-16
PH12324A (en) 1979-01-16
SE427752B (sv) 1983-05-02
DK138655C (da) 1979-02-26
DD119241A5 (da) 1976-04-12
YU40117B (en) 1985-08-31
AU8070175A (en) 1976-11-04
DE2519388B2 (de) 1977-07-14
IT1037766B (it) 1979-11-20
CS179938B2 (en) 1977-12-30
SE7505040L (sv) 1975-11-03
NL161763B (nl) 1979-10-15
GB1467778A (en) 1977-03-23
AR215840A1 (es) 1979-11-15
CH613210A5 (da) 1979-09-14
MY7800280A (en) 1978-12-31
YU111575A (en) 1982-06-30
RO70907A (ro) 1980-04-15
AT336637B (de) 1977-05-10
DK188175A (da) 1975-11-02
IE41118B1 (en) 1979-10-24
EG11700A (en) 1977-10-31
ATA333975A (de) 1976-09-15
ZA752792B (en) 1976-04-28
DE2519388C3 (de) 1978-03-09
IE41118L (en) 1975-11-01
BR7502651A (pt) 1976-03-16
FR2269533B1 (da) 1978-02-24
US3969398A (en) 1976-07-13
CA1030157A (en) 1978-04-25
KR790000297B1 (en) 1979-04-23

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