DE878473T1 - Styrenoxid derivate in kationisch härtende Zusammensetzungen - Google Patents

Styrenoxid derivate in kationisch härtende Zusammensetzungen

Info

Publication number
DE878473T1
DE878473T1 DE0878473T DE98107454T DE878473T1 DE 878473 T1 DE878473 T1 DE 878473T1 DE 0878473 T DE0878473 T DE 0878473T DE 98107454 T DE98107454 T DE 98107454T DE 878473 T1 DE878473 T1 DE 878473T1
Authority
DE
Germany
Prior art keywords
integer
radiation
curable compound
thermally
initiated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE0878473T
Other languages
English (en)
Other versions
DE19807454A1 (de
Inventor
Nikola A. Three Bridges New Jersey 08887 Nikolic
Rose Ann Westford Massachusetts 01886 Schultz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Starch and Chemical Investment Holding Corp
Original Assignee
National Starch and Chemical Investment Holding Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Starch and Chemical Investment Holding Corp filed Critical National Starch and Chemical Investment Holding Corp
Publication of DE878473T1 publication Critical patent/DE878473T1/de
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/12Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/28Ethers with hydroxy compounds containing oxirane rings
    • C07D303/30Ethers of oxirane-containing polyhydroxy compounds in which all hydroxyl radicals are etherified with oxirane-containing hydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/12Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/24Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D407/00Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
    • C07D407/02Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings
    • C07D407/12Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • C08G59/24Di-epoxy compounds carbocyclic
    • C08G59/245Di-epoxy compounds carbocyclic aromatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/038Macromolecular compounds which are rendered insoluble or differentially wettable

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Epoxy Resins (AREA)
  • Epoxy Compounds (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyethers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Claims (6)

:·&ggr;/ , -jD-&xgr;: I :&Egr;;&Rgr;&phgr; 818 4 7 3 107 454.5 Patentansprüche
1. Kationisch, durch Strahlung oder thermisch initiiert, aushärtbare Verbindung mit der Struktur:
Rl R3
&Pgr; oder 1
in der Q eine organische Gruppe verkörpert;
R1 bis R8 unabhängig Wasserstoff, aliphatische, alizyklische oder aromatische Gruppen verkörpern, die Heteroatome enthalten können, dadurch gekennzeichnet, daß sie die kationische Polymerisation der Epoxyfunktionalität weder durch sterische Wechselwirkung noch durch das Enthalten einer stickstoffhaltigen Lewis-Base behindern;
y eine ganze Zahl von 1 bis 5 ist, w eine ganze Zahl von 0 bis 4 ist, mit der Maßgabe, daß y + w < 5, und
&khgr; eine ganze Zahl von 1 bis 5 ist, &zgr; eine ganze Zahl von 0 bis 4 ist, mit der Maßgabe, daß &khgr; + &zgr; < 5 ist.
2. Kationisch, durch Strahlung oder thermisch initiiert, aushärtbare Verbindung mit der Struktur:
in der Q aliphatische, alizyklische oder aromatische Gruppen verkörpert, die Heteroatome enthalten können, dadurch gekennzeichnet, daß sie die kationische Polymerisation der Epoxyfunktionalität weder durch sterische Wechselwirkung noch durch die Wirkung einer Lewis-Base behindern, und
R1, R2, R4, R5, R7 und R8 unabhängig Wasserstoff, aliphatische, alizyklische oder aromatische Gruppen verkörpern, die Heteroatome enthalten können, dadurch gekennzeichnet, daß sie die kationische Polymerisation der Epoxyfunktionalität weder durch sterische Wechselwirkung noch durch die Wirkung einer Lewis-Base behindern, und
w und &zgr; unabhängig voneinander ganze Zahlen von 1 bis 5 sind.
3. Kationisch, durch Strahlung oder thermisch initiiert, aushärtbare Verbindung mit der Struktur:
rDi LQ1
L -1O1I L J>
&bull;&bull;&ggr;·:··, ·3 &£ &Lgr;&Bgr;*
in der D, Q und Z aliphatische, alizyklische oder aromatische Gruppen verkörpern, die Heteroatome enthalten können, dadurch gekennzeichnet, daß sie die kationische Polymerisation der Epoxyfunktionalität weder durch sterische Wechselwirkung noch durch die Wirkung einer Lewis-Base behindern, und
R1, R2, R3 und R7 unabhängig voneinander Wasserstoff, aliphatische, alizyklische oder aromatische Gruppen verkörpern, die Heteroatome enthalten können, dadurch gekennzeichnet, daß sie die kationische Polymerisation der Epoxyfunktionalität weder durch sterische Wechselwirkung noch durch die Wirkung einer Lewis-Base behindern, und
y eine ganze Zahl von 1 bis 5 ist, w eine ganze Zahl von
0 bis 4 ist, mit der Maßgabe, daß y + w < 5.
4. Eine Klebstoff- oder Beschichtungszusammensetzung, umfassend die, durch Strahlung oder thermisch initiiert, kationisch aushärtbare Verbindung nach Anspruch 1 und einen Photo- oder Thermo-Initiator.
5. Eine Klebstoff- oder Beschichtungszusammensetzung, umfassend die, durch Strahlung oder thermisch initiiert, kationisch aushärtbare Verbindung nach Anspruch 2 und einen Photo- oder Thermo-Initiator.
6. Eine Klebstoff- oder Beschichtungszusammensetzung, umfassend die, durch Strahlung oder thermisch initiiert, kationisch aushärtbare Verbindung nach Anspruch 3 und einen Photo- oder Thermo-Initiator.
DE0878473T 1997-05-16 1998-04-23 Styrenoxid derivate in kationisch härtende Zusammensetzungen Pending DE878473T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/857,668 US6020508A (en) 1997-05-16 1997-05-16 Radiation- or thermally-initiated cationically-curable epoxide compounds and compositions made from those compounds

Publications (1)

Publication Number Publication Date
DE878473T1 true DE878473T1 (de) 1999-05-06

Family

ID=25326487

Family Applications (1)

Application Number Title Priority Date Filing Date
DE0878473T Pending DE878473T1 (de) 1997-05-16 1998-04-23 Styrenoxid derivate in kationisch härtende Zusammensetzungen

Country Status (9)

Country Link
US (1) US6020508A (de)
EP (1) EP0878473A1 (de)
JP (3) JPH1135566A (de)
KR (1) KR100296186B1 (de)
AU (1) AU708773B2 (de)
CA (1) CA2237535A1 (de)
DE (1) DE878473T1 (de)
ES (1) ES2126544T1 (de)
MY (1) MY118149A (de)

Families Citing this family (8)

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FR2811922B1 (fr) * 2000-07-20 2003-01-10 Optoform Sarl Procedes De Prot Composition de pate chargee de poudre metallique, procede d'obtention de produits metalliques a partir de ladite composition, et produit metallique obtenu selon ledit procede
US6468595B1 (en) 2001-02-13 2002-10-22 Sigma Technologies International, Inc. Vaccum deposition of cationic polymer systems
US6656410B2 (en) 2001-06-22 2003-12-02 3D Systems, Inc. Recoating system for using high viscosity build materials in solid freeform fabrication
US6441121B1 (en) * 2001-09-28 2002-08-27 National Starch And Chemical Investment Holding Corporation Epoxy compounds containing styrenic or cinnamyl functionality
EP2585536B1 (de) * 2010-06-28 2015-04-29 Dow Global Technologies LLC Härtbare harzzusammensetzungen
MY182933A (en) * 2012-10-29 2021-02-05 Sicpa Holding Sa Protective coatings for security documents
WO2021059971A1 (ja) * 2019-09-24 2021-04-01 国立大学法人横浜国立大学 エポキシ樹脂、エポキシ樹脂硬化物及びエポキシ樹脂組成物
JPWO2021070727A1 (de) * 2019-10-09 2021-04-15

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DE1495874A1 (de) * 1962-08-14 1969-08-07 Grace W R & Co Dentalmaterial
US3455967A (en) * 1965-09-23 1969-07-15 Dow Chemical Co Synthesis of aromatic epoxides from benzylic sulfonium salts
US3506612A (en) * 1967-05-10 1970-04-14 North American Rockwell Diepoxy polyaryl monomers and polymers and method for making same
US3553162A (en) * 1969-06-27 1971-01-05 Dow Chemical Co Curable copolymers of perhaloacetone and epoxides
US4096154A (en) * 1972-06-30 1978-06-20 Ciba-Geigy Corporation Process for the manufacture of compounds containing vinyl groups
CH583668A5 (de) * 1972-06-30 1977-01-14 Ciba Geigy Ag
JPS5153600A (ja) * 1974-11-06 1976-05-12 Matsushita Electric Works Ltd Ehokishijushisoseibutsu
US4256828A (en) * 1975-09-02 1981-03-17 Minnesota Mining And Manufacturing Company Photocopolymerizable compositions based on epoxy and hydroxyl-containing organic materials
FR2508451A1 (fr) * 1981-06-26 1982-12-31 Interox Procede pour la fabrication d'epoxydes
JPS59124907A (ja) * 1983-01-06 1984-07-19 Asahi Chem Ind Co Ltd 新規なエポキシ化合物およびその製造法
JPS62500105A (ja) * 1984-09-04 1987-01-16 ヒユ−ズ・エアクラフト・カンパニ− ジフェニルヘキサフルオロプロパンの誘導体
US4731428A (en) * 1986-11-03 1988-03-15 American Cyanamid Co. Epoxidized isocyanates and process for their preparation
DE3842306A1 (de) * 1988-12-16 1990-06-21 Basf Ag Haertbare, zaehmodifizierte epoxidharze
US5118822A (en) * 1991-09-30 1992-06-02 Arco Chemical Technology, L.P. Olefin epoxidation using a perrhenate catalyst and an organic hydroperoxide
CA2086770A1 (en) * 1992-01-10 1993-07-11 Jyi-Faa Hwang Epoxy interpenetrating polymer networks having internetwork bonds
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AU700835B2 (en) * 1997-05-16 1999-01-14 National Starch And Chemical Investment Holding Corporation Reactive radiation- or thermally-initiated cationically-curable epoxide monomers and compositions made from those monomers

Also Published As

Publication number Publication date
JP2000095773A (ja) 2000-04-04
KR100296186B1 (ko) 2001-11-22
JPH1135566A (ja) 1999-02-09
JP2001064354A (ja) 2001-03-13
ES2126544T1 (es) 1999-04-01
US6020508A (en) 2000-02-01
CA2237535A1 (en) 1998-11-16
AU708773B2 (en) 1999-08-12
JP3479271B2 (ja) 2003-12-15
KR19980086660A (ko) 1998-12-05
EP0878473A1 (de) 1998-11-18
MY118149A (en) 2004-09-30
AU6193098A (en) 1998-11-19

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