DE69322865T2 - Hochtemperaturpolymerisationsverfahren zur herstellung von polyolefinen durch verwendung von ionischen katalysatoren - Google Patents

Hochtemperaturpolymerisationsverfahren zur herstellung von polyolefinen durch verwendung von ionischen katalysatoren

Info

Publication number
DE69322865T2
DE69322865T2 DE69322865T DE69322865T DE69322865T2 DE 69322865 T2 DE69322865 T2 DE 69322865T2 DE 69322865 T DE69322865 T DE 69322865T DE 69322865 T DE69322865 T DE 69322865T DE 69322865 T2 DE69322865 T2 DE 69322865T2
Authority
DE
Germany
Prior art keywords
high temperature
polymerization method
temperature polymerization
ionic catalysts
producing polyolefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69322865T
Other languages
English (en)
Other versions
DE69322865D1 (de
Inventor
Howard Turner
Jo Canich
Bernard Folie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of DE69322865D1 publication Critical patent/DE69322865D1/de
Publication of DE69322865T2 publication Critical patent/DE69322865T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69322865T 1992-06-15 1993-06-15 Hochtemperaturpolymerisationsverfahren zur herstellung von polyolefinen durch verwendung von ionischen katalysatoren Expired - Lifetime DE69322865T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US89863892A 1992-06-15 1992-06-15
PCT/US1993/005732 WO1993025590A1 (en) 1992-06-15 1993-06-15 High temperature polymerization process using ionic catalysts to produce polyolefins

Publications (2)

Publication Number Publication Date
DE69322865D1 DE69322865D1 (de) 1999-02-11
DE69322865T2 true DE69322865T2 (de) 1999-06-17

Family

ID=25409791

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69322865T Expired - Lifetime DE69322865T2 (de) 1992-06-15 1993-06-15 Hochtemperaturpolymerisationsverfahren zur herstellung von polyolefinen durch verwendung von ionischen katalysatoren

Country Status (6)

Country Link
EP (1) EP0646140B1 (de)
JP (1) JP3058690B2 (de)
CA (1) CA2117888C (de)
DE (1) DE69322865T2 (de)
ES (1) ES2126653T3 (de)
WO (1) WO1993025590A1 (de)

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US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US6313240B1 (en) * 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
JPH11501342A (ja) * 1995-03-01 1999-02-02 ミネソタ マイニング アンド マニュファクチャリング カンパニー トリス（ペンタフルオロフェニル）ボレート錯体およびそれらから誘導された触媒
US5696213A (en) * 1995-04-21 1997-12-09 Exxon Chemical Patents Inc. Ethylene-α-olefin-diolefin elastomers solution polymerization process
EP0868440B1 (de) * 1995-10-14 2001-12-12 Basell Polyolefine GmbH Verfahren zur herstellung von ethylen-copolymerisaten unter hochdruck
CN1113900C (zh) 1996-06-17 2003-07-09 埃克森美孚化学专利公司 用于烯烃聚合的混合过渡金属催化剂体系及用其聚合烯属不饱和单体的方法
ES2151279T3 (es) * 1996-06-17 2000-12-16 Exxon Chemical Patents Inc Procesos de polimerizacion a presion elevada con sistemas de catalizadores de metales de transicion retardada
US6812184B1 (en) 1996-06-17 2004-11-02 Exxonmobil Chemical Patents Inc. Supported late transition metal catalyst systems
DE19719517A1 (de) 1997-05-09 1998-11-12 Basf Ag Katalysatorlösung zur Polymerisation von alpha-Olefinen
DE19737306A1 (de) 1997-08-27 1999-03-04 Basf Ag Katalysatorzubereitung für die (Co)polymerisation von Alk-l-enen
CA2228802C (en) * 1998-02-04 2006-04-25 Stephen John Brown Solution polymerization of ethylene
KR100581789B1 (ko) 1998-07-01 2006-05-23 엑손모빌 케미칼 패턴츠 인코포레이티드 프로필렌의 결정성 중합체 및 결정화가능한 중합체를포함하는 탄성 블렌드 조성물
KR100714508B1 (ko) * 1999-12-10 2007-05-07 다우 글로벌 테크놀로지스 인크. 치환된 4족 금속 착체, 촉매 및 올레핀 중합 방법
EP1253158A1 (de) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituierte Gruppe 4-Metallkomplexe, Katalysatoren und Verfahren zur Olefinpolymerisation
US6727361B2 (en) 2000-11-07 2004-04-27 Symyx Technologies, Inc. Phosphino substituted pyridine amine ligands
DE60238049D1 (de) 2001-04-12 2010-12-02 Exxonmobil Chem Patents Inc Verfahren zur Polymerisation von Propylen und Ethylen in Lösung
US6943215B2 (en) 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
US7795365B2 (en) 2002-10-02 2010-09-14 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers
ATE402222T1 (de) 2002-10-17 2008-08-15 Dow Global Technologies Inc Hochgefüllte polymerzusammensetzungen
CN101831022B (zh) 2003-08-19 2012-07-04 陶氏环球技术有限责任公司 适用于热熔粘合剂的共聚体及其制备方法
CN102936304B (zh) 2004-03-24 2014-10-22 埃克森美孚化学专利公司 乙烯共聚体及其生产方法、含有乙烯共聚体的组合物和电装置
US7528222B1 (en) 2008-01-15 2009-05-05 Exxonmobil Chemical Patents Inc. Olefin polymerization process
WO2010114028A1 (ja) 2009-03-31 2010-10-07 日本ポリエチレン株式会社 太陽電池封止材用樹脂組成物、太陽電池封止材及びそれを用いた太陽電池モジュール
WO2012002264A1 (ja) 2010-06-28 2012-01-05 日本ポリエチレン株式会社 太陽電池封止材、及びそれを用いた太陽電池モジュール
WO2012036063A1 (ja) 2010-09-14 2012-03-22 日本ポリプロ株式会社 プロピレン系樹脂多層シートおよびそれを用いた加熱処理用包装体
EP2617765B1 (de) 2010-09-17 2014-11-05 Japan Polypropylene Corporation Propylenharzfolie und verpackungskörper zur wärmebehandlung damit
US10759880B2 (en) 2015-12-21 2020-09-01 Borealis Ag Process for recovering hydrocarbons in a solution polymerisation process
CN108473605B (zh) 2015-12-21 2021-03-26 博里利斯股份公司 用于聚合物的在线共混的方法和装置
KR101637234B1 (ko) * 2015-12-28 2016-08-02 주식회사 오프리스 보관 및 휴대가 용이한 신체착용식 의자장치
WO2019002137A1 (en) 2017-06-29 2019-01-03 Borealis Ag METHOD FOR REDUCING POLYMER DRIVE IN THE LOW POLYMER LIQUID PHASE IN A SEPARATOR
KR102340279B1 (ko) 2017-12-04 2021-12-17 보레알리스 아게 용액중합공정에서 올레핀을 회수하는 방법
BR112020005317A2 (pt) 2017-12-04 2020-09-24 Borealis Ag método para a recuperação de olefinas em um processo de polimerização em solução
EP3737704A1 (de) 2018-01-10 2020-11-18 Borealis AG Phasenstabilisierter ethylen-alpha-olefin-copolymerisierungsprozess
KR102633308B1 (ko) 2019-01-28 2024-02-06 보레알리스 아게 중합체 조성물
US20220089802A1 (en) 2019-01-28 2022-03-24 Borealis Ag Process for producing a polymer composition
WO2020178010A1 (en) 2019-03-04 2020-09-10 Borealis Ag Polymerization process
WO2021004684A1 (en) 2019-07-08 2021-01-14 Borealis Ag Polymerization process
CN115803391A (zh) 2020-07-13 2023-03-14 博里利斯股份公司 粘合剂聚乙烯组合物
KR20230038238A (ko) 2020-07-13 2023-03-17 보레알리스 아게 접착성 폴리에틸렌 조성물
EP3954448A1 (de) 2020-08-13 2022-02-16 Borealis AG Siebanordnung und verfahren zum sieben von polymer aus einem abgasstrom bei reduzierten niveaus von polymermitnahme
EP3954716B1 (de) 2020-08-13 2024-01-03 Borealis AG Siebanordnung und verfahren zum sieben von polymer aus einem abgasstrom bei reduzierten niveaus von polymermitnahme
EP4000723A1 (de) 2020-11-20 2022-05-25 Borealis AG Vorrichtung und verfahren zur herstellung eines zulaufstroms zur lösungspolymerisierung
US20240002552A1 (en) 2020-12-08 2024-01-04 Borealis Ag Polymerization Process and Arrangement

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0260999A1 (de) * 1986-09-19 1988-03-23 Exxon Chemical Patents Inc. Polymerisation von Ethylen bei hoher Temperatur und hohem Druck
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers

Also Published As

Publication number Publication date
JP3058690B2 (ja) 2000-07-04
WO1993025590A1 (en) 1993-12-23
CA2117888A1 (en) 1993-12-23
JPH07508545A (ja) 1995-09-21
EP0646140A1 (de) 1995-04-05
CA2117888C (en) 2001-05-15
DE69322865D1 (de) 1999-02-11
EP0646140B1 (de) 1998-12-30
ES2126653T3 (es) 1999-04-01

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