DE60109704D1 - Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator - Google Patents

Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator

Info

Publication number
DE60109704D1
DE60109704D1 DE60109704T DE60109704T DE60109704D1 DE 60109704 D1 DE60109704 D1 DE 60109704D1 DE 60109704 T DE60109704 T DE 60109704T DE 60109704 T DE60109704 T DE 60109704T DE 60109704 D1 DE60109704 D1 DE 60109704D1
Authority
DE
Germany
Prior art keywords
alkali metal
olefins
oxidation
catalyst containing
containing silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60109704T
Other languages
English (en)
Inventor
Katsumi Nakashiro
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2000324898A external-priority patent/JP3861585B2/ja
Priority claimed from JP2000324899A external-priority patent/JP3823716B2/ja
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Application granted granted Critical
Publication of DE60109704D1 publication Critical patent/DE60109704D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0203Impregnation the impregnation liquid containing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/086Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE60109704T 2000-10-25 2001-10-24 Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator Expired - Lifetime DE60109704D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2000324898A JP3861585B2 (ja) 2000-10-25 2000-10-25 酸化エチレン製造用触媒の製造方法及び該製法により得られた触媒
JP2000324899A JP3823716B2 (ja) 2000-10-25 2000-10-25 エチレンから酸化エチレンを製造するための触媒の製造方法

Publications (1)

Publication Number Publication Date
DE60109704D1 true DE60109704D1 (de) 2005-05-04

Family

ID=26602706

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60109704T Expired - Lifetime DE60109704D1 (de) 2000-10-25 2001-10-24 Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator

Country Status (4)

Country Link
US (1) US6498122B2 (de)
EP (1) EP1201301B1 (de)
AT (1) ATE291962T1 (de)
DE (1) DE60109704D1 (de)

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US20030165877A1 (en) * 1999-09-24 2003-09-04 Serge Muyldermans Recombinant phages capable of entering host cells via specific interaction with an artificial receptor
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AU2003217756B2 (en) * 2002-02-25 2008-11-20 Shell Internationale Research Maatschappij B.V. Supported silver catalyst and an epoxidation process using the catalyst
US20040002422A1 (en) * 2002-06-27 2004-01-01 Conoco Inc. Method for large-scale production of combustion deposited metal-metal oxide catalysts
CN100512966C (zh) * 2002-06-28 2009-07-15 国际壳牌研究有限公司 提高催化剂选择性的方法和烯烃环氧化方法
US7319156B2 (en) 2003-03-25 2008-01-15 Sumitomo Chemical Company, Limited Process for producing olefin oxide
BRPI0410090A (pt) 2003-05-07 2006-05-16 Shell Int Research catalisadores contendo prata, a fabricação de tais catalisadores contendo prata e o seu uso
US20040225138A1 (en) 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
US20040224841A1 (en) 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
US8148555B2 (en) * 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
RU2007115405A (ru) 2004-09-24 2008-10-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ выбора формированных частиц, способ сборки системы, способ реагирования газообразного сырья в такой системе, компьютерный программный продукт и компьютерная система
EP1819467A4 (de) * 2004-10-14 2010-01-20 Tokusen U S A Inc Verfahren zur herstellung hochreiner silberteilchen
BRPI0611676B1 (pt) 2005-06-07 2015-08-11 Shell Int Research Catalisador, processo para a preparação do catalisador, e processo para a produção de um óxido de olefina, um 1,2- diol, e um 1,2-diol éter e uma alcanolamina
KR101072239B1 (ko) * 2005-06-07 2011-10-12 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 촉매 캐리어
CA2641225A1 (en) * 2006-02-03 2007-08-16 Shell Internationale Research Maatschappij B.V. A process for treating a catalyst, the catalyst, and use of the catalyst
US7553795B2 (en) 2006-03-21 2009-06-30 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Activation of high selectivity ethylene oxide catalyst
WO2008036176A1 (en) 2006-09-21 2008-03-27 Tokusen U.S.A., Inc. Low temperature process for producing nano-sized titanium dioxide particles
US7932408B2 (en) * 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
US7977274B2 (en) 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
JP5542659B2 (ja) 2007-05-09 2014-07-09 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エポキシ化触媒、触媒を調製する方法、および酸化オレフィン、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートまたはアルカノールアミンの製造方法
JP5868703B2 (ja) 2008-05-07 2016-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー オレフィンオキシド、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートまたはアルカノールアミンの製造方法
WO2009137427A2 (en) * 2008-05-07 2009-11-12 Shell Oil Company A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
RU2506124C2 (ru) 2008-05-15 2014-02-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения алкиленкарбоната и/или алкиленгликоля
US8273912B2 (en) 2008-05-15 2012-09-25 Shell Oil Company Process for the preparation of an alkylene carbonate and an alkylene glycol
JP5574761B2 (ja) * 2009-04-17 2014-08-20 国立大学法人山形大学 被覆銀超微粒子とその製造方法
CN102527384B (zh) * 2010-12-29 2014-04-30 中国石油化工股份有限公司 生产环氧乙烷用银催化剂的制备方法、由此制备的银催化剂及其应用
JP6241908B2 (ja) * 2011-02-04 2017-12-06 国立大学法人山形大学 被覆金属微粒子とその製造方法
CN105618047B (zh) * 2014-11-03 2019-05-31 中国石油化工股份有限公司 一种制备环氧化用银催化剂的方法及其应用
CN105618048B (zh) * 2014-11-03 2018-11-02 中国石油化工股份有限公司 烯烃环氧化催化剂的制备方法、催化剂及其应用
PL3548471T3 (pl) 2016-12-02 2021-10-25 Shell Internationale Research Maatschappij B.V. Sposoby kondycjonowania katalizatora epoksydowania etylenu oraz powiązane sposoby wytwarzania tlenku etylenu

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US3702259A (en) 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
JPS57107240A (en) 1980-12-26 1982-07-03 Nippon Shokubai Kagaku Kogyo Co Ltd Production of silver catalyst for producing ethylene oxide
US4555501A (en) 1984-05-14 1985-11-26 The Halcon Sd Group, Inc. Process for preparing silver catalysts
US4864042A (en) 1984-05-14 1989-09-05 Scientific Design Company, Inc. Process for preparing silver catalysts
EP0172565B1 (de) 1984-08-21 1991-03-13 Mitsubishi Petrochemical Co., Ltd. Silberkatalysator für die Herstellung von Ethylenoxid aus Ethylen und Verfahren zu dessen Herstellung
CA2045396A1 (en) * 1989-03-20 1990-09-21 John R. Monnier Selective epoxidation of bicyclic olefins
JP3664502B2 (ja) * 1994-10-28 2005-06-29 旭化成ケミカルズ株式会社 低級オレフィン及び単環芳香族炭化水素の製造法
US5705661A (en) * 1995-09-25 1998-01-06 Mitsubishi Chemical Corporation Catalyst for production of ethylene oxide
US6455713B1 (en) 1998-09-14 2002-09-24 Eastman Chemical Company Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene
US6646142B1 (en) * 1998-12-16 2003-11-11 Dow Global Technologies Inc. Process for the direct oxidation of olefins to olefin oxides

Also Published As

Publication number Publication date
US20020091291A1 (en) 2002-07-11
EP1201301A1 (de) 2002-05-02
ATE291962T1 (de) 2005-04-15
US6498122B2 (en) 2002-12-24
EP1201301B1 (de) 2005-03-30

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