DE2039079A1 - Adhesives in film printing - Google Patents

Adhesives in film printing

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Publication number
DE2039079A1
DE2039079A1 DE19702039079 DE2039079A DE2039079A1 DE 2039079 A1 DE2039079 A1 DE 2039079A1 DE 19702039079 DE19702039079 DE 19702039079 DE 2039079 A DE2039079 A DE 2039079A DE 2039079 A1 DE2039079 A1 DE 2039079A1
Authority
DE
Germany
Prior art keywords
weight
carbon atoms
film printing
adhesives
aliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19702039079
Other languages
German (de)
Other versions
DE2039079C3 (en
DE2039079B2 (en
Inventor
Adolf Blum
Alfred Dr Muenster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE19702039079 priority Critical patent/DE2039079C3/en
Priority claimed from DE19702039079 external-priority patent/DE2039079C3/en
Priority to FR7128259A priority patent/FR2103858A5/en
Publication of DE2039079A1 publication Critical patent/DE2039079A1/en
Publication of DE2039079B2 publication Critical patent/DE2039079B2/en
Application granted granted Critical
Publication of DE2039079C3 publication Critical patent/DE2039079C3/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • C09J129/10—Homopolymers or copolymers of unsaturated ethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J139/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Adhesives based on derivatives of such polymers
    • C09J139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/10—Homopolymers or copolymers of unsaturated ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
    • C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Badische Anilin- & Soda-Fabrik AGBadische Anilin- & Soda-Fabrik AG

Unser Zeichen: 0.Z.26 911 Rt/AR 6700 Ludwigshafen, 4.&.197OOur reference: 0.Z.26 911 Rt / AR 6700 Ludwigshafen, 4. &. 197O

Klebemittel beim FilmdruckAdhesives in film printing

Damit sich beim Filmdruck das zu bedruckende Textilgut nicht verschieben kann* klebt man es üblicherweise auf der Textilbahnunterlage an. Es ist bekannt, als Klebemittel hierfür die verschiedensten wasserlöslichen Celluloseleime und Gummisorten sowie abgebaute und verätherte Stärke zu verwenden. Aus der deutschen Patentschrift 1 240 812 ist es außerdem bekannt, Polymerisate mit K-Werten zwischen 30 und 70 aus 0 bis 1OQ Mol/· N-Yinyllactam und 100 bis 0 Mol?i Vinylmethylather als Klebemittel beim Filmdruck zu verwenden. Diese Polymerisate haben gegenüber den erstgenannten Mitteln eine Reihe von Vorteilen; alle bisher gebräuchlichen Mittel müssen aber in verhältnismäßig großen Mengen angewendet werden, damit eine ausreichende Verklebung gewährleistet ^ist: in der deutschen Patentschrift 1 240 812 werden 25 $ige wäßrige lösungen der dort angegebenen Polymerisate empfohlen; in' der Praxis hat sich gezeigt, daß man die Konzentration an Polymerisaten bis auf ungefähr 18 f», aber nicht weiter verringern kann.So that the textile material to be printed cannot shift during film printing * it is usually glued to the textile web base. It is known to use a wide variety of water-soluble cellulose glues and types of rubber, as well as degraded and etherified starch, as adhesives for this purpose. From the German patent specification 1 240 812 it is also known to use polymers with K values between 30 and 70 composed of 0 to 10Q mol / · N-yinyllactam and 100 to 0 mol / l vinyl methyl ether as adhesives in film printing. These polymers have a number of advantages over the first-mentioned agents; However, all the agents used up to now must be used in relatively large quantities in order to ensure adequate bonding: German Patent 1,240,812 recommends 25% aqueous solutions of the polymers specified there; In practice it has been shown that the concentration of polymers can be reduced to about 18%, but not further.

Es wurden nun neue Stoffmischungen gefunden, die sich gegenüber den oben genannten Mitteln durch eine überlegene Klebwirkung auszeichnen. Die erfindungsgemäßen Stoffmischungen enthalten New mixtures of substances have now been found which are distinguished by a superior adhesive effect compared to the above-mentioned agents. The mixtures of substances according to the invention contain

a) wenigsten ein Polymerisat mit einem K-Wert zwischen 30 und 70 ausa) at least one polymer with one K value between 30 and 70

0 bis 100 Gew.i> N-Vinylcaprolactam, 100 bis 0 Gew.^ Vinylmethyläther und0 to 100 wt. I> N-vinylcaprolactam, 100 to 0 wt. ^ Vinyl methyl ether and

0 bis 5 Gew»?i eines vernetzenden Monomeren und0 to 5 percent by weight of a crosslinking monomer and

b) wenigstens ein Alkali- oder Ammoniumsalz eines Copolymerisate aus ' - b) at least one alkali or ammonium salt of a copolymer from '-

40 bis 60 Gew.i* eines oder mehrerer Acrylsäureester von40 to 60 wt. I * of one or more acrylic acid esters of

aliphatischen Alkoholen mit 1 bis 10 Kohlenstoffatomen, aliphatic alcohols with 1 to 10 carbon atoms,

20 bis 30 Gew.i» einer Qo,ß-ungesättigten aliphatischen Mono-20 to 30 wt. I »of a Qo, ß-unsaturated aliphatic mono-

58/70 1098&7/1625 "2- 58/70 1098 & 7/1625 "2 -

- 2 - O.Z. 2b 911- 2 - O.Z. 2b 911

oder Dicarbonsäure mit bis zu 6 Kohlenstoffatomen oder eines Halbesters einer solchen Dicarbonsäure mit einem aliphatischen, 1 bis 10 Kohlenstoffatome enthaltenden Alkohol, 20 bis 30 Gew./· Me thy !methacrylate 0 bis 5 Gew.ri» eines verriet senden Monomeren und 0 bis 20 Gew.^i einer oder mehrerer anderer polymerisier-or dicarboxylic acid having up to 6 carbon atoms, or a half ester of such dicarboxylic acid with an aliphatic, 1 to 10 carbon atoms-containing alcohol, 20 to 30 Gew./· Me thy! methacrylates 0 to 5 wt. r i »revealed a send monomers and from 0 to 20 wt. ^ I of one or more other polymerizing

barer äthyleiiigch ungesättigter Verbindungen im Gewichtsverhältnis s : b - 5 : 95 bis 95 : 5.free, ethylenically unsaturated compounds in the weight ratio s: b - 5:95 to 95: 5.

Unter vernetzenden Monomeren, wie sie in die Polymerisate a und bzw. oder b einpolymerisiert sein können, sind Stoffe zu verstehen, die außer einer polymerisierbar©!! C-C-Doppelblndung eine oder mehrere weitere funktioneile Gruppen entholten, die unter den Bedingungen der Polymerisation unter Vernetzung der Polymer- ■ ketten reagieren. Solche funktioneilen Gruppen sind insbesondere weitere polymerisierbare Doppelbindungen und N-Hydroxymethylgruppen. Als Beispiele für vernetzende Monomere, die solche Gruppen enthalten, seien genannt K--MethyIolamide von &,ß-ungesättigten Carbonsäuren, wie vor allem H-Methylolacryl- und -methacrylamid» Polyvinylester und -allylester von zwei- und mehrbasischen Garbonsäuren» wie Divinyladipat und Diallylphthalat, Polyester aus mehrwertigen Alkohole·1 uüd &, ^-ungesättigten Carbonsäuren» wie Butartdioldiacrylai und -dimethacrylat, Vinyl- und Allylester von g^ß-ungeaättlgten Garbonsäuren, wie Vinylacrylat, Allylacrylat und Allylmethacrylat, und andere Verbindungen mit zwei oder mehr nicht konjugierten olefinischen Doppelbindungen, wie Divinyldioxan» Divinylbenzol, Methylenbi3-acrylamici und K,N1 ».!"-Triacryloyl-hexahydro-s-triaziri.Crosslinking monomers, as they can be polymerized into the polymers a and / or b, are to be understood as meaning substances which, apart from one, are polymerizable © !! CC double bonded one or more further functional groups which react under the conditions of the polymerization with crosslinking of the polymer chains. Such functional groups are, in particular, further polymerizable double bonds and N-hydroxymethyl groups. Examples of crosslinking monomers that contain such groups are K - methylolamides of &, ß-unsaturated carboxylic acids, such as especially H-methylolacryl and methacrylamide »polyvinyl esters and allyl esters of di- and polybasic carboxylic acids» such as divinyl adipate and Diallyl phthalate, polyesters from polyhydric alcohols · 1 uüd &, ^ -unsaturated carboxylic acids »such as butartdiol diacrylate and dimethacrylate, vinyl and allyl esters of g ^ ß-unsaturated carboxylic acids, such as vinyl acrylate, allyl acrylate and allyl methacrylate, and other compounds with two or more unconjugated olefinic double bonds such as divinyldioxane »divinylbenzene, methylenebi3-acrylamici and K, N 1 ».! "- triacryloyl-hexahydro-s-triaziri.

Die vernetzenden Monomeren können z.„B. in Mengen von 0,01 bis 5 f· vorzugsweise 0,1 bis 1 i»% bezogen auf die Gesamtmenge aller Monomeren, in die Polymerisats (a) und bzw. oder (b) einpolymerisiert sein; sie bewirken vielfach eine Verbesserung der Klebkraft der erfindungsgeinäßen Mischungen, ohne in kleinen Mengen deren Löslichkeit la Wasser zu beeinträchtigen.The crosslinking monomers can, for example, · preferably 0.1 to the total amount of all monomers in the polymer (a) and or or (b) be present in amounts from 0.01 to 5 to 1 f i '% based copolymerized; they often result in an improvement in the bond strength of the erfindungsgeinäßen mixtures without impairing their solubility in small amounts la water.

Die Komponente (b) kann bis zu 20 Gew.$, bezogen auf die Gesamtmenge der Monomeren, an anderen polymeriaierbaren äthylenischThe component (b) can be up to 20% by weight, based on the total amount of monomers, ethylenically polymerizable with others

109887/1625 "3~109887/1625 " 3 ~

■ - 3 - 0.-Z..26 911■ - 3 - 0.-Z..26 911

ungesättigten Verbindungen enthalten, ohne daß ihre Eigenschaften wesentlich verändert werden. Als Beispiele für solche Verbindungen seien vor allem Amide und Nitrile &*ß-ungesättigter aliphatischer Carbonsäuren, Alkylvinylather und Vinylester gesättigter aliphatischer Carbonsäuren, und zwar besonders diejenigen mit bis zu 4 Kohlenstoffatomen im Alkyl- oder Carbonsäurerest, genannt.contain unsaturated compounds without their properties being significantly changed. As examples of such Compounds are mainly amides and nitriles & * ß-unsaturated of aliphatic carboxylic acids, alkyl vinyl ethers and saturated vinyl esters aliphatic carboxylic acids, especially those with up to 4 carbon atoms in the alkyl or carboxylic acid residue, called.

Die Copolymerisate b haben im allgemeinen einen K-Wert zwischen 60 und 130; besonders vorteilhaft sind diejenigen mit einem K-Wert zwischen 90 und 120.The copolymers b generally have a K value between 60 and 130; those with a K value are particularly advantageous between 90 and 120.

Die im folgenden beschriebenen erfindungsgemäßen Stoffmischungen haben sich hervorragend bewährtsThe mixtures of substances according to the invention described below have proven themselves excellently

1) Eine Mischung aus (a) 40 Gew.-Teilen Poly-N-vinylcaprolactam (K-Wert 60) und (b) 60 Gewichtsteilen eines mit Natriumhydroxid neutralisierten Copolymerisate aus 50 Gew.^ Äthylacrylat, 25 $ Acrylsäure und 25 Gew.^ Me thy lme tha cry la t.1) A mixture of (a) 40 parts by weight of poly-N-vinylcaprolactam (K value 60) and (b) 60 parts by weight of one with sodium hydroxide neutralized copolymers from 50 wt. ^ ethyl acrylate, 25 $ Acrylic acid and 25 wt. ^ Me thy lme tha cry la t.

2) Eine Mischung aus (a) 50 Gewichtsteilen PoIyvinylmethylather (K-Wert 50.) und (b) 50 Gewichtsteilen eines mit Natriumhydroxid neutralisierten Copolymerisate aus 22,5 Gew.^ Methylacrylat, 33,5 Gew.^ Butylacrylat, 21,0 Gew.# Acrylsäure und 23 Gew. # Me t hy lme tha cry la t.2) A mixture of (a) 50 parts by weight of polyvinyl methyl ether (K value 50.) and (b) 50 parts by weight of a copolymer of 22.5 wt. ^ Methyl acrylate neutralized with sodium hydroxide, 33.5% by weight of butyl acrylate, 21.0% by weight of acrylic acid and 23% by weight of methy lme tha cry la t.

3) Eine Mischung aus (a) 50 Gew.-Teilen PoIyvinylmethylather (K-Wert 50) und (b) 50 Gewichtsteilen eines Copolymerisate aus 17,8 Gew.^ Me thylacrylat, 37,0 Gew.^ Butylacrylat, 22,3 Gew.# Acrylsäure, 22,5 Gew.?£ Methylmethacrylat und 0,4 Gew.^ Divinyladipat. .3) A mixture of (a) 50 parts by weight of polyvinyl methyl ether (K value 50) and (b) 50 parts by weight of a copolymer of 17.8 wt. ^ Methyl acrylate, 37.0 wt. ^ Butyl acrylate, 22.3 Wt. # Acrylic acid, 22.5 wt.% Methyl methacrylate and 0.4 wt Divinyl adipate. .

Die oben angegebenen K-Werte wurden bestimmt nach H. Pitentscher, Cellulöse-Chemie V^ (1932), 58 ff und 71 ff in 0,1 #iger LösungThe K values given above were determined according to H. Pitentscher, Cellulöse-Chemie V ^ (1932), 58 ff and 71 ff in 0.1 # solution

in Wasser bei 200C; dabei bedeutet K = k.103.in water at 20 ° C .; where K = k.10 3 .

Die neuen Stoffmischungen können erfindungsgemäß mit besonderem Vorteil als Klebemittel beim Filmdruck verwendet werden. Sie werden dafür wie die für diesen Zweck bekannten Mittel als wäßrige Lösungen angewendet. Dabei genügt zur Erzielung einer bestimmten Klebwirkung von den erfindungsgemäßen StoffmischungenAccording to the invention, the new mixtures of substances can be used with particular Advantageously used as an adhesive in film printing. They are called for this as the means known for this purpose aqueous solutions applied. It is sufficient to achieve a certain adhesive effect from the mixtures of substances according to the invention

109887/1625109887/1625

- 4 - O.Z. 26 911- 4 - O.Z. 26 911

die Hälfte der Menge, die von ihren Komponenten a oder b allein erforderlich wäre: während man die Komponente a, wie oben erwähnt, in wenigstens 18 ^iger lösung anwenden muß, kann man die erfindungsgemäßen Mischungen aus den Komponenten a und b mit dem gleichen Erfolg in 9 ^iger Lösung einsetzen. Das war umso überraschender, als auch die Komponente b für sich nur in Konzentration von 18 oder mehr Prozent eine ausreichende Klebwirlcung entfaltet.half the amount that would be required of its components a or b alone: while component a, as mentioned above, must apply in at least 18 ^ solutions, one can use the Use mixtures according to the invention of components a and b with the same success in 9 ^ iger solution. That was so Surprisingly, as also the component b itself only has an adequate adhesive effect in a concentration of 18 or more percent unfolds.

Im übrigen unterscheidet sich die durch die Verwendung der genannten Polymerisatmischungen bedingte Arbeitsweise nicht von den herkömmlichen Methoden des manuellen oder maschinellen Filmdrucks, so daß auf die Erläuterung der Erfindung an Hand spezieller Ausführungsbeispiele verzichtet werden kann.Otherwise, it differs through the use of those mentioned Polymer mixtures-related mode of operation not of the conventional methods of manual or machine film printing, so that the explanation of the invention on hand is more specific Embodiments can be dispensed with.

109887/1625 "5"109887/1625 " 5 "

Claims (2)

-5 - O.Z. 25 911 Patentansprüche-5 - O.Z. 25 911 claims 1. Klebende Stoffmischung, enthaltend1. Adhesive mixture of substances containing a) wenigstens ein Polymerisat mib einem K-Wert zwischen und 70 ausa) at least one polymer with a K value between and 70 off bis 100 Gew.?i N-Vinylcaprolactam,
bis 0 Gew.# Vinylmethyläther undup to 100% by weight of N-vinylcaprolactam,
up to 0 wt. # vinyl methyl ether and bis 5 Gew.^ eines vernetzenden Monomeren
undup to 5 wt. ^ of a crosslinking monomer
and b) wenigstens ein Alkali- oder Ammoniumsalz eines Copolymerisate aus b) at least one alkali or ammonium salt of a copolymer bis 60 Gew.$ eines oder mehrerer Ac~y]säureester von aliphatischen Alkoholen mit 1 bis 10 Kohlenstoffatomen, up to 60% by weight of one or more ac ~ y] acid esters of aliphatic alcohols with 1 to 10 carbon atoms, bis 30 Gew.$ einer ^ß-ungesättigten aliphatischen Mono- oder Dicarbonsäure mit bis zu 6 Kohlenstoffatomen oder eines Halbeaters einer solchen Dicarbonsäure mit einem aliphatischen, 1 bis Kohlenstoffatome enthaltenden Alkohol,
bis 30 Gew.# Methylmethacrylat,
bis 5 Gew.^l eines vernetzenden Monomeren und
bis 20 Gew.?£ einer oder mehrerer anderer polymerisier-up to 30% by weight of a ^ ß-unsaturated aliphatic mono- or dicarboxylic acid with up to 6 carbon atoms or a hemi-ester of such a dicarboxylic acid with an aliphatic alcohol containing 1 to carbon atoms,
up to 30 wt. # methyl methacrylate,
to 5 wt. ^ l of a crosslinking monomer and
up to 20% by weight of one or more other polymerizing barer äthylenisch ungesättigter Verbindungen im Gewichtsverhältnis a : b = 5 : 95 bis 95 : 5.free ethylenically unsaturated compounds in the weight ratio a: b = 5: 95 to 95: 5. 2. Verwendung der Stoffmischung nach Anspruch 1 als Klebemittel beim Filmdruck.2. Use of the mixture of substances according to claim 1 as an adhesive in film printing. Badische Anilin- & Soda-Fabrik AGBadische Anilin- & Soda-Fabrik AG 109887/1625109887/1625
DE19702039079 1970-08-06 1970-08-06 Adhesive mixture based on polymers with a K value between 30 and 70 made of N-vinylcaprolactam and / or vinyl methyl ether and its use in film printing Expired DE2039079C3 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE19702039079 DE2039079C3 (en) 1970-08-06 Adhesive mixture based on polymers with a K value between 30 and 70 made of N-vinylcaprolactam and / or vinyl methyl ether and its use in film printing
FR7128259A FR2103858A5 (en) 1970-08-06 1971-08-02 Adhesives for textile printing - based on vinyl caprolactam vinyl methyl ether co-polymers and acrylic co-polymers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19702039079 DE2039079C3 (en) 1970-08-06 Adhesive mixture based on polymers with a K value between 30 and 70 made of N-vinylcaprolactam and / or vinyl methyl ether and its use in film printing

Publications (3)

Publication Number Publication Date
DE2039079A1 true DE2039079A1 (en) 1972-02-10
DE2039079B2 DE2039079B2 (en) 1977-06-16
DE2039079C3 DE2039079C3 (en) 1978-01-26

Family

ID=

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3642498A1 (en) * 1986-12-12 1988-06-23 Pelikan Ag ALKALINE AQUEOUS ALL-PURPOSE GLUE ON POLY (METH) ACRYLATE BASE
US5739195A (en) * 1994-09-30 1998-04-14 Basf Aktiengesellschaft Process for preparing aqueous solutions of poly(N-vinyl-ε-caprolactam) and their use
EP1229096A1 (en) * 2001-02-02 2002-08-07 Basf Aktiengesellschaft Blends of polyvinylalkylether and polyacrylate

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3642498A1 (en) * 1986-12-12 1988-06-23 Pelikan Ag ALKALINE AQUEOUS ALL-PURPOSE GLUE ON POLY (METH) ACRYLATE BASE
US5739195A (en) * 1994-09-30 1998-04-14 Basf Aktiengesellschaft Process for preparing aqueous solutions of poly(N-vinyl-ε-caprolactam) and their use
EP1229096A1 (en) * 2001-02-02 2002-08-07 Basf Aktiengesellschaft Blends of polyvinylalkylether and polyacrylate
US6734222B2 (en) 2001-02-02 2004-05-11 Basf Aktiengesellschaft Adhesives containing polyvinyl alkyl ethers

Also Published As

Publication number Publication date
FR2103858A5 (en) 1972-04-14
DE2039079B2 (en) 1977-06-16

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EHV Ceased/renunciation