DE1946225C3 - Verfahren zu der Herstellung von katalytisch wirksamen Material - Google Patents

Verfahren zu der Herstellung von katalytisch wirksamen Material

Info

Publication number: DE1946225C3
Authority: DE; Germany
Prior art keywords: solution; catalytically active; carrier; suspension; active substance
Prior art date: 1968-09-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

DE1946225A

Other languages

German (de)

English (en)

Other versions

DE1946225B2 (de

DE1946225A1 (de

Inventor

John Wilhelm Geleen Geus (Niederlande)

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Stamicarbon BV

Original Assignee

Stamicarbon BV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1968-09-16

Filing date

1969-09-12

Publication date

1978-06-15

1969-09-12 Application filed by Stamicarbon BV filed Critical Stamicarbon BV

1970-09-10 Publication of DE1946225A1 publication Critical patent/DE1946225A1/de

1977-09-29 Publication of DE1946225B2 publication Critical patent/DE1946225B2/de

1978-06-15 Application granted granted Critical

1978-06-15 Publication of DE1946225C3 publication Critical patent/DE1946225C3/de

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims description 26
238000004519 manufacturing process Methods 0.000 title description 10
239000011149 active material Substances 0.000 title description 6
239000000243 solution Substances 0.000 claims description 29
238000001556 precipitation Methods 0.000 claims description 22
239000000725 suspension Substances 0.000 claims description 18
239000012670 alkaline solution Substances 0.000 claims description 14
239000003054 catalyst Substances 0.000 claims description 14
238000003756 stirring Methods 0.000 claims description 11
239000013543 active substance Substances 0.000 claims description 10
-1 hydroxyl ions Chemical class 0.000 claims description 10
230000015572 biosynthetic process Effects 0.000 claims description 9
239000007788 liquid Substances 0.000 claims description 8
238000006243 chemical reaction Methods 0.000 claims description 6
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
239000004202 carbamide Substances 0.000 claims description 4
238000002347 injection Methods 0.000 claims description 4
239000007924 injection Substances 0.000 claims description 4
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
239000002244 precipitate Substances 0.000 claims description 3
239000007864 aqueous solution Substances 0.000 claims description 2
238000010438 heat treatment Methods 0.000 claims description 2
230000007062 hydrolysis Effects 0.000 claims description 2
238000006460 hydrolysis reaction Methods 0.000 claims description 2
229910021645 metal ion Inorganic materials 0.000 claims description 2
238000002360 preparation method Methods 0.000 claims description 2
230000002035 prolonged effect Effects 0.000 claims description 2
238000005259 measurement Methods 0.000 claims 1
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 18
239000002245 particle Substances 0.000 description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
239000012153 distilled water Substances 0.000 description 10
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 9
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 9
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
235000011114 ammonium hydroxide Nutrition 0.000 description 9
239000012876 carrier material Substances 0.000 description 9
239000000463 material Substances 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
238000002441 X-ray diffraction Methods 0.000 description 7
229910004298 SiO 2 Inorganic materials 0.000 description 6
229910021485 fumed silica Inorganic materials 0.000 description 6
239000000203 mixture Substances 0.000 description 6
238000004458 analytical method Methods 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 5
229910052759 nickel Inorganic materials 0.000 description 5
239000011701 zinc Substances 0.000 description 5
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
238000010586 diagram Methods 0.000 description 4
239000000126 substance Substances 0.000 description 4
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 3
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
238000009826 distribution Methods 0.000 description 3
239000000706 filtrate Substances 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
229910002651 NO3 Inorganic materials 0.000 description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
229940024548 aluminum oxide Drugs 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
239000001099 ammonium carbonate Substances 0.000 description 2
235000012501 ammonium carbonate Nutrition 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
230000000694 effects Effects 0.000 description 2
229960002089 ferrous chloride Drugs 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
238000011068 loading method Methods 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
230000001376 precipitating effect Effects 0.000 description 2
LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
239000012974 tin catalyst Substances 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011787 zinc oxide Substances 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229910002588 FeOOH Inorganic materials 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
229910008433 SnCU Inorganic materials 0.000 description 1
229910006404 SnO 2 Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
150000004645 aluminates Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
238000000137 annealing Methods 0.000 description 1
ZRUWFKRETRELPY-UHFFFAOYSA-N azane;nickel(2+) Chemical compound N.[Ni+2] ZRUWFKRETRELPY-UHFFFAOYSA-N 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000000635 electron micrograph Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
229910000069 nitrogen hydride Inorganic materials 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
239000000047 product Substances 0.000 description 1
238000010791 quenching Methods 0.000 description 1
230000000171 quenching effect Effects 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
238000005245 sintering Methods 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000010288 sodium nitrite Nutrition 0.000 description 1
239000007921 spray Substances 0.000 description 1
229940071182 stannate Drugs 0.000 description 1
125000005402 stannate group Chemical group 0.000 description 1
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
229910001887 tin oxide Inorganic materials 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
229940007718 zinc hydroxide Drugs 0.000 description 1
229910021511 zinc hydroxide Inorganic materials 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/392—Metal surface area

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

DE1946225A 1968-09-16 1969-09-12 Verfahren zu der Herstellung von katalytisch wirksamen Material Expired DE1946225C3 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
NL6813236.A NL159893C (nl)	1968-09-16	1968-09-16	Werkwijze voor het bereiden van katalytisch actief materiaal.

Publications (3)

Publication Number	Publication Date
DE1946225A1 DE1946225A1 (de)	1970-09-10
DE1946225B2 DE1946225B2 (de)	1977-09-29
DE1946225C3 true DE1946225C3 (de)	1978-06-15

Family

ID=19804673

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE1946225A Expired DE1946225C3 (de)	1968-09-16	1969-09-12	Verfahren zu der Herstellung von katalytisch wirksamen Material

Country Status (10)

Country	Link
JP (1)	JPS5147670B1 (es)
BE (1)	BE738866A (es)
CH (1)	CH548226A (es)
DE (1)	DE1946225C3 (es)
DK (1)	DK124516B (es)
ES (1)	ES371523A2 (es)
FR (1)	FR2018197A6 (es)
GB (1)	GB1281725A (es)
NL (1)	NL159893C (es)
SE (1)	SE408375B (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL168429C (nl) *	1970-04-18	1982-04-16	Stamicarbon	Werkwijze voor het bereiden van een dragerkatalysator en gevormde voortbrengsels, bestaande uit de aldus bereide dragerkatalysator.
WO2016126576A1 (en) *	2015-02-03	2016-08-11	Gencell Ltd.	Nickel-based catalyst for the decomposition of ammonia

1968
- 1968-09-16 NL NL6813236.A patent/NL159893C/xx not_active IP Right Cessation
1969
- 1969-09-11 GB GB44970/69A patent/GB1281725A/en not_active Expired
- 1969-09-12 DE DE1946225A patent/DE1946225C3/de not_active Expired
- 1969-09-13 ES ES371523A patent/ES371523A2/es not_active Expired
- 1969-09-15 BE BE738866D patent/BE738866A/xx unknown
- 1969-09-15 CH CH1391869A patent/CH548226A/xx not_active IP Right Cessation
- 1969-09-16 FR FR6931429A patent/FR2018197A6/fr not_active Expired
- 1969-09-16 DK DK493269AA patent/DK124516B/da not_active IP Right Cessation
- 1969-09-16 SE SE6912751A patent/SE408375B/xx unknown
- 1969-09-16 JP JP44072821A patent/JPS5147670B1/ja active Pending

Also Published As

Publication number	Publication date
NL6813236A (es)	1970-03-18
DK124516B (da)	1972-10-30
JPS5147670B1 (es)	1976-12-16
DE1946225B2 (de)	1977-09-29
CH548226A (de)	1974-04-30
NL159893C (nl)	1979-09-17
ES371523A2 (es)	1972-04-01
FR2018197A6 (es)	1970-05-29
GB1281725A (en)	1972-07-12
DE1946225A1 (de)	1970-09-10
BE738866A (es)	1970-03-16
SE408375B (sv)	1979-06-11
NL159893B (nl)	1979-04-17

Legal Events

Date	Code	Title	Description
1978-06-15	C3	Grant after two publication steps (3rd publication)
1985-11-21	8328	Change in the person/name/address of the agent	Free format text: TUERK, D., DIPL.-CHEM. DR.RER.NAT. GILLE, C., DIPL.-ING., PAT.-ANW., 4000 DUESSELDORF

Publication	Publication Date	Title
DE2748972C2 (es)	1990-05-17
DE2623977C3 (de)	1979-04-12	Verfahren und Vorrichtung zur Herstellung von rieselfähigem, direkt verpressbarem Urandioxid-Pulver
DE1767202A1 (de)	1971-03-18	Verfahren zur Herstellung eines Katalysators
DE2125625C2 (de)	1982-07-29	Verfahren zur Herstellung von Tonerde
DE3131255A1 (de)	1983-03-10	Verfahren zur herstellung eines eisen-(iii)-oxid-katalysators oder - absorptionsmittels
DE2615867C3 (de)	1979-12-20	Verfahren zur Herstellung kugeliger Tonerdeteilchen
DE2812875C2 (es)	1989-08-31
CH566809A5 (en)	1975-09-30	Metal oxide particle prodn. - for use in nuclear fuel elements
DE69209261T2 (de)	1996-10-31	Verfahren zur Herstellung eines hochdisperse Metallteilchen enthaltenden Trägerkatalysators
DE1592166B2 (de)	1973-11-22	Verfahren zur Bildung von kugel fbrmiger Tonerde
DE4319372C2 (de)	1997-11-06	Magnesiumhydroxid und Verfahren zu dessen Herstellung
DE69209625T2 (de)	1996-11-21	Verfahren zur Herstellung eines hochdisperse Metallteilchen enthaltenden Trägerkatalysators
DE1767627A1 (de)	1971-09-30	Verfahren zur Herstellung von Mikrokugeln
DE1946225C3 (de)	1978-06-15	Verfahren zu der Herstellung von katalytisch wirksamen Material
DE2945755C2 (de)	1981-12-03	Verfahren zur Herstellung kugeliger Tonerdeteilchen mit großer Dichte
DD279006A5 (de)	1990-05-23	Verfahren zur herstellung von chlor
AT300736B (de)	1972-08-10	Verfahren zur Herstellung eines Trägerkatalysators
DE2547288A1 (de)	1976-04-29	Verfahren zur herstellung von silberpulvern
DE69120782T2 (de)	1997-03-13	Verfahren zur Herstellung von gesinterten Kernbrennstofftabletten aus gefällten Lösungen mit Hilfe von Wasserstoffperoxyden in saurem Milieu
DE1963828A1 (de)	1970-10-08	Verfahren zu der Herstellung von ferromagnetischem Material
EP0736493A2 (de)	1996-10-09	Katalysierte Zersetzung von H2O2
DE1175658B (de)	1964-08-13	Verfahren zur Herstellung eines in Kern-reaktoren verwendbaren Uran(IV)-oxydsols
DE1964620C3 (de)	1980-11-13	Verfahren zur Herstellung von Katalysatoren
DE1961760A1 (de)	1970-07-09	Katalysatorherstellung
DE2027787C3 (de)	1976-08-12	Verfahren zur Herstellung eines mischgelierten Chromoxyd-Aluminiumoxyd-Katalysators in Form von kugelförmigen Teilchen