DE1127892B - Verfahren zur Herstellung von Thiophosphorsaeureestern - Google Patents

Verfahren zur Herstellung von Thiophosphorsaeureestern

Info

Publication number: DE1127892B
Authority: DE; Germany
Prior art keywords: ester; added; hour; heated; sulfur
Prior art date: 1960-05-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

DEF31173A

Other languages

German (de)

English (en)

Inventor

Dr H C Gerhard Schrader Dr

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer AG

Original Assignee

Bayer AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1960-05-06

Filing date

1960-05-06

Publication date

1962-04-19

Priority to BE603613D priority Critical patent/BE603613A/xx

Priority to NL264380D priority patent/NL264380A/xx

1960-05-06 Application filed by Bayer AG filed Critical Bayer AG

1960-05-06 Priority to DEF31173A priority patent/DE1127892B/de

1960-08-17 Priority claimed from DEF31899A external-priority patent/DE1126382B/de

1960-08-29 Priority claimed from DEF31992A external-priority patent/DE1138041B/de

1961-04-25 Priority to CH480461A priority patent/CH414597A/de

1961-05-02 Priority to GB1590661A priority patent/GB969029A/en

1961-05-03 Priority to FR860613A priority patent/FR1295613A/fr

1961-07-25 Priority to FR868902A priority patent/FR1301031A/fr

1962-04-19 Publication of DE1127892B publication Critical patent/DE1127892B/de

Status Pending legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims description 13
150000003580 thiophosphoric acid esters Chemical class 0.000 title claims description 5
238000002360 preparation method Methods 0.000 title claims description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 27
229910052717 sulfur Inorganic materials 0.000 claims description 27
239000011593 sulfur Substances 0.000 claims description 27
239000002253 acid Substances 0.000 claims description 15
229910052760 oxygen Inorganic materials 0.000 claims description 9
150000001298 alcohols Chemical class 0.000 claims description 4
150000001805 chlorine compounds Chemical class 0.000 claims description 4
150000002989 phenols Chemical class 0.000 claims description 4
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 54
150000002148 esters Chemical class 0.000 description 48
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 32
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
150000001875 compounds Chemical class 0.000 description 21
241000700159 Rattus Species 0.000 description 19
239000011541 reaction mixture Substances 0.000 description 19
230000001988 toxicity Effects 0.000 description 19
231100000419 toxicity Toxicity 0.000 description 19
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 17
241001454295 Tetranychidae Species 0.000 description 16
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 16
241001124076 Aphididae Species 0.000 description 13
241001465754 Metazoa Species 0.000 description 13
239000000203 mixture Substances 0.000 description 13
229910052757 nitrogen Inorganic materials 0.000 description 13
238000003756 stirring Methods 0.000 description 7
238000009835 boiling Methods 0.000 description 5
229910052698 phosphorus Inorganic materials 0.000 description 4
GWMWXFGQYATKBA-UHFFFAOYSA-N 4-methyl-2-sulfanylphenol Chemical compound CC1=CC=C(O)C(S)=C1 GWMWXFGQYATKBA-UHFFFAOYSA-N 0.000 description 3
206010004194 Bed bug infestation Diseases 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
241001414835 Cimicidae Species 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 3
230000003151 ovacidal effect Effects 0.000 description 3
RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
241000239290 Araneae Species 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
235000013601 eggs Nutrition 0.000 description 2
230000000749 insecticidal effect Effects 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
-1 nitroalkyl alcohols Chemical class 0.000 description 2
239000000047 product Substances 0.000 description 2
238000010626 work up procedure Methods 0.000 description 2
NUTVORGGYDQIDD-UHFFFAOYSA-N 1-ethylsulfanylethanol Chemical compound CCSC(C)O NUTVORGGYDQIDD-UHFFFAOYSA-N 0.000 description 1
LHJGJYXLEPZJPM-UHFFFAOYSA-N 2,4,5-trichlorophenol Chemical compound OC1=CC(Cl)=C(Cl)C=C1Cl LHJGJYXLEPZJPM-UHFFFAOYSA-N 0.000 description 1
HFZWRUODUSTPEG-UHFFFAOYSA-N 2,4-dichlorophenol Chemical compound OC1=CC=C(Cl)C=C1Cl HFZWRUODUSTPEG-UHFFFAOYSA-N 0.000 description 1
DKTRZBWXGOPYIX-UHFFFAOYSA-N 3-chloro-4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C(Cl)=C1 DKTRZBWXGOPYIX-UHFFFAOYSA-N 0.000 description 1
VKALYYFVKBXHTF-UHFFFAOYSA-N 4-(methylsulfanyl)-m-cresol Chemical compound CSC1=CC=C(O)C=C1C VKALYYFVKBXHTF-UHFFFAOYSA-N 0.000 description 1
VZXOZSQDJJNBRC-UHFFFAOYSA-N 4-chlorobenzenethiol Chemical compound SC1=CC=C(Cl)C=C1 VZXOZSQDJJNBRC-UHFFFAOYSA-N 0.000 description 1
WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
CVNOWLNNPYYEOH-UHFFFAOYSA-N 4-cyanophenol Chemical compound OC1=CC=C(C#N)C=C1 CVNOWLNNPYYEOH-UHFFFAOYSA-N 0.000 description 1
NIAAGQAEVGMHPM-UHFFFAOYSA-N 4-methylbenzene-1,2-dithiol Chemical compound CC1=CC=C(S)C(S)=C1 NIAAGQAEVGMHPM-UHFFFAOYSA-N 0.000 description 1
BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 description 1
XVMSFILGAMDHEY-UHFFFAOYSA-N 6-(4-aminophenyl)sulfonylpyridin-3-amine Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=N1 XVMSFILGAMDHEY-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
241000255925 Diptera Species 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
206010058667 Oral toxicity Diseases 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
241000607479 Yersinia pestis Species 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
230000004071 biological effect Effects 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
229940125904 compound 1 Drugs 0.000 description 1
229940125782 compound 2 Drugs 0.000 description 1
OYFJQPXVCSSHAI-QFPUQLAESA-N enalapril maleate Chemical compound OC(=O)\C=C/C(O)=O.C([C@@H](C(=O)OCC)N[C@@H](C)C(=O)N1[C@@H](CCC1)C(O)=O)CC1=CC=CC=C1 OYFJQPXVCSSHAI-QFPUQLAESA-N 0.000 description 1
230000032050 esterification Effects 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
231100000418 oral toxicity Toxicity 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
231100000194 ovacidal Toxicity 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000000575 pesticide Substances 0.000 description 1
PJGSXYOJTGTZAV-UHFFFAOYSA-N pinacolone Chemical compound CC(=O)C(C)(C)C PJGSXYOJTGTZAV-UHFFFAOYSA-N 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000007858 starting material Substances 0.000 description 1
125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
230000009897 systematic effect Effects 0.000 description 1

Classifications

- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F7/00—Shielded cells or rooms
- G21F7/005—Shielded passages through walls; Locks; Transferring devices between rooms
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/17—Esters of thiophosphoric acids with hydroxyalkyl compounds without further substituents on alkyl
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/18—Esters of thiophosphoric acids with hydroxyaryl compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/201—Esters of thiophosphorus acids
- C07F9/206—Esters of thiophosphorus acids containing P-halide groups

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Biochemistry (AREA)
Molecular Biology (AREA)
Engineering & Computer Science (AREA)
Physics & Mathematics (AREA)
General Engineering & Computer Science (AREA)
High Energy & Nuclear Physics (AREA)
Agronomy & Crop Science (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

DEF31173A 1960-05-06 1960-05-06 Verfahren zur Herstellung von Thiophosphorsaeureestern Pending DE1127892B (de)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
BE603613D BE603613A (es)	1960-05-06
NL264380D NL264380A (es)	1960-05-06
DEF31173A DE1127892B (de)	1960-05-06	1960-05-06	Verfahren zur Herstellung von Thiophosphorsaeureestern
CH480461A CH414597A (de)	1960-05-06	1961-04-25	Verfahren zur Herstellung von Thiophosphorsäureestern
GB1590661A GB969029A (en)	1960-05-06	1961-05-02	Thiophosphoric acid esters
FR860613A FR1295613A (fr)	1960-05-06	1961-05-03	Nouveaux esters thiophosphoriques et leur procédé de préparation
FR868902A FR1301031A (fr)	1960-05-06	1961-07-25	Dispositif étanche d'introduction et d'extraction d'éléments dangereux, en particulier d'éléments radioactifs, dans des cellules de traitement

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
DEF31173A DE1127892B (de)	1960-05-06	1960-05-06	Verfahren zur Herstellung von Thiophosphorsaeureestern
DEF31899A DE1126382B (de)	1960-08-17	1960-08-17	Verfahren zur Herstellung von Thiophosphorsaeureestern
DEF31992A DE1138041B (de)	1960-08-29	1960-08-29	Verfahren zur Herstellung von Thiophosphorsaeureestern

Publications (1)

Publication Number	Publication Date
DE1127892B true DE1127892B (de)	1962-04-19

Family

ID=27210174

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DEF31173A Pending DE1127892B (de)	1960-05-06	1960-05-06	Verfahren zur Herstellung von Thiophosphorsaeureestern

Country Status (5)

Country	Link
BE (1)	BE603613A (es)
CH (1)	CH414597A (es)
DE (1)	DE1127892B (es)
GB (1)	GB969029A (es)
NL (1)	NL264380A (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2360548C3 (de) *	1973-12-05	1981-12-17	Bayer Ag, 5090 Leverkusen	2-Cyanophenyldithiophosphorsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung als Insektizide und Akarizide

Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1023760B (de) *	1956-06-29	1958-02-06	Bayer Ag	Verfahren zur Herstellung von Nitroalkylthiophosphorsaeureestern
DE1032247B (de) *	1954-12-04	1958-06-19	Bayer Ag	Verfahren zur Herstellung von organischen Phosphorverbindungen
DE1044826B (de) *	1956-12-21	1958-11-27	Bayer Ag	Verfahren zur Herstellung von Dialkyl-thio?o-phosphorsaeureestern
DE1050761B (de) *	1956-12-21	1959-02-19	Bayer Ag	Verfahren zur Herstellung von Thionophosphorsaeureestern
DE1078117B (de) *	1958-10-18	1960-03-24	Bayer Ag	Verfahren zur Herstellung von Thiophosphorsaeureestern

0
- NL NL264380D patent/NL264380A/xx unknown
- BE BE603613D patent/BE603613A/xx unknown
1960
- 1960-05-06 DE DEF31173A patent/DE1127892B/de active Pending
1961
- 1961-04-25 CH CH480461A patent/CH414597A/de unknown
- 1961-05-02 GB GB1590661A patent/GB969029A/en not_active Expired

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1032247B (de) *	1954-12-04	1958-06-19	Bayer Ag	Verfahren zur Herstellung von organischen Phosphorverbindungen
DE1023760B (de) *	1956-06-29	1958-02-06	Bayer Ag	Verfahren zur Herstellung von Nitroalkylthiophosphorsaeureestern
DE1044826B (de) *	1956-12-21	1958-11-27	Bayer Ag	Verfahren zur Herstellung von Dialkyl-thio?o-phosphorsaeureestern
DE1050761B (de) *	1956-12-21	1959-02-19	Bayer Ag	Verfahren zur Herstellung von Thionophosphorsaeureestern
DE1078117B (de) *	1958-10-18	1960-03-24	Bayer Ag	Verfahren zur Herstellung von Thiophosphorsaeureestern

Also Published As

Publication number	Publication date
CH414597A (de)	1966-06-15
BE603613A (es)
GB969029A (en)	1964-09-09
NL264380A (es)

Publication	Publication Date	Title
DE1170401B (de)	1964-05-21	Verfahren zur Herstellung von Phosphor- bzw. Thiophosphor-(-phosphon-, -phosphin-) Saeureestern
DE1116656B (de)	1961-11-09	Verfahren zur Herstellung von Thionophosphorsaeureestern
DE1172667B (de)	1964-06-25	Verfahren zur Herstellung von O, O-Dialkyl-S-alkylthiolphosphorsaeureestern
DE1127892B (de)	1962-04-19	Verfahren zur Herstellung von Thiophosphorsaeureestern
DE1280256B (de)	1968-10-17	Neue O, O-Dialkylthionophosphorsaeureester und Verfahren zur Herstellung derselben
DE1074034B (de)	1960-01-28	Verfahren zur Herstellung von Thiophosphorsäureestern
DE1183494B (de)	1964-12-17	Verfahren zur Herstellung von Phosphor-, Phosphon- bzw. Thionophosphor-, -phosphonsaeureestern
DE1136328B (de)	1962-09-13	Verfahren zur Herstellung von Dithiolphosphorsaeureestern
DE1193036B (de)	1965-05-20	Verfahren zur Herstellung von Phosphor-, Phosphon-, Phosphin- bzw. Thiophosphor-, -phosphon-, -phosphinsaeureestern
DE1146883B (de)	1963-04-11	Verfahren zur Herstellung von Dithiophosphinsaeureestern
AT213906B (de)	1961-03-10	Verfahren zur Herstellung von neuen Thionophosphonsäureestern
AT231470B (de)	1964-01-27	Verfahren zur Herstellung neuer Organophosphorverbindungen
DE1126382B (de)	1962-03-29	Verfahren zur Herstellung von Thiophosphorsaeureestern
DE1142606B (de)	1963-01-24	Verfahren zur Herstellung von Thionophosphonsaeurethiocarbimiden
DE1056121B (de)	1959-04-30	Verfahren zur Herstellung von Thiophosphorsaeureestern
DE1493569B2 (de)	1974-03-14	Neue aromatische Phosphor- bzw. Phosphonsäureester, Verfahren zu ihrer Herstellung und solche enthaltende insektizide und akarizide Mittel
DE1146884B (de)	1963-04-11	Verfahren zur Herstellung von (Thio)Phosphonsaeureestern
DE1057112B (de)	1959-05-14	Verfahren zur Herstellung von Thionophosphonsaeureestern
DE1670592C3 (de)	1978-01-19	Pyridylthiophosphorsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung
DE1147227B (de)	1963-04-18	Verfahren zur Herstellung von Thio- bzw. Dithiophosphor-(-phosphon-, -phosphin-)saeureestern
DE1136333B (de)	1962-09-13	Verfahren zur Herstellung von Thio- bzw. Dithiophosphonsaeureesteramiden
DE1115248B (de)	1961-10-19	Verfahren zur Herstellung von Arylthionophosphinsaeure-O-alkylestern
DE1187849B (de)	1965-02-25	Insektizide Mittel
DE1145615B (de)	1963-03-21	Verfahren zur Herstellung von Trithiophosphonsaeureestern
DE1193055B (de)	1965-05-20	Verfahren zur Herstellung von Thionophosphon-saeureestern